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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-N-[2-(4-chlorophenyl)ethyl]-2-phenylsulfanylpropanamide —— C17H18ClNOS
    (2R)-N-[2-(4-chlorophenyl)ethyl]-2-phenylsulfanylpropanamide
    —— (2S)-N-[2-(4-chlorophenyl)ethyl]-2-phenylsulfanylpropanamide —— C17H18ClNOS
    (2S)-N-[2-(4-chlorophenyl)ethyl]-2-phenylsulfanylpropanamide
    —— 3-methyl-5-[(2R)-pentan-2-yl]sulfanyl-1,2,4-triazol-4-amine —— C8H16N4S
    3-methyl-5-[(2R)-pentan-2-yl]sulfanyl-1,2,4-triazol-4-amine
    —— (3R)-3-[1-(2-methylpropyl)tetrazol-5-yl]sulfanyl-1-propan-2-ylpiperidin-2-one —— C13H23N5OS
    (3R)-3-[1-(2-methylpropyl)tetrazol-5-yl]sulfanyl-1-propan-2-ylpiperidin-2-one
    —— (2S)-2-(1H-imidazol-2-ylsulfanyl)-N-(thiophen-2-ylmethyl)propanamide —— C11H13N3OS2
    (2S)-2-(1H-imidazol-2-ylsulfanyl)-N-(thiophen-2-ylmethyl)propanamide
    —— (2R)-2-(1H-imidazol-2-ylsulfanyl)-N-(thiophen-2-ylmethyl)propanamide —— C11H13N3OS2
    (2R)-2-(1H-imidazol-2-ylsulfanyl)-N-(thiophen-2-ylmethyl)propanamide
    —— 2-(4-chlorophenyl)sulfanyl-N-cyclopentyl-5-nitrobenzamide —— C18H17ClN2O3S
    2-(4-chlorophenyl)sulfanyl-N-cyclopentyl-5-nitrobenzamide
    —— 2-(4-bromo-2-methylphenyl)sulfanyl-N-cyclopentylacetamide —— C14H18BrNOS
    2-(4-bromo-2-methylphenyl)sulfanyl-N-cyclopentylacetamide
    —— (2S)-N-cyclopropyl-2-(1H-imidazol-2-ylsulfanyl)propanamide —— C9H13N3OS
    (2S)-N-cyclopropyl-2-(1H-imidazol-2-ylsulfanyl)propanamide
    —— (2R)-N-cyclopropyl-2-(1H-imidazol-2-ylsulfanyl)propanamide —— C9H13N3OS
    (2R)-N-cyclopropyl-2-(1H-imidazol-2-ylsulfanyl)propanamide
    —— 2-[[4-(4-Chlorophenyl)sulfanyl-3-nitrophenyl]sulfonylamino]ethyl-dimethylazanium —— C16H19ClN3O4S2+
    2-[[4-(4-Chlorophenyl)sulfanyl-3-nitrophenyl]sulfonylamino]ethyl-dimethylazanium
    —— 3-(2-bromophenyl)sulfanyl-N-methyl-N-[(2S)-1-methylsulfonylpropan-2-yl]propanamide —— C14H20BrNO3S2
    3-(2-bromophenyl)sulfanyl-N-methyl-N-[(2S)-1-methylsulfonylpropan-2-yl]propanamide
    —— 3-(2-bromophenyl)sulfanyl-N-methyl-N-[(2R)-1-methylsulfonylpropan-2-yl]propanamide —— C14H20BrNO3S2
    3-(2-bromophenyl)sulfanyl-N-methyl-N-[(2R)-1-methylsulfonylpropan-2-yl]propanamide
    —— (2R)-2-(1H-imidazol-2-ylsulfanyl)-N-prop-2-enylpropanamide —— C9H13N3OS
    (2R)-2-(1H-imidazol-2-ylsulfanyl)-N-prop-2-enylpropanamide
    —— 4-(4-chlorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]-3-nitrobenzenesulfonamide —— C16H17ClN2O5S2
    4-(4-chlorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]-3-nitrobenzenesulfonamide
    —— (3S)-N-(3,5-dimethyl-1,2-oxazol-4-yl)-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide —— C15H16N2O2S
    (3S)-N-(3,5-dimethyl-1,2-oxazol-4-yl)-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— 4-(4-chlorophenyl)sulfanyl-N-[2-(dimethylamino)ethyl]-3-nitrobenzenesulfonamide —— C16H18ClN3O4S2
    4-(4-chlorophenyl)sulfanyl-N-[2-(dimethylamino)ethyl]-3-nitrobenzenesulfonamide
    —— (3R)-N-(3,5-dimethyl-1,2-oxazol-4-yl)-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide —— C15H16N2O2S
    (3R)-N-(3,5-dimethyl-1,2-oxazol-4-yl)-N-methyl-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (2S)-2-(1H-imidazol-2-ylsulfanyl)-N-prop-2-enylpropanamide —— C9H13N3OS
    (2S)-2-(1H-imidazol-2-ylsulfanyl)-N-prop-2-enylpropanamide
    —— (2R)-2-(3,4-difluorophenyl)sulfanyl-N,N-dimethylpropanamide —— C11H13F2NOS
    (2R)-2-(3,4-difluorophenyl)sulfanyl-N,N-dimethylpropanamide
    —— (2S)-2-(3,4-difluorophenyl)sulfanyl-N,N-dimethylpropanamide —— C11H13F2NOS
    (2S)-2-(3,4-difluorophenyl)sulfanyl-N,N-dimethylpropanamide
    —— 2-(3,4-difluorophenyl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]acetamide —— C13H17F2NOS
    2-(3,4-difluorophenyl)sulfanyl-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— 2-(3,4-difluorophenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C13H15F2NO2S
    2-(3,4-difluorophenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-(3,4-difluorophenyl)sulfanyl-N-[(2R)-3-methylbutan-2-yl]acetamide —— C13H17F2NOS
    2-(3,4-difluorophenyl)sulfanyl-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— 2-(3,4-difluorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C13H15F2NO2S
    2-(3,4-difluorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 3-(oxan-4-yl)-5-[[(5R)-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-yl]sulfanyl]-1,2,4-triazol-4-amine —— C18H24N4OS
    3-(oxan-4-yl)-5-[[(5R)-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-yl]sulfanyl]-1,2,4-triazol-4-amine
    —— (E)-3-(4-methylsulfanylphenyl)-2-(4-methyl-1,3-thiazol-2-yl)prop-2-enenitrile —— C14H12N2S2
    (E)-3-(4-methylsulfanylphenyl)-2-(4-methyl-1,3-thiazol-2-yl)prop-2-enenitrile
    —— 3-(oxan-4-yl)-5-[[(5S)-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-yl]sulfanyl]-1,2,4-triazol-4-amine —— C18H24N4OS
    3-(oxan-4-yl)-5-[[(5S)-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-yl]sulfanyl]-1,2,4-triazol-4-amine
    —— 4-butyl-3-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one —— C14H17N5O2S2
    4-butyl-3-[(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— 4-butyl-3-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one —— C14H17N5O2S2
    4-butyl-3-[(1S)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— (2R)-2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dimethylpropanamide —— C16H22N4OS
    (2R)-2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dimethylpropanamide
    —— 2-[(1S)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C12H12N4OS4
    2-[(1S)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-[(1R)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C12H12N4OS4
    2-[(1R)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— (2S)-N,N-dimethyl-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C16H21N3O2S
    (2S)-N,N-dimethyl-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dimethylpropanamide —— C16H22N4OS
    (2S)-2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dimethylpropanamide
    —— 2-[(1S)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole —— C15H16N4OS3
    2-[(1S)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole
    —— (2R)-N,N-dimethyl-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C16H21N3O2S
    (2R)-N,N-dimethyl-2-[[5-[(2S)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-[(1R)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole —— C15H16N4OS3
    2-[(1R)-1-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole
    —— (2S)-N,N-dimethyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C8H13N3OS3
    (2S)-N,N-dimethyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N,N-dimethyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C8H13N3OS3
    (2R)-N,N-dimethyl-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N,N-dimethyl-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C16H21N3O2S
    (2R)-N,N-dimethyl-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— N-[2-(4-chlorophenyl)ethyl]-2-(2,5-difluorophenyl)sulfanylacetamide —— C16H14ClF2NOS
    N-[2-(4-chlorophenyl)ethyl]-2-(2,5-difluorophenyl)sulfanylacetamide
    —— N-cyclopropyl-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C13H19N3OS
    N-cyclopropyl-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(3-chlorophenyl)methyl]-3-(3,4-difluorophenyl)sulfanylpropanamide —— C16H14ClF2NOS
    N-[(3-chlorophenyl)methyl]-3-(3,4-difluorophenyl)sulfanylpropanamide
    —— [(1S)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl] (2S)-2,3-dihydro-1,4-benzoxathiine-2-carboxylate —— C14H14N2O4S
    [(1S)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl] (2S)-2,3-dihydro-1,4-benzoxathiine-2-carboxylate
    —— [(1R)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl] (2R)-2,3-dihydro-1,4-benzoxathiine-2-carboxylate —— C14H14N2O4S
    [(1R)-1-(3-methyl-1,2,4-oxadiazol-5-yl)ethyl] (2R)-2,3-dihydro-1,4-benzoxathiine-2-carboxylate
    —— (2R)-N-methyl-N-(1-oxothian-4-yl)-2-phenylsulfanylbutanamide —— C16H23NO2S2
    (2R)-N-methyl-N-(1-oxothian-4-yl)-2-phenylsulfanylbutanamide
    —— (3S,5S)-5-methyl-3-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanyloxolan-2-one —— C11H12N4O2S2
    (3S,5S)-5-methyl-3-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanyloxolan-2-one
    —— (2S)-N-methyl-N-(1-oxothian-4-yl)-2-phenylsulfanylbutanamide —— C16H23NO2S2
    (2S)-N-methyl-N-(1-oxothian-4-yl)-2-phenylsulfanylbutanamide
    —— [(1R,2R)-2-methoxycyclopentyl] 3-cyclopentylsulfonylpropanoate —— C14H24O5S
    [(1R,2R)-2-methoxycyclopentyl] 3-cyclopentylsulfonylpropanoate