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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Cyclohexanemethanamine, 4-ethyl-1-[2-(ethylsulfonyl)ethyl]- 1480538-27-9 C13H27NO2S
    Cyclohexanemethanamine, 4-ethyl-1-[2-(ethylsulfonyl)ethyl]-
    —— (4S,5R)-4-(fluoromethyl)-5-{4-[(fluoromethyl)thio]phenyl}-2-phenyl-4,5-dihydro-1,3-oxazole 859520-23-3 C17H15F2NOS
    (4S,5R)-4-(fluoromethyl)-5-{4-[(fluoromethyl)thio]phenyl}-2-phenyl-4,5-dihydro-1,3-oxazole
    —— 2-methyl-2-(propane-2-sulfonyl)-propionic acid 1017539-77-3 C7H14O4S
    2-methyl-2-(propane-2-sulfonyl)-propionic acid
    —— 2-Methylbutane-1,3-dithiol 54812-83-8 C5H12S2
    2-Methylbutane-1,3-dithiol
    —— methyl 2-(m-tolylthio)acetate 190005-34-6 C10H12O2S
    methyl 2-(m-tolylthio)acetate
    —— 8-methyl-5-methylsulfanyl-1,3-diphenyl-1H,8H-pyrimido[4,5-d]pyrimidine-2,4,7-trione 871699-92-2 C20H16N4O3S
    8-methyl-5-methylsulfanyl-1,3-diphenyl-1H,8H-pyrimido[4,5-d]pyrimidine-2,4,7-trione
    —— <i>S</i>-deuterio-ethynethiol 76596-41-3 C2H2S
    <i>S</i>-deuterio-ethynethiol
    —— 1-(2,4-difluoro-benzyl)-6-[5-(6-methylsulfanyl-pyridin-3-yl)-thiophen-2-yl]-2-oxo-4-trifluoromethyl-1,2-dihydro-pyridine-3-carbonitrile 849934-68-5 C24H14F5N3OS2
    1-(2,4-difluoro-benzyl)-6-[5-(6-methylsulfanyl-pyridin-3-yl)-thiophen-2-yl]-2-oxo-4-trifluoromethyl-1,2-dihydro-pyridine-3-carbonitrile
    —— (2S)-2-[(S)-[(2-ethylphenyl)thio](phenyl)methyl]morpholine 668470-64-2 C19H23NOS
    (2S)-2-[(S)-[(2-ethylphenyl)thio](phenyl)methyl]morpholine
    —— (2S)-2-((S)-phenyl{[2-(trifluoromethyl)phenyl]thio}methyl)morpholine 668470-57-3 C18H21NOS2
    (2S)-2-((S)-phenyl{[2-(trifluoromethyl)phenyl]thio}methyl)morpholine
    —— (2S)-2-[(S)-[(2-fluorophenyl)thio](phenyl)methyl]morpholine 668470-63-1 C17H18FNOS
    (2S)-2-[(S)-[(2-fluorophenyl)thio](phenyl)methyl]morpholine
    —— 2-{4-[2-bromo-4-(trifluoromethyl)thiazol-5-ylthio]phenyl}-1,1,1-trifluoropropan-2-ol 869854-06-8 C13H8BrF6NOS2
    2-{4-[2-bromo-4-(trifluoromethyl)thiazol-5-ylthio]phenyl}-1,1,1-trifluoropropan-2-ol
    —— 4-bromomethyl-5-isopropylsulfanyl-1-methyl-3-trifluoromethyl-1H-pyrazole 878204-79-6 C9H12BrF3N2S
    4-bromomethyl-5-isopropylsulfanyl-1-methyl-3-trifluoromethyl-1H-pyrazole
    —— 2-{4-[2-amino-4-(trifluoromethyl)thiazol-5-ylthio]phenyl}-1,1,1-trifluoropropan-2-ol 869854-05-7 C13H10F6N2OS2
    2-{4-[2-amino-4-(trifluoromethyl)thiazol-5-ylthio]phenyl}-1,1,1-trifluoropropan-2-ol
    —— 2-(4-(2,4-dichlorothiazol-5-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol 869854-20-6 C12H8Cl2F3NOS2
    2-(4-(2,4-dichlorothiazol-5-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol
    —— S-4-(1,1,1-trifluoro-2-hydroxypropan-2-yl)phenyl dimethylcarbamothioate 869854-54-6 C12H14F3NO2S
    S-4-(1,1,1-trifluoro-2-hydroxypropan-2-yl)phenyl dimethylcarbamothioate
    —— 2-(4-(2-chlorothiazol-5-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol 869854-19-3 C12H9ClF3NOS2
    2-(4-(2-chlorothiazol-5-ylthio)phenyl)-1,1,1-trifluoropropan-2-ol
    —— 3-chloro-4-[4-[(2S)-1,1,1-trifluoro-2-hydroxypropan-2-yl]phenyl]sulfanylbenzonitrile 869854-57-9 C16H11ClF3NOS
    3-chloro-4-[4-[(2S)-1,1,1-trifluoro-2-hydroxypropan-2-yl]phenyl]sulfanylbenzonitrile
    —— 2-{[4-(3-aminopropyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester 886527-36-2 C14H24N2O2S2
    2-{[4-(3-aminopropyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester
    —— 2-{[4-(2-aminoethyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester 886527-10-2 C13H22N2O2S2
    2-{[4-(2-aminoethyl)-1,3-thiazol-2-yl]thio}-2-methylpropionic acid tert-butyl ester
    —— 5-[2-(2-benzyloxy-ethyl)-5-ethyl-3H-imidazol-4-ylsulfanyl]-3-chloro-benzonitrile 897626-27-6 C21H20ClN3OS
    5-[2-(2-benzyloxy-ethyl)-5-ethyl-3H-imidazol-4-ylsulfanyl]-3-chloro-benzonitrile
    —— (4S,5R)-4-methyl-5-[4-(methylthio)phenyl]-1,3-oxazolidin-2-one 1028459-38-2 C11H13NO2S
    (4S,5R)-4-methyl-5-[4-(methylthio)phenyl]-1,3-oxazolidin-2-one
    —— Cyclopentyl-(4,6-dichloro-2-methylsulfanyl-pyrimidin-5-yl)-methanone 864301-12-2 C11H12Cl2N2OS
    Cyclopentyl-(4,6-dichloro-2-methylsulfanyl-pyrimidin-5-yl)-methanone
    —— (2-chlorophenyl)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)-methanol 864300-82-3 C12H9Cl3N2OS
    (2-chlorophenyl)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)-methanol
    —— tert-butyl-2-{[4-({(6-chloropyrimidm-4-yl)[(2-methyl-1,3-thiazol-4-yl)methyl]amino}methyl)-phenyl]thio}-2-methylpropanoate 881687-58-7 C24H29ClN4O2S2
    tert-butyl-2-{[4-({(6-chloropyrimidm-4-yl)[(2-methyl-1,3-thiazol-4-yl)methyl]amino}methyl)-phenyl]thio}-2-methylpropanoate
    —— tert-butyl-2-{[4-({[6-(cyclohexyloxy)pyrimidin-4-yl][(3,5-dimethylisoxazol-4-yl)methyl]amino}-methyl)phenyl]thio}-2-methylpropanoate 881687-56-5 C31H42N4O4S
    tert-butyl-2-{[4-({[6-(cyclohexyloxy)pyrimidin-4-yl][(3,5-dimethylisoxazol-4-yl)methyl]amino}-methyl)phenyl]thio}-2-methylpropanoate
    —— 4'-[(3-benzyloxy)phenylthio]-2'-chlorodihydrocinnamyl alcohol 676482-21-6 C22H21ClO2S
    4'-[(3-benzyloxy)phenylthio]-2'-chlorodihydrocinnamyl alcohol
    —— (R)-2-(3-chloro-4-cyclopropylsulfanyl-phenyl)-3-(tetrahydropyran-4-yl)-propionic acid 936362-93-5 C17H21ClO3S
    (R)-2-(3-chloro-4-cyclopropylsulfanyl-phenyl)-3-(tetrahydropyran-4-yl)-propionic acid
    —— tert-butyl N-[2-[2-amino-5-(2-oxopyridin-1-yl)phenyl]sulfanylethyl]carbamate 1039517-27-5 C18H23N3O3S
    tert-butyl N-[2-[2-amino-5-(2-oxopyridin-1-yl)phenyl]sulfanylethyl]carbamate
    —— (3aR,4S,7R,7aS)-7-[(5-amino-6-chloro-2-propylsulfanylpyrimidin-4-yl)amino]-2,2-dimethyl-3a,4,7,7a-tetrahydro-1,3-benzodioxol-4-ol 1022927-14-5 C16H23ClN4O3S
    (3aR,4S,7R,7aS)-7-[(5-amino-6-chloro-2-propylsulfanylpyrimidin-4-yl)amino]-2,2-dimethyl-3a,4,7,7a-tetrahydro-1,3-benzodioxol-4-ol
    —— {[4-(Phenylsulfanyl)phenyl]sulfanyl}acetic acid 152171-23-8 C14H12O2S2
    {[4-(Phenylsulfanyl)phenyl]sulfanyl}acetic acid
    —— 1,2-Di(ethenesulfonyl)ethan-1-ol 172650-62-3 C6H10O5S2
    1,2-Di(ethenesulfonyl)ethan-1-ol
    —— 6-methyl-4-(4-methylthio)phenyl-pyran-2-one 387866-30-0 C13H12O2S
    6-methyl-4-(4-methylthio)phenyl-pyran-2-one
    —— di(4-hydroxybut-2-ynyl)sulfone 122951-66-0 C8H10O4S
    di(4-hydroxybut-2-ynyl)sulfone
    —— 2,5-Dihydro-4-[4-(methylthio)phenyl]-2-[(trimethylsilyl)oxy]furan 179175-16-7 C14H20O2SSi
    2,5-Dihydro-4-[4-(methylthio)phenyl]-2-[(trimethylsilyl)oxy]furan
    —— Pyridazine, 6-[[(4-fluorophenyl)methyl]thio]-4-methoxy-3-methyl- 528878-34-4 C13H13FN2OS
    Pyridazine, 6-[[(4-fluorophenyl)methyl]thio]-4-methoxy-3-methyl-
    —— 1H-1,2,3-Triazole-4-methanamine, 1-[2-[(4-fluorophenyl)thio]ethyl]-N-methyl- 1481252-52-1 C12H15FN4S
    1H-1,2,3-Triazole-4-methanamine, 1-[2-[(4-fluorophenyl)thio]ethyl]-N-methyl-
    —— Propanoic acid, 2-[[1-[2-(ethylamino)ethyl]-1H-tetrazol-5-yl]thio]- 1479801-25-6 C8H15N5O2S
    Propanoic acid, 2-[[1-[2-(ethylamino)ethyl]-1H-tetrazol-5-yl]thio]-
    —— 1,2,4-Thiadiazol-5-amine, N-ethyl-3-[[(3-fluorophenyl)thio]methyl]- 1478590-05-4 C11H12FN3S2
    1,2,4-Thiadiazol-5-amine, N-ethyl-3-[[(3-fluorophenyl)thio]methyl]-
    —— Pyrimidine, 4-chloro-2-[[(2-chlorophenyl)thio]methyl]-6-cyclopropyl- 1492530-76-3 C14H12Cl2N2S
    Pyrimidine, 4-chloro-2-[[(2-chlorophenyl)thio]methyl]-6-cyclopropyl-
    —— 1-[(2-Aminoethyl)thio]-2-propanamine 23185-28-6 C5H14N2S
    1-[(2-Aminoethyl)thio]-2-propanamine
    —— Cyclohexanemethanamine, I+/--[[(4-fluorophenyl)thio]methyl]-N,4-dimethyl- 1493550-87-0 C16H24FNS
    Cyclohexanemethanamine, I+/--[[(4-fluorophenyl)thio]methyl]-N,4-dimethyl-
    —— Methyl 2-[(4-chlorophenyl)sulfanyl]ethanimidate 61671-49-6 C9H10ClNOS
    Methyl 2-[(4-chlorophenyl)sulfanyl]ethanimidate
    —— Bicyclo[4.2.0]octa-1,3,5-triene-7-ethanamine, I+/--[[(2-bromophenyl)thio]methyl]- 1533077-08-5 C17H18BrNS
    Bicyclo[4.2.0]octa-1,3,5-triene-7-ethanamine, I+/--[[(2-bromophenyl)thio]methyl]-
    —— (I+/-S)-3-(Methylthio)-I+/--(trifluoromethyl)benzenemethanamine 878539-33-4 C9H10F3NS
    (I+/-S)-3-(Methylthio)-I+/--(trifluoromethyl)benzenemethanamine
    —— (R)-1-(2-Methylsulfanyl-pyrimidin-4-yl)-pyrrolidin-3-ol 1261234-25-6 C9H13N3OS
    (R)-1-(2-Methylsulfanyl-pyrimidin-4-yl)-pyrrolidin-3-ol
    —— (1S)-1-[4-[(Trifluoromethyl)thio]phenyl]-1,2-ethanediamine 1213057-21-6 C9H11F3N2S
    (1S)-1-[4-[(Trifluoromethyl)thio]phenyl]-1,2-ethanediamine
    —— 11-Methyl-5-nitro-2-thia-10,13-diazatricyclo[13.4.0.03,8]nonadeca-1(19),3(8),4,6,15,17-hexaene-9,14-dione 1393085-59-0 C17H15N3O4S
    11-Methyl-5-nitro-2-thia-10,13-diazatricyclo[13.4.0.03,8]nonadeca-1(19),3(8),4,6,15,17-hexaene-9,14-dione
    —— 1-(6-Methoxy-2-(methylthio)pyrimidin-4-yl)azetidine-3-carboxylic acid 1353977-93-1 C10H13N3O3S
    1-(6-Methoxy-2-(methylthio)pyrimidin-4-yl)azetidine-3-carboxylic acid
    —— 2-Chloro-N-ethyl-N-(4-methylsulfanyl-benzyl)-acetamide 1353983-04-6 C12H16ClNOS
    2-Chloro-N-ethyl-N-(4-methylsulfanyl-benzyl)-acetamide