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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[2-[(3S)-3-methylpyrrolidin-1-yl]ethylsulfanyl]-5-(thiophen-2-ylmethyl)-1,3,4-oxadiazole —— C14H19N3OS2
    2-[2-[(3S)-3-methylpyrrolidin-1-yl]ethylsulfanyl]-5-(thiophen-2-ylmethyl)-1,3,4-oxadiazole
    —— 3-cyclopropyl-1-methyl-1-[(1R,2R)-2-methylsulfonylcyclopentyl]urea —— C11H20N2O3S
    3-cyclopropyl-1-methyl-1-[(1R,2R)-2-methylsulfonylcyclopentyl]urea
    —— 2-[[4-amino-5-[(1S,3S)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide —— C15H27N5O3S3
    2-[[4-amino-5-[(1S,3S)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide
    —— 3-cyclopropyl-1-methyl-1-[(1S,2S)-2-methylsulfonylcyclopentyl]urea —— C11H20N2O3S
    3-cyclopropyl-1-methyl-1-[(1S,2S)-2-methylsulfonylcyclopentyl]urea
    —— 3-cyclopropyl-1-methyl-1-[(1S,2R)-2-methylsulfonylcyclopentyl]urea —— C11H20N2O3S
    3-cyclopropyl-1-methyl-1-[(1S,2R)-2-methylsulfonylcyclopentyl]urea
    —— (2S)-N-[1-(6-methylpyridin-2-yl)piperidin-4-yl]-2-pyridin-2-ylsulfanylpropanamide —— C19H24N4OS
    (2S)-N-[1-(6-methylpyridin-2-yl)piperidin-4-yl]-2-pyridin-2-ylsulfanylpropanamide
    —— 4-cyclohexyl-3-(furan-2-yl)-5-[(1S,3S)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazole —— C19H27N3O3S2
    4-cyclohexyl-3-(furan-2-yl)-5-[(1S,3S)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazole
    —— 2-[[5-(Anilinomethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C12H14N4O2S
    2-[[5-(Anilinomethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 1,7-dicyclopropyl-5-[2-[(3S)-2-oxooxolan-3-yl]ethylsulfanyl]pyrimido[4,5-d]pyrimidine-2,4-dione —— C18H20N4O4S
    1,7-dicyclopropyl-5-[2-[(3S)-2-oxooxolan-3-yl]ethylsulfanyl]pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 4-cyclohexyl-3-(furan-2-yl)-5-[(1R,3S)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazole —— C19H27N3O3S2
    4-cyclohexyl-3-(furan-2-yl)-5-[(1R,3S)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazole
    —— 4-cyclohexyl-3-(furan-2-yl)-5-[(1R,3R)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazole —— C19H27N3O3S2
    4-cyclohexyl-3-(furan-2-yl)-5-[(1R,3R)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazole
    —— 1,7-dicyclopropyl-5-[2-[(3R)-2-oxooxolan-3-yl]ethylsulfanyl]pyrimido[4,5-d]pyrimidine-2,4-dione —— C18H20N4O4S
    1,7-dicyclopropyl-5-[2-[(3R)-2-oxooxolan-3-yl]ethylsulfanyl]pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 2-[[4-amino-5-[(1R,3S)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide —— C15H27N5O3S3
    2-[[4-amino-5-[(1R,3S)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide
    —— 2-[[4-amino-5-[(1S,3R)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide —— C15H27N5O3S3
    2-[[4-amino-5-[(1S,3R)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide
    —— 2-[2-[(3R)-3-methylpyrrolidin-1-yl]ethylsulfanyl]-5-(thiophen-2-ylmethyl)-1,3,4-oxadiazole —— C14H19N3OS2
    2-[2-[(3R)-3-methylpyrrolidin-1-yl]ethylsulfanyl]-5-(thiophen-2-ylmethyl)-1,3,4-oxadiazole
    —— 4-cyclohexyl-3-(furan-2-yl)-5-[(1S,3R)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazole —— C19H27N3O3S2
    4-cyclohexyl-3-(furan-2-yl)-5-[(1S,3R)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazole
    —— 2-[[4-amino-5-[(1R,3R)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide —— C15H27N5O3S3
    2-[[4-amino-5-[(1R,3R)-3-methylsulfonylcyclohexyl]sulfanyl-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide
    —— 1-[(3R)-3-[(2R)-2-hydroxy-2-thiophen-2-ylethyl]morpholin-4-yl]-2-(4-methylphenyl)sulfanylethanone —— C19H23NO3S2
    1-[(3R)-3-[(2R)-2-hydroxy-2-thiophen-2-ylethyl]morpholin-4-yl]-2-(4-methylphenyl)sulfanylethanone
    —— 1-[(3S)-3-[(2S)-2-hydroxy-2-thiophen-2-ylethyl]morpholin-4-yl]-2-(4-methylphenyl)sulfanylethanone —— C19H23NO3S2
    1-[(3S)-3-[(2S)-2-hydroxy-2-thiophen-2-ylethyl]morpholin-4-yl]-2-(4-methylphenyl)sulfanylethanone
    —— 1-[(3R)-3-[(2S)-2-hydroxy-2-thiophen-2-ylethyl]morpholin-4-yl]-2-(4-methylphenyl)sulfanylethanone —— C19H23NO3S2
    1-[(3R)-3-[(2S)-2-hydroxy-2-thiophen-2-ylethyl]morpholin-4-yl]-2-(4-methylphenyl)sulfanylethanone
    —— 1-[(3S)-3-[(2R)-2-hydroxy-2-thiophen-2-ylethyl]morpholin-4-yl]-2-(4-methylphenyl)sulfanylethanone —— C19H23NO3S2
    1-[(3S)-3-[(2R)-2-hydroxy-2-thiophen-2-ylethyl]morpholin-4-yl]-2-(4-methylphenyl)sulfanylethanone
    —— 2-[(3S)-3-(1H-imidazol-2-ylsulfanyl)-2-oxopyrrolidin-1-yl]thiophene-3-carbonitrile —— C12H10N4OS2
    2-[(3S)-3-(1H-imidazol-2-ylsulfanyl)-2-oxopyrrolidin-1-yl]thiophene-3-carbonitrile
    —— N-(2-tert-butylsulfonylethyl)-2-[(1R)-cyclopent-2-en-1-yl]acetamide —— C13H23NO3S
    N-(2-tert-butylsulfonylethyl)-2-[(1R)-cyclopent-2-en-1-yl]acetamide
    —— N-[(2S)-2-hydroxy-3-morpholin-4-ylpropyl]-N-methyl-2-phenylsulfanylpyridine-3-carboxamide —— C20H25N3O3S
    N-[(2S)-2-hydroxy-3-morpholin-4-ylpropyl]-N-methyl-2-phenylsulfanylpyridine-3-carboxamide
    —— N-(2-tert-butylsulfonylethyl)-2-[(1S)-cyclopent-2-en-1-yl]acetamide —— C13H23NO3S
    N-(2-tert-butylsulfonylethyl)-2-[(1S)-cyclopent-2-en-1-yl]acetamide
    —— N-[(2R)-2-hydroxy-3-morpholin-4-ylpropyl]-N-methyl-2-phenylsulfanylpyridine-3-carboxamide —— C20H25N3O3S
    N-[(2R)-2-hydroxy-3-morpholin-4-ylpropyl]-N-methyl-2-phenylsulfanylpyridine-3-carboxamide
    —— 2-[(3R)-3-(1H-imidazol-2-ylsulfanyl)-2-oxopyrrolidin-1-yl]thiophene-3-carbonitrile —— C12H10N4OS2
    2-[(3R)-3-(1H-imidazol-2-ylsulfanyl)-2-oxopyrrolidin-1-yl]thiophene-3-carbonitrile
    —— N-[(2S,3R)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide —— C13H25NO3S
    N-[(2S,3R)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylcyclohexanecarboxamide —— C13H25NO3S
    N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylcyclohexanecarboxamide
    —— N-[(2R,3R)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide —— C13H25NO3S
    N-[(2R,3R)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[(2R,3S)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide —— C13H25NO3S
    N-[(2R,3S)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylcyclopentanecarboxamide —— C12H23NO3S
    N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylcyclopentanecarboxamide
    —— N-[(2S,3S)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide —— C13H25NO3S
    N-[(2S,3S)-3-methylpentan-2-yl]-1-methylsulfonylcyclopentane-1-carboxamide
    —— N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylcyclohexanecarboxamide —— C13H25NO3S
    N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylcyclohexanecarboxamide
    —— N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylcyclopentanecarboxamide —— C12H23NO3S
    N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylcyclopentanecarboxamide
    —— 3-(2-bromophenyl)sulfanyl-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]propanamide —— C16H24BrNO3S2
    3-(2-bromophenyl)sulfanyl-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]propanamide
    —— (1S)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide —— C14H25NO3S
    (1S)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide
    —— 2-cyclopentylsulfonyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylacetamide —— C13H25NO5S2
    2-cyclopentylsulfonyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]-N-methylacetamide
    —— (1R)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide —— C14H25NO3S
    (1R)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide
    —— (1S)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide —— C14H25NO3S
    (1S)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide
    —— 2-(cyclohexen-1-yl)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]acetamide —— C15H27NO3S
    2-(cyclohexen-1-yl)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]acetamide
    —— (1R)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide —— C14H25NO3S
    (1R)-N-ethyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]cyclohex-3-ene-1-carboxamide
    —— 2-cyclopentylsulfonyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylacetamide —— C13H25NO5S2
    2-cyclopentylsulfonyl-N-[(2S)-1-ethylsulfonylpropan-2-yl]-N-methylacetamide
    —— 3-(2-bromophenyl)sulfanyl-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]propanamide —— C16H24BrNO3S2
    3-(2-bromophenyl)sulfanyl-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]propanamide
    —— (2R)-N-cyclohexyl-2-propan-2-ylsulfonyl-N-prop-2-ynylpropanamide —— C15H25NO3S
    (2R)-N-cyclohexyl-2-propan-2-ylsulfonyl-N-prop-2-ynylpropanamide
    —— 2-(cyclohexen-1-yl)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]acetamide —— C15H27NO3S
    2-(cyclohexen-1-yl)-N-ethyl-N-[(2R)-1-ethylsulfonylpropan-2-yl]acetamide
    —— (2S)-N-[5-fluoro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(1,2,4-triazol-1-yl)propanamide —— C15H15FN6OS
    (2S)-N-[5-fluoro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(1,2,4-triazol-1-yl)propanamide
    —— (2R)-N-[5-fluoro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(1,2,4-triazol-1-yl)propanamide —— C15H15FN6OS
    (2R)-N-[5-fluoro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(1,2,4-triazol-1-yl)propanamide
    —— (2S)-N-cyclohexyl-2-propan-2-ylsulfonyl-N-prop-2-ynylpropanamide —— C15H25NO3S
    (2S)-N-cyclohexyl-2-propan-2-ylsulfonyl-N-prop-2-ynylpropanamide
    —— (2R)-2-methylsulfonyl-N-(2-phenylsulfanylphenyl)propanamide —— C16H17NO3S2
    (2R)-2-methylsulfonyl-N-(2-phenylsulfanylphenyl)propanamide