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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-{[5-(benzylthio)-2-methoxy[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino}pentan-1-ol 849943-19-7 C18H22N4O2S2
    (2R)-2-{[5-(benzylthio)-2-methoxy[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino}pentan-1-ol
    —— (3,3-dimethyl-2-oxo-butane-1-sulfonyl)-acetic acid 502186-55-2 C8H14O5S
    (3,3-dimethyl-2-oxo-butane-1-sulfonyl)-acetic acid
    —— 5-(benzylthio)-7-{[(1R)-1-(hydroxymethyl)butyl]amino}[1,3]thiazolo[4,5-d]pyrimidin-2(3H)-one 849943-20-0 C17H20N4O2S2
    5-(benzylthio)-7-{[(1R)-1-(hydroxymethyl)butyl]amino}[1,3]thiazolo[4,5-d]pyrimidin-2(3H)-one
    —— 6-thia-1,11-dihydroxyundecan 903094-12-2 C10H22O2S
    6-thia-1,11-dihydroxyundecan
    —— (2R)-2-{[5-(benzylthio)-2-chloro[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino}pentan-1-ol 849943-18-6 C17H19ClN4OS2
    (2R)-2-{[5-(benzylthio)-2-chloro[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino}pentan-1-ol
    —— 2-benzylsulfanyl-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione 87789-33-1 C12H9N3O2S2
    2-benzylsulfanyl-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— tert-butyl (4E,6S,7Z)-6-[tert-butyl(dimethyl)silyl]oxy-10-oxo-12-phenylsulfanyldodeca-4,7-dienoate 948297-21-0 C28H44O4SSi
    tert-butyl (4E,6S,7Z)-6-[tert-butyl(dimethyl)silyl]oxy-10-oxo-12-phenylsulfanyldodeca-4,7-dienoate
    —— 2,6-bis(phenylthio)phenol 68143-72-6 C18H14OS2
    2,6-bis(phenylthio)phenol
    —— 4-(2-guanidinopyrid-6-ylthio)butyramide hydrogen maleate 84545-75-5 C4H4O4*C10H15N5OS
    4-(2-guanidinopyrid-6-ylthio)butyramide hydrogen maleate
    —— 4-[6-(2-[2,2,2-trifluoroethyl]guanidino)pyrid-2-ylthio]butyramide 84545-18-6 C12H16F3N5OS
    4-[6-(2-[2,2,2-trifluoroethyl]guanidino)pyrid-2-ylthio]butyramide
    —— (3R,4S,5S)-2-phenylsulfanyloxane-3,4,5-triol 1352718-30-9 C11H14O4S
    (3R,4S,5S)-2-phenylsulfanyloxane-3,4,5-triol
    —— 5-(4-Trimethylsilylphenyl)sulfanylhexan-3-one 497181-07-4 C15H24OSSi
    5-(4-Trimethylsilylphenyl)sulfanylhexan-3-one
    —— [(2S,3R,4S,5R)-2-phenylsulfanyl-3,5-bis[tri(propan-2-yl)silyloxy]oxan-4-yl]oxy-tri(propan-2-yl)silane 374115-42-1 C38H74O4SSi3
    [(2S,3R,4S,5R)-2-phenylsulfanyl-3,5-bis[tri(propan-2-yl)silyloxy]oxan-4-yl]oxy-tri(propan-2-yl)silane
    —— (p-Tolylthio)acetic acid 2-(dimethylamino)-1-methylethyl ester 35859-10-0 C14H21NO2S
    (p-Tolylthio)acetic acid 2-(dimethylamino)-1-methylethyl ester
    —— 1-[2-[(E)-prop-1-enyl]-1,3-dithian-2-yl]cyclopent-2-en-1-ol 106501-31-9 C12H18OS2
    1-[2-[(E)-prop-1-enyl]-1,3-dithian-2-yl]cyclopent-2-en-1-ol
    —— 3-cyano-6-(2-thienyl)-4-trifluoromethylpyridin-2-ylthioacetonitrile 330220-40-1 C13H6F3N3S2
    3-cyano-6-(2-thienyl)-4-trifluoromethylpyridin-2-ylthioacetonitrile
    —— (E)-1-(phenylthio)-2-(trimethylsilyl)ethene 95841-50-2 C11H16SSi
    (E)-1-(phenylthio)-2-(trimethylsilyl)ethene
    —— phenyl 1-thio-α-L-arabinopyranoside 122604-15-3 C11H14O4S
    phenyl 1-thio-α-L-arabinopyranoside
    —— threo-2-methyl-3-(phenylthio)butanoic acid methyl ester 126824-96-2 C12H16O2S
    threo-2-methyl-3-(phenylthio)butanoic acid methyl ester
    —— erythro-2-methyl-3-(phenylthio)butanoic acid methyl ester 126824-96-2 C12H16O2S
    erythro-2-methyl-3-(phenylthio)butanoic acid methyl ester
    —— methyl (2E,4E,6R)-6-[(2R,4R,6S)-4-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-6-phenylsulfanyloxan-2-yl]-2-methylhepta-2,4-dienoate 477200-83-2 C38H48O4SSi
    methyl (2E,4E,6R)-6-[(2R,4R,6S)-4-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-6-phenylsulfanyloxan-2-yl]-2-methylhepta-2,4-dienoate
    —— (-)-(2S,3S)-methyl 2-methyl-3-(2-trimethylsilylphenylsulfanyl)butanoate 392668-12-1 C15H24O2SSi
    (-)-(2S,3S)-methyl 2-methyl-3-(2-trimethylsilylphenylsulfanyl)butanoate
    —— (2S)-2-[(2R,4R,6S)-4-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-6-phenylsulfanyloxan-2-yl]propanal 477200-82-1 C32H40O3SSi
    (2S)-2-[(2R,4R,6S)-4-[2-[tert-butyl(diphenyl)silyl]oxyethyl]-6-phenylsulfanyloxan-2-yl]propanal
    —— ethyl [(4-cyano-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-3-yl)thio]acetate 54585-48-7 C18H23N3O3S
    ethyl [(4-cyano-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-3-yl)thio]acetate
    —— 9,9-ethylenedithio-4-oxospiro(5.5)undecane-1-carboxylic acid 108643-31-8 C14H20O3S2
    9,9-ethylenedithio-4-oxospiro(5.5)undecane-1-carboxylic acid
    —— 2,3-Dihydro-1,4-benzodithiin-6-ol 742080-41-7 C8H8OS2
    2,3-Dihydro-1,4-benzodithiin-6-ol
    —— 4,4-<1,2-ethanediylbis(thio)>-2-(hydroxymethylene)cyclohexanone 94250-46-1 C9H12O2S2
    4,4-<1,2-ethanediylbis(thio)>-2-(hydroxymethylene)cyclohexanone
    —— 8-hydroxy-1,4-dithia-spiro[4.5]dec-7-ene-7-carboxylic acid methyl ester 874281-27-3 C10H14O3S2
    8-hydroxy-1,4-dithia-spiro[4.5]dec-7-ene-7-carboxylic acid methyl ester
    —— 2-Methylthio-5-methyl-phenylessigsaeure 34617-93-1 C10H12O2S
    2-Methylthio-5-methyl-phenylessigsaeure
    —— 3-(1-methyl-1,2,5,6-tetrahydropyrid-4-yl)-5-(pyrid-2-ylthio)indole 163258-10-4 C19H19N3S
    3-(1-methyl-1,2,5,6-tetrahydropyrid-4-yl)-5-(pyrid-2-ylthio)indole
    —— methyl R-(+)-3-hydroxy-3-methyl-4-(thiophenyl)butanoate 175692-81-6 C12H16O3S
    methyl R-(+)-3-hydroxy-3-methyl-4-(thiophenyl)butanoate
    —— R-(+)-2,4-dimethyl-5-(thiophenyl)pentanediol-2,4 175692-82-7 C13H20O2S
    R-(+)-2,4-dimethyl-5-(thiophenyl)pentanediol-2,4
    —— 10,10-ethylenedithio-3,3-dimethyl-14-trimethylsilyloxy-2,4-dioxadispiro(5.0.5.4)hexadec-14-ene-1,5-dione 108643-27-2 C21H32O5S2Si
    10,10-ethylenedithio-3,3-dimethyl-14-trimethylsilyloxy-2,4-dioxadispiro(5.0.5.4)hexadec-14-ene-1,5-dione
    —— 10,10-ethylenedithio-3,3-dimethyl-2,4-dioxadispiro(5.0.5.4)hexadecane-1,5,14-trione 108643-29-4 C18H24O5S2
    10,10-ethylenedithio-3,3-dimethyl-2,4-dioxadispiro(5.0.5.4)hexadecane-1,5,14-trione
    —— ethyl ethylsulfonyl(diazo)acetate 161573-86-0 C6H10N2O4S
    ethyl ethylsulfonyl(diazo)acetate
    —— 2-[2-(4-tert-Butylcyclohexen-1-yloxyl)ethyl]-5-(3,5-dichlorophenylthio)-4-isopropyl-1-methyl-1H-imidazole 196405-66-0 C25H34Cl2N2OS
    2-[2-(4-tert-Butylcyclohexen-1-yloxyl)ethyl]-5-(3,5-dichlorophenylthio)-4-isopropyl-1-methyl-1H-imidazole
    —— 3-(1-methyl-1,2,5,6-tetrahydropyrid-4-yl)-5-phenylthioindole 163258-02-4 C20H20N2S
    3-(1-methyl-1,2,5,6-tetrahydropyrid-4-yl)-5-phenylthioindole
    —— 4-methyl-3-phenyl-2-(methylthio)-1,3-thiazol-3-ium iodide 33167-54-3 C11H12NS2*I
    4-methyl-3-phenyl-2-(methylthio)-1,3-thiazol-3-ium iodide
    —— thiocarbamic acid <i>S</i>-octadecyl ester 102013-82-1 C19H39NOS
    thiocarbamic acid <i>S</i>-octadecyl ester
    —— 1,1-bis-ethanesulfonyl-nonadecane 6330-05-8 C23H48O4S2
    1,1-bis-ethanesulfonyl-nonadecane
    —— 2-Octadecylsulfonylethanol 17353-91-2 C20H42O3S
    2-Octadecylsulfonylethanol
    —— S-n-octadecylisothiuronium bromide 5397-08-0 BrH*C19H40N2S
    S-n-octadecylisothiuronium bromide
    —— 3-(octadecylthio)propan-1-ol 83517-12-8 C21H44OS
    3-(octadecylthio)propan-1-ol
    —— 1,2-bis(octadecylthio)ethane 63347-81-9 C38H78S2
    1,2-bis(octadecylthio)ethane
    —— dioctadecyl sulfone 42714-86-3 C36H74O2S
    dioctadecyl sulfone
    —— dodecyl-octadecyl sulfide 13784-72-0 C30H62S
    dodecyl-octadecyl sulfide
    —— octadecyl-<i>p</i>-tolyl sulfide 120654-28-6 C25H44S
    octadecyl-<i>p</i>-tolyl sulfide
    —— [(2S,3S)-3-(diethoxyphosphorylmethyl)-5-phenylsulfanyloxolan-2-yl]methanol 220222-88-8 C16H25O5PS
    [(2S,3S)-3-(diethoxyphosphorylmethyl)-5-phenylsulfanyloxolan-2-yl]methanol
    —— 1-Methoxy-1-methylsulfanylnonane 99054-46-3 C11H24OS
    1-Methoxy-1-methylsulfanylnonane
    —— 2-(2,3-Dihydro-1-benzothiophen-5-yl)ethanol 188111-51-5 C10H12OS
    2-(2,3-Dihydro-1-benzothiophen-5-yl)ethanol