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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(2,4-Difluorophenylsulfanyl)-1-nitrobenzene 187845-74-5 C12H7F2NO2S
    2-(2,4-Difluorophenylsulfanyl)-1-nitrobenzene
    —— 2-(4-bromophenyl)-2-(phenylthio)penta-3,4-dienyl-2,2,2-trichloroacetimidate 1262633-73-7 C19H15BrCl3NOS
    2-(4-bromophenyl)-2-(phenylthio)penta-3,4-dienyl-2,2,2-trichloroacetimidate
    —— (R)-7-(4-(3-aminopyrrolidin-1-yl)-5-chloro-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)-1,5-naphthyridine-1-oxide 1275606-61-5 C20H20ClN7OS
    (R)-7-(4-(3-aminopyrrolidin-1-yl)-5-chloro-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)-1,5-naphthyridine-1-oxide
    —— 3-(5-hydroxymethyl-2-methylsulfanylpyrimidin-4-ylamino)propan-1-ol 1280218-29-2 C9H15N3O2S
    3-(5-hydroxymethyl-2-methylsulfanylpyrimidin-4-ylamino)propan-1-ol
    —— methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(phenylthio)-benzofuran-3-carboxylate 1257240-01-9 C18H17NO4S
    methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(phenylthio)-benzofuran-3-carboxylate
    —— 3-butylthio-5-(3-butylthio-1,2,4-triazin-5-yl)-1,2,4-triazine 1255789-65-1 C14H20N6S2
    3-butylthio-5-(3-butylthio-1,2,4-triazin-5-yl)-1,2,4-triazine
    —— Methyl 2-amino-4-(3-fluorophenyl)sulfanyl-5-hydroxy-6,7-dimethyl-benzofuran-3-carboxylate 1257240-04-2 C18H16FNO4S
    Methyl 2-amino-4-(3-fluorophenyl)sulfanyl-5-hydroxy-6,7-dimethyl-benzofuran-3-carboxylate
    —— Methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(m-tolylsulfanyl)benzofuran-3-carboxylate 1257240-05-3 C19H19NO4S
    Methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(m-tolylsulfanyl)benzofuran-3-carboxylate
    —— 4-[(4-chlorophenyl)sulfanyl]-1-[(E)-2-[(4-chlorophenyl)sulfanyl]-1-(2-naphthyl)ethenyl]-3-(2-naphthyl)-1H-pyrazole 1260255-06-8 C37H24Cl2N2S2
    4-[(4-chlorophenyl)sulfanyl]-1-[(E)-2-[(4-chlorophenyl)sulfanyl]-1-(2-naphthyl)ethenyl]-3-(2-naphthyl)-1H-pyrazole
    —— 4-[(4-chlorophenyl)sulfanyl]-1-[(Z)-2-[(4-chlorophenyl)sulfanyl]-1-(2-naphthyl)ethenyl]-3-(2-naphthyl)-1H-pyrazole 1260255-14-8 C37H24Cl2N2S2
    4-[(4-chlorophenyl)sulfanyl]-1-[(Z)-2-[(4-chlorophenyl)sulfanyl]-1-(2-naphthyl)ethenyl]-3-(2-naphthyl)-1H-pyrazole
    —— 2-[[5-[3-(2-diethylaminoethylsulfanyl)-1,2,4-triazin-5-yl]-1,2,4-triazin-3-yl]sulfanyl]-N,N-diethyl-ethanamine 1255789-73-1 C18H30N8S2
    2-[[5-[3-(2-diethylaminoethylsulfanyl)-1,2,4-triazin-5-yl]-1,2,4-triazin-3-yl]sulfanyl]-N,N-diethyl-ethanamine
    —— Methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(p-tolylsulfanyl)benzofuran-3-carboxylate 1257240-02-0 C19H19NO4S
    Methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(p-tolylsulfanyl)benzofuran-3-carboxylate
    —— 1-{4-[(5-methyl-5H-pyrrolo[3,2-d]pyrimidin-4-yl)sulfanyl]-phenyl}-3-phenylurea 1255948-56-1 C20H17N5OS
    1-{4-[(5-methyl-5H-pyrrolo[3,2-d]pyrimidin-4-yl)sulfanyl]-phenyl}-3-phenylurea
    —— (2S)-2-amino-4-methylpentanethiol hydrochloride 522607-42-7 C6H15NS*ClH
    (2S)-2-amino-4-methylpentanethiol hydrochloride
    —— 3,3′-bis(propylthio)-5,5′-bi(1,2,4-triazine) 1255789-64-0 C12H16N6S2
    3,3′-bis(propylthio)-5,5′-bi(1,2,4-triazine)
    —— 3-(2-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-00-0 C27H31F3NS*I
    3-(2-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(3-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-02-2 C27H31F3NS*I
    3-(3-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(4-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-04-4 C27H31F3NS*I
    3-(4-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 4-Nitro-1,3-oxathiol-2-amine 1233025-60-9 C3H4N2O3S
    4-Nitro-1,3-oxathiol-2-amine
    —— 1-bromo-3-cyclobutylsulfanylbenzene 1199773-05-1 C10H11BrS
    1-bromo-3-cyclobutylsulfanylbenzene
    —— (2,4,6-Tribromophenyl)(trifluoromethyl)sulfane 1215205-79-0 C7H2Br3F3S
    (2,4,6-Tribromophenyl)(trifluoromethyl)sulfane
    —— 1-Bromo-3-isobutylthiobenzene 1199773-06-2 C10H13BrS
    1-Bromo-3-isobutylthiobenzene
    —— 5-Bromo-2-isobutylthiopyrimidine 1242336-74-8 C8H11BrN2S
    5-Bromo-2-isobutylthiopyrimidine
    —— 3-(2-bromophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299398-97-2 C26H31BrNS*I
    3-(2-bromophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(3-methoxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299398-99-4 C27H34NOS*I
    3-(3-methoxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(4-hydroxyphenylthio)quinoline 1299398-60-9 C15H11NOS
    3-(4-hydroxyphenylthio)quinoline
    —— 3-(3-cyanophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-13-5 C27H31N2S*I
    3-(3-cyanophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(4-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-20-4 C26H32NOS*I
    3-(4-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(2-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-17-9 C26H32NOS*I
    3-(2-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(3-hydroxyphenylthio)quinoline 1299398-58-5 C15H11NOS
    3-(3-hydroxyphenylthio)quinoline
    —— 5-(cyclopent-1-en-1-yl)-2-(2-hydroxyethyl)-2-(phenylthio)pentanenitrile 1276114-82-9 C18H23NOS
    5-(cyclopent-1-en-1-yl)-2-(2-hydroxyethyl)-2-(phenylthio)pentanenitrile
    —— 3-(3-fluorophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299398-95-0 C26H31FNS*I
    3-(3-fluorophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(4-cyanophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-15-7 C27H31N2S*I
    3-(4-cyanophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(2-methylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-05-5 C27H34NS*I
    3-(2-methylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(3-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-18-0 C26H32NOS*I
    3-(3-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(2-hydroxyphenylthio)quinoline 1299398-56-3 C15H11NOS
    3-(2-hydroxyphenylthio)quinoline
    —— 5-(cyclopent-1-en-1-yl)-2-(phenylthio)pentanenitrile 1276114-81-8 C16H19NS
    5-(cyclopent-1-en-1-yl)-2-(phenylthio)pentanenitrile
    —— 3-(quinolin-3-ylsulfanyl)benzonitrile 1299398-64-3 C16H10N2S
    3-(quinolin-3-ylsulfanyl)benzonitrile
    —— 3-(phenylthio)-1-(5-cyclohexylpentyl)quinolinium iodide 1265087-27-1 C26H32NS*I
    3-(phenylthio)-1-(5-cyclohexylpentyl)quinolinium iodide
    —— 3-(4-methylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-09-9 C27H34NS*I
    3-(4-methylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— (4R,6S)-6-[(E)-2-[2-cyclopropyl-6-methoxy-4-(3-methoxyphenyl)sulfanylquinolin-3-yl]ethenyl]-4-hydroxyoxan-2-one 1202383-08-1 C27H27NO5S
    (4R,6S)-6-[(E)-2-[2-cyclopropyl-6-methoxy-4-(3-methoxyphenyl)sulfanylquinolin-3-yl]ethenyl]-4-hydroxyoxan-2-one
    —— 5-(2-bromoethylthio)selenophene-2-carbaldehyde 1297906-70-7 C7H7BrOSSe
    5-(2-bromoethylthio)selenophene-2-carbaldehyde
    —— (Z)-2-(1-bromodec-1-en-2-ylthio)aniline 1279713-37-9 C16H24BrNS
    (Z)-2-(1-bromodec-1-en-2-ylthio)aniline
    —— Fluhexafon 1097630-26-6 C12H17F3N2O3S
    Fluhexafon
    —— 4-fluoro-2-pentyl-3-(phenylthio)-1H-indole 1287792-06-6 C19H20FNS
    4-fluoro-2-pentyl-3-(phenylthio)-1H-indole
    —— tert-butyl-dimethyl-[(3S,4R)-4-[2-[(2R,4S,6S)-2,4,6,7-tetrakis[[tert-butyl(dimethyl)silyl]oxy]heptyl]-1,3-dithian-2-yl]pent-1-en-3-yl]oxysilane 1306603-25-7 C46H100O5S2Si5
    tert-butyl-dimethyl-[(3S,4R)-4-[2-[(2R,4S,6S)-2,4,6,7-tetrakis[[tert-butyl(dimethyl)silyl]oxy]heptyl]-1,3-dithian-2-yl]pent-1-en-3-yl]oxysilane
    —— 7-methyl-6-[2-(3-thienyl)ethyl]-1,4-dithiaspiro[4.5]dec-6-ene 1292848-63-5 C15H20S3
    7-methyl-6-[2-(3-thienyl)ethyl]-1,4-dithiaspiro[4.5]dec-6-ene
    —— N-(4-methylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)benzenecarboximidate 1217516-00-1 C13H15N3O2S
    N-(4-methylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)benzenecarboximidate
    —— 2-Methylmercapto-5-m-tolyl-1,3,4-oxadiazol 71134-60-6 C10H10N2OS
    2-Methylmercapto-5-m-tolyl-1,3,4-oxadiazol
    —— N-[4-(cyclopropylmethylsulfanyl)-3-propan-2-yloxadiazol-3-ium-5-yl]benzenecarboximidate 1217516-03-4 C16H19N3O2S
    N-[4-(cyclopropylmethylsulfanyl)-3-propan-2-yloxadiazol-3-ium-5-yl]benzenecarboximidate