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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(3,4-Dimethoxyphenyl)sulfanyl-2-phenyl-1-benzothiophene 1213779-95-3 C22H18O2S2
    3-(3,4-Dimethoxyphenyl)sulfanyl-2-phenyl-1-benzothiophene
    —— 4-Pyridinecarboxylic acid, 2-methyl-6-(2-thiazolylthio)- 1564663-23-5 C10H8N2O2S2
    4-Pyridinecarboxylic acid, 2-methyl-6-(2-thiazolylthio)-
    —— 2-[5-amino-2-(propylsulfanyl)-2-phenyl-4-cyano-2,3-dihydrofuran-3-ylidene]propanedinitrile 1334550-91-2 C17H14N4OS
    2-[5-amino-2-(propylsulfanyl)-2-phenyl-4-cyano-2,3-dihydrofuran-3-ylidene]propanedinitrile
    —— 6,7-Bis[(4-chlorophenyl)sulfanyl]-2,3-dihydro-1,4-benzodioxine-5,8-dione 129137-23-1 C20H12Cl2O4S2
    6,7-Bis[(4-chlorophenyl)sulfanyl]-2,3-dihydro-1,4-benzodioxine-5,8-dione
    —— 2-(2-{5'-[2-(2-Hydroxy-ethoxy)-ethyl]-5'H-[2,2']bi[[1,3]dithiolo[4,5-c]pyrrolylidene]-5-yl}-ethoxy)-ethanol 813439-49-5 C18H22N2O4S4
    2-(2-{5'-[2-(2-Hydroxy-ethoxy)-ethyl]-5'H-[2,2']bi[[1,3]dithiolo[4,5-c]pyrrolylidene]-5-yl}-ethoxy)-ethanol
    —— 2,2'-[1,4-phenylenedi(sulfanediyl)]bis(3-phenylthieno[2,3-d]pyrimidin-4(3H)-one) 1353680-83-7 C30H18N4O2S4
    2,2'-[1,4-phenylenedi(sulfanediyl)]bis(3-phenylthieno[2,3-d]pyrimidin-4(3H)-one)
    —— ethyl 2-{[5-amino-3-(dicyanomethylidene)-2-phenyl-4-cyano-2,3-dihydrofuran-2-yl]sulfanyl}acetate 1334550-93-4 C18H14N4O3S
    ethyl 2-{[5-amino-3-(dicyanomethylidene)-2-phenyl-4-cyano-2,3-dihydrofuran-2-yl]sulfanyl}acetate
    —— phenyl(2-phenyl-4,5-dihydroselenophen-3-yl)sulfane 1221975-49-0 C16H14SSe
    phenyl(2-phenyl-4,5-dihydroselenophen-3-yl)sulfane
    —— (1S,9R)-10-Oxa-4-thia-bicyclo[7.1.0]decane 4,4-dioxide 134333-89-4 C8H14O3S
    (1S,9R)-10-Oxa-4-thia-bicyclo[7.1.0]decane 4,4-dioxide
    —— 2-(methylsulfanyl)-3-methoxy-1-cyclopentylpyrrole 1247948-20-4 C11H17NOS
    2-(methylsulfanyl)-3-methoxy-1-cyclopentylpyrrole
    —— 2,2-bis(tributylstannyl)-1,3-benzodithiole 175167-25-6 C31H58S2Sn2
    2,2-bis(tributylstannyl)-1,3-benzodithiole
    —— methyl 4,6-dimethyl-5-(2-chloroethyl)-2-(3-methoxyphenyl-sulfanyl)benzoate 1023305-20-5 C19H21ClO3S
    methyl 4,6-dimethyl-5-(2-chloroethyl)-2-(3-methoxyphenyl-sulfanyl)benzoate
    —— 4-fluoro-2-(phenylthio)phenol 1350814-69-5 C12H9FOS
    4-fluoro-2-(phenylthio)phenol
    —— (Z)-5-methyl-4-(phenylthio)hex-2-en-1-ol 1246594-71-7 C13H18OS
    (Z)-5-methyl-4-(phenylthio)hex-2-en-1-ol
    —— 1,2,2-tris-isopropylsulfanyl-propane 13624-08-3 C12H26S3
    1,2,2-tris-isopropylsulfanyl-propane
    —— 1-Bromo-9-(methylsulfonyl)nonane 54863-58-0 C10H21BrO2S
    1-Bromo-9-(methylsulfonyl)nonane
    —— [2-(4-isopropyl-phenylsulfanyl)-pyridin-3-yl]-methanol 51723-84-3 C15H17NOS
    [2-(4-isopropyl-phenylsulfanyl)-pyridin-3-yl]-methanol
    —— 3-Pyridinemethanamine, N-(2-methoxyethyl)-2-[(1-methyl-1H-tetrazol-5-yl)thio]- 1958810-00-8 C11H16N6OS
    3-Pyridinemethanamine, N-(2-methoxyethyl)-2-[(1-methyl-1H-tetrazol-5-yl)thio]-
    —— N,N'-{Sulfanediylbis[(4,1-phenylene)methylene]}bis(N-methylmethanamine) 88847-35-2 C18H24N2S
    N,N'-{Sulfanediylbis[(4,1-phenylene)methylene]}bis(N-methylmethanamine)
    —— 1-Propanamine, N-[2-[(1-methylethyl)sulfonyl]ethyl]-3-propoxy- 1696540-74-5 C11H25NO3S
    1-Propanamine, N-[2-[(1-methylethyl)sulfonyl]ethyl]-3-propoxy-
    —— Acetic acid, 2-[[4-(4-chlorophenyl)-2-thiazolyl]thio]- 43045-18-7 C11H8ClNO2S2
    Acetic acid, 2-[[4-(4-chlorophenyl)-2-thiazolyl]thio]-
    —— N<sup>1</sup>-Aethyl-N<sup>2</sup>,N<sup>2</sup>-diisopropyl-thioharnstoff 24053-68-7 C9H20N2S
    N<sup>1</sup>-Aethyl-N<sup>2</sup>,N<sup>2</sup>-diisopropyl-thioharnstoff
    —— 3-[(3-chlorobenzyl)thio]-7-(3,5-dimethylphenyl)[1,2,4]triazolo[4,3-a]pyrazin-8(7H)-one 1242997-32-5 C20H17ClN4OS
    3-[(3-chlorobenzyl)thio]-7-(3,5-dimethylphenyl)[1,2,4]triazolo[4,3-a]pyrazin-8(7H)-one
    —— 3-[(2-chloro-4-fluorobenzyl)thio]-7-(5-chloro-2-methylphenyl)[1,2,4]triazolo[4,3-a]pyrazin-8(7H)-one 1243076-16-5 C19H13Cl2FN4OS
    3-[(2-chloro-4-fluorobenzyl)thio]-7-(5-chloro-2-methylphenyl)[1,2,4]triazolo[4,3-a]pyrazin-8(7H)-one
    —— 2-(4-Acetamido-phenyl-mercapto)-benzylalkohol 20904-47-6 C15H15NO2S
    2-(4-Acetamido-phenyl-mercapto)-benzylalkohol
    —— 2-(5-oxofuran-2(5H)-yliden)-1-benzothienyl-3(2H)-one 1260173-97-4 C12H6O3S
    2-(5-oxofuran-2(5H)-yliden)-1-benzothienyl-3(2H)-one
    —— (S,E)-1-(phenylthio)pent-3-en-2-ol 1257427-94-3 C11H14OS
    (S,E)-1-(phenylthio)pent-3-en-2-ol
    —— 4-Thiazolamine, 2-(methylthio)- 1264033-89-7 C4H6N2S2
    4-Thiazolamine, 2-(methylthio)-
    —— 1-[(1-Aminopropan-2-yl)sulfanyl]-4-bromobenzene hydrochloride 1269152-10-4 C9H13BrClNS
    1-[(1-Aminopropan-2-yl)sulfanyl]-4-bromobenzene hydrochloride
    —— 2-(Isopropylsulfonyl)ethanol hydrate 1242339-21-4 C5H14O4S
    2-(Isopropylsulfonyl)ethanol hydrate
    —— 2-(6-Chloro-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acetic acid 1053656-44-2 C8H5ClF3NO2S
    2-(6-Chloro-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acetic acid
    —— 2-(Propylthio)ethanamine hydrochloride 1242339-84-9 C5H14ClNS
    2-(Propylthio)ethanamine hydrochloride
    —— [2-(Methylsulfinyl)ethyl]amine hydrobromide 1242339-83-8 C3H10BrNOS
    [2-(Methylsulfinyl)ethyl]amine hydrobromide
    —— 6-bromo-7-(phenylthio)-1,2,3,5-tetrahydro-5-indolizinone 1261062-63-8 C14H12BrNOS
    6-bromo-7-(phenylthio)-1,2,3,5-tetrahydro-5-indolizinone
    —— 1-Amino-3-methoxythiourea;hydrochloride 1265622-67-0 C2H7N3OS*ClH
    1-Amino-3-methoxythiourea;hydrochloride
    —— 6-bromo-7-(phenylthio)-1,2,3,5,8,8a-hexahydro-5-indolizinone 1261062-60-5 C14H14BrNOS
    6-bromo-7-(phenylthio)-1,2,3,5,8,8a-hexahydro-5-indolizinone
    —— 6-phenyl-7-(phenylthio)-1,2,3,5,8,8a-hexahydro-5-indolizinone 1261062-62-7 C20H19NOS
    6-phenyl-7-(phenylthio)-1,2,3,5,8,8a-hexahydro-5-indolizinone
    —— 7-(phenylthio)-1,2,3,5-tetrahydro-5-indolizinone 1261062-61-6 C14H13NOS
    7-(phenylthio)-1,2,3,5-tetrahydro-5-indolizinone
    —— 2-(phenylthio)-6,7,8,9-tetrahydro-4-quinolizinone 1261062-66-1 C15H15NOS
    2-(phenylthio)-6,7,8,9-tetrahydro-4-quinolizinone
    —— (9S)-7-methyl-9-propyl-1,4-dithiaspiro[4.5]dec-6-ene 1266679-09-7 C12H20S2
    (9S)-7-methyl-9-propyl-1,4-dithiaspiro[4.5]dec-6-ene
    —— 1-[3-(Methylsulfanyl)phenyl]-4-oxo-1,4-dihydropyridazine-3-carboxylic acid 1291486-54-8 C12H10N2O3S
    1-[3-(Methylsulfanyl)phenyl]-4-oxo-1,4-dihydropyridazine-3-carboxylic acid
    —— (+/-)-ethyl 2-[4-[(2-chlorophenylthio)methyl]phenyl]-2-hydroxyacetate 1268473-45-5 C17H17ClO3S
    (+/-)-ethyl 2-[4-[(2-chlorophenylthio)methyl]phenyl]-2-hydroxyacetate
    —— Acetamide, N-[1-(4-fluorophenyl)ethyl]-2-[[4-methyl-5-(2-thienyl)-4H-1,2,4-triazol-3-yl]thio]- 1300254-52-7 C17H17FN4OS2
    Acetamide, N-[1-(4-fluorophenyl)ethyl]-2-[[4-methyl-5-(2-thienyl)-4H-1,2,4-triazol-3-yl]thio]-
    —— 1-(2-amino-6-methylpyrimidin-4-yl)-3-(1,3,5-trimethyl-1H-pyrazol-4-ylsulfanyl)-[1,2,4]triazole 1295576-30-5 C13H16N8S
    1-(2-amino-6-methylpyrimidin-4-yl)-3-(1,3,5-trimethyl-1H-pyrazol-4-ylsulfanyl)-[1,2,4]triazole
    —— (E)-6'-(4-hydroxybenzylidene)-4a'-methyl-4',4a',7',8'-tetrahydro-3'H-spiro[[1,3]dithiolane-2,2'-naphthalen]-5'(6'H)-one 1289642-67-6 C20H22O2S2
    (E)-6'-(4-hydroxybenzylidene)-4a'-methyl-4',4a',7',8'-tetrahydro-3'H-spiro[[1,3]dithiolane-2,2'-naphthalen]-5'(6'H)-one
    —— 2-Tert-butyl-5-methylsulfanyl-1,3,4-oxadiazole 83430-53-9 C7H12N2OS
    2-Tert-butyl-5-methylsulfanyl-1,3,4-oxadiazole
    —— Alyssin, (S)- 167963-04-4 C7H13NOS2
    Alyssin, (S)-
    —— 4-ethyl-3-methyl-5-methylsulfanyl-4<i>H</i>-[1,2,4]triazole 102170-30-9 C6H11N3S
    4-ethyl-3-methyl-5-methylsulfanyl-4<i>H</i>-[1,2,4]triazole
    —— 2-Pyrimidinamine, 4-chloro-6-[[5-(2-fluorophenyl)-4-(phenylmethyl)-4H-1,2,4-triazol-3-yl]thio]- 1376320-30-7 C19H14ClFN6S
    2-Pyrimidinamine, 4-chloro-6-[[5-(2-fluorophenyl)-4-(phenylmethyl)-4H-1,2,4-triazol-3-yl]thio]-
    —— 6-Benzylthio-tetrazolo<1.5-b>pyridazin 62645-24-3 C11H9N5S
    6-Benzylthio-tetrazolo<1.5-b>pyridazin