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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S,3S)-2-amino-3-methylpentane-1-thiol 681850-93-1 C6H15NS
    (2S,3S)-2-amino-3-methylpentane-1-thiol
    —— (E/Z)-5-phenylthio-4-penten-1-ol 111341-52-7 C11H14OS
    (E/Z)-5-phenylthio-4-penten-1-ol
    —— (S)-3-(3,3-bis(phenylthio)propyl)-5-((3E,5Z)-2-methyl-5-((trimethylsilyl)oxy)hepta-3,5-dien-2-yl)furan-2(5H)-one 1354572-34-1 C30H38O3S2Si
    (S)-3-(3,3-bis(phenylthio)propyl)-5-((3E,5Z)-2-methyl-5-((trimethylsilyl)oxy)hepta-3,5-dien-2-yl)furan-2(5H)-one
    —— (4S,5S,10S,E)-5,9,9-trimethyl-4-(phenylthio)-11-oxabicyclo[8.2.1]trideca-1(13),7-diene-6,12-dione 1354572-36-3 C21H24O3S
    (4S,5S,10S,E)-5,9,9-trimethyl-4-(phenylthio)-11-oxabicyclo[8.2.1]trideca-1(13),7-diene-6,12-dione
    —— 4-[(5-chloro-2-phenylsulfanyl-phenyl)-thioacetyl]-morpholine 67643-07-6 C18H18ClNOS2
    4-[(5-chloro-2-phenylsulfanyl-phenyl)-thioacetyl]-morpholine
    —— 3-benzyl-5-methylsulfanyl-1<i>H</i>-[1,2,4]triazole 103274-32-4 C10H11N3S
    3-benzyl-5-methylsulfanyl-1<i>H</i>-[1,2,4]triazole
    —— 2-(8-Hydroxy-7-oxo-6-phenylthiooctyl)-4-hydroxy-cyclopent-2-en-1-one 76329-76-5 C19H24O4S
    2-(8-Hydroxy-7-oxo-6-phenylthiooctyl)-4-hydroxy-cyclopent-2-en-1-one
    —— N-[2-(4-chlorophenyl)sulfanyl-1-phenylethylidene]hydroxylamine 338794-35-7 C14H12ClNOS
    N-[2-(4-chlorophenyl)sulfanyl-1-phenylethylidene]hydroxylamine
    —— Carbonic acid, thio-, bis(anhydrosulfide) with hexamethylenebis(dithiocarbamic acid), diethyl ester 19657-28-4 C14H24N2O4S4
    Carbonic acid, thio-, bis(anhydrosulfide) with hexamethylenebis(dithiocarbamic acid), diethyl ester
    —— 3-Methyl-5,6-dihydrothieno[2,3-c]pyridazine 74359-54-9 C7H8N2S
    3-Methyl-5,6-dihydrothieno[2,3-c]pyridazine
    —— phenyl 3-azido-4-O-tert-butyldimethylsilyl-2,3,6-trideoxy-1-thio-D-arabinohexopyranoside 258857-69-1 C18H29N3O2SSi
    phenyl 3-azido-4-O-tert-butyldimethylsilyl-2,3,6-trideoxy-1-thio-D-arabinohexopyranoside
    —— 2-Cyclohexyl-2-phenylthioaethanol 66164-83-8 C14H20OS
    2-Cyclohexyl-2-phenylthioaethanol
    —— Butyl 4-(4-chlorophenyl)sulfanylbutanoate 29107-88-8 C14H19ClO2S
    Butyl 4-(4-chlorophenyl)sulfanylbutanoate
    —— 2-[methyl-(9-oxo-9H-thioxanthen-2-yl)-carbamoyl]-3-phenylsulfanyl-benzo[b]thiophene-6-carboxylic acid 1440092-60-3 C30H19NO4S3
    2-[methyl-(9-oxo-9H-thioxanthen-2-yl)-carbamoyl]-3-phenylsulfanyl-benzo[b]thiophene-6-carboxylic acid
    —— 2-Cyclohexyl-2-(phenylthio)essigsaeureaethylester 66164-84-9 C16H22O2S
    2-Cyclohexyl-2-(phenylthio)essigsaeureaethylester
    —— 2-Butoxy-2-cyclohexylaethyl-phenylsulfid 66165-03-5 C18H28OS
    2-Butoxy-2-cyclohexylaethyl-phenylsulfid
    —— Butyl 4-phenylsulfanylbutanoate 29193-75-7 C14H20O2S
    Butyl 4-phenylsulfanylbutanoate
    —— 5-propylmercapto-thiophene-2-carbaldehyde 106166-77-2 C8H10OS2
    5-propylmercapto-thiophene-2-carbaldehyde
    —— 3-Methyl-2-phenylthiobutyl-phenylsulfid 34224-40-3 C17H20S2
    3-Methyl-2-phenylthiobutyl-phenylsulfid
    —— 2-hydroxymethyl-5-propylmercapto-thiophene 98558-24-8 C8H12OS2
    2-hydroxymethyl-5-propylmercapto-thiophene
    —— 2-propylsulfanyl-thiophene 89892-77-3 C7H10S2
    2-propylsulfanyl-thiophene
    —— 2-hydroxymethyl-5-isobutylmercapto-thiophene 104550-73-4 C9H14OS2
    2-hydroxymethyl-5-isobutylmercapto-thiophene
    —— 2-isobutylsulfanyl-thiophene 6911-37-1 C8H12S2
    2-isobutylsulfanyl-thiophene
    —— 5-isobutylmercapto-thiophene-2-carbaldehyde 98954-29-1 C9H12OS2
    5-isobutylmercapto-thiophene-2-carbaldehyde
    —— 2-Butoxy-3-methylbutyl-phenylsulfid 66165-02-4 C15H24OS
    2-Butoxy-3-methylbutyl-phenylsulfid
    —— 1,1-Diethoxy-3-methanesulfinyl-propan-2-one 87084-03-5 C8H16O4S
    1,1-Diethoxy-3-methanesulfinyl-propan-2-one
    —— 6-[bis(ethyloxy)methyl]-2-[(phenylmethyl)thio]-4(1H)-pyrimidinone 525559-02-8 C16H20N2O3S
    6-[bis(ethyloxy)methyl]-2-[(phenylmethyl)thio]-4(1H)-pyrimidinone
    —— 6<i>H</i>-benzo[5,6][1,4]dithiino[2,3-<i>b</i>]indole 24122-62-1 C14H9NS2
    6<i>H</i>-benzo[5,6][1,4]dithiino[2,3-<i>b</i>]indole
    —— (5S,7S)-5-hydroxy-7-phenyl-3,5,6,7-tetrahydro-2H-thiopyrano[2,3-d]thiazol-2-one 1433721-28-8 C12H11NO2S2
    (5S,7S)-5-hydroxy-7-phenyl-3,5,6,7-tetrahydro-2H-thiopyrano[2,3-d]thiazol-2-one
    —— 2-octadecylmercapto-thiophene 102945-08-4 C22H40S2
    2-octadecylmercapto-thiophene
    —— 5-dodecylmercapto-thiophene-2-carbaldehyde 62702-57-2 C17H28OS2
    5-dodecylmercapto-thiophene-2-carbaldehyde
    —— 8,8-dimethyl-5,8-dihydro-2H-[1,3]thiazolo[5',4':5,6]thiopyrano[2,3-d][1,3]thiazol-2,6(3H)-dione 924856-48-4 C9H8N2O2S3
    8,8-dimethyl-5,8-dihydro-2H-[1,3]thiazolo[5',4':5,6]thiopyrano[2,3-d][1,3]thiazol-2,6(3H)-dione
    —— spiro[cyclohexane-1,8'-(5,8-dihydro-2H-[1,3]thiazolo[5',4':5,6]thiopyrano[2,3-d][1,3]thiazol)]-2,6(3H)-dione 924875-50-3 C12H12N2O2S3
    spiro[cyclohexane-1,8'-(5,8-dihydro-2H-[1,3]thiazolo[5',4':5,6]thiopyrano[2,3-d][1,3]thiazol)]-2,6(3H)-dione
    —— 5-octadecylmercapto-thiophene-2-carbaldehyde 102899-22-9 C23H40OS2
    5-octadecylmercapto-thiophene-2-carbaldehyde
    —— 2-Phenylthiododecan-1-ol 66185-36-2 C18H30OS
    2-Phenylthiododecan-1-ol
    —— 1,2,5-dithiazepane hydrochloride 23353-11-9 C4H9NS2*ClH
    1,2,5-dithiazepane hydrochloride
    —— 5-isopropylmercapto-thiophene-2-carbaldehyde 106166-76-1 C8H10OS2
    5-isopropylmercapto-thiophene-2-carbaldehyde
    —— 5-ethylsulfanyl-thiophene-2-carbaldehyde 89639-68-9 C7H8OS2
    5-ethylsulfanyl-thiophene-2-carbaldehyde
    —— 2-ethylmercapto-5-hydroxymethyl-thiophene 98272-25-4 C7H10OS2
    2-ethylmercapto-5-hydroxymethyl-thiophene
    —— 5-(6,7-dichloro-3-(1-methyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-ol 1337928-01-4 C13H7Cl2N7OS2
    5-(6,7-dichloro-3-(1-methyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-ol
    —— cyclohexylidenedimercapto-di-acetic acid diethyl ester 101099-34-7 C14H24O4S2
    cyclohexylidenedimercapto-di-acetic acid diethyl ester
    —— 5-(6,7-dichloro-3-(1-isopropyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-ol 1337928-08-1 C15H11Cl2N7OS2
    5-(6,7-dichloro-3-(1-isopropyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-ol
    —— 1-(5-(6,7-dichloro-3-(1-isopropyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-yloxy)propane-2-ol 1337928-09-2 C18H17Cl2N7O2S2
    1-(5-(6,7-dichloro-3-(1-isopropyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-yloxy)propane-2-ol
    —— Dimethylphosphonylmethyl-p-tolylsulfid 63231-20-9 C10H15O3PS
    Dimethylphosphonylmethyl-p-tolylsulfid
    —— 7,7-Bis(methylthio)norcarane 36369-43-4 C9H16S2
    7,7-Bis(methylthio)norcarane
    —— 3-Methylmercapto-6-(4-methyl-benzyl)-as-triazin-5(4H)-on 118740-02-6 C12H13N3OS
    3-Methylmercapto-6-(4-methyl-benzyl)-as-triazin-5(4H)-on
    —— 1-(5-(6,7-dichloro-3-(1-methyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-yloxy)propane-2-ol 1337928-02-5 C16H13Cl2N7O2S2
    1-(5-(6,7-dichloro-3-(1-methyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-yloxy)propane-2-ol
    —— 5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-one oxime 7675-05-0 C7H7NOS2
    5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-one oxime
    —— 1-Methyl-4-[{[(4-methylphenyl)methyl]sulfanyl}(phenylsulfanyl)methyl]benzene 62740-58-3 C22H22S2
    1-Methyl-4-[{[(4-methylphenyl)methyl]sulfanyl}(phenylsulfanyl)methyl]benzene
    —— 3,4-dihydrothieno[3,2-f]-1,4-thiazepine-5(2H)-thione 187834-22-6 C7H7NS3
    3,4-dihydrothieno[3,2-f]-1,4-thiazepine-5(2H)-thione