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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— trimethyl(Z)-α-methylthio-α-(hydroxyimino)orthotrithioacetate 172531-53-2 C6H13NOS4
    trimethyl(Z)-α-methylthio-α-(hydroxyimino)orthotrithioacetate
    —— S-hexyl hexanethiosulfonate 88130-84-1 C12H26O2S2
    S-hexyl hexanethiosulfonate
    —— Bis(octadecylsulfanyl)methanone 112096-11-4 C37H74OS2
    Bis(octadecylsulfanyl)methanone
    —— (2-Chlor-aethyl)-decyl-sulfon 59682-01-8 C12H25ClO2S
    (2-Chlor-aethyl)-decyl-sulfon
    —— 2-hexylisothiourea hydrobromide 4270-01-3 BrH*C7H16N2S
    2-hexylisothiourea hydrobromide
    —— 3-Bromo-1-ethenyl-5-(methylsulfanyl)-1H-pyrazole 923036-03-7 C6H7BrN2S
    3-Bromo-1-ethenyl-5-(methylsulfanyl)-1H-pyrazole
    —— 3-[(4-tetradecylsulfanylphenyl)methyl]-4H-1,2,4-oxadiazol-5-one 850143-56-5 C23H36N2O2S
    3-[(4-tetradecylsulfanylphenyl)methyl]-4H-1,2,4-oxadiazol-5-one
    —— N-(phenylsulfanylmethyl)morpholine 10316-03-7 C11H15NOS
    N-(phenylsulfanylmethyl)morpholine
    —— 1-(phenylthio)-4-carbomethoxycyclohexene 60466-70-8 C14H16O2S
    1-(phenylthio)-4-carbomethoxycyclohexene
    —— [4aR]-4,4a,5,6,7,8-hexahydro-1-(methylthiophenyl)-4a-methyl-6,6'-(1,3-dioxolane)-2(3H)-naphthalenone 270927-44-1 C20H24O3S
    [4aR]-4,4a,5,6,7,8-hexahydro-1-(methylthiophenyl)-4a-methyl-6,6'-(1,3-dioxolane)-2(3H)-naphthalenone
    —— [2,2'-bi(1,3-dithianyl-2-yl)](1,3-dithian-2-yl)methanone 1155851-76-5 C13H20OS6
    [2,2'-bi(1,3-dithianyl-2-yl)](1,3-dithian-2-yl)methanone
    —— 3-Methyl-2-pyridin-2-ylsulfanylpyridine 76093-19-1 C11H10N2S
    3-Methyl-2-pyridin-2-ylsulfanylpyridine
    —— 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrahydroxy-2-thiapentacyclo[19.3.1.1<sup>3,7</sup>.1<sup>9,13</sup>.1<sup>15,19</sup>]octacosa-1(25),3,5,7(26),9,11,13(27),15,17,19(28),21,23-dodecaene 195056-78-1 C43H54O4S
    5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrahydroxy-2-thiapentacyclo[19.3.1.1<sup>3,7</sup>.1<sup>9,13</sup>.1<sup>15,19</sup>]octacosa-1(25),3,5,7(26),9,11,13(27),15,17,19(28),21,23-dodecaene
    —— tert-butyl 4-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}piperidine-1-carboxylate 1156468-95-9 C22H25BrN6O4S
    tert-butyl 4-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}piperidine-1-carboxylate
    —— 8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9-piperidin-4-yl-9H-purin-6-amine 1156467-71-8 C17H17BrN6O2S
    8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9-piperidin-4-yl-9H-purin-6-amine
    —— 4-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}piperidine-1-carbaldehyde 1156467-75-2 C18H17BrN6O3S
    4-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}piperidine-1-carbaldehyde
    —— 4-(1-methyl-5-phenylthio-1H-1, 2, 4-triazol-3-yl)-2, 4-dioxobutanoic acid ethyl ester 875553-65-4 C15H15N3O4S
    4-(1-methyl-5-phenylthio-1H-1, 2, 4-triazol-3-yl)-2, 4-dioxobutanoic acid ethyl ester
    —— 1-(o-methylthiophenyl)-4,5-dihydro-5-hydroxy-1H-1,2,3-triazole 108429-49-8 C9H11N3OS
    1-(o-methylthiophenyl)-4,5-dihydro-5-hydroxy-1H-1,2,3-triazole
    —— α-Cyanthioisobuttersaeureamid 89181-74-8 C5H8N2S
    α-Cyanthioisobuttersaeureamid
    —— [[2-(2-chloroethoxy)ethyl]thio]ethene 170135-59-8 C6H11ClOS
    [[2-(2-chloroethoxy)ethyl]thio]ethene
    —— 5-chloro-2-(pyridin-4-ylsulfanyl)-pyridin-3-ylamine 899424-04-5 C10H8ClN3S
    5-chloro-2-(pyridin-4-ylsulfanyl)-pyridin-3-ylamine
    —— 4-bromobutyl 1,1-dimethylethyl sulfone 1119801-61-4 C8H17BrO2S
    4-bromobutyl 1,1-dimethylethyl sulfone
    —— 4-bromobutyl 1,1-dimethylethyl sulfide 1119801-76-1 C8H17BrS
    4-bromobutyl 1,1-dimethylethyl sulfide
    —— methyl 2,2-difluoro-2-(fluorosulfonyl)acetate 27825-80-5 C4H6F2O4S
    methyl 2,2-difluoro-2-(fluorosulfonyl)acetate
    —— 1-chloro-3-i-propylsulfonylpropane 128147-27-3 C6H13ClO2S
    1-chloro-3-i-propylsulfonylpropane
    —— 5-nitro-2-phenylsulfanyl-benzenesulfinic acid 200422-32-8 C12H9NO4S2
    5-nitro-2-phenylsulfanyl-benzenesulfinic acid
    —— 3,5-dichloro-4-[(6-methyl-1H-benzimidazol-2-yl)sulfanyl]aniline 315228-22-9 C14H11Cl2N3S
    3,5-dichloro-4-[(6-methyl-1H-benzimidazol-2-yl)sulfanyl]aniline
    —— (1E)-1-(phenylsulfanylmethyl)cyclopentadecene 125335-05-9 C22H34S
    (1E)-1-(phenylsulfanylmethyl)cyclopentadecene
    —— 1-(phenylthiomethyl)cyclopentadecanol 78514-60-0 C22H36OS
    1-(phenylthiomethyl)cyclopentadecanol
    —— 3,5-Bis(trifluormethylthio)anilin 57830-52-1 C8H5F6NS2
    3,5-Bis(trifluormethylthio)anilin
    —— cyclopropyl isopropyl sulphone 112981-24-5 C6H12O2S
    cyclopropyl isopropyl sulphone
    —— 1-chloro-3-i-propylsulfinylpropane 128147-22-8 C6H13ClOS
    1-chloro-3-i-propylsulfinylpropane
    —— 6-Ethylsulfenyl-6-ethylsulfinyl-4-methylthiomethyleneheptan-3-one 94272-43-2 C13H26O2S3
    6-Ethylsulfenyl-6-ethylsulfinyl-4-methylthiomethyleneheptan-3-one
    —— Monosulfoxide of Acetaldehyde Diethyl Thioacetal 72796-28-2 C6H14OS2
    Monosulfoxide of Acetaldehyde Diethyl Thioacetal
    —— 4-isocyanatomethyl-2,2-bis(trifluoromethyl)-[1,3]oxathiolan-5-one 170997-01-0 C7H3F6NO3S
    4-isocyanatomethyl-2,2-bis(trifluoromethyl)-[1,3]oxathiolan-5-one
    —— 2-(6-(2-amidinoethyl)phenyl)thio-1-(2-amidinoethyl)benzene 1062597-71-0 C18H22N4S
    2-(6-(2-amidinoethyl)phenyl)thio-1-(2-amidinoethyl)benzene
    —— bis-methylsulfanyl-acetic acid methyl ester 51534-59-9 C5H10O2S2
    bis-methylsulfanyl-acetic acid methyl ester
    —— 4-(4-(4-methoxyphenylthio)-2,6-dimethylphenyl)thiazol-2-amine 1334923-02-2 C18H18N2OS2
    4-(4-(4-methoxyphenylthio)-2,6-dimethylphenyl)thiazol-2-amine
    —— N-(4-(4-(4-methoxyphenylthio)-2,6-dimethylphenyl)thiazol-2-yl)isonicotinamide 1334921-43-5 C24H21N3O2S2
    N-(4-(4-(4-methoxyphenylthio)-2,6-dimethylphenyl)thiazol-2-yl)isonicotinamide
    —— N-{4-(2,6-dimethyl-4-(pyrazin-2-ylthio)phenyl)thiazol-2-yl}isonicotinamide 1439936-14-7 C21H17N5OS2
    N-{4-(2,6-dimethyl-4-(pyrazin-2-ylthio)phenyl)thiazol-2-yl}isonicotinamide
    —— tert-butyl-2-[(4-{[(6-chloropyrimidin-4-yl)(2-methoxyethyl)amino]methyl}phenyl)thio]-2-methyl-propanoate 881687-22-5 C22H30ClN3O3S
    tert-butyl-2-[(4-{[(6-chloropyrimidin-4-yl)(2-methoxyethyl)amino]methyl}phenyl)thio]-2-methyl-propanoate
    —— 2-cyano-3-<(4-methylphenyl)thio>cyclopentan-1-one 149325-39-3 C13H13NOS
    2-cyano-3-<(4-methylphenyl)thio>cyclopentan-1-one
    —— (+/-)-10-phenylthio-1,4-dioxaspiro[4.5]dec-6-en-8-one 173383-41-0 C14H14O3S
    (+/-)-10-phenylthio-1,4-dioxaspiro[4.5]dec-6-en-8-one
    —— 2-cyclopentanespiro-1,3-dithia-4-cyclohexene 83236-46-8 C15H16N2S2
    2-cyclopentanespiro-1,3-dithia-4-cyclohexene
    —— (2-amino-5-chloro-3-methyl-phenyl-mercapto)-acetic acid 861870-28-2 C9H10ClNO2S
    (2-amino-5-chloro-3-methyl-phenyl-mercapto)-acetic acid
    —— (<i>E</i>)-2-methyl-1-methylsulfanyl-but-2-ene 137175-32-7 C6H12S
    (<i>E</i>)-2-methyl-1-methylsulfanyl-but-2-ene
    —— (R)-1-isothiocyanato-5-(methylsulfinyl)pentane 646-23-1 C7H13NOS2
    (R)-1-isothiocyanato-5-(methylsulfinyl)pentane
    —— 1,5-dihydro-3-methyl-10-thiaisoalloxazine 65693-74-5 C11H9N3O2S
    1,5-dihydro-3-methyl-10-thiaisoalloxazine
    —— (<i>E</i>)-1-ethylsulfanyl-2-methyl-but-2-ene 69690-80-8 C7H14S
    (<i>E</i>)-1-ethylsulfanyl-2-methyl-but-2-ene
    —— 4-chloro-3-hydroxy-1-methyl-5-methylthiopyrazole 92607-63-1 C5H7ClN2OS
    4-chloro-3-hydroxy-1-methyl-5-methylthiopyrazole