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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Hydroxyprop-2-en-1-yl carbamimidothioate 147608-23-9 C4H8N2OS
    2-Hydroxyprop-2-en-1-yl carbamimidothioate
    —— Acetic acid;2-(2-hydroxyethylsulfanylmethylsulfanyl)ethanol 41123-73-3 C9H20O6S2
    Acetic acid;2-(2-hydroxyethylsulfanylmethylsulfanyl)ethanol
    —— 5H-[1,2,4]Triazolo[3,4-b][1,3]thiazocine 585528-63-8 C7H7N3S
    5H-[1,2,4]Triazolo[3,4-b][1,3]thiazocine
    —— N-Carbamothioyl-N,N'-diethylmethanehydrazonamide 577746-68-0 C6H14N4S
    N-Carbamothioyl-N,N'-diethylmethanehydrazonamide
    —— [(2-Methoxybuta-1,3-dien-1-yl)sulfanyl]benzene 60466-66-2 C11H12OS
    [(2-Methoxybuta-1,3-dien-1-yl)sulfanyl]benzene
    —— N-Carbamothioyl-N-methylmethanehydrazonamide 577746-69-1 C3H8N4S
    N-Carbamothioyl-N-methylmethanehydrazonamide
    —— 6-Chloro-4-methyl-2-(phenylimino)benzo[B]thiophen-3(2H)-one 5858-08-2 C15H10ClNOS
    6-Chloro-4-methyl-2-(phenylimino)benzo[B]thiophen-3(2H)-one
    —— 3,3'-[Sulfanediylbis(methylene)]bis{3-[(2-hydroxyethyl)sulfanyl]pentane-1,5-diol} 64036-92-6 C16H34O6S3
    3,3'-[Sulfanediylbis(methylene)]bis{3-[(2-hydroxyethyl)sulfanyl]pentane-1,5-diol}
    —— 2-ethyl-6-thiomethoxy-7-azabenzothiazole 666702-54-1 C9H10N2S2
    2-ethyl-6-thiomethoxy-7-azabenzothiazole
    —— S-pyridin-2-yl 2-(2-amino-1,3-thiazol-4-yl)-2-methoxyiminoethanethioate —— C11H10N4O2S2
    S-pyridin-2-yl 2-(2-amino-1,3-thiazol-4-yl)-2-methoxyiminoethanethioate
    —— 1-Chloropyrrolidine-2,5-dione;methylsulfanylbenzene 82661-92-5 C11H12ClNO2S
    1-Chloropyrrolidine-2,5-dione;methylsulfanylbenzene
    —— 2-Ethoxy-5-[(phenylsulfanyl)methyl]-3-(prop-1-en-1-yl)furan 941270-51-5 C16H18O2S
    2-Ethoxy-5-[(phenylsulfanyl)methyl]-3-(prop-1-en-1-yl)furan
    —— 3-(3-Chlorophenyl)-2-methyl-5-(phenylthio)furan 941270-45-7 C17H13ClOS
    3-(3-Chlorophenyl)-2-methyl-5-(phenylthio)furan
    —— 2-tert-Butyl-5-phenylsulfanyl-furan 941270-60-6 C14H16OS
    2-tert-Butyl-5-phenylsulfanyl-furan
    —— 1-(2-methyl-5-(phenylthiomethyl)furan-3-yl)ethanone 941270-52-6 C14H14O2S
    1-(2-methyl-5-(phenylthiomethyl)furan-3-yl)ethanone
    —— 3-(2-Chlorophenyl)-2-methyl-5-(phenylthio)furan 941270-46-8 C17H13ClOS
    3-(2-Chlorophenyl)-2-methyl-5-(phenylthio)furan
    —— 3-(2,4-Dichlorophenyl)-2-methoxy-5-(phenylthio)furan 941270-41-3 C17H12Cl2O2S
    3-(2,4-Dichlorophenyl)-2-methoxy-5-(phenylthio)furan
    —— 2-methoxy-3-phenyl-5-[(phenylthio)methyl]furan 941270-39-9 C18H16O2S
    2-methoxy-3-phenyl-5-[(phenylthio)methyl]furan
    —— 2-methoxy-3-(3-methylphenyl)-5-[(phenylthio)methyl]furan 941270-43-5 C19H18O2S
    2-methoxy-3-(3-methylphenyl)-5-[(phenylthio)methyl]furan
    —— Tetramethylen tetraxanthogen 35106-11-7 C12H16O4S8
    Tetramethylen tetraxanthogen
    —— 2-(Trifluoromethylthio)-benzeneboronic acid 947533-17-7 C7H6BF3O2S
    2-(Trifluoromethylthio)-benzeneboronic acid
    —— 3-[(Hexa-1,4-dien-3-yl)disulfanyl]hexa-1,4-diene 33368-82-0 C12H18S2
    3-[(Hexa-1,4-dien-3-yl)disulfanyl]hexa-1,4-diene
    —— 2H-Thieno[2',3':4,5]pyrrolo[1,2-c]imidazole 389860-21-3 C8H6N2S
    2H-Thieno[2',3':4,5]pyrrolo[1,2-c]imidazole
    —— 2,4-Dioxo-1,3-diazetidine-1,3-diylbis(p-phenylenethio-o-phenylene)diisocyanate 85818-49-1 C28H16N4O4S2
    2,4-Dioxo-1,3-diazetidine-1,3-diylbis(p-phenylenethio-o-phenylene)diisocyanate
    —— 12-Azidododecylmethanethiosulfonate 1215670-42-0 C13H27N3O2S2
    12-Azidododecylmethanethiosulfonate
    —— 2-(3-Trifluoromethyl-pyridin-2-ylsulfanyl)-ethylamine; hydrochloride 1208081-53-1 C8H10ClF3N2S
    2-(3-Trifluoromethyl-pyridin-2-ylsulfanyl)-ethylamine; hydrochloride
    —— (6-Methoxy-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acetic acid 1053657-58-1 C9H8F3NO3S
    (6-Methoxy-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acetic acid
    —— (6-Chloro-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acethydrazide 1053657-49-0 C8H7ClF3N3OS
    (6-Chloro-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acethydrazide
    —— 2-[[6-Chloro-4-(trifluoromethyl)-2-pyridyl]sulfanyl]ethanamine hydrochloride 1208081-83-7 C8H9Cl2F3N2S
    2-[[6-Chloro-4-(trifluoromethyl)-2-pyridyl]sulfanyl]ethanamine hydrochloride
    —— 10-(t-Boc-amino)-1-decylmethanethiosulfonate 1216932-86-3 C16H33NO4S2
    10-(t-Boc-amino)-1-decylmethanethiosulfonate
    —— Spiro[bicyclo[3.1.1]heptane-6,2'-[1,3]dithiolane] 18543-35-6 C9H14S2
    Spiro[bicyclo[3.1.1]heptane-6,2'-[1,3]dithiolane]
    —— Copper(1+);thiourea 27316-89-8 C3H12CuN6S3
    Copper(1+);thiourea
    —— (3S)-1-(Methanesulfonyl)-5-methylhex-1-en-3-amine 193482-44-9 C8H17NO2S
    (3S)-1-(Methanesulfonyl)-5-methylhex-1-en-3-amine
    —— O,O-Dimethyl S-[2-(propane-2-sulfinyl)ethyl] phosphorothioate 2635-50-9 C7H17O4PS2
    O,O-Dimethyl S-[2-(propane-2-sulfinyl)ethyl] phosphorothioate
    —— Chionxalin-2,3-sulfid 286-91-9 C8H4N2S
    Chionxalin-2,3-sulfid
    —— 2,3,7,8,12,13,17,18-octakis-(4-fluorobutylthio)porphyrazinatomagnesium(II) 1360897-06-8 C48H64F8MgN8S8
    2,3,7,8,12,13,17,18-octakis-(4-fluorobutylthio)porphyrazinatomagnesium(II)
    —— 2,3,7,8,12,13,17,18-octakis-[2-(2-ethoxyethoxy)ethylthio]porphyrazine 1360897-10-4 C64H106N8O16S8
    2,3,7,8,12,13,17,18-octakis-[2-(2-ethoxyethoxy)ethylthio]porphyrazine
    —— 2(1,3)-benzena-1(4),3(4)-diethyl-4,8-dithia-6-thio-(1,3)(3,5)-1,2,4-triazolacyclooctaphan 1375489-00-1 C17H18N6S3
    2(1,3)-benzena-1(4),3(4)-diethyl-4,8-dithia-6-thio-(1,3)(3,5)-1,2,4-triazolacyclooctaphan
    —— 3-(4-Fluorophenyl)sulfanyl-1-methylquinolin-1-ium;iodide 1383710-37-9 C16H13FNS*I
    3-(4-Fluorophenyl)sulfanyl-1-methylquinolin-1-ium;iodide
    —— 2(1,3)-benzena-1(4),3(4)-diethyl-4,8-dithia-(1,3)(3,5)-1,2,4-triazolacyclooctaphane-6-one 1375488-97-3 C17H18N6OS2
    2(1,3)-benzena-1(4),3(4)-diethyl-4,8-dithia-(1,3)(3,5)-1,2,4-triazolacyclooctaphane-6-one
    —— ACP1a 1371635-84-5 C18H18ClF3N2O3S2
    ACP1a
    —— 2-methyl-N-(3-(phenylthio)propyl)-2-((5-(trifluoromethyl)-pyridin-2-yl)sulfonyl)propanamide 1382488-96-1 C19H21F3N2O3S2
    2-methyl-N-(3-(phenylthio)propyl)-2-((5-(trifluoromethyl)-pyridin-2-yl)sulfonyl)propanamide
    —— 2-[4-(7-Methyl-5,8,10-trithia-3-azatricyclo[7.3.0.02,6]dodeca-1(9),2(6),3,11-tetraen-4-yl)-5-oxo-1,2,4-triazol-1-yl]acetonitrile 1343408-85-4 C13H9N5OS3
    2-[4-(7-Methyl-5,8,10-trithia-3-azatricyclo[7.3.0.02,6]dodeca-1(9),2(6),3,11-tetraen-4-yl)-5-oxo-1,2,4-triazol-1-yl]acetonitrile
    —— 2-(2-Bromophenyl)sulfanyl-1-(6-chloropyridin-3-yl)ethanone 1350522-24-5 C13H9BrClNOS
    2-(2-Bromophenyl)sulfanyl-1-(6-chloropyridin-3-yl)ethanone
    —— amino-4-[5-(2-pyrimidinylsulfanyl)-1,3,4-oxadiazol-2-yl]anilinomethanethione 1350301-83-5 C13H10N6OS2
    amino-4-[5-(2-pyrimidinylsulfanyl)-1,3,4-oxadiazol-2-yl]anilinomethanethione
    —— 2-[[5-(3-Chlorophenyl)-2-methylfuran-3-yl]methylsulfanyl]-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-4-one 1351525-82-0 C19H17ClN2O2S
    2-[[5-(3-Chlorophenyl)-2-methylfuran-3-yl]methylsulfanyl]-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-4-one
    —— (E)-4-(dimethylamino)-N-methyl-N-[4-(2-methylphenyl)sulfanylimidazo[1,5-a]quinoxalin-8-yl]but-2-enamide 1345250-86-3 C24H25N5OS
    (E)-4-(dimethylamino)-N-methyl-N-[4-(2-methylphenyl)sulfanylimidazo[1,5-a]quinoxalin-8-yl]but-2-enamide
    —— 2-(1-Methyl-1H-indazol-5-ylsulfanyl)-5-fluorobenzylamine 756839-32-4 C15H14FN3S
    2-(1-Methyl-1H-indazol-5-ylsulfanyl)-5-fluorobenzylamine
    —— 2-(5-bromo-2-(methylthio)pyrimidin-4-yl)thiazolo[5,4-c]pyridine 893441-61-7 C11H7BrN4S2
    2-(5-bromo-2-(methylthio)pyrimidin-4-yl)thiazolo[5,4-c]pyridine
    —— 3-(4-dimethylcarbamoylsulfanyl-2-methyl-phenyl)-propionic acid methyl ester 591775-11-0 C14H19NO3S
    3-(4-dimethylcarbamoylsulfanyl-2-methyl-phenyl)-propionic acid methyl ester