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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-Benzylthio-3H-1,2-dithiole-3-thione 120060-18-6 C10H8S4
    5-Benzylthio-3H-1,2-dithiole-3-thione
    —— 5-(3,5-Dichlorophenylthio)-1-(2-carbamoyloxyethyl)-2-carbamoyloxymethyl-4-isopropyl-1H-imidazole 178980-28-4 C17H20Cl2N4O4S
    5-(3,5-Dichlorophenylthio)-1-(2-carbamoyloxyethyl)-2-carbamoyloxymethyl-4-isopropyl-1H-imidazole
    —— 2-(5-(3,5-dichlorophenylthio)-2-hydroxymethyl-4-isopropyl-1H-imidazol-1-yl)ethanol 178980-54-6 C15H18Cl2N2O2S
    2-(5-(3,5-dichlorophenylthio)-2-hydroxymethyl-4-isopropyl-1H-imidazol-1-yl)ethanol
    —— N,N,3-Trimethylbut-2-enethioamide 67797-24-4 C7H13NS
    N,N,3-Trimethylbut-2-enethioamide
    —— (E)-N,N-dimethylbut-2-enethioamide 80095-84-7 C6H11NS
    (E)-N,N-dimethylbut-2-enethioamide
    —— 3-ethyl-4-methyl-2-methylsulfanyl-thiazolium; iodide 53845-14-0 C7H12NS2*I
    3-ethyl-4-methyl-2-methylsulfanyl-thiazolium; iodide
    —— (2E,4E)-N,N-dimethylhexa-2,4-dienethioamide 67797-27-7 C8H13NS
    (2E,4E)-N,N-dimethylhexa-2,4-dienethioamide
    —— dimethyl-(5-methylsulfanyl-[1,3,4]thiadiazol-2-yl)-amine 51412-78-3 C5H9N3S2
    dimethyl-(5-methylsulfanyl-[1,3,4]thiadiazol-2-yl)-amine
    —— 2-Ethylamino-4,6-dichloro-5-methylthio-pyrimidine 40765-74-0 C7H9Cl2N3S
    2-Ethylamino-4,6-dichloro-5-methylthio-pyrimidine
    —— 5-(2-amino-ethylsulfanyl)-[1,3,4]thiadiazol-2-ylamine 111461-31-5 C4H8N4S2
    5-(2-amino-ethylsulfanyl)-[1,3,4]thiadiazol-2-ylamine
    —— 1-Methylthiomethyloxy-butan 61865-93-8 C6H14OS
    1-Methylthiomethyloxy-butan
    —— <i>N</i>-(2,2-diethoxy-ethyl)-<i>N</i>'-methyl-thiourea 90203-43-3 C8H18N2O2S
    <i>N</i>-(2,2-diethoxy-ethyl)-<i>N</i>'-methyl-thiourea
    —— N-benzyl-2-methyl-3-phenylsulfanylpropan-1-imine 183381-81-9 C17H19NS
    N-benzyl-2-methyl-3-phenylsulfanylpropan-1-imine
    —— O-ethyl [(1S,3R)-2,2-dimethyl-3-[2-(2-methyl-1,3-dithiolan-2-yl)ethyl]cyclopropanecarbonyl]sulfanylmethanethioate 823797-68-8 C15H24O2S4
    O-ethyl [(1S,3R)-2,2-dimethyl-3-[2-(2-methyl-1,3-dithiolan-2-yl)ethyl]cyclopropanecarbonyl]sulfanylmethanethioate
    —— metazathioprine 97746-12-8 C10H9N7O2S
    metazathioprine
    —— (3R,4R)-3-<(tert-Butyldimethylsilyl)oxy>-4-<(phenylthio)methyl>-γ-butyrolactone 159685-36-6 C17H26O3SSi
    (3R,4R)-3-<(tert-Butyldimethylsilyl)oxy>-4-<(phenylthio)methyl>-γ-butyrolactone
    —— 1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-(4-cyanophenyl)urea 417715-71-0 C25H19N5O3S2
    1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]thiophen-2-yl}-3-(4-cyanophenyl)urea
    —— 3-(4-Bromo-2-fluorophenyl)-3,4-dihydro-2-methylthio-6-trifluoromethylpyrimidin-4-one 205385-33-7 C12H7BrF4N2OS
    3-(4-Bromo-2-fluorophenyl)-3,4-dihydro-2-methylthio-6-trifluoromethylpyrimidin-4-one
    —— (2R)-2-[[6-amino-2-[[(2,3-difluorophenyl)methyl]thio]-5-nitroso-4-pyrimidinyl]amino]-1-propanol 503271-72-5 C14H15F2N5O2S
    (2R)-2-[[6-amino-2-[[(2,3-difluorophenyl)methyl]thio]-5-nitroso-4-pyrimidinyl]amino]-1-propanol
    —— 3-Azidopropyl [(ethoxycarbonothioyl)sulfanyl]acetate 921940-78-5 C8H13N3O3S2
    3-Azidopropyl [(ethoxycarbonothioyl)sulfanyl]acetate
    —— (2R)-2-[(2-chloro-5-{[(1R)-1-phenylethyl]sulfanyl}[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-methylpentan-1-ol 911715-88-3 C19H23ClN4OS2
    (2R)-2-[(2-chloro-5-{[(1R)-1-phenylethyl]sulfanyl}[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-methylpentan-1-ol
    —— (2R)-2-[(2-chloro-5-{[(1S)-1-phenylethyl]sulfanyl}[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-methylpentan-1-ol 911715-91-8 C19H23ClN4OS2
    (2R)-2-[(2-chloro-5-{[(1S)-1-phenylethyl]sulfanyl}[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-methylpentan-1-ol
    —— (2R)-2-[(2-methoxy-5-{[(1S)-1-phenylethyl]sulfanyl}[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-methylpentan-1-ol 911715-92-9 C20H26N4O2S2
    (2R)-2-[(2-methoxy-5-{[(1S)-1-phenylethyl]sulfanyl}[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-methylpentan-1-ol
    —— (2R)-2-[(2-methoxy-5-{[(1R)-1-phenylethyl]sulfanyl}-[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-methylpentan-1-ol 911715-89-4 C20H26N4O2S2
    (2R)-2-[(2-methoxy-5-{[(1R)-1-phenylethyl]sulfanyl}-[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-methylpentan-1-ol
    —— 2-chloro-6-<2-hydroxy-3-(phenylthio)propyl>phenol 126708-05-2 C15H15ClO2S
    2-chloro-6-<2-hydroxy-3-(phenylthio)propyl>phenol
    —— 2-chloro-6-<3-hydroxy-2-(phenylthio)propyl>phenol 126708-15-4 C15H15ClO2S
    2-chloro-6-<3-hydroxy-2-(phenylthio)propyl>phenol
    —— 3-(cyclopropylthio)-1H-pyrazole 1196875-52-1 C6H8N2S
    3-(cyclopropylthio)-1H-pyrazole
    —— 2-(((1-(pyridin-4-ylmethyl)-1H-1,2,3-triazol-4-yl)methyl)-thio)pyridine 1445876-53-8 C14H13N5S
    2-(((1-(pyridin-4-ylmethyl)-1H-1,2,3-triazol-4-yl)methyl)-thio)pyridine
    —— (4S)-3-<(2S,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclopentyl)propyl>-4-phenylmethyl-1,3-oxazolidin-2-one 138649-96-4 C25H29NO4S
    (4S)-3-<(2S,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclopentyl)propyl>-4-phenylmethyl-1,3-oxazolidin-2-one
    —— 4-hydroxy-4-(1-(phenylthio)cyclopentyl)butan-2-one 179806-59-8 C15H20O2S
    4-hydroxy-4-(1-(phenylthio)cyclopentyl)butan-2-one
    —— (3R,4R)-3-methyl-4-phenylsulfanyl-1-oxa-spiro<4.4>nonane 138751-05-0 C15H20OS
    (3R,4R)-3-methyl-4-phenylsulfanyl-1-oxa-spiro<4.4>nonane
    —— 2,3,4-trimethyl-5-oxo-4,5-dihydro-1,4-benzothiazepine 93301-47-4 C12H13NOS
    2,3,4-trimethyl-5-oxo-4,5-dihydro-1,4-benzothiazepine
    —— 3-hydroxy-[(1'-phenylsulfanyl)cyclopentyl]-propanol 175439-57-3 C14H20O2S
    3-hydroxy-[(1'-phenylsulfanyl)cyclopentyl]-propanol
    —— 3-ethyl-4-methyl-5-oxo-4,5-dihydro-1,4-benzothiazepine 93301-44-1 C12H13NOS
    3-ethyl-4-methyl-5-oxo-4,5-dihydro-1,4-benzothiazepine
    —— 3-hydroxy-2,2-dimethyl-[(1'-phenylsulfanyl)cyclopentyl]-propanol 175439-59-5 C16H24O2S
    3-hydroxy-2,2-dimethyl-[(1'-phenylsulfanyl)cyclopentyl]-propanol
    —— (1S,2S)-2-methyl-1-(1-phenylsulfanylcyclopentyl)propane-1,3-diol 138751-07-2 C15H22O2S
    (1S,2S)-2-methyl-1-(1-phenylsulfanylcyclopentyl)propane-1,3-diol
    —— Ethyl 3-hydroxy-3-[1'-(phenylsulfanyl)cyclopentyl]propanedithioate 174784-04-4 C16H22OS3
    Ethyl 3-hydroxy-3-[1'-(phenylsulfanyl)cyclopentyl]propanedithioate
    —— (E)-4-(1-phenylsulfanylcyclopentyl)but-3-en-2-one 711028-37-4 C15H18OS
    (E)-4-(1-phenylsulfanylcyclopentyl)but-3-en-2-one
    —— ethyl 3-hydroxy-3-(1'-phenylsulfanylcyclopentyl)propanoate 406701-00-6 C16H22O3S
    ethyl 3-hydroxy-3-(1'-phenylsulfanylcyclopentyl)propanoate
    —— (R)-2-methyl-3-(phenylsulfanyl)propanal 221372-46-9 C10H12OS
    (R)-2-methyl-3-(phenylsulfanyl)propanal
    —— 6-bromo-2-pyridyl-N-(2'-methylthiophenyl)methyleneimine 1384182-25-5 C13H11BrN2S
    6-bromo-2-pyridyl-N-(2'-methylthiophenyl)methyleneimine
    —— [(2R,3S)-3-methyl-4-phenylsulfanylbutan-2-yl] acetate 187671-48-3 C13H18O2S
    [(2R,3S)-3-methyl-4-phenylsulfanylbutan-2-yl] acetate
    —— (S)-(+)-2-methyl-3-(phenylthio)propan-1-ol 121783-49-1 C10H14OS
    (S)-(+)-2-methyl-3-(phenylthio)propan-1-ol
    —— (S)-2-methyl-3-(phenylsulfanyl)propanoic acid methyl ester 121783-48-0 C11H14O2S
    (S)-2-methyl-3-(phenylsulfanyl)propanoic acid methyl ester
    —— 2-[(5-pyrazin-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetic acid —— C8H7N5O2S
    2-[(5-pyrazin-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetic acid
    —— (1R,2R,5S,10S,11R,14R,15R,23R)-1,2,8,8,15,22,22-heptamethyl-5-(phenylsulfanylmethyl)-20-oxa-19-azahexacyclo[12.11.0.02,11.05,10.015,23.017,21]pentacosa-17(21),18-dien-12-one 1191916-83-2 C37H51NO2S
    (1R,2R,5S,10S,11R,14R,15R,23R)-1,2,8,8,15,22,22-heptamethyl-5-(phenylsulfanylmethyl)-20-oxa-19-azahexacyclo[12.11.0.02,11.05,10.015,23.017,21]pentacosa-17(21),18-dien-12-one
    —— 4-{[2,6-dinitro-4-(trifluoromethyl)phenyl]sulfanyl}phenyl methyl ether 1137560-31-6 C14H9F3N2O5S
    4-{[2,6-dinitro-4-(trifluoromethyl)phenyl]sulfanyl}phenyl methyl ether
    —— 1,3-dinitro-2-phenylsulfanyl-5-(trifluoromethyl)benzene 17811-49-3 C13H7F3N2O4S
    1,3-dinitro-2-phenylsulfanyl-5-(trifluoromethyl)benzene
    —— 5-(2,6-dinitro-4-trifluoromethyl-phenylsulfanyl)-1-methyl-1,2-dihydro-[1,2,4]triazol-3-one 53709-71-0 C10H6F3N5O5S
    5-(2,6-dinitro-4-trifluoromethyl-phenylsulfanyl)-1-methyl-1,2-dihydro-[1,2,4]triazol-3-one
    —— 2-[2,6-dinitro-4-(trifluoromethyl)phenyl]sulfanyl-1H-imidazo[4,5-b]pyrazine 79100-29-1 C12H5F3N6O4S
    2-[2,6-dinitro-4-(trifluoromethyl)phenyl]sulfanyl-1H-imidazo[4,5-b]pyrazine