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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(2-chlorophenylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide 1057256-52-6 C26H19ClN2O4S2
    N-(2-chlorophenylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide
    —— N-(3-chlorophenylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide 1057256-54-8 C26H19ClN2O4S2
    N-(3-chlorophenylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide
    —— N-(4,5-dichlorothiophen-2-ylsulfonyl)-2-(3-(phenylthio)-1H-indol-4-yloxy)acetamide 1057256-18-4 C20H14Cl2N2O4S3
    N-(4,5-dichlorothiophen-2-ylsulfonyl)-2-(3-(phenylthio)-1H-indol-4-yloxy)acetamide
    —— 2-(3-(benzo[d]thiazol-2-ylthio)-1H-indol-4-yloxy)-N-(4,5-dichlorothiophen-2-ylsulfonyl)acetamide 1057256-13-9 C21H13Cl2N3O4S4
    2-(3-(benzo[d]thiazol-2-ylthio)-1H-indol-4-yloxy)-N-(4,5-dichlorothiophen-2-ylsulfonyl)acetamide
    —— 2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)-N-(phenylsulfonyl)acetamide 1057256-42-4 C26H20N2O4S2
    2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)-N-(phenylsulfonyl)acetamide
    —— 2-(3-(4-chlorophenylthio)-1H-indol-4-yloxy)-N-(4,5-dichlorothiophen-2-ylsulfonyl)acetamide 1057256-08-2 C20H13Cl3N2O4S3
    2-(3-(4-chlorophenylthio)-1H-indol-4-yloxy)-N-(4,5-dichlorothiophen-2-ylsulfonyl)acetamide
    —— N-(4,5-dichlorothiophen-2-ylsulfonyl)-2-(3-(4-methoxyphenylthio)-1H-indol-4-yloxy)acetamide 1057256-20-8 C21H16Cl2N2O5S3
    N-(4,5-dichlorothiophen-2-ylsulfonyl)-2-(3-(4-methoxyphenylthio)-1H-indol-4-yloxy)acetamide
    —— N-(4,5-dichlorothiophen-2-ylsulfonyl)-2-(3-(3,4-dimethoxyphenylthio)-1H-indol-4-yloxy)acetamide 1057256-04-8 C22H18Cl2N2O6S3
    N-(4,5-dichlorothiophen-2-ylsulfonyl)-2-(3-(3,4-dimethoxyphenylthio)-1H-indol-4-yloxy)acetamide
    —— N-(3,5-dichlorophenylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide 1124195-74-9 C26H18Cl2N2O4S2
    N-(3,5-dichlorophenylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide
    —— N-(4-methoxyphenylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide 1057256-56-0 C27H22N2O5S2
    N-(4-methoxyphenylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide
    —— N-(5-chlorothiophen-2-ylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide 1057256-39-9 C24H17ClN2O4S3
    N-(5-chlorothiophen-2-ylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide
    —— N-(3,5-dimethylisoxazol-4-ylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide 1057257-15-4 C25H21N3O5S2
    N-(3,5-dimethylisoxazol-4-ylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide
    —— N-(3,5-difluorophenylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide 1057256-66-2 C26H18F2N2O4S2
    N-(3,5-difluorophenylsulfonyl)-2-(3-(naphthalen-2-ylthio)-1H-indol-4-yloxy)acetamide
    —— N-(4,5-dichlorothiophen-2-ylsulfonyl)-2-(3-(2,5-dimethoxyphenylthio)-1H-indol-4-yloxy)acetamide 1057256-14-0 C22H18Cl2N2O6S3
    N-(4,5-dichlorothiophen-2-ylsulfonyl)-2-(3-(2,5-dimethoxyphenylthio)-1H-indol-4-yloxy)acetamide
    —— 2-(2-Methanesulfinyl-ethylamino)-ethanol 73761-83-8 C5H13NO2S
    2-(2-Methanesulfinyl-ethylamino)-ethanol
    —— (3S,4R,5R)-4,5-diallyl-3-phenylthio-dihydrofuran-2-one 920502-63-2 C16H18O2S
    (3S,4R,5R)-4,5-diallyl-3-phenylthio-dihydrofuran-2-one
    —— (3S,4R,5R)-4-allyl-5-(2-hydroxyethyl)-3-phenylthio-dihydrofuran-2-one 920502-62-1 C15H18O3S
    (3S,4R,5R)-4-allyl-5-(2-hydroxyethyl)-3-phenylthio-dihydrofuran-2-one
    —— (2R,3R,4S)-[5-oxo-4-(phenylthio)-2-(2-tert-butyldiphenylsilyloxy)ethyl-tetrahydrofuran-3-yl]acetic acid 920502-56-3 C30H34O5SSi
    (2R,3R,4S)-[5-oxo-4-(phenylthio)-2-(2-tert-butyldiphenylsilyloxy)ethyl-tetrahydrofuran-3-yl]acetic acid
    —— (3S,4R,5R)-4-(2-hydroxy-ethyl)-3-phenylthio-5-(2-tert-butyldiphenylsilyloxy)ethyl-dihydrofuran-2-one 920502-57-4 C30H36O4SSi
    (3S,4R,5R)-4-(2-hydroxy-ethyl)-3-phenylthio-5-(2-tert-butyldiphenylsilyloxy)ethyl-dihydrofuran-2-one
    —— (3S,4R,5R)-4-allyl-3-phenylthio-5-(2-tert-butyldiphenylsilyloxy)ethyl-dihydrofuran-2-one 920502-58-5 C31H36O3SSi
    (3S,4R,5R)-4-allyl-3-phenylthio-5-(2-tert-butyldiphenylsilyloxy)ethyl-dihydrofuran-2-one
    —— 2-methylthio-5-methyl-6-[1-hydroxy-1-(phenyl)methyl]cytosine 1093390-12-5 C13H15N3OS
    2-methylthio-5-methyl-6-[1-hydroxy-1-(phenyl)methyl]cytosine
    —— 2-methylthio-5-methyl-6-[1-chloro-1-(phenyl)methyl]cytosine 1093390-14-7 C13H14ClN3S
    2-methylthio-5-methyl-6-[1-chloro-1-(phenyl)methyl]cytosine
    —— Ethanamine, 2-[(1-butyl-3,5-dimethyl-1H-pyrazol-4-yl)thio]- 1429904-05-1 C11H21N3S
    Ethanamine, 2-[(1-butyl-3,5-dimethyl-1H-pyrazol-4-yl)thio]-
    —— 4-[2,6-dinitro-4-(trifluoromethyl)phenylsulfanyl]phenol 1137560-32-7 C13H7F3N2O5S
    4-[2,6-dinitro-4-(trifluoromethyl)phenylsulfanyl]phenol
    —— 8-(4-chlorophenylthio)-6-methyl-3-phenethylthiomethylimidazo[1,2-a]pyridine 1076691-36-5 C23H21ClN2S2
    8-(4-chlorophenylthio)-6-methyl-3-phenethylthiomethylimidazo[1,2-a]pyridine
    —— 5-[2-(4-Methylphenyl)ethynyl]-2-methylsulfanylpyrimidine 1172612-55-3 C14H12N2S
    5-[2-(4-Methylphenyl)ethynyl]-2-methylsulfanylpyrimidine
    —— 5-[2-(3-Methylphenyl)ethynyl]-2-methylsulfanylpyrimidine 1172612-54-2 C14H12N2S
    5-[2-(3-Methylphenyl)ethynyl]-2-methylsulfanylpyrimidine
    —— N-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]formamide 1185189-96-1 C16H17IN2O2S
    N-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]formamide
    —— 5-aminomethyl-4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-pyridin-2(1H)-one 1185189-94-9 C15H17IN2OS
    5-aminomethyl-4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-pyridin-2(1H)-one
    —— 4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarbonitrile 1185189-92-7 C15H13IN2OS
    4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylcarbonitrile
    —— 3-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]-5-methyl-3H-imidazol-4-ylcarbonitrile 1185190-29-7 C20H19IN4OS
    3-[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]-5-methyl-3H-imidazol-4-ylcarbonitrile
    —— [(4R,6R)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl] butanoate 1202395-63-8 C12H16O2S2
    [(4R,6R)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl] butanoate
    —— 4-[(2-bromo-4-ethyl-N-methylanilino)methyl]-7-methyl-2H-thiopyrano[3,2-c]pyran-5-one 1205745-53-4 C19H20BrNO2S
    4-[(2-bromo-4-ethyl-N-methylanilino)methyl]-7-methyl-2H-thiopyrano[3,2-c]pyran-5-one
    —— 3-(5-(cyclopropylmethyl)-3-isopropyl-6-methyl-2-oxo-1,2-dihydropyridin-4-ylthio)-5-methylbenzonitrile 1205513-56-9 C21H24N2OS
    3-(5-(cyclopropylmethyl)-3-isopropyl-6-methyl-2-oxo-1,2-dihydropyridin-4-ylthio)-5-methylbenzonitrile
    —— 4-Bromo-6-[(1-methylethyl)thio]pyrimidine 889942-35-2 C7H9BrN2S
    4-Bromo-6-[(1-methylethyl)thio]pyrimidine
    —— 5-(5-cyclopropylmethyl-3-isopropyl-6-methyl-2-oxo-1,2-dihydro-pyridin-4-ylsulfanyl)-isophthalonitrile 1205513-50-3 C21H21N3OS
    5-(5-cyclopropylmethyl-3-isopropyl-6-methyl-2-oxo-1,2-dihydro-pyridin-4-ylsulfanyl)-isophthalonitrile
    —— methyl 3-[4-chloro-5-(dodecylthio)-1-oxido-3-oxoisothiazol-2(3H)-yl]propanoate 1203704-50-0 C19H32ClNO4S2
    methyl 3-[4-chloro-5-(dodecylthio)-1-oxido-3-oxoisothiazol-2(3H)-yl]propanoate
    —— [2-(1,3-Benzodithiol-2-ylidene)-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane 1206719-67-6 C46H44O2S4Si2
    [2-(1,3-Benzodithiol-2-ylidene)-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane
    —— 1,4-bis(4-methoxybenzyl)-2-(phenylthio)-1H-imidazole 1202222-94-3 C25H24N2O2S
    1,4-bis(4-methoxybenzyl)-2-(phenylthio)-1H-imidazole
    —— [2-[4,5-Bis(propylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane 1206719-63-2 C48H54O2S6Si2
    [2-[4,5-Bis(propylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane
    —— (4'S,2''R,3''R)-2-[4',5'-bis((tert-butyldimethylsilyl)oxy)pentyl]-2-[2''-methyl-3''-((tetrahydropyran-2-yl)oxy)butyl]-1,3-dithiane 1206551-63-4 C31H64O4S2Si2
    (4'S,2''R,3''R)-2-[4',5'-bis((tert-butyldimethylsilyl)oxy)pentyl]-2-[2''-methyl-3''-((tetrahydropyran-2-yl)oxy)butyl]-1,3-dithiane
    —— 2-(1,3-Benzodithiol-2-ylidene)-1,3-benzodithiole-4,7-dione 1206719-74-5 C14H6O2S4
    2-(1,3-Benzodithiol-2-ylidene)-1,3-benzodithiole-4,7-dione
    —— 1,4-dibenzyl-2-(phenylthio)-1H-imidazole 1202223-04-8 C23H20N2S
    1,4-dibenzyl-2-(phenylthio)-1H-imidazole
    —— [2-[4,5-Bis(dodecylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane 1206719-66-5 C66H90O2S6Si2
    [2-[4,5-Bis(dodecylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane
    —— [2-[4,5-Bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane 1206719-61-0 C44H46O2S6Si2
    [2-[4,5-Bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-4-[tert-butyl(diphenyl)silyl]oxy-1,3-benzodithiol-7-yl]oxy-tert-butyl-diphenylsilane
    —— 5-(4-(benzyloxy)benzyl)-4-(4-methoxybenzyl)-1-methyl-2-(phenylthio)-1H-imidazole 1202223-18-4 C32H30N2O2S
    5-(4-(benzyloxy)benzyl)-4-(4-methoxybenzyl)-1-methyl-2-(phenylthio)-1H-imidazole
    —— 4,5-dibenzyl-1-methyl-2-(phenylthio)-1H-imidazole 1202223-11-7 C24H22N2S
    4,5-dibenzyl-1-methyl-2-(phenylthio)-1H-imidazole
    —— 2-[(4-Aminophenyl)sulfanyl]propanoic acid hydrochloride 1803584-33-9 C9H12ClNO2S
    2-[(4-Aminophenyl)sulfanyl]propanoic acid hydrochloride
    —— (E)-1,2-Bis-trifluoromethanesulfonyl-ethene 56172-19-1 C4H2F6O4S2
    (E)-1,2-Bis-trifluoromethanesulfonyl-ethene
    —— 2-[(2-chlorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole;chloride 1049727-24-3 C13H15Cl2N3OS
    2-[(2-chlorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole;chloride