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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-cyclohexylsulfanyl-5-methyl-4-(m-tolylmethyl)-1H-pyrimidin-6-one 169772-02-5 C19H24N2OS
    2-cyclohexylsulfanyl-5-methyl-4-(m-tolylmethyl)-1H-pyrimidin-6-one
    —— 5,5-dimethyl-1-(2-propynylsulfonyl)-3-vinyl-2-cyclohexene 155996-25-1 C13H18O2S
    5,5-dimethyl-1-(2-propynylsulfonyl)-3-vinyl-2-cyclohexene
    —— (1E,3E)-1-methoxy-4-phenylsulfanyl-1,3-butadiene 67700-13-4 C11H12OS
    (1E,3E)-1-methoxy-4-phenylsulfanyl-1,3-butadiene
    —— 2-[2-(2-Sulfanylethylsulfanyl)ethylsulfanyl]ethanol 99805-41-1 C6H14OS3
    2-[2-(2-Sulfanylethylsulfanyl)ethylsulfanyl]ethanol
    —— methyl 3-(methylthio)-1,2,4-triazin-5-yl ketone oxime 153461-94-0 C6H8N4OS
    methyl 3-(methylthio)-1,2,4-triazin-5-yl ketone oxime
    —— 8-(6-(furan-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine 1289543-83-4 C22H24N6O3S
    8-(6-(furan-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine
    —— 1-methanesulfonyl-1-methylsulfanyl-ethane 67658-93-9 C4H10O2S2
    1-methanesulfonyl-1-methylsulfanyl-ethane
    —— 5-benzylsulfanyl-2,4-dihydro-[1,2,4]triazol-3-one 65479-47-2 C9H9N3OS
    5-benzylsulfanyl-2,4-dihydro-[1,2,4]triazol-3-one
    —— 3-(chloromethyl)-1,4-benzoxathian 65331-11-5 C9H9ClOS
    3-(chloromethyl)-1,4-benzoxathian
    —— [3-(4-chloro-phenylsulfanyl)-propyl]-dimethyl-amine 71177-72-5 C11H16ClNS
    [3-(4-chloro-phenylsulfanyl)-propyl]-dimethyl-amine
    —— 2,3-dihydrobenzo[b][1,4]oxathiine-2-carboxylic acid 92642-95-0 C9H8O3S
    2,3-dihydrobenzo[b][1,4]oxathiine-2-carboxylic acid
    —— erythro-2-methyl-3-(phenylthio)hexanoic acid methyl ester 137542-25-7 C15H22O2S
    erythro-2-methyl-3-(phenylthio)hexanoic acid methyl ester
    —— 3-Methyl-1-(4-phenylsulfanyl-3,4,5,6-tetrahydro-(2H)-pyran-4-yl)butane-1,3-diol 179806-69-0 C16H24O3S
    3-Methyl-1-(4-phenylsulfanyl-3,4,5,6-tetrahydro-(2H)-pyran-4-yl)butane-1,3-diol
    —— (2R,3R)-2-Methyl-1-(4-phenylsulfanyl-3,4,5,6-tetrahydro-(2H)-pyran-4-yl)propane-1,3-diol 179238-92-7 C15H22O3S
    (2R,3R)-2-Methyl-1-(4-phenylsulfanyl-3,4,5,6-tetrahydro-(2H)-pyran-4-yl)propane-1,3-diol
    —— (2S,3R)-2-Methyl-1-(4-phenylsulfanyl-3,4,5,6-tetrahydro-(2H)-pyran-4-yl)propane-1,3-diol 179238-95-0 C15H22O3S
    (2S,3R)-2-Methyl-1-(4-phenylsulfanyl-3,4,5,6-tetrahydro-(2H)-pyran-4-yl)propane-1,3-diol
    —— (2S,3S)-4-Benzyl-3-[3-hydroxy-2-methyl-1-oxo-3-[(4-phenylsulfanyl)-3,4,5,6-tetrahydro-(2H)-pyran-4-yl]propionyl]oxazolidin-2-one 179088-59-6 C25H29NO5S
    (2S,3S)-4-Benzyl-3-[3-hydroxy-2-methyl-1-oxo-3-[(4-phenylsulfanyl)-3,4,5,6-tetrahydro-(2H)-pyran-4-yl]propionyl]oxazolidin-2-one
    —— 1-[4-(phenylsulfanyl)tetrahydropyran-4-yl]but-3-en-1-one 511547-14-1 C15H18O2S
    1-[4-(phenylsulfanyl)tetrahydropyran-4-yl]but-3-en-1-one
    —— (1RS)-1-[4-(phenylsulfanyl)tetrahydropyran-4-yl]but-3-en-1-ol 511547-13-0 C15H20O2S
    (1RS)-1-[4-(phenylsulfanyl)tetrahydropyran-4-yl]but-3-en-1-ol
    —— (2S,3R)-4-Benzyl-3-[3-hydroxy-2-methyl-1-oxo-3-[(4-phenylsulfanyl)-3,4,5,6-tetrahydro-(2H)-pyran-4-yl]propionyl]oxazolidin-2-one 179238-94-9 C25H29NO5S
    (2S,3R)-4-Benzyl-3-[3-hydroxy-2-methyl-1-oxo-3-[(4-phenylsulfanyl)-3,4,5,6-tetrahydro-(2H)-pyran-4-yl]propionyl]oxazolidin-2-one
    —— 4-Hydroxy-4-(phenylsulfanyl-3,4,5,6-tetrahydro-(2H)-pyran-4-yl)butan-2-one 179088-61-0 C15H20O3S
    4-Hydroxy-4-(phenylsulfanyl-3,4,5,6-tetrahydro-(2H)-pyran-4-yl)butan-2-one
    —— 4-[Methoxy(phenylsulfanyl)methyl]-3,4,5,6-tetrahydro-(2H)-pyran-4-ol 294211-62-4 C13H18O3S
    4-[Methoxy(phenylsulfanyl)methyl]-3,4,5,6-tetrahydro-(2H)-pyran-4-ol
    —— Methyl 5-pyridin-2-ylsulfanylpentanoate 114050-40-7 C11H15NO2S
    Methyl 5-pyridin-2-ylsulfanylpentanoate
    —— 4-(Phenylsulfanyl)-3,4,5,6-tetrahydropyran-4(2H)-carboxaldehyde 179088-48-3 C12H14O2S
    4-(Phenylsulfanyl)-3,4,5,6-tetrahydropyran-4(2H)-carboxaldehyde
    —— 1,μ-dithio-dicarbonic acid-2-ethyl ester-1-diethylamide 3052-64-0 C8H15NO2S2
    1,μ-dithio-dicarbonic acid-2-ethyl ester-1-diethylamide
    —— 1,3-bis[3-(dimethylamino)propyl]-5H-pyrimido[4,5-b][1,4]benzothiazine-2,4-dione 1061317-93-8 C20H29N5O2S
    1,3-bis[3-(dimethylamino)propyl]-5H-pyrimido[4,5-b][1,4]benzothiazine-2,4-dione
    —— 1,5-dihydro-10-thiaisoalloxazine 65693-75-6 C10H7N3O2S
    1,5-dihydro-10-thiaisoalloxazine
    —— S-(4,4-dimethylpent-2-ynyl) N,N-di(propan-2-yl)carbamothioate 868704-58-9 C14H25NOS
    S-(4,4-dimethylpent-2-ynyl) N,N-di(propan-2-yl)carbamothioate
    —— Dimaprit dihydrochloride 23256-33-9 C6H16ClN3S
    Dimaprit dihydrochloride
    —— Dimaprit hydrochloride 23256-33-9 C6H15N3S*2ClH
    Dimaprit hydrochloride
    —— trans-1-(phenylthio)-6-oxo-4-oxahept-1-ene 108270-23-1 C12H14O2S
    trans-1-(phenylthio)-6-oxo-4-oxahept-1-ene
    —— 2-benzylmercapto-5-(2-hydroxyphenyl)-1,3,4-oxadiazole 158361-94-5 C15H12N2O2S
    2-benzylmercapto-5-(2-hydroxyphenyl)-1,3,4-oxadiazole
    —— 3-Amino-2-cyano-4-methyl-2-pententhiocarboxamid 41808-32-6 C7H11N3S
    3-Amino-2-cyano-4-methyl-2-pententhiocarboxamid
    —— (2R)-2-{[2-amino-5-(benzylsulfanyl)-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino}pentan-1-ol 849943-17-5 C17H21N5OS2
    (2R)-2-{[2-amino-5-(benzylsulfanyl)-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino}pentan-1-ol
    —— (E)-2-hydroxy-N'-((2-(p-tolylthio)quinolin-3-yl)methylene)benzohydrazide 1443242-48-5 C24H19N3O2S
    (E)-2-hydroxy-N'-((2-(p-tolylthio)quinolin-3-yl)methylene)benzohydrazide
    —— benzylmercapto-[1,3,4]thiadiazole 42609-18-7 C9H8N2S2
    benzylmercapto-[1,3,4]thiadiazole
    —— methyl 2-(tert-butylsulfonyl)acetate 63864-29-9 C7H14O4S
    methyl 2-(tert-butylsulfonyl)acetate
    —— 2,4-Dihydroxy-2-methyl-4-[(4'-phenylsulfanyl)thianyl]butane 179806-70-3 C16H24O2S2
    2,4-Dihydroxy-2-methyl-4-[(4'-phenylsulfanyl)thianyl]butane
    —— 4-(Phenylsulfanyl)thiane-4-carboxaldehyde 179088-49-4 C12H14OS2
    4-(Phenylsulfanyl)thiane-4-carboxaldehyde
    —— 5-benzylsulfanyl-[1,2,3,4]thiatriazole 34930-32-0 C8H7N3S2
    5-benzylsulfanyl-[1,2,3,4]thiatriazole
    —— 1-[2-(2-Butylsulfinylethyldisulfanyl)ethylsulfinyl]butane 1133065-26-5 C12H26O2S4
    1-[2-(2-Butylsulfinylethyldisulfanyl)ethylsulfinyl]butane
    —— [5-(4-methyl-5-oxy-furazan-3-yl)-1<i>H</i>-[1,2,4]triazol-3-ylsulfanyl]-acetic acid hydrazide 50412-83-4 C7H9N7O3S
    [5-(4-methyl-5-oxy-furazan-3-yl)-1<i>H</i>-[1,2,4]triazol-3-ylsulfanyl]-acetic acid hydrazide
    —— [5-(4-methyl-furazan-3-yl)-1<i>H</i>-[1,2,4]triazol-3-ylsulfanyl]-acetic acid hydrazide 50412-82-3 C7H9N7O2S
    [5-(4-methyl-furazan-3-yl)-1<i>H</i>-[1,2,4]triazol-3-ylsulfanyl]-acetic acid hydrazide
    —— 1-isocyanato-2-methanesulfonyl-ethane 631912-32-8 C4H7NO3S
    1-isocyanato-2-methanesulfonyl-ethane
    —— Bis(2-butylsulfinylethyl)phosphane 1159005-17-0 C12H27O2PS2
    Bis(2-butylsulfinylethyl)phosphane
    —— 1-[3-(N,N-dimethylamino)propylthio]-4-bromobenzene 403793-24-8 C11H16BrNS
    1-[3-(N,N-dimethylamino)propylthio]-4-bromobenzene
    —— 2-Butylsulfinylethylphosphane 1159005-16-9 C6H15OPS
    2-Butylsulfinylethylphosphane
    —— Tris(2-butylsulfinylethyl)phosphane 1159005-18-1 C18H39O3PS3
    Tris(2-butylsulfinylethyl)phosphane
    —— isocyanato-methanesulfonyl-methane 1161826-12-5 C3H5NO3S
    isocyanato-methanesulfonyl-methane
    —— 4,5-Dihydrothieno[2,3-d]-1,3-dithiol-2-thion 67188-87-8 C5H4S4
    4,5-Dihydrothieno[2,3-d]-1,3-dithiol-2-thion
    —— 3-({4-[(1-methylazetidin-3-yl)oxy]phenyl}thio)-N-(1-methyl-1H-pyrazol-3-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide 1164103-28-9 C23H24N8O2S2
    3-({4-[(1-methylazetidin-3-yl)oxy]phenyl}thio)-N-(1-methyl-1H-pyrazol-3-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide