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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[p-(phenylthio)phenoxy]ethylcarbamic acid S-ethyl ester 72489-94-2 C17H19NO3S
    2-[p-(phenylthio)phenoxy]ethylcarbamic acid S-ethyl ester
    —— 2,4,6,8-Tetramethylcyclotetrasiloxane-2,4,6,8-tetrapropanethiol 66607-96-3 C16H40O4S4Si4
    2,4,6,8-Tetramethylcyclotetrasiloxane-2,4,6,8-tetrapropanethiol
    —— 3-Iodoprop-2-yn-1-yl thiocyanate 113079-26-8 C4H2INS
    3-Iodoprop-2-yn-1-yl thiocyanate
    —— [4-chloro-6-(4-fluoro-anilino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester 50892-16-5 C14H13ClFN3O2S
    [4-chloro-6-(4-fluoro-anilino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester
    —— 1H-1,2,4-Triazole, 3-[[2-(2,2,2-trifluoroethoxy)phenyl]thio]- 141547-55-9 C10H8F3N3OS
    1H-1,2,4-Triazole, 3-[[2-(2,2,2-trifluoroethoxy)phenyl]thio]-
    —— 3-[(2,5-Dimethylfuran-3-yl)sulfanyl]heptan-4-one 61295-45-2 C13H20O2S
    3-[(2,5-Dimethylfuran-3-yl)sulfanyl]heptan-4-one
    —— 3-[(11-ethyl-12-phenyl-6H-benzo[c][1]benzothiocin-3-yl)oxy]propane-1,2-diol 85850-92-6 C26H26O3S
    3-[(11-ethyl-12-phenyl-6H-benzo[c][1]benzothiocin-3-yl)oxy]propane-1,2-diol
    —— 5-nitrofuran-2-carboxaldehyde O-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]benzyl}oxime 153581-69-2 C24H23FN2O6S
    5-nitrofuran-2-carboxaldehyde O-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]benzyl}oxime
    —— [2-(2-Diethylaminomethyl-phenylsulfanyl)-phenyl]-methanol 62220-67-1 C18H23NOS
    [2-(2-Diethylaminomethyl-phenylsulfanyl)-phenyl]-methanol
    —— 2-Bromo-6-methylsulfanyl-phenol 107724-67-4 C7H7BrOS
    2-Bromo-6-methylsulfanyl-phenol
    —— 1-tetrahydropyranyloxy-1-[2-(4-fluorophenylthio)phenyl]prop-2-ene 146372-82-9 C20H21FO2S
    1-tetrahydropyranyloxy-1-[2-(4-fluorophenylthio)phenyl]prop-2-ene
    —— 2-Methyl-3-[(2-methylprop-2-en-1-yl)sulfanyl]furan 61720-52-3 C9H12OS
    2-Methyl-3-[(2-methylprop-2-en-1-yl)sulfanyl]furan
    —— methyl N'-(methylcarbamoyl)carbamimidothioate —— C4H9N3OS
    methyl N'-(methylcarbamoyl)carbamimidothioate
    —— 2-tert-butyl-4-chloro-5-(4-isopropoxymethyl-cyclohexyl)-methylthio-3(2H)-pyridazinone 141604-31-1 C19H31ClN2O2S
    2-tert-butyl-4-chloro-5-(4-isopropoxymethyl-cyclohexyl)-methylthio-3(2H)-pyridazinone
    —— 4-[(2,2,3,3-Tetrafluoropropyl)sulfanyl]benzene-1,2-diamine 54029-84-4 C9H10F4N2S
    4-[(2,2,3,3-Tetrafluoropropyl)sulfanyl]benzene-1,2-diamine
    —— 2-[(4-Hydroxyphenyl)sulfanyl]ethyl [(4-hydroxyphenyl)sulfanyl]acetate 130876-55-0 C16H16O4S2
    2-[(4-Hydroxyphenyl)sulfanyl]ethyl [(4-hydroxyphenyl)sulfanyl]acetate
    —— methyl N-[N'-[4-phenylsulfanyl-2-(propanoylamino)phenyl]-N-propanoylcarbamimidoyl]carbamate 58306-24-4 C21H24N4O4S
    methyl N-[N'-[4-phenylsulfanyl-2-(propanoylamino)phenyl]-N-propanoylcarbamimidoyl]carbamate
    —— 1-(5-amino-2-chloro-4-fluorophenylthio)-cyclopropanecarboxylic acid ethyl ester 140909-33-7 C12H13ClFNO2S
    1-(5-amino-2-chloro-4-fluorophenylthio)-cyclopropanecarboxylic acid ethyl ester
    —— {[(2-Chloroethyl)sulfanyl]methyl}cyclopropane 56988-06-8 C6H11ClS
    {[(2-Chloroethyl)sulfanyl]methyl}cyclopropane
    —— O-Ethyl hydroxycarbamothioate 116312-12-0 C3H7NO2S
    O-Ethyl hydroxycarbamothioate
    —— 1-Chloro-4-{[2-(ethenesulfonyl)ethenyl]sulfanyl}benzene 61441-97-2 C10H9ClO2S2
    1-Chloro-4-{[2-(ethenesulfonyl)ethenyl]sulfanyl}benzene
    —— methyl N-[N'-(2-acetamido-4-phenylsulfanylphenyl)-N-propanoylcarbamimidoyl]carbamate 58306-22-2 C20H22N4O4S
    methyl N-[N'-(2-acetamido-4-phenylsulfanylphenyl)-N-propanoylcarbamimidoyl]carbamate
    —— 3-[(2,5-Dimethylfuran-3-yl)sulfanyl]butane-2-thiol 59190-21-5 C10H16OS2
    3-[(2,5-Dimethylfuran-3-yl)sulfanyl]butane-2-thiol
    —— 2-[(4-Nitrophenyl)sulfanyl]-5-phenyl-1,3,4-thiadiazole 62652-43-1 C14H9N3O2S2
    2-[(4-Nitrophenyl)sulfanyl]-5-phenyl-1,3,4-thiadiazole
    —— 3-[(2-Methylfuran-3-yl)sulfanyl]butane-2-thiol 59190-23-7 C9H14OS2
    3-[(2-Methylfuran-3-yl)sulfanyl]butane-2-thiol
    —— 3-Methylthio-2-propenylcyanid 36756-71-5 C5H7NS
    3-Methylthio-2-propenylcyanid
    —— 4-(isopropylamino)-2-(methylmercapto)pyrimidine-5-carbonitrile 251372-08-4 C9H12N4S
    4-(isopropylamino)-2-(methylmercapto)pyrimidine-5-carbonitrile
    —— 2-Methylhept-2-ene-1-thiol 61758-09-6 C8H16S
    2-Methylhept-2-ene-1-thiol
    —— methyl N-[N-methoxycarbonyl-N'-[2-(2-methylpropanoylamino)-4-phenylsulfanylphenyl]carbamimidoyl]carbamate 73851-13-5 C21H24N4O5S
    methyl N-[N-methoxycarbonyl-N'-[2-(2-methylpropanoylamino)-4-phenylsulfanylphenyl]carbamimidoyl]carbamate
    —— 1-Methyl-5-(methylsulfanyl)-1,3-dihydro-2H-imidazole-2-thione 89367-89-5 C5H8N2S2
    1-Methyl-5-(methylsulfanyl)-1,3-dihydro-2H-imidazole-2-thione
    —— 1-ethylsulfanyl-1-fluoro-ethane 65038-45-1 C4H9FS
    1-ethylsulfanyl-1-fluoro-ethane
    —— 3-Chlor-4-trichlormethylmercapto-phenylisocyanat 74159-83-4 C8H3Cl4NOS
    3-Chlor-4-trichlormethylmercapto-phenylisocyanat
    —— Butyl-thiocarbamic acid O-(2-dimethylamino-ethyl) ester 59884-02-5 C9H20N2OS
    Butyl-thiocarbamic acid O-(2-dimethylamino-ethyl) ester
    —— methyl N-[N'-[4-(2-chlorophenyl)sulfanyl-2-(propanoylamino)phenyl]-N-methoxycarbonylcarbamimidoyl]carbamate 73851-15-7 C20H21ClN4O5S
    methyl N-[N'-[4-(2-chlorophenyl)sulfanyl-2-(propanoylamino)phenyl]-N-methoxycarbonylcarbamimidoyl]carbamate
    —— 2-tert-butyl-4-chloro-5-(4-isobutoxycyclohexyl)-methylthio-3(2H)-pyridazinone 141604-47-9 C19H31ClN2O2S
    2-tert-butyl-4-chloro-5-(4-isobutoxycyclohexyl)-methylthio-3(2H)-pyridazinone
    —— N-Hexyl-6-(methylsulfanyl)-1,2,4,5-tetrazin-3-amine 95573-59-4 C9H17N5S
    N-Hexyl-6-(methylsulfanyl)-1,2,4,5-tetrazin-3-amine
    —— 3-(2,3-dimethyl-phenylsulfanyl)-propionic acid 104216-76-4 C11H14O2S
    3-(2,3-dimethyl-phenylsulfanyl)-propionic acid
    —— Trimethyl thiuram disulfide 3983-53-7 C5H10N2S4
    Trimethyl thiuram disulfide
    —— bis-(2-mercapto-ethyl)-tetrasulfide 15576-65-5 C4H10S6
    bis-(2-mercapto-ethyl)-tetrasulfide
    —— 2-chloro-4-methylmercapto-6-(thien-3-ylmethyloxy)pyridine 175461-32-2 C11H10ClNOS2
    2-chloro-4-methylmercapto-6-(thien-3-ylmethyloxy)pyridine
    —— 1-Methyl-sulfinyl-undecen-(1) 97029-63-5 C12H24OS
    1-Methyl-sulfinyl-undecen-(1)
    —— (E)-3-Methanesulfonyl-acrylic acid 63068-43-9 C4H6O4S
    (E)-3-Methanesulfonyl-acrylic acid
    —— 4-Thiocyanatothiazol-2-amine 64603-56-1 C4H3N3S2
    4-Thiocyanatothiazol-2-amine
    —— 1H-Imidazol-2-yl diethylcarbamodithioate 62652-39-5 C8H13N3S2
    1H-Imidazol-2-yl diethylcarbamodithioate
    —— 2-[[(4-Methylphenyl)thio]methylene]propanedinitrile 64688-77-3 C11H8N2S
    2-[[(4-Methylphenyl)thio]methylene]propanedinitrile
    —— 1,3-Thiazol-2-yl dimethylcarbamodithioate 62652-45-3 C6H8N2S3
    1,3-Thiazol-2-yl dimethylcarbamodithioate
    —— N-Chlorothiourea 114019-32-8 CH3ClN2S
    N-Chlorothiourea
    —— 2-(2,3,6-trimethylphenylmethylthio)pyridine N-oxide 60263-91-4 C15H17NOS
    2-(2,3,6-trimethylphenylmethylthio)pyridine N-oxide
    —— N-Decyl-11-[(4-hydroxyphenyl)sulfanyl]undecanamide 400024-28-4 C27H47NO2S
    N-Decyl-11-[(4-hydroxyphenyl)sulfanyl]undecanamide
    —— 4-[(2-Ethoxyethyl)sulfanyl]benzene-1,2-diamine 54029-82-2 C10H16N2OS
    4-[(2-Ethoxyethyl)sulfanyl]benzene-1,2-diamine