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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]-3-(tetrahydro-2H-pyran-4-yl)propanoic acid 1192004-52-6 C13H20N2O3S
    2-[1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]-3-(tetrahydro-2H-pyran-4-yl)propanoic acid
    —— 5-(3-cyclopropylmethyl-5-isopropyl-6-methoxy-2-methyl-pyridin-4-ylsulfanyl)-isophthalonitrile 1205514-42-6 C22H23N3OS
    5-(3-cyclopropylmethyl-5-isopropyl-6-methoxy-2-methyl-pyridin-4-ylsulfanyl)-isophthalonitrile
    —— 7-hydroxy-6-methyl-8-nitro-2,3-dihydro-thiazolo[3,2-a]pyridin-5-one 1303510-46-4 C8H8N2O4S
    7-hydroxy-6-methyl-8-nitro-2,3-dihydro-thiazolo[3,2-a]pyridin-5-one
    —— 7-Hydroxy-8-nitro-2,3-dihydro-thiazolo[3,2-a]pyridin-5-one 1303510-58-8 C7H6N2O4S
    7-Hydroxy-8-nitro-2,3-dihydro-thiazolo[3,2-a]pyridin-5-one
    —— 5-[1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]-6-(tetrahydro-2H-pyran-4-yl)-1-{5-[(tetrahydro-2H-pyran-2-yloxy)methyl]-1,3-thiazol-2-yl}hexane-1,4-dione 1192004-55-9 C25H35N3O5S2
    5-[1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]-6-(tetrahydro-2H-pyran-4-yl)-1-{5-[(tetrahydro-2H-pyran-2-yloxy)methyl]-1,3-thiazol-2-yl}hexane-1,4-dione
    —— N-Carbamothioylethanethioamide 91936-07-1 C3H6N2S2
    N-Carbamothioylethanethioamide
    —— (3-Bromo-4-((methoxymethoxy)methyl)phenyl)(phenyl)sulfane 1226773-52-9 C15H15BrO2S
    (3-Bromo-4-((methoxymethoxy)methyl)phenyl)(phenyl)sulfane
    —— Isopropyl-trimethyl-thioharnstoff 32773-12-9 C7H16N2S
    Isopropyl-trimethyl-thioharnstoff
    —— Propanamide, 2-methyl-2-(methylsulfonyl)-N-2-propen-1-yl- 1341845-76-8 C8H15NO3S
    Propanamide, 2-methyl-2-(methylsulfonyl)-N-2-propen-1-yl-
    —— Cyclopentanemethanamine, N-[2-(ethylsulfonyl)ethyl]-I+/--methyl- 1342595-29-2 C11H23NO2S
    Cyclopentanemethanamine, N-[2-(ethylsulfonyl)ethyl]-I+/--methyl-
    —— 3-(5-chloro-pyridin-2-ylsulfanyl)-benzoic acid 1227843-19-7 C12H8ClNO2S
    3-(5-chloro-pyridin-2-ylsulfanyl)-benzoic acid
    —— 3-aminomethyl-6-[(3,3-dimethylcyclohexyl)thio]-pyridine 928648-47-9 C14H22N2S
    3-aminomethyl-6-[(3,3-dimethylcyclohexyl)thio]-pyridine
    —— <3-Chlor-2-methyl-propyl>-ethyl-sulfid 13012-63-0 C6H13ClS
    <3-Chlor-2-methyl-propyl>-ethyl-sulfid
    —— 2-[2-(2-fluoromethylphenylsulfanyl)ethyl]aldehyde 758717-10-1 C10H11FOS
    2-[2-(2-fluoromethylphenylsulfanyl)ethyl]aldehyde
    —— 4-Methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-pyridin-3-ylamine 96592-39-1 C10H12N4S
    4-Methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-pyridin-3-ylamine
    —— 3-Pyridinamine, 2-[(1,1-dimethylethyl)thio]-4-methyl- 1344306-64-4 C10H16N2S
    3-Pyridinamine, 2-[(1,1-dimethylethyl)thio]-4-methyl-
    —— 2-Phenylthio-3-amino-4-methylpyridin 53421-01-5 C12H12N2S
    2-Phenylthio-3-amino-4-methylpyridin
    —— 2-Methylthio-4-hydroxy-6-fluormethyl-pyrimidin 6096-24-8 C6H7FN2OS
    2-Methylthio-4-hydroxy-6-fluormethyl-pyrimidin
    —— 3,3-dimethyl-2H-1-benzothiophene-6-carboxylic acid 874279-53-5 C11H12O2S
    3,3-dimethyl-2H-1-benzothiophene-6-carboxylic acid
    —— N-[3-(3-dimethoxymethyl-4-nitro-phenylsulfanyl)-phenyl]-benzenesulfonamide 1184181-73-4 C21H20N2O6S2
    N-[3-(3-dimethoxymethyl-4-nitro-phenylsulfanyl)-phenyl]-benzenesulfonamide
    —— 2-Pyrazinecarboxylic acid, 5-(2-pyrazinylthio)- 1344240-98-7 C9H6N4O2S
    2-Pyrazinecarboxylic acid, 5-(2-pyrazinylthio)-
    —— 3,3-dimethyl-2H-1-benzothiophene-4-carboxylic acid 874279-52-4 C11H12O2S
    3,3-dimethyl-2H-1-benzothiophene-4-carboxylic acid
    —— ethyl N-(4-sulfanylbutoxy)ethanimidate 60302-08-1 C8H17NO2S
    ethyl N-(4-sulfanylbutoxy)ethanimidate
    —— ethyl 4-ethyl-2-oxo-6-[4-(methylthio)phenyl]-2H-pyran-3-carboxylate 675618-12-9 C17H18O4S
    ethyl 4-ethyl-2-oxo-6-[4-(methylthio)phenyl]-2H-pyran-3-carboxylate
    —— Acetamide, 2-[(3-amino-5-fluorophenyl)thio]-N-ethyl- 1340191-32-3 C10H13FN2OS
    Acetamide, 2-[(3-amino-5-fluorophenyl)thio]-N-ethyl-
    —— ethyl 3-(1,5-dimethylpyrazol-3-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-6-carboxylate 873804-57-0 C12H14N6O2S
    ethyl 3-(1,5-dimethylpyrazol-3-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-6-carboxylate
    —— 2-[[4-(3-Chlorophenyl)-2-thiazolyl]thio]acetic acid 43045-10-9 C11H8ClNO2S2
    2-[[4-(3-Chlorophenyl)-2-thiazolyl]thio]acetic acid
    —— 4-Thiazoleacetic acid, 2-[[2-(acetylamino)ethyl]thio]- 1343659-81-3 C9H12N2O3S2
    4-Thiazoleacetic acid, 2-[[2-(acetylamino)ethyl]thio]-
    —— 2-<4'-(pyridin-4''-yl)thiazol-4'-ylthio>acetic acid 80947-89-3 C10H8N2O2S2
    2-<4'-(pyridin-4''-yl)thiazol-4'-ylthio>acetic acid
    —— 4-Chloro-2-(2-fluorophenyl)sulfanyl-1-nitrobenzene 872983-65-8 C12H7ClFNO2S
    4-Chloro-2-(2-fluorophenyl)sulfanyl-1-nitrobenzene
    —— Cyano-ethylthiocarbamoyl-acetic acid propyl ester 623558-70-3 C9H14N2O2S
    Cyano-ethylthiocarbamoyl-acetic acid propyl ester
    —— (S)-2-(2-phenylsulfanylethyl)piperazine 660862-64-6 C12H18N2S
    (S)-2-(2-phenylsulfanylethyl)piperazine
    —— 4-Chloro-2-(2-fluorophenyl)sulfanylaniline 872983-67-0 C12H9ClFNS
    4-Chloro-2-(2-fluorophenyl)sulfanylaniline
    —— N-[(1S)-1-[4-[4-chloro-2-(1H-imidazol-2-ylsulfanyl)phenyl]sulfonylphenyl]ethyl]-1,1,1-trifluoromethanesulfonamide 447460-41-5 C18H15ClF3N3O4S3
    N-[(1S)-1-[4-[4-chloro-2-(1H-imidazol-2-ylsulfanyl)phenyl]sulfonylphenyl]ethyl]-1,1,1-trifluoromethanesulfonamide
    —— N-(2-Chloroethyl)-2-(decane-1-sulfonyl)acetamide 646482-98-6 C14H28ClNO3S
    N-(2-Chloroethyl)-2-(decane-1-sulfonyl)acetamide
    —— 18F-propylthiol 852954-26-8 C3H7FS
    18F-propylthiol
    —— 6-[2-(tert-butyl-dimethyl-silanyloxy)-ethylsulfanyl]-2-methyl-pyridin-3-ylamine 897732-89-7 C14H26N2OSSi
    6-[2-(tert-butyl-dimethyl-silanyloxy)-ethylsulfanyl]-2-methyl-pyridin-3-ylamine
    —— 6-[2-(tert-butyl-dimethyl-silanyloxy)-ethylsulfanyl]-2-methyl-3-nitro-pyridine 897732-88-6 C14H24N2O3SSi
    6-[2-(tert-butyl-dimethyl-silanyloxy)-ethylsulfanyl]-2-methyl-3-nitro-pyridine
    —— 2-[(3-Chloro-2-pyridinyl)thio]acetaldehyde 690945-51-8 C7H6ClNOS
    2-[(3-Chloro-2-pyridinyl)thio]acetaldehyde
    —— 1-Butanamine, 4-[(3-chloro-2-pyridinyl)thio]-N-propyl- 1339874-94-0 C12H19ClN2S
    1-Butanamine, 4-[(3-chloro-2-pyridinyl)thio]-N-propyl-
    —— 3-(2-Chlorophenyl)-1-(2-methylsulfanyl-1,3-thiazol-5-yl)prop-2-yn-1-one 905300-67-6 C13H8ClNOS2
    3-(2-Chlorophenyl)-1-(2-methylsulfanyl-1,3-thiazol-5-yl)prop-2-yn-1-one
    —— 3-Methanesulfinylbutan-1-amine 1394042-27-3 C5H13NOS
    3-Methanesulfinylbutan-1-amine
    —— Propanoic acid, 2-[(3-chloro-2-pyridinyl)thio]-, hydrazide 1343697-78-8 C8H10ClN3OS
    Propanoic acid, 2-[(3-chloro-2-pyridinyl)thio]-, hydrazide
    —— Benzenecarboximidamide, 2-[[(5-chloro-2-pyridinyl)thio]methyl]-5-fluoro- 1379260-16-8 C13H11ClFN3S
    Benzenecarboximidamide, 2-[[(5-chloro-2-pyridinyl)thio]methyl]-5-fluoro-
    —— Pyridine, 5-bromo-2-[(3-pyrrolidinylmethyl)thio]- 1338990-69-4 C10H13BrN2S
    Pyridine, 5-bromo-2-[(3-pyrrolidinylmethyl)thio]-
    —— 1-Propanol, 3-[[4-(1-aminoethyl)phenyl]thio]- 1342502-30-0 C11H17NOS
    1-Propanol, 3-[[4-(1-aminoethyl)phenyl]thio]-
    —— 3-Thiopheneethanamine, I(2)-[(5-chloro-2-pyridinyl)thio]- 1344070-00-3 C11H11ClN2S2
    3-Thiopheneethanamine, I(2)-[(5-chloro-2-pyridinyl)thio]-
    —— Benzeneethanamine, I(2)-[(5-chloro-2-pyridinyl)thio]-3-fluoro- 1481480-77-6 C13H12ClFN2S
    Benzeneethanamine, I(2)-[(5-chloro-2-pyridinyl)thio]-3-fluoro-
    —— Benzenamine, 2-[(3-bromo-2-pyridinyl)thio]-3-chloro- 1339210-39-7 C11H8BrClN2S
    Benzenamine, 2-[(3-bromo-2-pyridinyl)thio]-3-chloro-
    —— 1,2-Bis[(3-methylphenyl)sulfanyl]benzene 1617520-46-3 C20H18S2
    1,2-Bis[(3-methylphenyl)sulfanyl]benzene