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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Methoxy-N-(2-vinyloxy-ethyl)-buta-2,3-dienimidothioic acid methyl ester —— C10H15NO2S
    2-Methoxy-N-(2-vinyloxy-ethyl)-buta-2,3-dienimidothioic acid methyl ester
    —— α,α'-bis[(5-amino-1,3,4-thiadiazol-2-yl)thio]-m-xylene —— C12H12N6S4
    α,α'-bis[(5-amino-1,3,4-thiadiazol-2-yl)thio]-m-xylene
    —— (Z)-6-methyl-5-(trimethylsiloxy)-1-(trimethylsilyl)-1-(phenylthio)-4-octene —— C21H38OSSi2
    (Z)-6-methyl-5-(trimethylsiloxy)-1-(trimethylsilyl)-1-(phenylthio)-4-octene
    —— (+/-)-4a'-methyl-3',4',4a',7',8',8a'-hexahydro-2'H-spiro[1,3-dithiolane-2,1'-naphthalene] —— C13H20S2
    (+/-)-4a'-methyl-3',4',4a',7',8',8a'-hexahydro-2'H-spiro[1,3-dithiolane-2,1'-naphthalene]
    —— 2,3-bis((4-nitrophenyl)thio)indole —— C20H13N3O4S2
    2,3-bis((4-nitrophenyl)thio)indole
    —— 2-(hydroxyethylsulfanyl)-2'-(hydroxyethylsulfinyl)diethyl ether —— C8H18O4S2
    2-(hydroxyethylsulfanyl)-2'-(hydroxyethylsulfinyl)diethyl ether
    —— 3-phenyl-2,3-dihydrobenzo[e]1,4-oxathiepin-5-one —— C15H12O2S
    3-phenyl-2,3-dihydrobenzo[e]1,4-oxathiepin-5-one
    —— 1-(o-tolyl)-2-(p-tolylthio)ethan-1-ol —— C16H18OS
    1-(o-tolyl)-2-(p-tolylthio)ethan-1-ol
    —— 2-(4-bromophenylsulfanyl)-1,1,2,2-tetrafluoroethanesulfonyl fluoride —— C8H4BrF5O2S2
    2-(4-bromophenylsulfanyl)-1,1,2,2-tetrafluoroethanesulfonyl fluoride
    —— 7-((2,2-dimethylpropyl)amino)-2,3-dihydro[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C11H17N3OS
    7-((2,2-dimethylpropyl)amino)-2,3-dihydro[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— 6,7-dihydro-2H-thiazolo<3,2-a>-1,3,5-triazine-2,4(3H)-dione —— C5H5N3O2S
    6,7-dihydro-2H-thiazolo<3,2-a>-1,3,5-triazine-2,4(3H)-dione
    —— 1-(3-methyl-4-methylthiophenyl)-2-bromoethanol —— C10H13BrOS
    1-(3-methyl-4-methylthiophenyl)-2-bromoethanol
    —— N-[4-(4-Piperidinomethyl-pyridin-2-yloxy)-cis-2-butenyl]-4-(5-methyl-1,3,4-thiadiazol-2-ylthio)butyramide —— C22H31N5O2S2
    N-[4-(4-Piperidinomethyl-pyridin-2-yloxy)-cis-2-butenyl]-4-(5-methyl-1,3,4-thiadiazol-2-ylthio)butyramide
    —— 3-(phenylthio)butyramide —— C10H13NOS
    3-(phenylthio)butyramide
    —— 1-methylthio-1-[2-(methoxymethylthio)ethylamino]-2-nitroethene —— C7H14N2O3S2
    1-methylthio-1-[2-(methoxymethylthio)ethylamino]-2-nitroethene
    —— N-hydroxy-N-(cis-3-phenylthiocyclopentyl)urea —— C12H16N2O2S
    N-hydroxy-N-(cis-3-phenylthiocyclopentyl)urea
    —— 2-(9-hydroxynonyl)-3-(p-nitrophenylsulfenyl)benzo[b]thiophene —— C23H27NO3S2
    2-(9-hydroxynonyl)-3-(p-nitrophenylsulfenyl)benzo[b]thiophene
    —— 1,4-bis((4-(methylthio)phenyl)ethynyl)benzene —— C24H18S2
    1,4-bis((4-(methylthio)phenyl)ethynyl)benzene
    —— 4,6-dimethyl-2-[2,6-dimethyl-4-(3-phenylpropoxy)phenylthio]pyrimidine —— C23H26N2OS
    4,6-dimethyl-2-[2,6-dimethyl-4-(3-phenylpropoxy)phenylthio]pyrimidine
    —— ethyl 2-methoxy-3-phenylthio-4,6-bis(trifluoromethyl)pyridine-5-carboxylate —— C17H13F6NO3S
    ethyl 2-methoxy-3-phenylthio-4,6-bis(trifluoromethyl)pyridine-5-carboxylate
    —— [10-[(3,4-dichlorophenyl)sulfanyl]-1-(methylsulfonyl)-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-9-yl]acetic acid —— C20H18Cl2N2O4S2
    [10-[(3,4-dichlorophenyl)sulfanyl]-1-(methylsulfonyl)-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-9-yl]acetic acid
    —— 3-chloro-5-methylphenyl cyclohexyl sulfide —— C13H17ClS
    3-chloro-5-methylphenyl cyclohexyl sulfide
    —— 3-(6-(4-chlorobenzyl)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazol-3-ylthio)thieno[2,3-e][1,2,4]triazolo[4,3-c]pyrimidine —— C17H9ClN8S3
    3-(6-(4-chlorobenzyl)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazol-3-ylthio)thieno[2,3-e][1,2,4]triazolo[4,3-c]pyrimidine
    —— O-(4-hydroxyphenyl) (4-((4-(trichloromethyl)phenyl)thio)phenyl)carbamothioate —— C20H14Cl3NO2S2
    O-(4-hydroxyphenyl) (4-((4-(trichloromethyl)phenyl)thio)phenyl)carbamothioate
    —— N-<(phenylthio)methyl>pyridinium chloride —— C12H12NS*Cl
    N-<(phenylthio)methyl>pyridinium chloride
    —— (1S,2R,3S,4R,5S)-ethyl 4-(azidocarbonyl)-5-nitro-3-(pentan-3-yloxy)-2-(p-tolylthio)cyclohexanecarboxylate —— C22H30N4O6S
    (1S,2R,3S,4R,5S)-ethyl 4-(azidocarbonyl)-5-nitro-3-(pentan-3-yloxy)-2-(p-tolylthio)cyclohexanecarboxylate
    —— 4-diazophenyl disulfide —— C12H10N4S2
    4-diazophenyl disulfide
    —— 2-propylthio-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile —— C13H12N4OS
    2-propylthio-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile
    —— 4-[[2-[(1-methylimidazol-2-yl)thio]ethyl]thio]aniline —— C12H15N3S2
    4-[[2-[(1-methylimidazol-2-yl)thio]ethyl]thio]aniline
    —— 2-amino-4-fluoromethyl-6-methylthiopyrimidine —— C6H8FN3S
    2-amino-4-fluoromethyl-6-methylthiopyrimidine
    —— 2-[(1H-Imidazol-4-yl)methylthio]-5-nitropyridine —— C9H8N4O2S
    2-[(1H-Imidazol-4-yl)methylthio]-5-nitropyridine
    —— 2,6-Bis(4,5-dihexyl-1,3-dithiole-2-ylidene)bis-1,3-dithiolo<4,5-b:4',5'-e>pyrazine —— C36H52N2S8
    2,6-Bis(4,5-dihexyl-1,3-dithiole-2-ylidene)bis-1,3-dithiolo<4,5-b:4',5'-e>pyrazine
    —— mesylic acid —— C2H4O4S
    mesylic acid
    —— ethyl {3-[4-(3-phenylpropylamino)phenylsulphanyl]phenyl}acetate —— C25H27NO2S
    ethyl {3-[4-(3-phenylpropylamino)phenylsulphanyl]phenyl}acetate
    —— Cyclopent-1-enyl phenylthiomethyl ketone —— C13H14OS
    Cyclopent-1-enyl phenylthiomethyl ketone
    —— 4-methylthiobenzenesulfenyl chloride —— C7H7ClS2
    4-methylthiobenzenesulfenyl chloride
    —— 2-(2-bromophenylthio)-4,5-dimethoxyaniline —— C14H14BrNO2S
    2-(2-bromophenylthio)-4,5-dimethoxyaniline
    —— 5-Methylthiothiophene-2-carboxamidine —— C6H8N2S2
    5-Methylthiothiophene-2-carboxamidine
    —— 4-methoxy-2-(m-tolylthio)aniline —— C14H15NOS
    4-methoxy-2-(m-tolylthio)aniline
    —— 8-hydroxymethyl-2,3-dihydrothiazolo<3,2-c>pyrimidine-5,7-dione —— C7H8N2O3S
    8-hydroxymethyl-2,3-dihydrothiazolo<3,2-c>pyrimidine-5,7-dione
    —— (S)-cyclohexyl n-decyl sulfoxide —— C16H32OS
    (S)-cyclohexyl n-decyl sulfoxide
    —— methyl 5'-methylspiro[adamantan-2,2'-[1,3]oxathiole]-4'-carboxylate —— C15H20O3S
    methyl 5'-methylspiro[adamantan-2,2'-[1,3]oxathiole]-4'-carboxylate
    —— (3-((3,4-dimethylphenyl)thio)-4-hydroxyphenyl)(isoindolin-2-yl)methanone —— C23H21NO2S
    (3-((3,4-dimethylphenyl)thio)-4-hydroxyphenyl)(isoindolin-2-yl)methanone
    —— 2-amino-5-[5-(1H-benzimidazol-2-ylsulfanyl)-2-furyl]-4-hydroxy-7,8,9,10-tetrahydro-5H-pyrimido[4,5-b]quinolin-6-one —— C22H18N6O3S
    2-amino-5-[5-(1H-benzimidazol-2-ylsulfanyl)-2-furyl]-4-hydroxy-7,8,9,10-tetrahydro-5H-pyrimido[4,5-b]quinolin-6-one
    —— N-({5-[4-(methylsulfanyl)phenyl]-1,2-oxazol-3-yl}methyl)tricycle[3.3.1.0(3,7)]nonan-3-amine —— C20H24N2OS
    N-({5-[4-(methylsulfanyl)phenyl]-1,2-oxazol-3-yl}methyl)tricycle[3.3.1.0(3,7)]nonan-3-amine
    —— 3-ethyl-2-ethylthio-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile —— C14H14N4OS
    3-ethyl-2-ethylthio-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile
    —— 4-(5-formyl-2-furyl)-2-methylthiopyrimidine —— C10H8N2O2S
    4-(5-formyl-2-furyl)-2-methylthiopyrimidine
    —— 5-((4-chlorophenyl)thio)-3,4-dimethylthran-2(5H)-one —— C12H11ClO2S
    5-((4-chlorophenyl)thio)-3,4-dimethylthran-2(5H)-one
    —— 5-(3,5-Dichlorophenylthio)-4-isopropyl-2-[2-(1-methoxycyclooctyloxy)ethyl]-1-methyl-1H-imidazole —— C24H34Cl2N2O2S
    5-(3,5-Dichlorophenylthio)-4-isopropyl-2-[2-(1-methoxycyclooctyloxy)ethyl]-1-methyl-1H-imidazole
    —— 4-[(4-ethylthiophenyl)methyl]-1,2-dihydro-5-methyl-3H-pyrazol-3-one —— C13H16N2OS
    4-[(4-ethylthiophenyl)methyl]-1,2-dihydro-5-methyl-3H-pyrazol-3-one