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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-Amino-phenylmercapto)-benzoesaeure-methylester 20904-43-2 C14H13NO2S
    2-(4-Amino-phenylmercapto)-benzoesaeure-methylester
    —— 4-(o-Amino-phenylthio)-5-ethoxy-2-phenyl-3(2H)-pyridazinon 41739-77-9 C18H17N3O2S
    4-(o-Amino-phenylthio)-5-ethoxy-2-phenyl-3(2H)-pyridazinon
    —— Heptafluor-orthothiobuttersaeure-methylester 679-32-3 C7H9F7S3
    Heptafluor-orthothiobuttersaeure-methylester
    —— ethyl 2-allyl-4-(methylthio)thiophene-3-carboxylate 1097189-84-8 C11H14O2S2
    ethyl 2-allyl-4-(methylthio)thiophene-3-carboxylate
    —— Bis(pentafluorophenylthio)chlorofluoromethane 250259-15-5 C13ClF11S2
    Bis(pentafluorophenylthio)chlorofluoromethane
    —— 1,1,1,4,4,4-hexafluoro-2,3-bis-methylsulfanyl-butane 67560-45-6 C6H8F6S2
    1,1,1,4,4,4-hexafluoro-2,3-bis-methylsulfanyl-butane
    —— [5-Methylsulfanyl-4-p-tolyl-[1,2]dithiol-(3Z)-ylidene]-p-tolyl-amine 52444-80-1 C18H17NS3
    [5-Methylsulfanyl-4-p-tolyl-[1,2]dithiol-(3Z)-ylidene]-p-tolyl-amine
    —— N-<2-(4-Chlor-phenylmercapto)-aethyl>-4-chlor-thiobenzamid 13094-99-0 C15H13Cl2NS2
    N-<2-(4-Chlor-phenylmercapto)-aethyl>-4-chlor-thiobenzamid
    —— (2,2-Bis-phenylsulfanyl-ethyl)-triethyl-stannane 54948-44-6 C20H28S2Sn
    (2,2-Bis-phenylsulfanyl-ethyl)-triethyl-stannane
    —— μ-disulfido-1,2-dithio-dicarbonic acid <i>O</i>,<i>O</i>'-bis-diethylaminomethyl ester 108991-45-3 C12H24N2O2S4
    μ-disulfido-1,2-dithio-dicarbonic acid <i>O</i>,<i>O</i>'-bis-diethylaminomethyl ester
    —— 3-(Bis-ethylsulfanyl-methyl)-pentane 36055-98-8 C10H22S2
    3-(Bis-ethylsulfanyl-methyl)-pentane
    —— 3-Chloro-3-methyl-2-phenylsulfanyl-2,3-dihydro-benzo[b]thiophene 1,1-dioxide 28633-66-1 C15H13ClO2S2
    3-Chloro-3-methyl-2-phenylsulfanyl-2,3-dihydro-benzo[b]thiophene 1,1-dioxide
    —— 3,5-Difluor-1,3,5-trioxo-1-piperidino-1,3,5-2,4,6-trithiatriazin(1,3,5-S(VI)) 51591-12-9 C5H10F2N4O3S3
    3,5-Difluor-1,3,5-trioxo-1-piperidino-1,3,5-2,4,6-trithiatriazin(1,3,5-S(VI))
    —— 1,2-Bis<2-(2-benzo<b>thienylthio)-5-nitrophenyl>ethylen 54970-51-3 C30H18N2O4S4
    1,2-Bis<2-(2-benzo<b>thienylthio)-5-nitrophenyl>ethylen
    —— 2-(2-Benzo<b>thienylthio)-N,N-diethylanilin 54970-39-7 C18H19NS2
    2-(2-Benzo<b>thienylthio)-N,N-diethylanilin
    —— <i>S</i>-methoxymethyl-isothiourea; hydrochloride 88394-64-3 C3H8N2OS*ClH
    <i>S</i>-methoxymethyl-isothiourea; hydrochloride
    —— {3-[6-chloro-7-fluoro-2-methyl-1-(1-propyl-1H-pyrazol-4-yl)-1H-indol-3-ylsulfanyl]-2-fluoro-phenyl}-acetic acid 1359983-37-1 C23H20ClF2N3O2S
    {3-[6-chloro-7-fluoro-2-methyl-1-(1-propyl-1H-pyrazol-4-yl)-1H-indol-3-ylsulfanyl]-2-fluoro-phenyl}-acetic acid
    —— 3-(6-chloro-2-methyl-1-naphthalen-2-ylmethyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 1359980-15-6 C28H22ClNO2S
    3-(6-chloro-2-methyl-1-naphthalen-2-ylmethyl-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester
    —— [5-(2-oxo-propylsulfanyl)-2-trifluoromethyl-phenyl]acetic acid ethyl ester 1359983-50-8 C20H16ClF4NO2S
    [5-(2-oxo-propylsulfanyl)-2-trifluoromethyl-phenyl]acetic acid ethyl ester
    —— 1-bromo-1-methyl-4-phenylsulfanylspiro[2.2]pentane 1413926-38-1 C12H13BrS
    1-bromo-1-methyl-4-phenylsulfanylspiro[2.2]pentane
    —— 2-<3-nitro-4-<(p-chlorophenyl)thio>phenyl>-as-triazine-3,5(2H,4H)-dione 38560-78-0 C15H9ClN4O4S
    2-<3-nitro-4-<(p-chlorophenyl)thio>phenyl>-as-triazine-3,5(2H,4H)-dione
    —— {NiBr2(Bis-(2-dimethylamino-aethyl)-sulfid)} 17967-71-4 C8H20Br2N2NiS
    {NiBr2(Bis-(2-dimethylamino-aethyl)-sulfid)}
    —— 3-[6-chloro-1-(1-ethyl-1H-pyrazol-4-yl)-7-fluoro-2-methyl-1H-indol-3-ylsulfanyl]-benzoic acid ethyl ester 1359982-40-3 C23H21ClFN3O2S
    3-[6-chloro-1-(1-ethyl-1H-pyrazol-4-yl)-7-fluoro-2-methyl-1H-indol-3-ylsulfanyl]-benzoic acid ethyl ester
    —— Dithiocarbonic acid S-cyanomethyl ester O-isobutyl ester 25542-31-8 C7H11NOS2
    Dithiocarbonic acid S-cyanomethyl ester O-isobutyl ester
    —— (6-methylhept-5-en-2-yl)(pent-1-yn-1-yl)copper 86680-08-2 C13H22Cu
    (6-methylhept-5-en-2-yl)(pent-1-yn-1-yl)copper
    —— [2-(2,6-diamino-phenylsulfanyl)-ethyl]-carbamic acid tert-butyl ester 898809-06-8 C13H21N3O2S
    [2-(2,6-diamino-phenylsulfanyl)-ethyl]-carbamic acid tert-butyl ester
    —— 2,2'-dithiodi-<N-(di-2-methyl-2-propenyl)methyl>aniline 91258-36-5 C30H40N2S2
    2,2'-dithiodi-<N-(di-2-methyl-2-propenyl)methyl>aniline
    —— 1,5-dihydro-5-deazaflavin 86737-01-1 C19H23N3O4
    1,5-dihydro-5-deazaflavin
    —— [1,4-bis[(2-methylpropan-2-yl)oxy]-2,3-diphenyl-3-phenylsulfanylbutan-2-yl]sulfanylbenzene 112163-88-9 C36H42O2S2
    [1,4-bis[(2-methylpropan-2-yl)oxy]-2,3-diphenyl-3-phenylsulfanylbutan-2-yl]sulfanylbenzene
    —— 42498-08-8 C15H10N2S3
    —— 5-ethyl-4,6-dimethyl-2-thiocyanato-pyrimidine 55055-26-0 C9H11N3S
    5-ethyl-4,6-dimethyl-2-thiocyanato-pyrimidine
    —— 1221577-60-1 C14H16ClF2N3O2S2
    —— 11-Ethyl-10-methylene-8-oxa-1,5-dithia-spiro[5.5]undecan-7-one 162086-46-6 C11H16O2S2
    11-Ethyl-10-methylene-8-oxa-1,5-dithia-spiro[5.5]undecan-7-one
    —— 3'-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]acetophenone oxime 158346-69-1 C20H22FNO3S
    3'-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]acetophenone oxime
    —— 4-Nitro-2-(toluol-4-mercapto)-benzyliden-diacetat 95168-79-9 C18H17NO6S
    4-Nitro-2-(toluol-4-mercapto)-benzyliden-diacetat
    —— (5-ethylsulfanyl-4-phenyl-[1,2]dithiol-3-ylidene)-<i>p</i>-tolyl-amine 52444-82-3 C18H17NS3
    (5-ethylsulfanyl-4-phenyl-[1,2]dithiol-3-ylidene)-<i>p</i>-tolyl-amine
    —— 81337-71-5 C18H30HoN3S6
    —— 1-Trimethylsilanyl-propa-1,2-diene-1-sulfonic acid amide 55499-89-3 C6H13NO2SSi
    1-Trimethylsilanyl-propa-1,2-diene-1-sulfonic acid amide
    —— Tribromessigsaeure-(4-phenylmercapto-butylester) 52060-31-8 C12H13Br3O2S
    Tribromessigsaeure-(4-phenylmercapto-butylester)
    —— 3,7-dimethyl-6-methylsulfanyl-3,7-dihydro-purin-8-one 42930-96-1 C8H10N4OS
    3,7-dimethyl-6-methylsulfanyl-3,7-dihydro-purin-8-one
    —— 3-Amino-2-methoxycarbonyl-thieno<3,2-b><1,4>benzodithiin-4,4-dioxide 95066-74-3 C12H9NO4S3
    3-Amino-2-methoxycarbonyl-thieno<3,2-b><1,4>benzodithiin-4,4-dioxide
    —— Dithiocarbonic acid S-cyanomethyl ester O-pentyl ester 25542-32-9 C8H13NOS2
    Dithiocarbonic acid S-cyanomethyl ester O-pentyl ester
    —— <1.1.1.3.3.3-Hexafluor-2-propyl>-3-cyclopentenyl-sulfid 3108-04-1 C8H8F6S
    <1.1.1.3.3.3-Hexafluor-2-propyl>-3-cyclopentenyl-sulfid
    —— sulfurofluoridic acid,N-propylidynemethanaminium salt 107574-63-0 C4H8N*FO3S
    sulfurofluoridic acid,N-propylidynemethanaminium salt
    —— 3-Methylthio-6-methylsulfonyl-pyridazin 40953-88-6 C6H8N2O2S2
    3-Methylthio-6-methylsulfonyl-pyridazin
    —— Methyl-phenyl-(2-phenylsulfanyl-1-phenylsulfanylmethyl-ethyl)-amine 42872-03-7 C22H23NS2
    Methyl-phenyl-(2-phenylsulfanyl-1-phenylsulfanylmethyl-ethyl)-amine
    —— 4-(4-amino-5-(2,4-dinitrophenylthio)-4H-1,2,4-triazol-3-yl)phenol 1187818-78-5 C14H10N6O5S
    4-(4-amino-5-(2,4-dinitrophenylthio)-4H-1,2,4-triazol-3-yl)phenol
    —— β-2-(6-Methylpyridyl)-thiopropensaeure 37020-28-3 C9H9NO2S
    β-2-(6-Methylpyridyl)-thiopropensaeure
    —— 3-[6-chloro-1-(1-ethyl-1H-pyrazol-4-yl)-7-fluoro-2-methyl-1H-indol-3-ylsulfanyl]-benzoic acid 1359982-38-9 C21H17ClFN3O2S
    3-[6-chloro-1-(1-ethyl-1H-pyrazol-4-yl)-7-fluoro-2-methyl-1H-indol-3-ylsulfanyl]-benzoic acid
    —— 2,4-Dimethyl-10H-9-thia-1,3,10-triaza-anthracene 94350-89-7 C12H11N3S
    2,4-Dimethyl-10H-9-thia-1,3,10-triaza-anthracene