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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— trifluoro-[methoxyl-(trifluoromethylsulphonyl)-methylsulphonyl]-methane 132273-41-7 C4H4F6O5S2
    trifluoro-[methoxyl-(trifluoromethylsulphonyl)-methylsulphonyl]-methane
    —— 7,7-bis(trifluoromethanesulphonyl)bicyclo<4.1.0>heptane 132273-40-6 C9H10F6O4S2
    7,7-bis(trifluoromethanesulphonyl)bicyclo<4.1.0>heptane
    —— 5-phenylsulfanyl-valeryl chloride 343941-84-4 C11H13ClOS
    5-phenylsulfanyl-valeryl chloride
    —— (E)-N'-(4-fluorobenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide 1480226-89-8 C16H12FN5O2S
    (E)-N'-(4-fluorobenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide
    —— 1,3-Diazecane-2-thione 72995-02-9 C8H16N2S
    1,3-Diazecane-2-thione
    —— 2-(5-(4-chlorophenyl)-4,5-dihydro-1-phenyl-1H-pyrazol-3-yl)-5-(methylthio)-1,3,4-thiadiazole 1345041-92-0 C18H15ClN4S2
    2-(5-(4-chlorophenyl)-4,5-dihydro-1-phenyl-1H-pyrazol-3-yl)-5-(methylthio)-1,3,4-thiadiazole
    —— octahydro-[1,3]diazonine-2-thione 92897-36-4 C7H14N2S
    octahydro-[1,3]diazonine-2-thione
    —— (E)-N'-(5-chloro-2-hydroxybenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide 1480227-22-2 C16H12ClN5O3S
    (E)-N'-(5-chloro-2-hydroxybenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide
    —— (E)-N'-(5-bromo-2-hydroxybenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide 1523215-53-3 C16H12BrN5O3S
    (E)-N'-(5-bromo-2-hydroxybenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide
    —— (E)-N'-(2-fluorobenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide 1480227-14-2 C16H12FN5O2S
    (E)-N'-(2-fluorobenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide
    —— (E)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)-N'-(thiophen-2-ylmethylene)acetohydrazide 1480227-29-9 C14H11N5O2S2
    (E)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)-N'-(thiophen-2-ylmethylene)acetohydrazide
    —— (E)-N'-(4-methylbenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide 1523215-41-9 C17H15N5O2S
    (E)-N'-(4-methylbenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide
    —— (E)-N'-(3,5-dibromo-2-hydroxybenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide 1480227-24-4 C16H11Br2N5O3S
    (E)-N'-(3,5-dibromo-2-hydroxybenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide
    —— (E)-N'-(4-chlorobenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide 1480226-90-1 C16H12ClN5O2S
    (E)-N'-(4-chlorobenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide
    —— [5-(4-pyridyl)-1,3,4-oxadiazol-2-ylthio]acetic acid methyl ester 139980-86-2 C10H9N3O3S
    [5-(4-pyridyl)-1,3,4-oxadiazol-2-ylthio]acetic acid methyl ester
    —— (E)-N'-benzylidene-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide 1480226-86-5 C16H13N5O2S
    (E)-N'-benzylidene-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide
    —— (E)-N'-(4-hydroxybenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide 1480226-97-8 C16H13N5O3S
    (E)-N'-(4-hydroxybenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide
    —— (E)-N'-(3-fluorobenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide 1480226-99-0 C16H12FN5O2S
    (E)-N'-(3-fluorobenzylidene)-2-((5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)thio)acetohydrazide
    —— methyl 2-(2-fluoro-4-((2-methoxyethyl)thio)phenyl)acetate 1622242-94-7 C12H15FO3S
    methyl 2-(2-fluoro-4-((2-methoxyethyl)thio)phenyl)acetate
    —— Boc-NMe-Ala-Thioamide 860344-09-8 C9H18N2O2S
    Boc-NMe-Ala-Thioamide
    —— 1-methyl-5-(methylsulfanyl)-1H-pyrazole-3-carbaldehyde 1192004-48-0 C6H8N2OS
    1-methyl-5-(methylsulfanyl)-1H-pyrazole-3-carbaldehyde
    —— methyl [1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]acetate 1192004-49-1 C8H12N2O2S
    methyl [1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]acetate
    —— methyl 2-[1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]-3-(tetrahydro-2H-pyran-4-yl)propanoate 1192004-51-5 C14H22N2O3S
    methyl 2-[1-methyl-5-(methylsulfanyl)-1H-pyrazol-3-yl]-3-(tetrahydro-2H-pyran-4-yl)propanoate
    —— Ethyl ((4-cyano-3-((2-ethoxy-2-oxoethyl)thio)-5-isothiazolyl)thio)acetate 311333-74-1 C12H14N2O4S3
    Ethyl ((4-cyano-3-((2-ethoxy-2-oxoethyl)thio)-5-isothiazolyl)thio)acetate
    —— 2-[(3-cyano-4-methyl-6-oxo-1,6-dihydropyridin-2-yl)sulfanyl]acetic acid 134616-73-2 C9H8N2O3S
    2-[(3-cyano-4-methyl-6-oxo-1,6-dihydropyridin-2-yl)sulfanyl]acetic acid
    —— bis{9-cyano-3-(4-fluorophenyl)-8-methyl-6-oxo-3,4-dihydro-2H,6H-pyrido[2,1-b][1,3,5]thiadiazin-7-yl}methane 1114956-77-2 C31H24F2N6O2S2
    bis{9-cyano-3-(4-fluorophenyl)-8-methyl-6-oxo-3,4-dihydro-2H,6H-pyrido[2,1-b][1,3,5]thiadiazin-7-yl}methane
    —— 4-methyl-6-oxo-2-prop-2-enylsulfanyl-1H-pyridine-3-carbonitrile 134616-85-6 C10H10N2OS
    4-methyl-6-oxo-2-prop-2-enylsulfanyl-1H-pyridine-3-carbonitrile
    —— 4,5,6-Trimethyl-2-(methylthio)nicotinonitrile 151693-69-5 C10H12N2S
    4,5,6-Trimethyl-2-(methylthio)nicotinonitrile
    —— 4-Phenylthio-7-acetylamino-2,1,3-bemzoxadiazole 215818-22-7 C14H11N3O2S
    4-Phenylthio-7-acetylamino-2,1,3-bemzoxadiazole
    —— (E)-hex-3-ene-1,6-dithiol 901772-76-7 C6H12S2
    (E)-hex-3-ene-1,6-dithiol
    —— Ethyl 4-[(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl]-3-oxobutanoate 263890-55-7 C15H18N2O3S
    Ethyl 4-[(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl]-3-oxobutanoate
    —— S-Ethyl-N-(3-pentyliden)thioformhydrazonat 62104-28-3 C8H16N2S
    S-Ethyl-N-(3-pentyliden)thioformhydrazonat
    —— 4-Phenylthio-7-benzoylamino-2,1,3-benzoxadiazole 215818-23-8 C19H13N3O2S
    4-Phenylthio-7-benzoylamino-2,1,3-benzoxadiazole
    —— 2-(3-cyano-4-dimethylaminopyridin-2-ylsulfanyl)acetamide 147992-93-6 C10H12N4OS
    2-(3-cyano-4-dimethylaminopyridin-2-ylsulfanyl)acetamide
    —— 4-chloro-2-methylsulfanylbenzo[4,5]imidazo[2,1-b]pyrimido[5,4-f][1,3,4]thiadiazepin-5-ol 180298-94-6 C13H8ClN5S2
    4-chloro-2-methylsulfanylbenzo[4,5]imidazo[2,1-b]pyrimido[5,4-f][1,3,4]thiadiazepin-5-ol
    —— Ethyl 2-(1,5-dimethyl-4-oxopyrazolo[3,4-d]pyridazin-3-yl)sulfanylacetate 96988-08-8 C11H14N4O3S
    Ethyl 2-(1,5-dimethyl-4-oxopyrazolo[3,4-d]pyridazin-3-yl)sulfanylacetate
    —— Ethyl 2-(1,6-dimethyl-5-oxopyridazino[4,5-e][1,3,4]thiadiazin-3-yl)sulfanylacetate 96988-27-1 C11H14N4O3S2
    Ethyl 2-(1,6-dimethyl-5-oxopyridazino[4,5-e][1,3,4]thiadiazin-3-yl)sulfanylacetate
    —— 4-chloro-2-methylsulfanyl-5,6-dihydrobenzo[4,5]imidazo[2,1-b]pyrimido[5,4-f][1,3,4]thiadiazepin-5-ol 308110-96-5 C13H10ClN5OS2
    4-chloro-2-methylsulfanyl-5,6-dihydrobenzo[4,5]imidazo[2,1-b]pyrimido[5,4-f][1,3,4]thiadiazepin-5-ol
    —— 3-carboxymethylthio-1,5-dimethyl-1H-pyrazolo<3,4-d>pyridazin-4(5H)-one 96988-03-3 C9H10N4O3S
    3-carboxymethylthio-1,5-dimethyl-1H-pyrazolo<3,4-d>pyridazin-4(5H)-one
    —— 7-methyl-4-piperidin-1-yl-5H-pyrimido[4,5-b][1,4]thiazin-6-one 54660-38-7 C12H16N4OS
    7-methyl-4-piperidin-1-yl-5H-pyrimido[4,5-b][1,4]thiazin-6-one
    —— 4-piperidin-1-yl-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one 54660-31-0 C11H14N4OS
    4-piperidin-1-yl-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one
    —— 5-methyl-2-(6-methylsulfanylpyrimidin-4-yl)-2H-pyrazol-3-ylamine 1018473-15-8 C9H11N5S
    5-methyl-2-(6-methylsulfanylpyrimidin-4-yl)-2H-pyrazol-3-ylamine
    —— 2-(2-Carbomethoxyethylthio)-3-cyanopyridine 111042-81-0 C10H10N2O2S
    2-(2-Carbomethoxyethylthio)-3-cyanopyridine
    —— bromoethyl methanethiosulfonate 26139-15-1 C3H7BrO2S2
    bromoethyl methanethiosulfonate
    —— di(4-hydroxy-3-n-nonylphenyl)sulphide 1108607-45-9 C30H46O2S
    di(4-hydroxy-3-n-nonylphenyl)sulphide
    —— S-(5-bromopentyl)methanesulfonothioate 212262-06-1 C6H13BrO2S2
    S-(5-bromopentyl)methanesulfonothioate
    —— 4-Methylbenzyl-phenyl-disulfid, 4-Methyl-thiobenzyl-phenylsulfid 92191-54-3 C14H14S2
    4-Methylbenzyl-phenyl-disulfid, 4-Methyl-thiobenzyl-phenylsulfid
    —— α,α-Dichlor-N-(2-hydroxy-aethyl)-N-(4-methylmercapto-benzyl)-acetamid 3576-65-6 C12H15Cl2NO2S
    α,α-Dichlor-N-(2-hydroxy-aethyl)-N-(4-methylmercapto-benzyl)-acetamid
    —— 4-Methylthiobenzylthiol 108499-20-3 C8H10S2
    4-Methylthiobenzylthiol
    —— 2-(p-Methylthiophenyl)hexanenitrile 61023-48-1 C13H17NS
    2-(p-Methylthiophenyl)hexanenitrile