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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N,1-Dimethyl-4-[2-(methylthio)-4-pyrimidinyl]-1H-pyrazol-5-amine 1057385-32-6 C10H13N5S
    N,1-Dimethyl-4-[2-(methylthio)-4-pyrimidinyl]-1H-pyrazol-5-amine
    —— 3-Methyl-6-(4-methyl-1,2,3-thiadiazol-5-yl)-2-(methylthio)-4(3H)-pyrimidinone 1184917-63-2 C9H10N4OS2
    3-Methyl-6-(4-methyl-1,2,3-thiadiazol-5-yl)-2-(methylthio)-4(3H)-pyrimidinone
    —— 4-(2-methyl-1H-imidazol-4-yl)-2-(methylthio)pyrimidine 1184920-27-1 C9H10N4S
    4-(2-methyl-1H-imidazol-4-yl)-2-(methylthio)pyrimidine
    —— 6-(furan-3-yl)-3-methyl-2-(methylthio)pyrimidin-4(3H)-one 1184917-23-4 C10H10N2O2S
    6-(furan-3-yl)-3-methyl-2-(methylthio)pyrimidin-4(3H)-one
    —— 6-(2-methoxyethyl)-3-methyl-2-(methylthio)pyrimidin-4(3H)-one 1184919-92-3 C9H14N2O2S
    6-(2-methoxyethyl)-3-methyl-2-(methylthio)pyrimidin-4(3H)-one
    —— 3-((Pyridin-4-ylthio)methyl)pyrrolidin-3-ol 1184913-77-6 C10H14N2OS
    3-((Pyridin-4-ylthio)methyl)pyrrolidin-3-ol
    —— [5-(aminomethyl)spiro[2H-1-benzofuran-3,4'-piperidine]-1'-yl]-(5-phenylsulfanylfuran-2-yl)methanone 1025688-27-0 C24H24N2O3S
    [5-(aminomethyl)spiro[2H-1-benzofuran-3,4'-piperidine]-1'-yl]-(5-phenylsulfanylfuran-2-yl)methanone
    —— 5-Methyl-N-({6-[(methylcarbamoyl)amino]-4-(methylthio)pyridin-2-yl}carbamoyl)thiophene-3-sulfonamide 1158784-75-8 C14H17N5O4S3
    5-Methyl-N-({6-[(methylcarbamoyl)amino]-4-(methylthio)pyridin-2-yl}carbamoyl)thiophene-3-sulfonamide
    —— N-({6-[(2-Fluoroethyl)amino]-4-(methylthio)pyridin-2-yl}carbamoyl)-5-(2-methoxyethyl)-4-methylthiophene-2-sulfonamide 1158785-96-6 C17H23FN4O4S3
    N-({6-[(2-Fluoroethyl)amino]-4-(methylthio)pyridin-2-yl}carbamoyl)-5-(2-methoxyethyl)-4-methylthiophene-2-sulfonamide
    —— 4-(4,5-dibromo-1H-pyrrole-2-carbonyl)-2-phenylsulfanyl-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide 1146689-51-1 C19H19Br2N5O3S2
    4-(4,5-dibromo-1H-pyrrole-2-carbonyl)-2-phenylsulfanyl-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide
    —— 2-benzyl-3-(4-chlorophenylthio)-N-phenethylpropanamide 1146929-37-4 C24H24ClNOS
    2-benzyl-3-(4-chlorophenylthio)-N-phenethylpropanamide
    —— 4-[4,5-dibromo-1-(2-trimethylsilanyl-ethoxymethyl)-1H-pyrrole-2-carbonyl]-2-phenylsulfanyl-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide 1146689-69-1 C25H33Br2N5O4S2Si
    4-[4,5-dibromo-1-(2-trimethylsilanyl-ethoxymethyl)-1H-pyrrole-2-carbonyl]-2-phenylsulfanyl-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide
    —— 4-(4,5-dibromo-1-methoxymethyl-1H-pyrrole-2-carbonyl)-2-phenylsulfanyl-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide 1146689-68-0 C21H23Br2N5O4S2
    4-(4,5-dibromo-1-methoxymethyl-1H-pyrrole-2-carbonyl)-2-phenylsulfanyl-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide
    —— 4-(4,5-dibromo-1-methyl-1H-pyrrole-2-carbonyl)-2-phenylsulfanyl-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide 1146689-67-9 C20H21Br2N5O3S2
    4-(4,5-dibromo-1-methyl-1H-pyrrole-2-carbonyl)-2-phenylsulfanyl-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide
    —— 2-phenylsulfanyl-4-(3,4,5-tribromo-1H-pyrrole-2-carbonyl)-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide 1146689-59-9 C19H18Br3N5O3S2
    2-phenylsulfanyl-4-(3,4,5-tribromo-1H-pyrrole-2-carbonyl)-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide
    —— (4,5-dibromo-1H-pyrrol-2-yl)-(2-phenylsulfanyl-1,5,6,7-tetrahydro-imidazo[4,5-b]pyridin-4-yl)-methanone 1146689-47-5 C17H14Br2N4OS
    (4,5-dibromo-1H-pyrrol-2-yl)-(2-phenylsulfanyl-1,5,6,7-tetrahydro-imidazo[4,5-b]pyridin-4-yl)-methanone
    —— 4-(4-bromo-1-methyl-1H-pyrrole-2-carbonyl)-2-phenylsulfanyl-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide 1146689-46-4 C20H22BrN5O3S2
    4-(4-bromo-1-methyl-1H-pyrrole-2-carbonyl)-2-phenylsulfanyl-4,5,6,7-tetrahydro-imidazo[4,5-b]pyridine-1-sulfonic acid dimethylamide
    —— 5-(difluoro(phenylsulfanyl)methyl)-5-hydroxy-1-(prop-2-ynyl)pyrrolidin-2-one 1152033-08-3 C14H13F2NO2S
    5-(difluoro(phenylsulfanyl)methyl)-5-hydroxy-1-(prop-2-ynyl)pyrrolidin-2-one
    —— cyclopropanecarboxylic acid {4-[4-(5-hydroxycarbamoyl-pentylamino)-6-(5-methyl-2H-pyrazol-3-ylamino)-pyrimidin-2-ylsulfanyl]-phenyl}-amide 1170187-92-4 C24H30N8O3S
    cyclopropanecarboxylic acid {4-[4-(5-hydroxycarbamoyl-pentylamino)-6-(5-methyl-2H-pyrazol-3-ylamino)-pyrimidin-2-ylsulfanyl]-phenyl}-amide
    —— 3-[(2-Aminophenyl)sulfanyl-phenylmethyl]pentane-2,4-dione 1332326-05-2 C18H19NO2S
    3-[(2-Aminophenyl)sulfanyl-phenylmethyl]pentane-2,4-dione
    —— 5-acetyl-4-[4-(2-fluoro-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one 1173658-58-6 C19H17FN2O2S
    5-acetyl-4-[4-(2-fluoro-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one
    —— 5-(difluoro(phenylsulfanyl)methyl)-5-hydroxy-1-(3-(tri-methylsilyl)prop-2-ynyl)pyrrolidin-2-one 1152033-06-1 C17H21F2NO2SSi
    5-(difluoro(phenylsulfanyl)methyl)-5-hydroxy-1-(3-(tri-methylsilyl)prop-2-ynyl)pyrrolidin-2-one
    —— 4-[4-(3-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-71-3 C20H19FN2O2S2
    4-[4-(3-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 1-{4-[4-(3-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-ethanone 1173658-72-4 C19H17FN2OS2
    1-{4-[4-(3-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-ethanone
    —— 4-[4-(2-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-73-5 C20H19FN2O2S2
    4-[4-(2-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 4-[4-(2-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-57-5 C20H19FN2O3S
    4-[4-(2-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 3-[[2-(Cyclopropylamino)-1-methyl-2-oxoethyl]sulfonyl]propanoic acid 1038977-57-9 C9H15NO5S
    3-[[2-(Cyclopropylamino)-1-methyl-2-oxoethyl]sulfonyl]propanoic acid
    —— I(2)-[4-[(Trifluoromethyl)thio]phenyl]-1-piperidineethanamine 1041551-10-3 C14H19F3N2S
    I(2)-[4-[(Trifluoromethyl)thio]phenyl]-1-piperidineethanamine
    —— 2-[(3,4-Dimethylphenyl)thio]-I+/--methylbenzenemethanamine 1036555-20-0 C16H19NS
    2-[(3,4-Dimethylphenyl)thio]-I+/--methylbenzenemethanamine
    —— 1-[4-(Methylsulfanyl)phenyl]ethane-1-thiol 83776-51-6 C9H12S2
    1-[4-(Methylsulfanyl)phenyl]ethane-1-thiol
    —— 2-[[2-(Cyclopentylamino)-1-methyl-2-oxoethyl]sulfonyl]propanoic acid 1039902-72-1 C11H19NO5S
    2-[[2-(Cyclopentylamino)-1-methyl-2-oxoethyl]sulfonyl]propanoic acid
    —— 2-[4-(Methylthio)phenyl]-5-pyrimidinamine 1094311-68-8 C11H11N3S
    2-[4-(Methylthio)phenyl]-5-pyrimidinamine
    —— 6-Amino-5-[(2-aminophenyl)thio]-1-methyl-2,4(1H,3H)-pyrimidinedione 1094481-94-3 C11H12N4O2S
    6-Amino-5-[(2-aminophenyl)thio]-1-methyl-2,4(1H,3H)-pyrimidinedione
    —— 2-(4-Fluoro-phenylsulfanyl)-5-methyl-phenylamine 943615-82-5 C13H12FNS
    2-(4-Fluoro-phenylsulfanyl)-5-methyl-phenylamine
    —— I+/--Methyl-N-[3-(methylthio)phenyl]benzenemethanamine 1019560-89-4 C15H17NS
    I+/--Methyl-N-[3-(methylthio)phenyl]benzenemethanamine
    —— 1-[2-[(4-Fluorophenyl)thio]ethyl]hexahydro-1H-1,4-diazepine 1094668-17-3 C13H19FN2S
    1-[2-[(4-Fluorophenyl)thio]ethyl]hexahydro-1H-1,4-diazepine
    —— 2-Fluoro-I+/--methyl-6-[(4-methyl-2-thiazolyl)thio]benzenemethanamine 1019624-00-0 C12H13FN2S2
    2-Fluoro-I+/--methyl-6-[(4-methyl-2-thiazolyl)thio]benzenemethanamine
    —— 2-[[(2,5-Dimethylphenyl)thio]methyl]oxirane 20032-58-0 C11H14OS
    2-[[(2,5-Dimethylphenyl)thio]methyl]oxirane
    —— N-Hydroxy-2-[(1H-1,2,4-triazol-5-ylthio)methyl]benzenecarboximidamide 1021085-47-1 C10H11N5OS
    N-Hydroxy-2-[(1H-1,2,4-triazol-5-ylthio)methyl]benzenecarboximidamide
    —— 1-[(3,4-Difluorophenyl)sulfanyl]propan-2-one 1152913-89-7 C9H8F2OS
    1-[(3,4-Difluorophenyl)sulfanyl]propan-2-one
    —— 2-Chloro-5-[[(2,4-dimethylphenyl)thio]methyl]benzenamine 1097802-79-3 C15H16ClNS
    2-Chloro-5-[[(2,4-dimethylphenyl)thio]methyl]benzenamine
    —— 1-(2,5-Dichlorothiophen-3-yl)-2-(2-fluorophenyl)sulfanylethanone 1152929-25-3 C12H7Cl2FOS2
    1-(2,5-Dichlorothiophen-3-yl)-2-(2-fluorophenyl)sulfanylethanone
    —— 1-(2,5-Dichlorothiophen-3-yl)-2-(4-fluorophenyl)sulfanylethanone 1152658-63-3 C12H7Cl2FOS2
    1-(2,5-Dichlorothiophen-3-yl)-2-(4-fluorophenyl)sulfanylethanone
    —— (4-Thiomethoxy-benzylthio)-essigsaeure 34722-36-6 C10H12O2S2
    (4-Thiomethoxy-benzylthio)-essigsaeure
    —— Methyl 3-[(2,4-difluorophenyl)thio]propanoate 1097125-27-3 C10H10F2O2S
    Methyl 3-[(2,4-difluorophenyl)thio]propanoate
    —— 4-[[(4-Bromophenyl)thio]methyl]-2-thiazolamine 1097168-40-5 C10H9BrN2S2
    4-[[(4-Bromophenyl)thio]methyl]-2-thiazolamine
    —— 2-[[(2-Bromo-5-fluorophenyl)methyl]thio]-5-fluorobenzenamine 1095493-97-2 C13H10BrF2NS
    2-[[(2-Bromo-5-fluorophenyl)methyl]thio]-5-fluorobenzenamine
    —— 2-[(3,4-Difluorophenyl)sulfanyl]-2-phenylacetic acid 1097125-23-9 C14H10F2O2S
    2-[(3,4-Difluorophenyl)sulfanyl]-2-phenylacetic acid
    —— 5-Bromo-2-[[(2-chloro-6-fluorophenyl)methyl]thio]benzenamine 1095621-97-8 C13H10BrClFNS
    5-Bromo-2-[[(2-chloro-6-fluorophenyl)methyl]thio]benzenamine
    —— 2-{[(2-Aminophenyl)sulfanyl]methyl}-5-hydroxy-4H-pyran-4-one 138426-84-3 C12H11NO3S
    2-{[(2-Aminophenyl)sulfanyl]methyl}-5-hydroxy-4H-pyran-4-one