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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-chlorophenylsulfanyl)-4,6-dimethyl-benzoic acid methyl ester 1190220-03-1 C16H15ClO2S
    2-(4-chlorophenylsulfanyl)-4,6-dimethyl-benzoic acid methyl ester
    —— 2-(3-chlorophenylsulfanyl)-4,6-dimethyl-benzoic acid methyl ester 1190220-06-4 C16H15ClO2S
    2-(3-chlorophenylsulfanyl)-4,6-dimethyl-benzoic acid methyl ester
    —— ethanesulfonyl-acetic acid amide 10152-03-1 C4H9NO3S
    ethanesulfonyl-acetic acid amide
    —— 2-(4-fluorophenylsulfanyl)-4,6-dimethyl-benzoic acid methyl ester 1190220-07-5 C16H15FO2S
    2-(4-fluorophenylsulfanyl)-4,6-dimethyl-benzoic acid methyl ester
    —— 2,4-dimethyl-6-(4-tolylsulfanyl)benzoic acid methyl ester 1190219-98-7 C17H18O2S
    2,4-dimethyl-6-(4-tolylsulfanyl)benzoic acid methyl ester
    —— 2-(4-fluorophenylsulfanyl)-3,4,6-trimethylbenzoic acid methyl ester 1190220-08-6 C17H17FO2S
    2-(4-fluorophenylsulfanyl)-3,4,6-trimethylbenzoic acid methyl ester
    —— 2-(4-ethylphenylsulfanyl)-4,6-dimethyl-benzoic acid methyl ester 1190220-01-9 C18H20O2S
    2-(4-ethylphenylsulfanyl)-4,6-dimethyl-benzoic acid methyl ester
    —— 3-chloro-6-(4-chlorophenylsulfanyl)-2,4-dimethyl-benzoic acid methyl ester 1190220-04-2 C16H14Cl2O2S
    3-chloro-6-(4-chlorophenylsulfanyl)-2,4-dimethyl-benzoic acid methyl ester
    —— 3,4,6-trimethyl-2-(4-tolylsulfanyl)benzoic acid methyl ester 1190219-99-8 C18H20O2S
    3,4,6-trimethyl-2-(4-tolylsulfanyl)benzoic acid methyl ester
    —— 2-(4-ethylphenylsulfanyl)-3,4,6-trimethyl-benzoic acid methyl ester 1190220-02-0 C19H22O2S
    2-(4-ethylphenylsulfanyl)-3,4,6-trimethyl-benzoic acid methyl ester
    —— 2-(2-Butenylthio)ethanol 82010-89-7 C6H12OS
    2-(2-Butenylthio)ethanol
    —— 6-methyl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one 32084-45-0 C7H8N2OS
    6-methyl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one
    —— 2,4-dimethyl-6-(m-tolylsulfanyl)benzoic acid methyl ester 1190220-00-8 C17H18O2S
    2,4-dimethyl-6-(m-tolylsulfanyl)benzoic acid methyl ester
    —— Ethyl 5,6-dihydro[1,3]thiazolo[3,2-d][1,4,2]diazaphosphole-3-carboxylate 141366-60-1 C7H9N2O2PS
    Ethyl 5,6-dihydro[1,3]thiazolo[3,2-d][1,4,2]diazaphosphole-3-carboxylate
    —— N<sup>6</sup>-methyl-2-(methylthio)pyrimidine-4,6-diamine 96225-63-7 C6H10N4S
    N<sup>6</sup>-methyl-2-(methylthio)pyrimidine-4,6-diamine
    —— N<sup>6</sup>-methyl-2-(methylthio)-5-nitrosopyrimidin-4,6-diamine 99357-36-5 C6H9N5OS
    N<sup>6</sup>-methyl-2-(methylthio)-5-nitrosopyrimidin-4,6-diamine
    —— Agn-PC-0lsw0L 17695-87-3 C3H9ClI2S
    Agn-PC-0lsw0L
    —— 4-amino-2-methylthio-5,6-trimethylenepyrimidine 77766-02-0 C8H11N3S
    4-amino-2-methylthio-5,6-trimethylenepyrimidine
    —— 2-methylsulfanyl-6,7,8,9-tetrahydro-5H-cyclohepta[d]pyrimidin-4-amine 77766-05-3 C10H15N3S
    2-methylsulfanyl-6,7,8,9-tetrahydro-5H-cyclohepta[d]pyrimidin-4-amine
    —— 1-methoxy-3-methylsulfanyl-penta-1,2-diene 56699-03-7 C7H12OS
    1-methoxy-3-methylsulfanyl-penta-1,2-diene
    —— 4-ethoxy-6-ethyl-2-(pyridin-3-ylthio)-7H-pyrrolo[2,3-d]pyrimidin-5-carbaldehyde 1275598-68-9 C16H16N4O2S
    4-ethoxy-6-ethyl-2-(pyridin-3-ylthio)-7H-pyrrolo[2,3-d]pyrimidin-5-carbaldehyde
    —— 3-ethyl-1-methyl-2-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine 1012787-09-5 C21H22N4S
    3-ethyl-1-methyl-2-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine
    —— 4-(dimethylamino)-6-ethyl-2-(pyridin-3-ylthio)-7H-pyrrolo[2,3-d]pyrimidin-5-carbaldehyde 1275598-71-4 C16H17N5OS
    4-(dimethylamino)-6-ethyl-2-(pyridin-3-ylthio)-7H-pyrrolo[2,3-d]pyrimidin-5-carbaldehyde
    —— 5-(4-ethoxy-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)3-fluoropicolinonitrile 1275608-18-8 C14H10FN5OS
    5-(4-ethoxy-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)3-fluoropicolinonitrile
    —— 3-(2-(1,5-naphtyridin-3-ylthio)-5-chloro-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin4-yl)-3-azabicyclo[3.1.0]hexan-6-amine 1275605-00-9 C21H20ClN7S
    3-(2-(1,5-naphtyridin-3-ylthio)-5-chloro-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin4-yl)-3-azabicyclo[3.1.0]hexan-6-amine
    —— (3R)-4-hydroxy-3-methyl-2-(phenylthio)butanenitrile 1276114-97-6 C11H13NOS
    (3R)-4-hydroxy-3-methyl-2-(phenylthio)butanenitrile
    —— methyl N-heptyl-N-methylcarbamimidothioate 1028293-85-7 C10H22N2S
    methyl N-heptyl-N-methylcarbamimidothioate
    —— 3-benzyl-1,2-dimethyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine 1012787-10-8 C21H22N4S
    3-benzyl-1,2-dimethyl-5-phenylthio-1,2,3,4-tetrahydropyrimido[4,5-d]pyrimidine
    —— 3,3-Bis(methylthio)butan-2-one oxime 94291-65-3 C6H13NOS2
    3,3-Bis(methylthio)butan-2-one oxime
    —— 5-(cyclopent-1-en-1-yl)-2-((R)-1-hydroxypropan-2-yl)-2-(phenylthio)pentanenitrile 1276114-91-0 C19H25NOS
    5-(cyclopent-1-en-1-yl)-2-((R)-1-hydroxypropan-2-yl)-2-(phenylthio)pentanenitrile
    —— 2-((S)-1-chloropropan-2-yl)-5-(cyclopent-1-en-1-yl)-2-(phenylthio)pentanenitrile 1276114-92-1 C19H24ClNS
    2-((S)-1-chloropropan-2-yl)-5-(cyclopent-1-en-1-yl)-2-(phenylthio)pentanenitrile
    —— 2-((S)-1-chloropropan-2-yl)-5-(cyclopent-1-en-1-yl)-2-(phenylthio)pentanal 1276114-93-2 C19H25ClOS
    2-((S)-1-chloropropan-2-yl)-5-(cyclopent-1-en-1-yl)-2-(phenylthio)pentanal
    —— 1-cyano-1-phenylthio-2-methanesulfonyl-ethane 141739-78-8 C10H11NO2S2
    1-cyano-1-phenylthio-2-methanesulfonyl-ethane
    —— N-[5-chloro-2-(phenylthio)phenyl]-3-(4-methylpiperazine-1-yl)-propanamidine 1100793-89-2 C20H25ClN4S
    N-[5-chloro-2-(phenylthio)phenyl]-3-(4-methylpiperazine-1-yl)-propanamidine
    —— 1-methanesulfonyl-2-cyano-hexane 141739-82-4 C8H15NO2S
    1-methanesulfonyl-2-cyano-hexane
    —— 1-cyano-1-ethoxy-2-methanesulfonyl-ethane 141739-74-4 C6H11NO3S
    1-cyano-1-ethoxy-2-methanesulfonyl-ethane
    —— ethyl 2-(6-amino-3,5-dicyanopyridin-2-ylthio)acetate 119022-82-1 C11H10N4O2S
    ethyl 2-(6-amino-3,5-dicyanopyridin-2-ylthio)acetate
    —— 2-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]-1-phenylethanone 53633-39-9 C16H14N2OS
    2-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]-1-phenylethanone
    —— 1,1',1''-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2-aminophenylthio)propan-1-one) 1123041-99-5 C30H36N6O3S3
    1,1',1''-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2-aminophenylthio)propan-1-one)
    —— 1-benzyloxymethyl-5-phenylsulfenyl-2(1H)-pyrimidinone 116392-88-2 C18H16N2O2S
    1-benzyloxymethyl-5-phenylsulfenyl-2(1H)-pyrimidinone
    —— 2-methylthio-5-phenylthiopyrimidine 61727-19-3 C11H10N2S2
    2-methylthio-5-phenylthiopyrimidine
    —— O-Thiocarbamoyl-acetonoxim 85053-88-9 C4H8N2OS
    O-Thiocarbamoyl-acetonoxim
    —— 3-Amino-4-(butylthio)-6-methylpyridazine 82608-17-1 C9H15N3S
    3-Amino-4-(butylthio)-6-methylpyridazine
    —— s-Triazolo<4.3-d>-as-triazin 32331-08-1 C11H9N5OS
    s-Triazolo<4.3-d>-as-triazin
    —— Dimethyl-cyclooctyl-sulfonium 94602-68-3 C10H21S*I
    Dimethyl-cyclooctyl-sulfonium
    —— α-ethylsulfinylacetyl chloride 56796-31-7 C4H7ClO3S
    α-ethylsulfinylacetyl chloride
    —— Ethyl-jodmethyl-sulfon 31355-01-8 C3H7IO2S
    Ethyl-jodmethyl-sulfon
    —— 2,4,5,7,9-pentathiadecane 155994-67-5 C5H12S5
    2,4,5,7,9-pentathiadecane
    —— 1,2,3-Trithia-5-cycloheptene 13005-82-8 C4H6S3
    1,2,3-Trithia-5-cycloheptene
    —— Ethyl-dijodmethyl-sulfon 31350-59-1 C3H6I2O2S
    Ethyl-dijodmethyl-sulfon