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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-Propyl-4-[(1,3,4-thiadiazol-2-ylthio)methyl]-1,2,3-thiadiazol-5-amine 1250389-80-0 C8H11N5S3
    N-Propyl-4-[(1,3,4-thiadiazol-2-ylthio)methyl]-1,2,3-thiadiazol-5-amine
    —— N1-(1-Methylethyl)-1-[4-(methylthio)phenyl]-1,2-ethanediamine 1247556-05-3 C12H20N2S
    N1-(1-Methylethyl)-1-[4-(methylthio)phenyl]-1,2-ethanediamine
    —— 2-[[(6-Amino-3-pyridinyl)methyl]thio]phenol 1249564-27-9 C12H12N2OS
    2-[[(6-Amino-3-pyridinyl)methyl]thio]phenol
    —— 4-(2-Pyridinylthio)pentanoic acid 1247746-12-8 C10H13NO2S
    4-(2-Pyridinylthio)pentanoic acid
    —— 4-(2-Thiazolylthio)pentanoic acid 1247885-10-4 C8H11NO2S2
    4-(2-Thiazolylthio)pentanoic acid
    —— [(3R,4R)-3,4-dihydroxy-5-(4-methylphenyl)sulfanyloxolan-3-yl]methyl 2-chloroacetate 1334533-15-1 C14H17ClO5S
    [(3R,4R)-3,4-dihydroxy-5-(4-methylphenyl)sulfanyloxolan-3-yl]methyl 2-chloroacetate
    —— p-tolyl 3-C-chloroacetoxymethyl-2,3-O-(S)-benzylidene-1-thio-α-D-erythrofuranoside 1334533-16-2 C21H21ClO5S
    p-tolyl 3-C-chloroacetoxymethyl-2,3-O-(S)-benzylidene-1-thio-α-D-erythrofuranoside
    —— diethyl (1S,2S,3S,4S,5S)-3-methyl-2-(4-methylphenyl)sulfanyl-5-nitrocyclohexane-1,4-dicarboxylate 1334997-75-9 C20H27NO6S
    diethyl (1S,2S,3S,4S,5S)-3-methyl-2-(4-methylphenyl)sulfanyl-5-nitrocyclohexane-1,4-dicarboxylate
    —— diethyl (1S,2S,3S,4S,5S)-2-(4-methylphenyl)sulfanyl-5-nitro-3-octylcyclohexane-1,4-dicarboxylate 1334997-77-1 C27H41NO6S
    diethyl (1S,2S,3S,4S,5S)-2-(4-methylphenyl)sulfanyl-5-nitro-3-octylcyclohexane-1,4-dicarboxylate
    —— 4-[(4-Methoxypyrimidin-2-yl)amino]-2-(m-tolylsulfanyl)benzonitrile 1333950-24-5 C19H16N4OS
    4-[(4-Methoxypyrimidin-2-yl)amino]-2-(m-tolylsulfanyl)benzonitrile
    —— 2-(3-Chlorophenyl)sulfanyl-4-[(4-methoxypyrimidin-2-yl)amino]benzonitrile 1333950-23-4 C18H13ClN4OS
    2-(3-Chlorophenyl)sulfanyl-4-[(4-methoxypyrimidin-2-yl)amino]benzonitrile
    —— N-[4-chloro-3-(3-chlorophenyl)sulfanyl-phenyl]-4-methoxy-pyrimidin-2-amine 1333950-21-2 C17H13Cl2N3OS
    N-[4-chloro-3-(3-chlorophenyl)sulfanyl-phenyl]-4-methoxy-pyrimidin-2-amine
    —— 4-[(4-Cyclopropylpyrimidin-2-yl)amino]-2-phenylsulfanyl-benzonitrile 1333950-25-6 C20H16N4S
    4-[(4-Cyclopropylpyrimidin-2-yl)amino]-2-phenylsulfanyl-benzonitrile
    —— (1R,3R,5R,6S)-5-(tert-butyldimethylsilyloxy)-3-methyl-3-(phenylthio)-7-oxabicyclo[4.1.0]heptan-2-one 1289117-11-8 C19H28O3SSi
    (1R,3R,5R,6S)-5-(tert-butyldimethylsilyloxy)-3-methyl-3-(phenylthio)-7-oxabicyclo[4.1.0]heptan-2-one
    —— 6,6,6-Trifluorohexylmercaptan 914642-05-0 C6H11F3S
    6,6,6-Trifluorohexylmercaptan
    —— 3-[(5-Methyl-1,3,4-oxadiazol-2-yl)thio]-2-(propylamino)propanenitrile 1247243-32-8 C9H14N4OS
    3-[(5-Methyl-1,3,4-oxadiazol-2-yl)thio]-2-(propylamino)propanenitrile
    —— 2-chloro-4-(trifluoromethylthio)-aniline 99479-67-1 C7H5ClF3NS
    2-chloro-4-(trifluoromethylthio)-aniline
    —— 2-Hexanone, 6-[(4-methyl-2-pyrimidinyl)thio]- 1250920-31-0 C11H16N2OS
    2-Hexanone, 6-[(4-methyl-2-pyrimidinyl)thio]-
    —— 4-[(5-Methyl-1,3,4-oxadiazol-2-yl)thio]butanoic acid 98321-77-8 C7H10N2O3S
    4-[(5-Methyl-1,3,4-oxadiazol-2-yl)thio]butanoic acid
    —— (<sup>124</sup>I)-PUH71 1352930-11-0 C18H21IN6O2S
    (<sup>124</sup>I)-PUH71
    —— 2-(2-(trifluoromethyl)phenylthio)phenol 1254831-60-1 C13H9F3OS
    2-(2-(trifluoromethyl)phenylthio)phenol
    —— 3-phenyl-6,7-dihydro-thiazolo[3,2-<i>a</i>][1,3,5]triazine-2,4-dione 30006-89-4 C11H9N3O2S
    3-phenyl-6,7-dihydro-thiazolo[3,2-<i>a</i>][1,3,5]triazine-2,4-dione
    —— 1-Cyclopropyl-5-(3-pyrrolidinylthio)-1H-tetrazole 1248106-67-3 C8H13N5S
    1-Cyclopropyl-5-(3-pyrrolidinylthio)-1H-tetrazole
    —— N-(2-Hydroxypropyl)-N-methyl-2-(4-pyridinylthio)acetamide 1247227-08-2 C11H16N2O2S
    N-(2-Hydroxypropyl)-N-methyl-2-(4-pyridinylthio)acetamide
    —— 5-Bromo-4-methoxy-6,6-dimethyl-6,7-dihydro-5H,10H-9-thia-1,3,10-triaza-anthracen-8-one 109880-29-7 C13H14BrN3O2S
    5-Bromo-4-methoxy-6,6-dimethyl-6,7-dihydro-5H,10H-9-thia-1,3,10-triaza-anthracen-8-one
    —— Pyrimidine, 2-chloro-4-(1,3,4-thiadiazol-2-ylthio)- 1250316-57-4 C6H3ClN4S2
    Pyrimidine, 2-chloro-4-(1,3,4-thiadiazol-2-ylthio)-
    —— 4-Fluoro-2-[(2-methylpropyl)thio]benzenamine 1249593-40-5 C10H14FNS
    4-Fluoro-2-[(2-methylpropyl)thio]benzenamine
    —— 4-(Ethoxymethylthio)phenylboronic acid 2096331-89-2 C9H13BO3S
    4-(Ethoxymethylthio)phenylboronic acid
    —— N-[(7S,8aS)-2-methyloctahydropyrrolo[1,2-a]pyrazin-7-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)thio]propanamide 1331944-77-4 C14H23N5OS2
    N-[(7S,8aS)-2-methyloctahydropyrrolo[1,2-a]pyrazin-7-yl]-3-[(5-methyl-1,3,4-thiadiazol-2-yl)thio]propanamide
    —— 2-{[4-allyl-5-(anilinomethyl)-4H-1,2,4-triazol-3-yl]thio}acetohydrazide 1306738-34-0 C14H18N6OS
    2-{[4-allyl-5-(anilinomethyl)-4H-1,2,4-triazol-3-yl]thio}acetohydrazide
    —— 2-[(5-{1-[(4-Bromophenyl)amino]ethyl}-4-methyl-4H-1,2,4-triazol-3-yl)thio]acetohydrazide 1306738-58-8 C13H17BrN6OS
    2-[(5-{1-[(4-Bromophenyl)amino]ethyl}-4-methyl-4H-1,2,4-triazol-3-yl)thio]acetohydrazide
    —— 5-Bromo-2-[(1,3-dimethyl-1H-pyrazol-5-yl)thio]-3-pyridinamine 1249028-11-2 C10H11BrN4S
    5-Bromo-2-[(1,3-dimethyl-1H-pyrazol-5-yl)thio]-3-pyridinamine
    —— 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-4-((trifluoromethyl)thio)phenol 2096340-17-7 C13H16BF3O3S
    2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-4-((trifluoromethyl)thio)phenol
    —— 2-Chlor-3-<(2-amino-phenyl)-thiomethyl>-pyridin 92696-10-1 C12H11ClN2S
    2-Chlor-3-<(2-amino-phenyl)-thiomethyl>-pyridin
    —— 5-Methyl-6-(2-pyrimidinylthio)-3-pyridinamine 1249465-17-5 C10H10N4S
    5-Methyl-6-(2-pyrimidinylthio)-3-pyridinamine
    —— 2-[3-[(2-Methylphenyl)thio]propyl]pyrrolidine 1250115-40-2 C14H21NS
    2-[3-[(2-Methylphenyl)thio]propyl]pyrrolidine
    —— 5-methyl-6-(methylthio)pyridin-3-amine 935252-77-0 C7H10N2S
    5-methyl-6-(methylthio)pyridin-3-amine
    —— 2-[(E)-7-[2-[(2S)-butan-2-yl]-1,3-dithian-2-yl]hept-2-enoxy]oxane 1354575-64-6 C20H36O2S2
    2-[(E)-7-[2-[(2S)-butan-2-yl]-1,3-dithian-2-yl]hept-2-enoxy]oxane
    —— 3-(cyclopentylthio)-6-(3,5-dimethylpyrazol-1-yl)[1,2,4]triazolo[4,3-b][1,2,4,5]tetrazine 1300041-13-7 C13H16N8S
    3-(cyclopentylthio)-6-(3,5-dimethylpyrazol-1-yl)[1,2,4]triazolo[4,3-b][1,2,4,5]tetrazine
    —— 3-(6-chloro-1-isothiazol-4-yl-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid 1359980-62-3 C19H13ClN2O2S2
    3-(6-chloro-1-isothiazol-4-yl-2-methyl-1H-indol-3-ylsulfanyl)-benzoic acid
    —— Methanesulfenyl chloride, dichloro 42172-24-7 C2H3Cl3S
    Methanesulfenyl chloride, dichloro
    —— Einecs 252-850-9 36058-55-6 C14H12Cl5N3SZn
    Einecs 252-850-9
    —— Thioimidodicarbonic diamide (((H2N)C(S))2NH), mixt. with sodium hydroxide (Na(OH)) 87558-76-7 C2H6N3NaOS2
    Thioimidodicarbonic diamide (((H2N)C(S))2NH), mixt. with sodium hydroxide (Na(OH))
    —— Thioimidodicarbonic acid ((HO)C(O)NHC(S)(OH)), O1,O3-dipropyl ester 39142-31-9 C8H15NO2S2
    Thioimidodicarbonic acid ((HO)C(O)NHC(S)(OH)), O1,O3-dipropyl ester
    —— 4-methylcarbamoyloxy-2,3-dihydro-benzo[<i>b</i>]thiophene 22069-03-0 C10H11NO2S
    4-methylcarbamoyloxy-2,3-dihydro-benzo[<i>b</i>]thiophene
    —— 4-(3-(4-Imidazolyl)thioacryloyl)morpholine 88167-13-9 C10H13N3O2S
    4-(3-(4-Imidazolyl)thioacryloyl)morpholine
    —— N,N'-Thioperoxydicarbamic acid 93892-75-2 C26H52N2S4
    N,N'-Thioperoxydicarbamic acid
    —— Pseudourea, 2,2'-(iminodiethylene)bis(2-thio-, dihydrobromide 90000-16-1 C6H17Br2N5S2
    Pseudourea, 2,2'-(iminodiethylene)bis(2-thio-, dihydrobromide
    —— N-[2-(2-Thienylthio)ethyl]-2-heptanamine 1247783-33-0 C13H23NS2
    N-[2-(2-Thienylthio)ethyl]-2-heptanamine
    —— 2-[(Difluoromethyl)thio]-N-(2-methoxy-1-methylethyl)benzenamine 1247342-24-0 C11H15F2NOS
    2-[(Difluoromethyl)thio]-N-(2-methoxy-1-methylethyl)benzenamine