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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-(difluoro(phenylsulfanyl)methyl)-5-hydroxy-1-(3-methylbut-2-enyl)pyrrolidin-2-one 1152033-02-7 C16H19F2NO2S
    5-(difluoro(phenylsulfanyl)methyl)-5-hydroxy-1-(3-methylbut-2-enyl)pyrrolidin-2-one
    —— S-404 38058-82-1 C7H17O5PS2
    S-404
    —— [2-(2-methylsulfanyl-imidazol-1-yl)-ethyl]-carbamic acid tert-butyl ester 1202690-33-2 C11H19N3O2S
    [2-(2-methylsulfanyl-imidazol-1-yl)-ethyl]-carbamic acid tert-butyl ester
    —— 8-(6-(furan-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(2-(neopentylamino)ethyl)-9H-purin-6-amine 1289544-12-2 C23H26N6O3S
    8-(6-(furan-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(2-(neopentylamino)ethyl)-9H-purin-6-amine
    —— Ethyl-(2-cyanopyridine-4-ylthio)acetate 256657-61-1 C10H10N2O2S
    Ethyl-(2-cyanopyridine-4-ylthio)acetate
    —— 1-adamantyl tert-butyl thioketone 185817-24-7 C15H24S
    1-adamantyl tert-butyl thioketone
    —— (E)-3-benzylidene-5-(4-(methylthio)benzyl)furan-2(3H)-one 1350721-00-4 C19H16O2S
    (E)-3-benzylidene-5-(4-(methylthio)benzyl)furan-2(3H)-one
    —— (S)-2-(2-hydroxypropyl)-2-nonyl-1,3-dithiane 173266-65-4 C16H32OS2
    (S)-2-(2-hydroxypropyl)-2-nonyl-1,3-dithiane
    —— (Z)-4-phenylsulfinyl-3-buten-2-one 33944-97-7 C10H10OS
    (Z)-4-phenylsulfinyl-3-buten-2-one
    —— benzyldimethyl(1-thiophenyl)cyclopropylsilane 166672-24-8 C18H22SSi
    benzyldimethyl(1-thiophenyl)cyclopropylsilane
    —— 2-Amino-5,6-dihydrothiazolo<3,2-b>-1,2,4-triazole 116544-90-2 C4H6N4S
    2-Amino-5,6-dihydrothiazolo<3,2-b>-1,2,4-triazole
    —— N,N-diisopropyl-bis<2-(methylsulfonyl)ethyl> phosphoramidite 157728-69-3 C12H28NO6PS2
    N,N-diisopropyl-bis<2-(methylsulfonyl)ethyl> phosphoramidite
    —— 2-methylthio-5-(3-phenylpropyn-1-yl)-6-methylaminopyrimidine 598298-06-7 C15H15N3S
    2-methylthio-5-(3-phenylpropyn-1-yl)-6-methylaminopyrimidine
    —— 6-(2-oxopropyl)-2,3-dihydrothiazolo<3,2-c>pyrimidine-5,7-dione 149221-51-2 C9H10N2O3S
    6-(2-oxopropyl)-2,3-dihydrothiazolo<3,2-c>pyrimidine-5,7-dione
    —— (4S,5S)-1-[4-(3,5-difluoro-benzyl)-2-phenyl-5-phenylsulfanylmethyl-oxazolidin-3-yl]-ethanone 951401-50-6 C25H23F2NO2S
    (4S,5S)-1-[4-(3,5-difluoro-benzyl)-2-phenyl-5-phenylsulfanylmethyl-oxazolidin-3-yl]-ethanone
    —— [(R)-8-fluoro-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-ylmethyl]-urea 1231765-22-2 C18H18F2N2OS
    [(R)-8-fluoro-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-ylmethyl]-urea
    —— 4-(2-(methylthio)pyrimidin-4-yl)pyrimidin-2(1H)-one 1453852-78-2 C9H8N4OS
    4-(2-(methylthio)pyrimidin-4-yl)pyrimidin-2(1H)-one
    —— 2-[(3-Cyano-6-methylpyridin-2-yl)sulfanyl]-2-methylpropanoic acid 681840-66-4 C11H12N2O2S
    2-[(3-Cyano-6-methylpyridin-2-yl)sulfanyl]-2-methylpropanoic acid
    —— 2-Cyclohex-2-en-1-ylsulfanyl-6-methylpyridine-3-carbonitrile 121567-79-1 C13H14N2S
    2-Cyclohex-2-en-1-ylsulfanyl-6-methylpyridine-3-carbonitrile
    —— (1Z,3R)-3-hydroxy-1-(4'-methylphenylthio)-1-nitro-3-phenylprop-1-ene 228716-87-8 C16H15NO3S
    (1Z,3R)-3-hydroxy-1-(4'-methylphenylthio)-1-nitro-3-phenylprop-1-ene
    —— (E)-3-(dimethylamino)-1-(2-(methylthio)pyrimidin-4-yl)prop-2-en-1-one 496863-49-1 C10H13N3OS
    (E)-3-(dimethylamino)-1-(2-(methylthio)pyrimidin-4-yl)prop-2-en-1-one
    —— 3-acetyl-6-methyl-2-(methylthio)pyridine 1191923-85-9 C9H11NOS
    3-acetyl-6-methyl-2-(methylthio)pyridine
    —— 1-(2-(tert-butyldimethylsilyloxy)-1-(4-chloro-3-fluorophenyl)ethyl)-4-(2-(methylthio)pyrimidin-4-yl)pyrimidin-2(1H)-one 1453852-80-6 C23H28ClFN4O2SSi
    1-(2-(tert-butyldimethylsilyloxy)-1-(4-chloro-3-fluorophenyl)ethyl)-4-(2-(methylthio)pyrimidin-4-yl)pyrimidin-2(1H)-one
    —— (1'S,2R,3R)-3-(1'-hydroxy-1'-phenylmethyl)-2-(4''-methylphenylthio)-2-nitrooxirane 228716-89-0 C16H15NO4S
    (1'S,2R,3R)-3-(1'-hydroxy-1'-phenylmethyl)-2-(4''-methylphenylthio)-2-nitrooxirane
    —— 6-Methyl-3-cyano-2-allylthiopyridine 112629-70-6 C10H10N2S
    6-Methyl-3-cyano-2-allylthiopyridine
    —— N'-cyano-2-(3-cyano-6-methylpyridin-2-yl)sulfanylethanimidamide 159717-90-5 C10H9N5S
    N'-cyano-2-(3-cyano-6-methylpyridin-2-yl)sulfanylethanimidamide
    —— 1-Phenyl-2-<(phenylthio)methyl>-1-propen 79597-56-1 C16H16S
    1-Phenyl-2-<(phenylthio)methyl>-1-propen
    —— ethyl 5-methyl-2-(phenylthio)-2-(trifluoromethyl)-4-hexenoate 134427-77-3 C16H19F3O2S
    ethyl 5-methyl-2-(phenylthio)-2-(trifluoromethyl)-4-hexenoate
    —— <4-chlorophenylthio(4-methylphenyl)methyl>trimethylsilane 103559-10-0 C17H21ClSSi
    <4-chlorophenylthio(4-methylphenyl)methyl>trimethylsilane
    —— 3,4-Bis(trifluormethylthio)pyrazol 114861-77-7 C5H2F6N2S2
    3,4-Bis(trifluormethylthio)pyrazol
    —— (1Z,3R)-3-tert-butyldimethylsilyloxy-1-(4'-methylphenylthio)-1-nitro-3-phenylprop-1-ene 228716-85-6 C22H29NO3SSi
    (1Z,3R)-3-tert-butyldimethylsilyloxy-1-(4'-methylphenylthio)-1-nitro-3-phenylprop-1-ene
    —— (1'S,2R,3R)-3-(1'-tert-butoxydimethylsilyloxy-1'-phenylmethyl)-2-(4''-methylphenylthio)-2-nitrooxirane 228716-91-4 C22H29NO4SSi
    (1'S,2R,3R)-3-(1'-tert-butoxydimethylsilyloxy-1'-phenylmethyl)-2-(4''-methylphenylthio)-2-nitrooxirane
    —— 7-chloro-2,3-dihydro-5H-thiazolo[3,2-a]pyrimidin-5-one 72211-60-0 C6H5ClN2OS
    7-chloro-2,3-dihydro-5H-thiazolo[3,2-a]pyrimidin-5-one
    —— 7-morpholin-4-yl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one 32090-53-2 C10H13N3O2S
    7-morpholin-4-yl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one
    —— 5,7-dioxo-3,5,6,7-tetrahydro-2H-thiazolo<3,2-c>pyrimidine-8-carbaldehyde 161094-28-6 C7H6N2O3S
    5,7-dioxo-3,5,6,7-tetrahydro-2H-thiazolo<3,2-c>pyrimidine-8-carbaldehyde
    —— 7-methanesulfonyloxy-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one 72211-62-2 C7H8N2O4S2
    7-methanesulfonyloxy-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one
    —— 6-(2-Methylpropyl)-2,3-dihydro-[1,3]thiazolo[3,2-c]pyrimidine-5,7-dione 149221-47-6 C10H14N2O2S
    6-(2-Methylpropyl)-2,3-dihydro-[1,3]thiazolo[3,2-c]pyrimidine-5,7-dione
    —— 2<(4-chlorophenylthio)methyl>furan 5380-97-2 C11H9ClOS
    2<(4-chlorophenylthio)methyl>furan
    —— 1-Methyl-3,4-bis(trifluormethylthio)pyrazol 114861-78-8 C6H4F6N2S2
    1-Methyl-3,4-bis(trifluormethylthio)pyrazol
    —— 3-[Dimethyl-(1-phenylsulfanylcyclopropyl)silyl]-3-phenylpropan-1-ol 166672-30-6 C20H26OSSi
    3-[Dimethyl-(1-phenylsulfanylcyclopropyl)silyl]-3-phenylpropan-1-ol
    —— Ethyl 2-[4-cyano-5,6-bis(furan-2-yl)pyridazin-3-yl]sulfanylacetate 158014-42-7 C17H13N3O4S
    Ethyl 2-[4-cyano-5,6-bis(furan-2-yl)pyridazin-3-yl]sulfanylacetate
    —— methyl 3-(2-hydroxyphenylsulfanyl)propanoate 938435-58-6 C10H12O3S
    methyl 3-(2-hydroxyphenylsulfanyl)propanoate
    —— 2-Ethoxycarbonylmethylthio-6-methyl-4-(2-thienyl)-pyridin-3-carbonitril 127144-11-0 C15H14N2O2S2
    2-Ethoxycarbonylmethylthio-6-methyl-4-(2-thienyl)-pyridin-3-carbonitril
    —— 1-Methyl-4,5-bis(trifluormethylthio)pyrazol 114861-79-9 C6H4F6N2S2
    1-Methyl-4,5-bis(trifluormethylthio)pyrazol
    —— 2-Phenyl-5-pyrrolidino-3,4-bis(trifluormethylthio)furan 114861-81-3 C16H13F6NOS2
    2-Phenyl-5-pyrrolidino-3,4-bis(trifluormethylthio)furan
    —— 2-(pentafluorosulfanyl)acetaldehyde 762-57-2 C2H3F5OS
    2-(pentafluorosulfanyl)acetaldehyde
    —— 1,3-Dioxolane-2-thione, 4-(2-hydroxyethyl)- 189280-29-3 C5H8O3S
    1,3-Dioxolane-2-thione, 4-(2-hydroxyethyl)-
    —— 3,4,4-tris-methylsulfanyl-butan-2-one 7714-01-4 C7H14OS3
    3,4,4-tris-methylsulfanyl-butan-2-one
    —— (2S)-1-[2-[[2-(hydroxymethyl)-1,3-dithian-2-yl]methyl]-1,3-dithian-2-yl]propan-2-ol 175030-54-3 C13H24O2S4
    (2S)-1-[2-[[2-(hydroxymethyl)-1,3-dithian-2-yl]methyl]-1,3-dithian-2-yl]propan-2-ol
    —— 4-thioxo-3,4,7,8-tetrahydro-6<i>H</i>-[1,3]thiazino[3,2-<i>a</i>][1,3,5]triazin-2-one 51270-95-2 C6H7N3OS2
    4-thioxo-3,4,7,8-tetrahydro-6<i>H</i>-[1,3]thiazino[3,2-<i>a</i>][1,3,5]triazin-2-one