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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[2,5-dimethyl-1-[(1R)-1-phenylethyl]pyrrol-3-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone —— C24H23N3O2S
    1-[2,5-dimethyl-1-[(1R)-1-phenylethyl]pyrrol-3-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethanone
    —— N-[(1R)-1-(4-ethylphenyl)ethyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C20H21N3O2S
    N-[(1R)-1-(4-ethylphenyl)ethyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 2-(Furan-2-yl)-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C15H10N4O3S
    2-(Furan-2-yl)-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— (2R)-N-(furan-2-ylmethyl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C16H15N3O3S
    (2R)-N-(furan-2-ylmethyl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— N-[(1R)-1-(2,3-dihydro-1,4-benzodioxin-6-yl)ethyl]-2-phenylsulfanylpyridine-3-carboxamide —— C22H20N2O3S
    N-[(1R)-1-(2,3-dihydro-1,4-benzodioxin-6-yl)ethyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— N-(cyclohexen-1-yl)-2-(1-cyclopropyltetrazol-5-yl)sulfanyl-N-(furan-2-ylmethyl)acetamide —— C17H21N5O2S
    N-(cyclohexen-1-yl)-2-(1-cyclopropyltetrazol-5-yl)sulfanyl-N-(furan-2-ylmethyl)acetamide
    —— 2-(2,5-Dimethylfuran-3-yl)-5-[[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylmethyl]-1,3,4-oxadiazole —— C15H14N6O2S2
    2-(2,5-Dimethylfuran-3-yl)-5-[[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylmethyl]-1,3,4-oxadiazole
    —— 1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylethanone —— C18H18N6O2S2
    1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylethanone
    —— 2-[(1S)-1-(1-cyclopentyltetrazol-5-yl)sulfanylethyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole —— C16H17FN6OS
    2-[(1S)-1-(1-cyclopentyltetrazol-5-yl)sulfanylethyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole
    —— 1-(1-Benzyl-2,5-dimethylpyrrol-3-yl)-2-(1-cyclopropyltetrazol-5-yl)sulfanylethanone —— C19H21N5OS
    1-(1-Benzyl-2,5-dimethylpyrrol-3-yl)-2-(1-cyclopropyltetrazol-5-yl)sulfanylethanone
    —— 4-[(1-Cyclopropyltetrazol-5-yl)sulfanylmethyl]-2-phenyl-1,3-thiazole —— C14H13N5S2
    4-[(1-Cyclopropyltetrazol-5-yl)sulfanylmethyl]-2-phenyl-1,3-thiazole
    —— 3-(3-methylbut-2-enylsulfanyl)-5-thiophen-2-yl-1H-1,2,4-triazole —— C11H13N3S2
    3-(3-methylbut-2-enylsulfanyl)-5-thiophen-2-yl-1H-1,2,4-triazole
    —— 3-[(2-chlorophenyl)methylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole —— C13H10ClN3S2
    3-[(2-chlorophenyl)methylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole
    —— 1-[1-(3-methoxypropyl)-2,5-dimethylpyrrol-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C18H22N4O2S2
    1-[1-(3-methoxypropyl)-2,5-dimethylpyrrol-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 2-(2-chlorophenyl)-4-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-thiazole —— C16H11ClN4S3
    2-(2-chlorophenyl)-4-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-thiazole
    —— (2R)-N-[(1R,2R)-2-methylcyclohexyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C16H22N4OS2
    (2R)-N-[(1R,2R)-2-methylcyclohexyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-[(4-chlorophenyl)methyl]-N-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H15ClN4OS2
    N-[(4-chlorophenyl)methyl]-N-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-(2-chloroprop-2-enylsulfanyl)-5-thiophen-2-yl-1H-1,2,4-triazole —— C9H8ClN3S2
    3-(2-chloroprop-2-enylsulfanyl)-5-thiophen-2-yl-1H-1,2,4-triazole
    —— 3-(cyclohexylmethylsulfanyl)-5-thiophen-2-yl-1H-1,2,4-triazole —— C13H17N3S2
    3-(cyclohexylmethylsulfanyl)-5-thiophen-2-yl-1H-1,2,4-triazole
    —— (2R)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one —— C12H13N3OS2
    (2R)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one
    —— 3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-5-thiophen-2-yl-1H-1,2,4-triazole —— C14H12ClN3S2
    3-[(1R)-1-(2-chlorophenyl)ethyl]sulfanyl-5-thiophen-2-yl-1H-1,2,4-triazole
    —— 2-(4-chlorophenyl)-4-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-thiazole —— C16H11ClN4S3
    2-(4-chlorophenyl)-4-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-thiazole
    —— methyl (2R)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C10H11N3O2S2
    methyl (2R)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— (2S)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one —— C12H13N3OS2
    (2S)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one
    —— 3-[(4-methylsulfanylphenyl)methylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole —— C14H13N3S3
    3-[(4-methylsulfanylphenyl)methylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole
    —— N-(furan-2-ylmethyl)-N-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H14N4O2S2
    N-(furan-2-ylmethyl)-N-methyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-[4-(2,4-dimethylphenyl)sulfanylphenyl]-3-[[(2S)-oxolan-2-yl]methyl]thiourea —— C20H24N2OS2
    1-[4-(2,4-dimethylphenyl)sulfanylphenyl]-3-[[(2S)-oxolan-2-yl]methyl]thiourea
    —— (2R)-N-cyclohexyl-N-ethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C17H24N4OS2
    (2R)-N-cyclohexyl-N-ethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H22N4O3S3
    N-butyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N,N-bis(2-cyanoethyl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H14N6OS2
    N,N-bis(2-cyanoethyl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C17H20N4OS2
    1-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 3-[[(2R)-oxan-2-yl]methylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole —— C12H15N3OS2
    3-[[(2R)-oxan-2-yl]methylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole
    —— (2R)-N-[2-(4-fluorophenyl)ethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C17H17FN4OS2
    (2R)-N-[2-(4-fluorophenyl)ethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H22N4O3S3
    N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N,N-dimethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C10H12N4OS2
    N,N-dimethyl-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2S)-2-[[5-benzyl-4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile —— C15H18N4OS
    (2S)-2-[[5-benzyl-4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]propanenitrile
    —— N-[(1R)-1-thiophen-2-ylethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H14N4OS3
    N-[(1R)-1-thiophen-2-ylethyl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-(1H-pyrrol-2-yl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C12H10N4OS2
    1-(1H-pyrrol-2-yl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 3-(2-methylprop-2-enylsulfanyl)-5-thiophen-2-yl-1H-1,2,4-triazole —— C10H11N3S2
    3-(2-methylprop-2-enylsulfanyl)-5-thiophen-2-yl-1H-1,2,4-triazole
    —— 3-(2-phenylethylsulfanyl)-5-thiophen-2-yl-1H-1,2,4-triazole —— C14H13N3S2
    3-(2-phenylethylsulfanyl)-5-thiophen-2-yl-1H-1,2,4-triazole
    —— 2-methyl-4-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-thiazole —— C11H10N4S3
    2-methyl-4-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3-thiazole
    —— 3-[[(2S)-oxan-2-yl]methylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole —— C12H15N3OS2
    3-[[(2S)-oxan-2-yl]methylsulfanyl]-5-thiophen-2-yl-1H-1,2,4-triazole
    —— 3-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanenitrile —— C9H8N4S2
    3-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanenitrile
    —— (2S)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanenitrile —— C9H8N4S2
    (2S)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanenitrile
    —— N-(2-cyanoethyl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H11N5OS2
    N-(2-cyanoethyl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-N-(1-adamantyl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C19H24N4OS2
    (2R)-N-(1-adamantyl)-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— 3-[(1S)-1-phenylethyl]sulfanyl-5-thiophen-2-yl-1H-1,2,4-triazole —— C14H13N3S2
    3-[(1S)-1-phenylethyl]sulfanyl-5-thiophen-2-yl-1H-1,2,4-triazole
    —— N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H16N4O3S3
    N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-(2,5-Dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylethanone —— C17H21N5OS2
    1-(2,5-Dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylethanone
    —— 6-amino-1-cyclopropyl-5-[2-(1H-1,2,4-triazol-5-ylsulfanyl)acetyl]pyrimidine-2,4-dione —— C11H12N6O3S
    6-amino-1-cyclopropyl-5-[2-(1H-1,2,4-triazol-5-ylsulfanyl)acetyl]pyrimidine-2,4-dione