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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(2-methylsulfanyl-pyrimidin-4-yl)-6,7-dihydro-5H-pyrazolo[1,2-a]pyrazol-1-one 852164-96-6 C11H12N4OS
    3-(2-methylsulfanyl-pyrimidin-4-yl)-6,7-dihydro-5H-pyrazolo[1,2-a]pyrazol-1-one
    —— 5-[3-(4-benzoxyphenylthio)fur-2-yl]imidazoline-2,4-dione 877176-12-0 C20H16N2O4S
    5-[3-(4-benzoxyphenylthio)fur-2-yl]imidazoline-2,4-dione
    —— 2-(2-chloro-benzyl)-3-(2-methylsulfanyl-pyrimidin-4-yl)-6,7-dihydro-5H-pyrazolo[1,2-a]pyrazol-1-one 852165-07-2 C18H17ClN4OS
    2-(2-chloro-benzyl)-3-(2-methylsulfanyl-pyrimidin-4-yl)-6,7-dihydro-5H-pyrazolo[1,2-a]pyrazol-1-one
    —— 1-(4-Methoxybenzyl)-2-(6-methylbenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine 1061318-23-7 C22H20N4O3S
    1-(4-Methoxybenzyl)-2-(6-methylbenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine
    —— [(Methanesulfonyl)methyl]cyclopropane 62427-76-3 C5H10O2S
    [(Methanesulfonyl)methyl]cyclopropane
    —— 4-Cyclopentylsulfanylbutan-1-amine 1339531-15-5 C9H19NS
    4-Cyclopentylsulfanylbutan-1-amine
    —— Cycloprop-1-ene-1-thiol 81788-90-1 C3H4S
    Cycloprop-1-ene-1-thiol
    —— [2-(1H-indol-5-ylsulfanyl)-benzyl]-methyl-amine 857499-82-2 C16H16N2S
    [2-(1H-indol-5-ylsulfanyl)-benzyl]-methyl-amine
    —— 2-(phenylthio)-4-(5-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridin-3-yl)pyrimidine-5-carbonitrile 1036027-21-0 C19H10F3N5S
    2-(phenylthio)-4-(5-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridin-3-yl)pyrimidine-5-carbonitrile
    —— N,N'-(Ethane-1,2-diyl)bis[3-(ethenesulfonyl)propanamide] 67326-55-0 C12H20N2O6S2
    N,N'-(Ethane-1,2-diyl)bis[3-(ethenesulfonyl)propanamide]
    —— Cyclopentanemethanamine, I+/--[3-(methylsulfonyl)propyl]- 1341975-52-7 C10H21NO2S
    Cyclopentanemethanamine, I+/--[3-(methylsulfonyl)propyl]-
    —— 3-(4-(trifluoromethoxy)phenylthio)pyrazin-2(1H)-one 1099664-67-1 C11H7F3N2O2S
    3-(4-(trifluoromethoxy)phenylthio)pyrazin-2(1H)-one
    —— 1-Pentanamine, 2-(1-methylethyl)-5-(methylsulfonyl)-N-propyl- 1343640-84-5 C12H27NO2S
    1-Pentanamine, 2-(1-methylethyl)-5-(methylsulfonyl)-N-propyl-
    —— 1-[4-(2-hydroxy-2-methylpropoxy)-3-methylphenyl]-3-[4-(trifluoromethoxy)phenylthio]pyrazine-2(1H)-one 1099662-74-4 C22H21F3N2O4S
    1-[4-(2-hydroxy-2-methylpropoxy)-3-methylphenyl]-3-[4-(trifluoromethoxy)phenylthio]pyrazine-2(1H)-one
    —— 2-[3-(4-morpholin-4-ylmethylphenyl)-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl]-benzylamine 946050-93-7 C24H25N5OS
    2-[3-(4-morpholin-4-ylmethylphenyl)-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl]-benzylamine
    —— 4-(3-Chloro-2-hydroxypropyl)sulfanylphenol 915155-43-0 C9H11ClO2S
    4-(3-Chloro-2-hydroxypropyl)sulfanylphenol
    —— 3-(2-(pyridin-2-yl)ethylthio)pyrazin-2(1H)-one 1099665-60-7 C11H11N3OS
    3-(2-(pyridin-2-yl)ethylthio)pyrazin-2(1H)-one
    —— Dibenzyl 3,3-difluoro-1-((2-methoxy-4-(2-oxo-3-(4-(trifluoromethoxy)phenylthio)pyrazin-1(2H)-yl)phenoxy)methyl)cyclobutyl phosphate 1099664-77-3 C37H32F5N2O8PS
    Dibenzyl 3,3-difluoro-1-((2-methoxy-4-(2-oxo-3-(4-(trifluoromethoxy)phenylthio)pyrazin-1(2H)-yl)phenoxy)methyl)cyclobutyl phosphate
    —— 3-(phenethylthio)pyrazin-2(1H)-one 942910-23-8 C12H12N2OS
    3-(phenethylthio)pyrazin-2(1H)-one
    —— 5-(tert-butyl-dimethyl-silanyloxymethyl)-4-methyl-2-phenylsulfanyl-oxazole 1030014-61-9 C17H25NO2SSi
    5-(tert-butyl-dimethyl-silanyloxymethyl)-4-methyl-2-phenylsulfanyl-oxazole
    —— 5,5-dimethyl-3-phenyl-sulfanyl-4,5-dihydro-isoxazole 447401-72-1 C11H13NOS
    5,5-dimethyl-3-phenyl-sulfanyl-4,5-dihydro-isoxazole
    —— 4-bromomethyl-5-ethylsulfanyl-1-methyl-3-trifluoromethyl-1H-pyrazole 915137-37-0 C8H10BrF3N2S
    4-bromomethyl-5-ethylsulfanyl-1-methyl-3-trifluoromethyl-1H-pyrazole
    —— 2-chloro-6-(4-fluorophenylthio)pyridine 1112982-60-1 C11H7ClFNS
    2-chloro-6-(4-fluorophenylthio)pyridine
    —— 2-(6-methylsulfanyl-pyrimidin-4-yl)-malonic acid dimethyl ester 946422-09-9 C10H12N2O4S
    2-(6-methylsulfanyl-pyrimidin-4-yl)-malonic acid dimethyl ester
    —— Ethyl (3Z)-3-ethoxy-3-{[2-(methylsulfanyl)phenyl]imino}propanoate 861397-42-4 C14H19NO3S
    Ethyl (3Z)-3-ethoxy-3-{[2-(methylsulfanyl)phenyl]imino}propanoate
    —— (3-dimethylcarbamoyl-sulfanyl-4-fluorophenyl)-acetic acid methyl ester 915789-08-1 C12H14FNO3S
    (3-dimethylcarbamoyl-sulfanyl-4-fluorophenyl)-acetic acid methyl ester
    —— ethyl (6-methanesulfanylpyridin-3-yl)glyoxylate 745816-49-3 C10H11NO3S
    ethyl (6-methanesulfanylpyridin-3-yl)glyoxylate
    —— 4,4,5,5-Tetramethyl-2-[4-(phenylsulfanylmethyl)phenyl]-1,3,2-dioxaborolane 1029438-27-4 C19H23BO2S
    4,4,5,5-Tetramethyl-2-[4-(phenylsulfanylmethyl)phenyl]-1,3,2-dioxaborolane
    —— 2-Ethoxyethymethylensulfon 28525-27-1 C5H12O3S
    2-Ethoxyethymethylensulfon
    —— 4H-1,2,4-Triazole-3-methanamine, 4-cyclopropyl-5-[(2-methylbutyl)thio]- 1344359-13-2 C11H20N4S
    4H-1,2,4-Triazole-3-methanamine, 4-cyclopropyl-5-[(2-methylbutyl)thio]-
    —— tert-butyl (2S,4S)-4-[[3-[[(3S,5S)-1-[(2-methylpropan-2-yl)oxycarbonyl]-5-[(5-phenylsulfanyltetrazol-1-yl)methyl]pyrrolidin-3-yl]carbamoyl]benzoyl]amino]-2-[(5-phenylsulfanyltetrazol-1-yl)methyl]pyrrolidine-1-carboxylate 1072146-99-6 C42H50N12O6S2
    tert-butyl (2S,4S)-4-[[3-[[(3S,5S)-1-[(2-methylpropan-2-yl)oxycarbonyl]-5-[(5-phenylsulfanyltetrazol-1-yl)methyl]pyrrolidin-3-yl]carbamoyl]benzoyl]amino]-2-[(5-phenylsulfanyltetrazol-1-yl)methyl]pyrrolidine-1-carboxylate
    —— 8-fluoro-3,4-dihydro-2H-1,5-benzoxathiepine 915771-65-2 C9H9FOS
    8-fluoro-3,4-dihydro-2H-1,5-benzoxathiepine
    —— 1H-Pyrazol-3-amine, 1-[2-(2-pyrimidinylthio)ethyl]- 1340433-80-8 C9H11N5S
    1H-Pyrazol-3-amine, 1-[2-(2-pyrimidinylthio)ethyl]-
    —— 2-n-Amylthio-4,5,6-triaminopyrimidin 70805-46-8 C9H17N5S
    2-n-Amylthio-4,5,6-triaminopyrimidin
    —— tert-butyl methyl{[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methyl}carbamate 952191-77-4 C22H24N2O2S2
    tert-butyl methyl{[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methyl}carbamate
    —— 2-n-Amylthio-5-nitroso-4,6-diaminopyrimidin 70805-45-7 C9H15N5OS
    2-n-Amylthio-5-nitroso-4,6-diaminopyrimidin
    —— 1-[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methanamine 952191-75-2 C16H14N2S2
    1-[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methanamine
    —— tert-butyl {[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methyl}carbamate 952191-76-3 C21H22N2O2S2
    tert-butyl {[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methyl}carbamate
    —— 3,4-bis(decylsulfanyl)thiophene 913964-73-5 C24H44S3
    3,4-bis(decylsulfanyl)thiophene
    —— 2-(3-Chlorophenyl)sulfanyl-1-(2,5-dichlorothiophen-3-yl)ethanone 1405282-29-2 C12H7Cl3OS2
    2-(3-Chlorophenyl)sulfanyl-1-(2,5-dichlorothiophen-3-yl)ethanone
    —— 2,4-dichloro-N-{4-formyl-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridin-2-yl}-benzenesulfonamide 882500-09-6 C23H21Cl2N3O5S3
    2,4-dichloro-N-{4-formyl-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridin-2-yl}-benzenesulfonamide
    —— Benzenemethanamine, 3-bromo-I+/--methyl-4-[(1-methylethyl)thio]-, (I+/-R)- 1344948-05-5 C11H16BrNS
    Benzenemethanamine, 3-bromo-I+/--methyl-4-[(1-methylethyl)thio]-, (I+/-R)-
    —— 2-amino-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-isonicotinic acid pentyl ester 882500-06-3 C22H29N3O4S2
    2-amino-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-isonicotinic acid pentyl ester
    —— Benzenamine, 2-chloro-5-[(2-pyrazinylthio)methyl]- 1342772-42-2 C11H10ClN3S
    Benzenamine, 2-chloro-5-[(2-pyrazinylthio)methyl]-
    —— Pyrazine, 2-[(2-azidoethyl)thio]- 1343894-51-8 C6H7N5S
    Pyrazine, 2-[(2-azidoethyl)thio]-
    —— Pentanoic acid, 5-(2-pyrazinylthio)- 1344114-54-0 C9H12N2O2S
    Pentanoic acid, 5-(2-pyrazinylthio)-
    —— 3-(Propyldisulfanyl)propanoic acid 112401-23-7 C6H12O2S2
    3-(Propyldisulfanyl)propanoic acid
    —— 2,4-Dichloro-N-{4-hydroxy-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyrimidin-2-yl}-benzenesulfonamide 882496-56-2 C21H20Cl2N4O5S3
    2,4-Dichloro-N-{4-hydroxy-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyrimidin-2-yl}-benzenesulfonamide
    —— 2,4-dichloro-N-{4-(cyclopropyl-hydroxy-methyl)-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridin-2-yl}-benzenesulfonamide 882500-10-9 C26H27Cl2N3O5S3
    2,4-dichloro-N-{4-(cyclopropyl-hydroxy-methyl)-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridin-2-yl}-benzenesulfonamide
    —— 3-phenylsulfanyl-thioxanthen-9-one 875664-53-2 C19H12OS2
    3-phenylsulfanyl-thioxanthen-9-one