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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-pentan-2-yl]acetamide —— C15H27N5O2S
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-pentan-2-yl]acetamide
    —— 6-amino-1-cyclopropyl-5-[2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetyl]pyrimidine-2,4-dione —— C16H19N5O4S
    6-amino-1-cyclopropyl-5-[2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetyl]pyrimidine-2,4-dione
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-pentan-2-yl]acetamide —— C15H27N5O2S
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-pentan-2-yl]acetamide
    —— 2-(4-chlorophenyl)sulfanylethyl N'-propan-2-ylcarbamimidothioate —— C12H17ClN2S2
    2-(4-chlorophenyl)sulfanylethyl N'-propan-2-ylcarbamimidothioate
    —— [(1S,2R)-2-phenylsulfanylcyclohexyl]hydrazine —— C12H18N2S
    [(1S,2R)-2-phenylsulfanylcyclohexyl]hydrazine
    —— (2Z)-3-[2-(4-chlorophenyl)sulfanylethyl]-2-(3,3-dimethyl-2-oxobutylidene)-1,3-thiazolidin-4-one —— C17H20ClNO2S2
    (2Z)-3-[2-(4-chlorophenyl)sulfanylethyl]-2-(3,3-dimethyl-2-oxobutylidene)-1,3-thiazolidin-4-one
    —— 4-[(6-chloro-1H-benzimidazol-2-yl)sulfanyl]thieno[2,3-d]pyrimidine —— C13H7ClN4S2
    4-[(6-chloro-1H-benzimidazol-2-yl)sulfanyl]thieno[2,3-d]pyrimidine
    —— 4-cyclopropyl-3-(2-phenylethylsulfanyl)-1H-1,2,4-triazol-5-one —— C13H15N3OS
    4-cyclopropyl-3-(2-phenylethylsulfanyl)-1H-1,2,4-triazol-5-one
    —— N-[2-(2-fluorophenyl)ethyl]-2-pyridin-2-ylsulfanylacetamide —— C15H15FN2OS
    N-[2-(2-fluorophenyl)ethyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-pyridin-2-ylsulfanylacetamide —— C20H24N2O3S
    N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-(cyclopropylmethyl)-2-[(4-cyclopropyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-propylacetamide —— C14H22N4O2S
    N-(cyclopropylmethyl)-2-[(4-cyclopropyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-propylacetamide
    —— N-[2-(N-ethyl-3-methylanilino)ethyl]-2-pyridin-2-ylsulfanylacetamide —— C18H23N3OS
    N-[2-(N-ethyl-3-methylanilino)ethyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-pyridin-2-ylsulfanylacetamide —— C20H24N2O3S
    N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[2-(2-methylphenyl)ethyl]-2-pyridin-2-ylsulfanylacetamide —— C16H18N2OS
    N-[2-(2-methylphenyl)ethyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(R)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-pyridin-2-ylsulfanylacetamide —— C18H15FN2OS2
    N-[(R)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-pyridin-2-ylsulfanylacetamide
    —— 4-cyclopropyl-3-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C15H15N5O2S
    4-cyclopropyl-3-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— N-[(R)-phenyl(thiophen-2-yl)methyl]-2-pyridin-2-ylsulfanylacetamide —— C18H16N2OS2
    N-[(R)-phenyl(thiophen-2-yl)methyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-benzyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-pyridin-2-ylsulfanylacetamide —— C18H18N2O3S2
    N-benzyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-pyridin-2-ylsulfanylacetamide —— C18H15FN2OS2
    N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[2-(4-bromophenyl)sulfanylethyl]-2-pyridin-2-ylsulfanylacetamide —— C15H15BrN2OS2
    N-[2-(4-bromophenyl)sulfanylethyl]-2-pyridin-2-ylsulfanylacetamide
    —— 2-[(4-cyclopropyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N,N-bis(2-methylpropyl)acetamide —— C15H26N4O2S
    2-[(4-cyclopropyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N,N-bis(2-methylpropyl)acetamide
    —— N-[(1S)-1-(furan-2-yl)ethyl]-2-pyridin-2-ylsulfanylacetamide —— C13H14N2O2S
    N-[(1S)-1-(furan-2-yl)ethyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[3-(N-methylanilino)propyl]-2-pyridin-2-ylsulfanylacetamide —— C17H21N3OS
    N-[3-(N-methylanilino)propyl]-2-pyridin-2-ylsulfanylacetamide
    —— N-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methyl]-N-cyclopropyl-2-pyridin-2-ylsulfanylacetamide —— C19H17ClN4O2S
    N-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methyl]-N-cyclopropyl-2-pyridin-2-ylsulfanylacetamide
    —— 4-cyclopropyl-3-(2-oxo-2-pyrrolidin-1-ylethyl)sulfanyl-1H-1,2,4-triazol-5-one —— C11H16N4O2S
    4-cyclopropyl-3-(2-oxo-2-pyrrolidin-1-ylethyl)sulfanyl-1H-1,2,4-triazol-5-one
    —— 2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2,4,4-trimethylpentan-2-yl)acetamide —— C19H27N3O2S
    2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2,4,4-trimethylpentan-2-yl)acetamide
    —— N-[(2-fluorophenyl)methyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H16FN3O2S
    N-[(2-fluorophenyl)methyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 4-cyclopropyl-3-[(3R)-2-oxooxolan-3-yl]sulfanyl-1H-1,2,4-triazol-5-one —— C9H11N3O3S
    4-cyclopropyl-3-[(3R)-2-oxooxolan-3-yl]sulfanyl-1H-1,2,4-triazol-5-one
    —— N-(2-methylbutan-2-yl)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H21N3O2S
    N-(2-methylbutan-2-yl)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethanone —— C22H21N3O2S
    2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethanone
    —— N-[(1S)-1-cyclopropylethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H19N3O2S
    N-[(1S)-1-cyclopropylethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-3-ylmethyl)acetamide —— C17H17N3O2S2
    N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-3-ylmethyl)acetamide
    —— N-[(4-ethylphenyl)methyl]-N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H23N3O2S
    N-[(4-ethylphenyl)methyl]-N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C20H18N2O4S
    1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— N-cyclopropyl-N-[(2-fluorophenyl)methyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H20FN3O2S
    N-cyclopropyl-N-[(2-fluorophenyl)methyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2-fluorophenyl)methyl]-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H16FN3O2S
    N-[(2-fluorophenyl)methyl]-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-pentylacetamide —— C16H21N3O2S
    2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-pentylacetamide
    —— N-[2-(3-chlorophenyl)ethyl]-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H18ClN3O2S
    N-[2-(3-chlorophenyl)ethyl]-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-methyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-3-ylmethyl)acetamide —— C17H17N3O2S2
    N-methyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-3-ylmethyl)acetamide
    —— N-benzyl-N-(furan-2-ylmethyl)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C23H21N3O3S
    N-benzyl-N-(furan-2-ylmethyl)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2-fluorophenyl)methyl]-N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H18FN3O2S
    N-[(2-fluorophenyl)methyl]-N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(5-chlorothiophen-2-yl)methyl]-N-ethyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H18ClN3O2S2
    N-[(5-chlorothiophen-2-yl)methyl]-N-ethyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[4-(2-methylbutan-2-yl)cyclohexyl]-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C22H31N3O2S
    N-[4-(2-methylbutan-2-yl)cyclohexyl]-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(2-methylphenyl)ethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H21N3O2S
    N-[2-(2-methylphenyl)ethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[2-(2-methylphenyl)ethyl]-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H21N3O2S
    N-[2-(2-methylphenyl)ethyl]-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(3-chlorophenyl)methyl]-N-methyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H18ClN3O2S
    N-[(3-chlorophenyl)methyl]-N-methyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-methylsulfanylphenyl)methyl]acetamide —— C20H21N3O2S2
    N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-methylsulfanylphenyl)methyl]acetamide
    —— N-[(2S)-5-methylhexan-2-yl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H25N3O2S
    N-[(2S)-5-methylhexan-2-yl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-(2-Methylphenyl)-5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole —— C19H15N3O2S
    2-(2-Methylphenyl)-5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— N-(2-cyanopropan-2-yl)-N-methyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H18N4O2S
    N-(2-cyanopropan-2-yl)-N-methyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide