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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-ethyl-6-methyl-2-[(4-methylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine 1321891-23-9 C21H26N4S2
    5-ethyl-6-methyl-2-[(4-methylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine
    —— 1-Propanamine, N-(2-methoxyethyl)-2-(2-pyridinylthio)- 1251380-34-3 C11H18N2OS
    1-Propanamine, N-(2-methoxyethyl)-2-(2-pyridinylthio)-
    —— N-Methyl-4-[(2-methylphenyl)thio]-1-butanamine 1249382-73-7 C12H19NS
    N-Methyl-4-[(2-methylphenyl)thio]-1-butanamine
    —— 3-Fluoro-7-(methylthio)-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4(8H)-one 1353761-16-6 C5H4FN5OS
    3-Fluoro-7-(methylthio)-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4(8H)-one
    —— 5-ethyl-6-methyl-2-[(4-ethylpiperazin-1-yl)methyl]-4-(4-methoxyphenylthio)thieno[2,3-d]pyrimidine 1321891-13-7 C23H30N4OS2
    5-ethyl-6-methyl-2-[(4-ethylpiperazin-1-yl)methyl]-4-(4-methoxyphenylthio)thieno[2,3-d]pyrimidine
    —— N1,N1-Dimethyl-N3-[2-[(3-methyl-1H-1,2,4-triazol-5-yl)thio]ethyl]-1,3-propanediamine 1247632-04-7 C10H21N5S
    N1,N1-Dimethyl-N3-[2-[(3-methyl-1H-1,2,4-triazol-5-yl)thio]ethyl]-1,3-propanediamine
    —— 5-ethyl-6-methyl-2-[(4-methylpiperazin-1-yl)methyl]-4-(4-methoxyphenylthio)thieno[2,3-d]pyrimidine 1321891-19-3 C22H28N4OS2
    5-ethyl-6-methyl-2-[(4-methylpiperazin-1-yl)methyl]-4-(4-methoxyphenylthio)thieno[2,3-d]pyrimidine
    —— N-(2-Methoxyethyl)-2-[(1-methyl-1H-tetrazol-5-yl)thio]-1-propanamine 1249836-01-8 C8H17N5OS
    N-(2-Methoxyethyl)-2-[(1-methyl-1H-tetrazol-5-yl)thio]-1-propanamine
    —— 7-Methylsulfanyl-3-pyridin-1-ium-1-yl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-olate 1353761-18-8 C10H8N6OS
    7-Methylsulfanyl-3-pyridin-1-ium-1-yl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-olate
    —— 5-ethyl-6-methyl-2-[(4-ethylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine 1321891-12-6 C22H28N4S2
    5-ethyl-6-methyl-2-[(4-ethylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine
    —— 5,6-dimethyl-2-[(4-methylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine 1321891-35-3 C20H24N4S2
    5,6-dimethyl-2-[(4-methylpiperazin-1-yl)methyl]-4-phenylthiothieno[2,3-d]pyrimidine
    —— 4-[(1,3-Dimethyl-1H-pyrazol-5-yl)thio]-N-methyl-1-butanamine 1247450-27-6 C10H19N3S
    4-[(1,3-Dimethyl-1H-pyrazol-5-yl)thio]-N-methyl-1-butanamine
    —— 3-butylsulfanyl-4-methyl-aniline 100056-24-4 C11H17NS
    3-butylsulfanyl-4-methyl-aniline
    —— 1-carbamoyl-2-methyl-3-phenylthio-1H-pyrrole 1353137-65-1 C12H12N2OS
    1-carbamoyl-2-methyl-3-phenylthio-1H-pyrrole
    —— 7-methyl-4,6-di(phenylthio)-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-57-1 C18H18N2OS2
    7-methyl-4,6-di(phenylthio)-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-55-9 C12H14N2OS
    7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 4-[di(ethoxycarbonyl)methyl]-7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-48-0 C19H24N2O5S
    4-[di(ethoxycarbonyl)methyl]-7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 4-cyano-7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-46-8 C13H13N3OS
    4-cyano-7-methyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— Cycloheptanecarboxamide, N-[1-(aminothioxomethyl)propyl]- 1250406-45-1 C12H22N2OS
    Cycloheptanecarboxamide, N-[1-(aminothioxomethyl)propyl]-
    —— triethyl-[(1R,2S)-2-methyl-5-phenylsulfanylcyclohepta-3,5-dien-1-yl]oxysilane 1349053-88-8 C20H30OSSi
    triethyl-[(1R,2S)-2-methyl-5-phenylsulfanylcyclohepta-3,5-dien-1-yl]oxysilane
    —— Propanamide, N-(2-amino-1-methyl-2-thioxoethyl)-3-methoxy-N-methyl- 1250900-55-0 C8H16N2O2S
    Propanamide, N-(2-amino-1-methyl-2-thioxoethyl)-3-methoxy-N-methyl-
    —— 4-methyl-3-propylsulfanyl-aniline 104396-08-9 C10H15NS
    4-methyl-3-propylsulfanyl-aniline
    —— 4-methyl-3-phenylsulfanyl-aniline 105901-47-1 C13H13NS
    4-methyl-3-phenylsulfanyl-aniline
    —— 3-ethylsulfanyl-4-methyl-aniline 98960-72-6 C9H13NS
    3-ethylsulfanyl-4-methyl-aniline
    —— 3-Hexanamine, N-ethyl-5-methyl-1-(methylsulfonyl)- 1250404-36-4 C10H23NO2S
    3-Hexanamine, N-ethyl-5-methyl-1-(methylsulfonyl)-
    —— 2-[(S)-2-Hydroxy-4-pentenyl]-2-[(R)-2-(methoxymethoxy)propanyl]-1,3-dithiane 1388627-17-5 C14H26O3S2
    2-[(S)-2-Hydroxy-4-pentenyl]-2-[(R)-2-(methoxymethoxy)propanyl]-1,3-dithiane
    —— [1-(14)C]thioacetamide 1356571-39-5 C2H5NS
    [1-(14)C]thioacetamide
    —— [1-(14)C]thioacetamide S-oxide 1356571-40-8 C2H5NOS
    [1-(14)C]thioacetamide S-oxide
    —— 1,3-diphenyl-1H-[1,2,4]triazino[6,5-b]phenothiazine 1359739-86-8 C25H16N4S
    1,3-diphenyl-1H-[1,2,4]triazino[6,5-b]phenothiazine
    —— (E)-ethyl 3-(5-(methylthio)-1H-tetrazol-1-yl)acrylate 1349709-83-6 C7H10N4O2S
    (E)-ethyl 3-(5-(methylthio)-1H-tetrazol-1-yl)acrylate
    —— 4-(4-isopropyl-phenylsulfanyl)-benzene-1,2-diol 1362410-19-2 C15H16O2S
    4-(4-isopropyl-phenylsulfanyl)-benzene-1,2-diol
    —— allyl 2,3-O-cyclopentylidene-5-deoxy-5-S-(1,2,4-triazol-3-yl)-β-D-ribofuranoside 1356821-69-6 C15H21N3O4S
    allyl 2,3-O-cyclopentylidene-5-deoxy-5-S-(1,2,4-triazol-3-yl)-β-D-ribofuranoside
    —— (I+/-S)-2-(Methylthio)-I+/--(trifluoromethyl)benzenemethanamine 878539-32-3 C9H10F3NS
    (I+/-S)-2-(Methylthio)-I+/--(trifluoromethyl)benzenemethanamine
    —— 2-(3-Chloro-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 942069-61-6 C18H20BClO2S
    2-(3-Chloro-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
    —— 4-Chloro-2-(propylthio)pyridine 1346707-21-8 C8H10ClNS
    4-Chloro-2-(propylthio)pyridine
    —— 2-(3-Bromo-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 942069-55-8 C18H20BBrO2S
    2-(3-Bromo-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
    —— 2-(3-Methoxy-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 942069-83-2 C19H23BO3S
    2-(3-Methoxy-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
    —— 3-Chloro-4-[(3-chlorophenyl)thio]-1,2,5-thiadiazole 1248914-27-3 C8H4Cl2N2S2
    3-Chloro-4-[(3-chlorophenyl)thio]-1,2,5-thiadiazole
    —— 2-Chloro-3-[[(3-chlorophenyl)thio]methyl]pyridine 1248794-33-3 C12H9Cl2NS
    2-Chloro-3-[[(3-chlorophenyl)thio]methyl]pyridine
    —— 2-[(3-Chlorophenyl)thio]butanoic acid 103040-44-4 C10H11ClO2S
    2-[(3-Chlorophenyl)thio]butanoic acid
    —— 1-(Ethanesulfinyl)but-2-ene 88170-50-7 C6H12OS
    1-(Ethanesulfinyl)but-2-ene
    —— 1,2-Diethoxy-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene 1403580-50-6 C29H23NO2S3
    1,2-Diethoxy-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene
    —— 2-(4-Chloro-phenylsulfanyl)-6-methyl-nicotinic acid 958-61-2 C13H10ClNO2S
    2-(4-Chloro-phenylsulfanyl)-6-methyl-nicotinic acid
    —— 4-Methyl-1-(methylthio)-2-pentanamine 1247496-39-4 C7H17NS
    4-Methyl-1-(methylthio)-2-pentanamine
    —— (2-(2-(hydroxymethyl)-4-methylphenylthio)phenyl)methanol 1062599-57-8 C15H16O2S
    (2-(2-(hydroxymethyl)-4-methylphenylthio)phenyl)methanol
    —— (4-fluoro-2-(2-(hydroxymethyl)phenylthio)phenyl)methanol 1062599-59-0 C14H13FO2S
    (4-fluoro-2-(2-(hydroxymethyl)phenylthio)phenyl)methanol
    —— bis-(5-amino-pentyl)-sulfide 91135-26-1 C10H24N2S
    bis-(5-amino-pentyl)-sulfide
    —— (2-(2-(hydroxymethyl)-6-methylphenylthio)phenyl)methanol 1062599-55-6 C15H16O2S
    (2-(2-(hydroxymethyl)-6-methylphenylthio)phenyl)methanol
    —— 1-Ethoxy-2-methyl-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene 1403580-47-1 C28H21NOS3
    1-Ethoxy-2-methyl-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene
    —— 2-Ethoxy-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene 1403580-43-7 C27H19NOS3
    2-Ethoxy-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene