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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-ethyl-6-(methylthio)-1-(3-phenylpropyl)uracil 172256-47-2 C16H20N2O2S
    5-ethyl-6-(methylthio)-1-(3-phenylpropyl)uracil
    —— 1-butyl-5-ethyl-6-(methylthio)uracil 172256-46-1 C11H18N2O2S
    1-butyl-5-ethyl-6-(methylthio)uracil
    —— 5-Ethyl-6-methylsulfanyl-1-propoxypyrimidine-2,4-dione 191472-44-3 C10H16N2O3S
    5-Ethyl-6-methylsulfanyl-1-propoxypyrimidine-2,4-dione
    —— 1-Butoxy-5-ethyl-6-methylsulfanylpyrimidine-2,4-dione 191472-46-5 C11H18N2O3S
    1-Butoxy-5-ethyl-6-methylsulfanylpyrimidine-2,4-dione
    —— 5-Methyl-6-methylsulfanyl-1-propoxypyrimidine-2,4-dione 191472-58-9 C9H14N2O3S
    5-Methyl-6-methylsulfanyl-1-propoxypyrimidine-2,4-dione
    —— 5-Methyl-6-methylsulfanyl-1-(2-phenylethoxy)pyrimidine-2,4-dione 191472-61-4 C14H16N2O3S
    5-Methyl-6-methylsulfanyl-1-(2-phenylethoxy)pyrimidine-2,4-dione
    —— 3-(phenylthio)propanal dimethyl acetal 52072-17-0 C11H16O2S
    3-(phenylthio)propanal dimethyl acetal
    —— 1-Butyl-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione 172256-48-3 C12H20N2O2S
    1-Butyl-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione
    —— 5-Methyl-6-methylsulfanyl-1-phenylmethoxypyrimidine-2,4-dione 191472-60-3 C13H14N2O3S
    5-Methyl-6-methylsulfanyl-1-phenylmethoxypyrimidine-2,4-dione
    —— 6-Methylsulfanyl-1-(2-phenylethoxy)-5-propan-2-ylpyrimidine-2,4-dione 191472-40-9 C16H20N2O3S
    6-Methylsulfanyl-1-(2-phenylethoxy)-5-propan-2-ylpyrimidine-2,4-dione
    —— 1-Butoxy-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione 191472-38-5 C12H20N2O3S
    1-Butoxy-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione
    —— 1-(2-Methoxyethoxy)-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione 191472-42-1 C11H18N2O4S
    1-(2-Methoxyethoxy)-6-methylsulfanyl-5-propan-2-ylpyrimidine-2,4-dione
    —— 6-Methylsulfanyl-1-phenylmethoxy-5-propan-2-ylpyrimidine-2,4-dione 191472-39-6 C15H18N2O3S
    6-Methylsulfanyl-1-phenylmethoxy-5-propan-2-ylpyrimidine-2,4-dione
    —— 4-(benzylthio)-N'-hydroxybenzocarboximidamide 947689-76-1 C14H14N2OS
    4-(benzylthio)-N'-hydroxybenzocarboximidamide
    —— 4-Chlor-2-ethylmercapto-pyrimidin 98198-74-4 C6H7ClN2S
    4-Chlor-2-ethylmercapto-pyrimidin
    —— (1R,2S)-2-methylsulfanylthioxocarbonyloxycyclopentanecarboxylic acid ethyl ester 162084-62-0 C10H16O3S2
    (1R,2S)-2-methylsulfanylthioxocarbonyloxycyclopentanecarboxylic acid ethyl ester
    —— 2,2-difluoroethanethioamide 180002-32-8 C2H3F2NS
    2,2-difluoroethanethioamide
    —— 3-Methylmercapto-6-(4-aminobenzyl)-2,5-dihydro-1,2,4-triazin-5-on 77441-96-4 C11H12N4OS
    3-Methylmercapto-6-(4-aminobenzyl)-2,5-dihydro-1,2,4-triazin-5-on
    —— N-benzal-5-(methylthio)pyridine-2-amine 1374129-87-9 C13H12N2S
    N-benzal-5-(methylthio)pyridine-2-amine
    —— 2-(2-amino-4-chloro-phenylsulfanyl)-benzoic acid methyl ester 93535-13-8 C14H12ClNO2S
    2-(2-amino-4-chloro-phenylsulfanyl)-benzoic acid methyl ester
    —— 2,3-Bis-butylsulfanyl-6,7,9,10,12,13,15,16,18,19-decahydro-5,8,11,14,17,20-hexaoxa-benzocyclooctadecene 150921-07-6 C24H40O6S2
    2,3-Bis-butylsulfanyl-6,7,9,10,12,13,15,16,18,19-decahydro-5,8,11,14,17,20-hexaoxa-benzocyclooctadecene
    —— (3S)-3-methyl-4-phenylsulfanylbutanenitrile 157733-10-3 C11H13NS
    (3S)-3-methyl-4-phenylsulfanylbutanenitrile
    —— 1,1-bis(3-phenylpropoxymethyl)-3-(p-tolylsulfanyl)cyclobutane 1221171-40-9 C31H38O2S
    1,1-bis(3-phenylpropoxymethyl)-3-(p-tolylsulfanyl)cyclobutane
    —— S,S'-bis-p-chlorophenyl dithiocarbonate 24455-27-4 C13H8Cl2OS2
    S,S'-bis-p-chlorophenyl dithiocarbonate
    —— N(2-Chlorethyl)-S-(p-chlorphenylthiocarbamat) 22039-90-3 C9H9Cl2NOS
    N(2-Chlorethyl)-S-(p-chlorphenylthiocarbamat)
    —— (3S)-3-mercapto-1-heptanol 914910-69-3 C7H16OS
    (3S)-3-mercapto-1-heptanol
    —— 2,5-bis(4-fluorobenzylthio)-1,3,4-thiadiazole 401641-24-5 C16H12F2N2S3
    2,5-bis(4-fluorobenzylthio)-1,3,4-thiadiazole
    —— 2-[(E)-hept-2-enyl]sulfanylphenol 210350-96-2 C13H18OS
    2-[(E)-hept-2-enyl]sulfanylphenol
    —— 3-Methylsulfanylhept-1-ene 90370-34-6 C8H16S
    3-Methylsulfanylhept-1-ene
    —— 2-(4-fluorobenzylthio)pyrimidine-4,6-diol 401581-40-6 C11H9FN2O2S
    2-(4-fluorobenzylthio)pyrimidine-4,6-diol
    —— 4-(4-aminobenzyl)-3-n-butyl-5-(carbomethoxymethylthio)-4H-1,2,4-triazole 134402-56-5 C16H22N4O2S
    4-(4-aminobenzyl)-3-n-butyl-5-(carbomethoxymethylthio)-4H-1,2,4-triazole
    —— 1-Fluoro-4-[(3-chloro-4-fluorophenyl)sulfanylmethyl]benzene 1443302-30-4 C13H9ClF2S
    1-Fluoro-4-[(3-chloro-4-fluorophenyl)sulfanylmethyl]benzene
    —— N,N-dimethylthiocarbamoyl-glycolonitrile 153648-58-9 C5H8N2OS
    N,N-dimethylthiocarbamoyl-glycolonitrile
    —— 4-(4-aminobenzyl)-3-n-butyl-5-phenylthio-4H-1,2,4-triazole 134402-65-6 C19H22N4S
    4-(4-aminobenzyl)-3-n-butyl-5-phenylthio-4H-1,2,4-triazole
    —— 3-n-butyl-4-(4-nitrobenzyl)-5-(phenylthio)-4H-1,2,4-triazole 134402-64-5 C19H20N4O2S
    3-n-butyl-4-(4-nitrobenzyl)-5-(phenylthio)-4H-1,2,4-triazole
    —— 5-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidin-1-yl]-3,4-dihydro-2H-pyrrol-2-one 1156466-89-5 C24H26BrN7O3S
    5-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidin-1-yl]-3,4-dihydro-2H-pyrrol-2-one
    —— 4-(4-aminobenzyl)-3-n-butyl-5-(N-methylcarbamoylmethylthio)-4H-1,2,4-triazole 134402-58-7 C16H23N5OS
    4-(4-aminobenzyl)-3-n-butyl-5-(N-methylcarbamoylmethylthio)-4H-1,2,4-triazole
    —— 4-(4-aminobenzyl)-3-n-butyl-5-<(4-chlorobenzyl)thio>-4H-1,2,4-triazole 134425-24-4 C20H23ClN4S
    4-(4-aminobenzyl)-3-n-butyl-5-<(4-chlorobenzyl)thio>-4H-1,2,4-triazole
    —— 4-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidin-1-yl]-4-oxobutanamide 1156466-88-4 C24H28BrN7O4S
    4-[4-(2-{6-amino-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-9-yl}ethyl)piperidin-1-yl]-4-oxobutanamide
    —— 5-((4-fluorobenzyl)thio)-4H-1,2,4-triazol-3-amine 714203-98-2 C9H9FN4S
    5-((4-fluorobenzyl)thio)-4H-1,2,4-triazol-3-amine
    —— N-methyl-2-(pyrid-2-yl)-1,3-dithiane-2-carbothioamide 82081-52-5 C11H14N2S3
    N-methyl-2-(pyrid-2-yl)-1,3-dithiane-2-carbothioamide
    —— ethyl 2-butyl-4-(phenylthio)-1H-imidazole-5-carboxylate 140917-49-3 C16H20N2O2S
    ethyl 2-butyl-4-(phenylthio)-1H-imidazole-5-carboxylate
    —— ethyl 2-butyl-4-thiophen-2-ylsulfanyl-1H-imidazole-5-carboxylate 164412-29-7 C14H18N2O2S2
    ethyl 2-butyl-4-thiophen-2-ylsulfanyl-1H-imidazole-5-carboxylate
    —— methyl thioallophanimidate 41160-90-1 C3H7N3OS
    methyl thioallophanimidate
    —— 2-(pyrid-2-yl)-1,3-dithiane-2-carbothioamide 82081-48-9 C10H12N2S3
    2-(pyrid-2-yl)-1,3-dithiane-2-carbothioamide
    —— Methyl 2-(pyrid-2-yl)-1,3-dithiane-2-carbodithioate 82081-47-8 C11H13NS4
    Methyl 2-(pyrid-2-yl)-1,3-dithiane-2-carbodithioate
    —— (2-methyl-6-methylidene-8-phenylsulfanyloct-1-en-3-yl) acetate 87639-59-6 C18H24O2S
    (2-methyl-6-methylidene-8-phenylsulfanyloct-1-en-3-yl) acetate
    —— 2-[[3-Hydroxy-2-(hydroxymethyl)propyl]sulfanylmethyl]propane-1,3-diol 189223-86-7 C8H18O4S
    2-[[3-Hydroxy-2-(hydroxymethyl)propyl]sulfanylmethyl]propane-1,3-diol
    —— 5-ethylsulfanyl-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine 50621-52-8 C11H13N3S2
    5-ethylsulfanyl-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— ethyl N-(dimethylcarbamoyl)carbamimidothioate 41160-49-0 C6H13N3OS
    ethyl N-(dimethylcarbamoyl)carbamimidothioate