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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Dimethylamino-1,1-bis-trifluormethansulfonyl-ethen 58510-91-1 C6H7F6NO4S2
    2-Dimethylamino-1,1-bis-trifluormethansulfonyl-ethen
    —— 2-(3,4-difluorophenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one 1373433-08-9 C26H25F2N3O3S
    2-(3,4-difluorophenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one
    —— 2-(2,4-difluorophenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one 1373433-06-7 C26H25F2N3O3S
    2-(2,4-difluorophenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one
    —— 4-[3-[2-(dimethylamino)ethoxy]-11-ethyl-6H-benzo[c][1]benzothiocin-12-yl]phenol 85850-81-3 C27H29NO2S
    4-[3-[2-(dimethylamino)ethoxy]-11-ethyl-6H-benzo[c][1]benzothiocin-12-yl]phenol
    —— 1-(Trifluoromethanesulfonyl)heptane 61795-00-4 C8H15F3O2S
    1-(Trifluoromethanesulfonyl)heptane
    —— 1-[2-[(3,5-Dibromophenyl)methylsulfanyl]phenyl]guanidine 1314034-06-4 C14H13Br2N3S
    1-[2-[(3,5-Dibromophenyl)methylsulfanyl]phenyl]guanidine
    —— 7-(3-trifluoromethyl-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-92-7 C18H17F3N2S
    7-(3-trifluoromethyl-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 2-(6-hydroxy-6-methylheptylthio)-4-methyl-6-(5-methyl-1H-pyrazol-3-ylamino)nicotinonitrile 1024869-24-6 C19H27N5OS
    2-(6-hydroxy-6-methylheptylthio)-4-methyl-6-(5-methyl-1H-pyrazol-3-ylamino)nicotinonitrile
    —— 7-(4-trifluoromethyl-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-94-9 C18H17F3N2S
    7-(4-trifluoromethyl-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 7-p-tolylsulfanyl-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-78-9 C18H20N2S
    7-p-tolylsulfanyl-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 6-phenylthio-1,3-dihydro-1-hydroxy-2,1-benzoxaborole 906673-34-5 C13H11BO2S
    6-phenylthio-1,3-dihydro-1-hydroxy-2,1-benzoxaborole
    —— 1,2-Dicyclohexyl-3-[2-[(3,5-dibromophenyl)methylsulfanyl]phenyl]guanidine 1314034-07-5 C26H33Br2N3S
    1,2-Dicyclohexyl-3-[2-[(3,5-dibromophenyl)methylsulfanyl]phenyl]guanidine
    —— 7-(4-fluoro-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-82-5 C17H17FN2S
    7-(4-fluoro-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 7-(3-methoxy-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-86-9 C18H20N2OS
    7-(3-methoxy-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 7-o-tolylsulfanyl-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-75-6 C18H20N2S
    7-o-tolylsulfanyl-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 1-[2-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine 1314033-98-1 C14H14ClN3S
    1-[2-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine
    —— 3-[(4-Chlorophenyl)sulfanylmethyl]pyridine;hydrochloride 88594-68-7 C12H11Cl2NS
    3-[(4-Chlorophenyl)sulfanylmethyl]pyridine;hydrochloride
    —— 1-[2-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine 1314033-99-2 C26H34ClN3S
    1-[2-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine
    —— 7-(4-methoxy-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-88-1 C18H20N2OS
    7-(4-methoxy-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine 1314034-01-9 C26H34ClN3S
    1-[3-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine
    —— 2-(3,5-Dibromobenzylthio)Aniline 1314034-08-6 C13H11Br2NS
    2-(3,5-Dibromobenzylthio)Aniline
    —— 7-(2-fluoro-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-80-3 C17H17FN2S
    7-(2-fluoro-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 1,2-Dicyclohexyl-3-[4-[(3,5-dibromophenyl)methylsulfanyl]phenyl]guanidine 1314034-13-3 C26H33Br2N3S
    1,2-Dicyclohexyl-3-[4-[(3,5-dibromophenyl)methylsulfanyl]phenyl]guanidine
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine 1314034-00-8 C14H14ClN3S
    1-[3-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine
    —— 2-(6-hydroxyhexylthio)-4-methyl-6-(5-methyl-1H-pyrazol-3-ylamino)nicotinonitrile 1024600-40-5 C17H23N5OS
    2-(6-hydroxyhexylthio)-4-methyl-6-(5-methyl-1H-pyrazol-3-ylamino)nicotinonitrile
    —— Prop-2-enenitrile--(ethenesulfonyl)ethene (1/1) 28931-39-7 C7H9NO2S
    Prop-2-enenitrile--(ethenesulfonyl)ethene (1/1)
    —— Tetracosyl carbamimidothioate--hydrogen bromide (1/1) 7399-05-5 C25H53BrN2S
    Tetracosyl carbamimidothioate--hydrogen bromide (1/1)
    —— (5Z)-6-Oxo-5-{2-[4-({4-[(2E)-2-(2-oxo-6-sulfonaphthalen-1(2H)-ylidene)hydrazinyl]phenyl}sulfanyl)phenyl]hydrazinylidene}-5,6-dihydronaphthalene-2-sulfonic acid 6661-25-2 C32H22N4O8S3
    (5Z)-6-Oxo-5-{2-[4-({4-[(2E)-2-(2-oxo-6-sulfonaphthalen-1(2H)-ylidene)hydrazinyl]phenyl}sulfanyl)phenyl]hydrazinylidene}-5,6-dihydronaphthalene-2-sulfonic acid
    —— 3-Dimethylsulfoniobutan-2-yl(dimethyl)sulfanium;2,4,6-trinitrobenzenesulfonate 2026-33-7 C14H22N3O9S3+
    3-Dimethylsulfoniobutan-2-yl(dimethyl)sulfanium;2,4,6-trinitrobenzenesulfonate
    —— 17-Oxa-8,16-dithia-6,14-diazatetracyclo[7.7.1.02,7.010,15]heptadeca-2(7),3,5,10(15),11,13-hexaene;hydrochloride 62295-88-9 C12H9ClN2OS2
    17-Oxa-8,16-dithia-6,14-diazatetracyclo[7.7.1.02,7.010,15]heptadeca-2(7),3,5,10(15),11,13-hexaene;hydrochloride
    —— 2-(Hexadecylsulfanyl)pyridine--hydrogen bromide (1/1) 6313-83-3 C21H38BrNS
    2-(Hexadecylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— Hexacosyl carbamimidothioate--hydrogen bromide (1/1) 6624-74-4 C27H57BrN2S
    Hexacosyl carbamimidothioate--hydrogen bromide (1/1)
    —— O-Ethyl hydrogen carbonodithioate--lead (1/1) 5439-55-4 C3H6OPbS2
    O-Ethyl hydrogen carbonodithioate--lead (1/1)
    —— 2-(Octylsulfanyl)pyridine--hydrogen bromide (1/1) 6313-79-7 C13H22BrNS
    2-(Octylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— S-[2-(Diethylamino)ethyl] 2-(diethylamino)ethane-1-sulfonothioate--hydrogen chloride (1/1) 88890-27-1 C12H29ClN2O2S2
    S-[2-(Diethylamino)ethyl] 2-(diethylamino)ethane-1-sulfonothioate--hydrogen chloride (1/1)
    —— Diethylcarbamodithioic acid--ethane-1,2-diyl dicarbamimidothioate (1/1) 68059-73-4 C9H21N5S4
    Diethylcarbamodithioic acid--ethane-1,2-diyl dicarbamimidothioate (1/1)
    —— Octacosyl carbamimidothioate--hydrogen bromide (1/1) 7154-96-3 C29H61BrN2S
    Octacosyl carbamimidothioate--hydrogen bromide (1/1)
    —— Nonane-1,9-diyl dicarbamimidothioate--hydrogen bromide (1/1) 5433-13-6 C11H25BrN4S2
    Nonane-1,9-diyl dicarbamimidothioate--hydrogen bromide (1/1)
    —— Ethenyl acetate--(ethenesulfonyl)ethene (1/1) 27358-55-0 C8H12O4S
    Ethenyl acetate--(ethenesulfonyl)ethene (1/1)
    —— Carbamothioic acid, sodium salt 21055-93-6 C5H11NNaOS+
    Carbamothioic acid, sodium salt
    —— 2-(Tridecylsulfanyl)pyridine--hydrogen bromide (1/1) 6313-82-2 C18H32BrNS
    2-(Tridecylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— 2-(Hexylsulfanyl)pyridine--hydrogen bromide (1/1) 6937-14-0 C11H18BrNS
    2-(Hexylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— Hexane-1,6-diyl bis(N'-prop-2-en-1-ylcarbamimidothioate)--hydrogen bromide (1/1) 6323-55-3 C14H27BrN4S2
    Hexane-1,6-diyl bis(N'-prop-2-en-1-ylcarbamimidothioate)--hydrogen bromide (1/1)
    —— Pentane-1,5-diyl bis(N'-prop-2-en-1-ylcarbamimidothioate)--hydrogen bromide (1/1) 6276-61-5 C13H25BrN4S2
    Pentane-1,5-diyl bis(N'-prop-2-en-1-ylcarbamimidothioate)--hydrogen bromide (1/1)
    —— Xanthic acid, lead(II) salt 5439-59-8 C4H8OPbS2
    Xanthic acid, lead(II) salt
    —— 2,4-Dioxo-1,2,3,4-tetrahydropyrimidin-5-yl carbamimidothioate hydrochloride 42074-70-4 C5H7ClN4O2S
    2,4-Dioxo-1,2,3,4-tetrahydropyrimidin-5-yl carbamimidothioate hydrochloride
    —— 2-Oxopropyl carbamimidothioate--hydrogen chloride (1/1) 6333-72-8 C4H9ClN2OS
    2-Oxopropyl carbamimidothioate--hydrogen chloride (1/1)
    —— (2Z)-2-Methylbut-2-ene-1,4-diyl dicarbamimidothioate--hydrogen bromide (1/1) 16464-63-4 C7H15BrN4S2
    (2Z)-2-Methylbut-2-ene-1,4-diyl dicarbamimidothioate--hydrogen bromide (1/1)
    —— 3,3-Dimethylbutyl carbamimidothioate--hydrogen bromide (1/1) 5467-41-4 C7H17BrN2S
    3,3-Dimethylbutyl carbamimidothioate--hydrogen bromide (1/1)
    —— 2-(Butylsulfanyl)-1H-imidazole--hydrogen chloride (1/1) 6946-12-9 C7H13ClN2S
    2-(Butylsulfanyl)-1H-imidazole--hydrogen chloride (1/1)