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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4-bromo-2-nitrophenyl)(phenyl)sulfane 33358-33-7 C12H8BrNO2S
    (4-bromo-2-nitrophenyl)(phenyl)sulfane
    —— N-methyl-2-(4-bromo-2-nitrophenylthio)benzamide 334632-65-4 C14H11BrN2O3S
    N-methyl-2-(4-bromo-2-nitrophenylthio)benzamide
    —— <i>N</i>-(1-cyano-ethyl)-<i>N</i>'-methyl-thiourea 409314-78-9 C5H9N3S
    <i>N</i>-(1-cyano-ethyl)-<i>N</i>'-methyl-thiourea
    —— 3-chloro-4-dimethylcarbamoylthio-phenylacetic acid methyl ester 91361-78-3 C12H14ClNO3S
    3-chloro-4-dimethylcarbamoylthio-phenylacetic acid methyl ester
    —— bis<2-<4-methyl(thiophenoxy)>benzyl> oxalate 120454-39-9 C30H26O4S2
    bis<2-<4-methyl(thiophenoxy)>benzyl> oxalate
    —— methyl 3-chloro-4-(3-bromopropylthio)-phenylacetate 194792-52-4 C12H14BrClO2S
    methyl 3-chloro-4-(3-bromopropylthio)-phenylacetate
    —— dodecyldimethylsulfonium chloride 41580-87-4 C14H31S*Cl
    dodecyldimethylsulfonium chloride
    —— adamantylideneadamantanethiirane 1-oxide 62281-76-9 C20H28OS
    adamantylideneadamantanethiirane 1-oxide
    —— 11-benzenesulfanyl-drim-7-ene 155191-62-1 C21H30S
    11-benzenesulfanyl-drim-7-ene
    —— 1-ethoxy-2,2-bismethylsulphonylethane 115373-71-2 C6H14O5S2
    1-ethoxy-2,2-bismethylsulphonylethane
    —— (R)-(+)-2,2-dimethyl-6-methylene-1-[1'-(phenylthio)methyl]cyclohexane 502763-41-9 C16H22S
    (R)-(+)-2,2-dimethyl-6-methylene-1-[1'-(phenylthio)methyl]cyclohexane
    —— 2-benzylthio-5-trifluoromethylpyrimidine 94447-84-4 C12H9F3N2S
    2-benzylthio-5-trifluoromethylpyrimidine
    —— (8S,10R)-10-phenylthio-1,4-dioxaspiro[4.5]dec-6-en-8-ol 697741-18-7 C14H16O3S
    (8S,10R)-10-phenylthio-1,4-dioxaspiro[4.5]dec-6-en-8-ol
    —— deuterioisothiocyanic acid 141312-03-0 CHNS
    deuterioisothiocyanic acid
    —— ethyl 2-(5,6,7,8-tetrahydro-3,5,5,8,8-pentamethyl-2-naphthylthio)-5-thiazolecarboxylate 190596-60-2 C21H27NO2S2
    ethyl 2-(5,6,7,8-tetrahydro-3,5,5,8,8-pentamethyl-2-naphthylthio)-5-thiazolecarboxylate
    —— 4-methyl-5-phenylthiomethyl-1,2,3-thiadiazole 205131-55-1 C10H10N2S2
    4-methyl-5-phenylthiomethyl-1,2,3-thiadiazole
    —— 5-ethylsulfanyl-[1,2,3]thiadiazole-4-carboxylic acid ethyl ester 64837-50-9 C7H10N2O2S2
    5-ethylsulfanyl-[1,2,3]thiadiazole-4-carboxylic acid ethyl ester
    —— 5-(1-amino-4-ethoxycarbonyl-1,2,3-triazol-5-yl)mercapto-4-ethoxycarbonyl-1,2,3-thiadiazole 127098-23-1 C10H12N6O4S2
    5-(1-amino-4-ethoxycarbonyl-1,2,3-triazol-5-yl)mercapto-4-ethoxycarbonyl-1,2,3-thiadiazole
    —— 2,6-di(4-methoxyphenylthio)pyridine 1263672-74-7 C19H17NO2S2
    2,6-di(4-methoxyphenylthio)pyridine
    —— 3-carboxymethylsulfanyl-5-(4,6-dimethyl-2-pyrimidinylsulfanyl)methyl-1,2,4-triazole 497059-84-4 C11H13N5O2S2
    3-carboxymethylsulfanyl-5-(4,6-dimethyl-2-pyrimidinylsulfanyl)methyl-1,2,4-triazole
    —— 1-adamantylthioacetic acid amide 56432-91-8 C12H19NS
    1-adamantylthioacetic acid amide
    —— diallyl-N-(prop-2-ynyl) dithiocarbonimidate 1315267-98-1 C10H13NS2
    diallyl-N-(prop-2-ynyl) dithiocarbonimidate
    —— 6-chloro-4-methoxy-2-methylsulfanylpyrimidine-5-carbaldehyde 308110-95-4 C7H7ClN2O2S
    6-chloro-4-methoxy-2-methylsulfanylpyrimidine-5-carbaldehyde
    —— 5-(4,6-dimethyl-2-pyrimidinylsulfanyl)methyl-1,2,4-triazole-3-thione 347344-48-3 C9H11N5S2
    5-(4,6-dimethyl-2-pyrimidinylsulfanyl)methyl-1,2,4-triazole-3-thione
    —— 2-(2-Phenylethylidene)-1,3-benzodithiole 161091-65-2 C15H12S2
    2-(2-Phenylethylidene)-1,3-benzodithiole
    —— 3-(t-butyldiphenylsiloxy)-1-(phenylsulfanyl)propene 1164274-71-8 C25H28OSSi
    3-(t-butyldiphenylsiloxy)-1-(phenylsulfanyl)propene
    —— N,N-dimethyl-2-<(6'-methyl-4'-thien-2''-ylpyrimidin-2'-yl)thio>ethylamine 109628-21-9 C13H17N3S2
    N,N-dimethyl-2-<(6'-methyl-4'-thien-2''-ylpyrimidin-2'-yl)thio>ethylamine
    —— 4-methoxy-2-(phenylthio)phenol 59010-80-9 C13H12O2S
    4-methoxy-2-(phenylthio)phenol
    —— 2-(allylthio)propionyl chloride 53234-73-4 C6H9ClOS
    2-(allylthio)propionyl chloride
    —— bis-(2,2-dichlorotrifluoroethyl) disulfide 83353-93-9 C4Cl4F6S2
    bis-(2,2-dichlorotrifluoroethyl) disulfide
    —— butyl 4-phenylthiopent-2-enoate 88088-00-0 C15H20O2S
    butyl 4-phenylthiopent-2-enoate
    —— 3-trifluoromethyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-21-1 C9H9F3N4S
    3-trifluoromethyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— butyl 4-phenylthiopent-2-enoate 88087-86-9 C15H20O2S
    butyl 4-phenylthiopent-2-enoate
    —— butyl 2-methyl-4-phenylthiopent-3-enoate 88088-02-2 C16H22O2S
    butyl 2-methyl-4-phenylthiopent-3-enoate
    —— butyl 2,2-diethyl-4-phenylthiopent-3-enoate 88088-08-8 C19H28O2S
    butyl 2,2-diethyl-4-phenylthiopent-3-enoate
    —— butyl 2,2-dimethyl-4-phenylthiopent-3-enoate 88088-06-6 C17H24O2S
    butyl 2,2-dimethyl-4-phenylthiopent-3-enoate
    —— 5-methyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one 61452-41-3 C11H12O2S
    5-methyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one
    —— butyl 4-phenylthio-2,2-dipropylpent-3-enoate 88088-09-9 C21H32O2S
    butyl 4-phenylthio-2,2-dipropylpent-3-enoate
    —— 3-methyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-20-0 C9H12N4S
    3-methyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-methoxymethyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-18-6 C10H14N4OS
    3-methoxymethyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-ethyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-22-2 C10H14N4S
    3-ethyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-(2-ethoxy-ethyl)-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-27-7 C12H18N4OS
    3-(2-ethoxy-ethyl)-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— tert-butyl (2-((5-(hydroxymethyl)-2-(methylthio) pyrimidin-4-yl)amino)ethyl)carbamate 1189532-28-2 C13H22N4O3S
    tert-butyl (2-((5-(hydroxymethyl)-2-(methylthio) pyrimidin-4-yl)amino)ethyl)carbamate
    —— 3-propyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-24-4 C11H16N4S
    3-propyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-19-7 C8H10N4S
    7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-ethoxymethyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-25-5 C11H16N4OS
    3-ethoxymethyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-tridecyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60246-39-1 C21H36N4S
    3-tridecyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-heptyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60246-38-0 C15H24N4S
    3-heptyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-cyclopropyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-23-3 C11H14N4S
    3-cyclopropyl-7,8,9,9a-tetrahydro-6<i>H</i>-benzo[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3,5-bis(ethylthio)-4-pyridinecarbonitrile 183679-39-2 C10H12N2S2
    3,5-bis(ethylthio)-4-pyridinecarbonitrile