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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 10,11,37,38-tetrakis(phenylthio)-23,26,31,34-tetraoxa-8,13-dithio-1,20-diazapentacyclo[18.8.8.2<sup>9,12</sup>.1<sup>3,7</sup>.1<sup>14,18</sup>]-tetraconta-3(40),4,6,9(10),11,14(15),16,18(39),37-nonaene —— C56H56N2O4S6
    10,11,37,38-tetrakis(phenylthio)-23,26,31,34-tetraoxa-8,13-dithio-1,20-diazapentacyclo[18.8.8.2<sup>9,12</sup>.1<sup>3,7</sup>.1<sup>14,18</sup>]-tetraconta-3(40),4,6,9(10),11,14(15),16,18(39),37-nonaene
    —— (methoxycarbonyldithio)ethylamine hydrochloride —— C4H9NO2S2*ClH
    (methoxycarbonyldithio)ethylamine hydrochloride
    —— N-((1R,2R)-2-Thioacetylamino-cyclohexyl)-thioacetamide —— C10H18N2S2
    N-((1R,2R)-2-Thioacetylamino-cyclohexyl)-thioacetamide
    —— D-(1-ethoxycarbonyleth-1-yl)sulfonyl isocyanate —— C6H9NO5S
    D-(1-ethoxycarbonyleth-1-yl)sulfonyl isocyanate
    —— 6-chloro-2,4-dihydroxy-5-methylthio pyrimidine —— C5H5ClN2O2S
    6-chloro-2,4-dihydroxy-5-methylthio pyrimidine
    —— methyl (Z)-4,4-dimethyl-3-phenylthio-2-pentenoate —— C14H18O2S
    methyl (Z)-4,4-dimethyl-3-phenylthio-2-pentenoate
    —— L-cysteine —— C3H7NOS
    L-cysteine
    —— trimethyl((5-methyl-2-(4-(methylthio)phenyl)-1,3,2-dioxaborinan-5-yl)methoxy)silane —— C15H25BO3SSi
    trimethyl((5-methyl-2-(4-(methylthio)phenyl)-1,3,2-dioxaborinan-5-yl)methoxy)silane
    —— 1-cyano-6-p-methoxyphenylthioazulene —— C18H13NOS
    1-cyano-6-p-methoxyphenylthioazulene
    —— 2-((4-(trifluoromethyl)phenyl)thio)pyridine —— C12H8F3NS
    2-((4-(trifluoromethyl)phenyl)thio)pyridine
    —— [5-fluoro-2-(5-methoxy-4-methyl-1H-indol-3-ylsulfanyl)-benzyl]-methyl-amine 857499-01-5 C18H19FN2OS
    [5-fluoro-2-(5-methoxy-4-methyl-1H-indol-3-ylsulfanyl)-benzyl]-methyl-amine
    —— [((2R,4R,5R)-4,5-Dihydroxy-2-methylsulfanyl-tetrahydro-thiopyran-2-yl)-difluoro-methyl]-phosphonic acid diethyl ester —— C11H21F2O5PS2
    [((2R,4R,5R)-4,5-Dihydroxy-2-methylsulfanyl-tetrahydro-thiopyran-2-yl)-difluoro-methyl]-phosphonic acid diethyl ester
    —— [((2R,4S,5S)-4,5-Dihydroxy-2-methylsulfanyl-tetrahydro-thiopyran-2-yl)-difluoro-methyl]-phosphonic acid diethyl ester —— C11H21F2O5PS2
    [((2R,4S,5S)-4,5-Dihydroxy-2-methylsulfanyl-tetrahydro-thiopyran-2-yl)-difluoro-methyl]-phosphonic acid diethyl ester
    —— 4-(tert-butyl)-2-(p-tolylthio)phenol —— C18H22S
    4-(tert-butyl)-2-(p-tolylthio)phenol
    —— 4-phenyl-2-methylthio-1,3-selenathiolium iodide —— C10H9S2Se*I
    4-phenyl-2-methylthio-1,3-selenathiolium iodide
    —— Ethyl α-chloro-α-fluoro-α-(phenylthio)acetate —— C10H10ClFO2S
    Ethyl α-chloro-α-fluoro-α-(phenylthio)acetate
    —— 2-methyl-3-<(2-furylmethyl)thio>furan —— C10H10O2S
    2-methyl-3-<(2-furylmethyl)thio>furan
    —— (R,E)-3-Methyl-4-phenylsulfanylbut-3-en-2-ol —— C11H14OS
    (R,E)-3-Methyl-4-phenylsulfanylbut-3-en-2-ol
    —— 1-<4-(methylamino)butoxy>-2-(phenylthio)benzene —— C17H21NOS
    1-<4-(methylamino)butoxy>-2-(phenylthio)benzene
    —— 2,4-dimethyl-thien-3-yl-sulphonyl isocyanate —— C7H7NO3S2
    2,4-dimethyl-thien-3-yl-sulphonyl isocyanate
    —— N-hydroxy-N-[5-(phenylthio)thien-2-yl]methyl urea —— C12H12N2O2S2
    N-hydroxy-N-[5-(phenylthio)thien-2-yl]methyl urea
    —— 4-hydroxy-4-(1-(phenylthio)cyclobutyl)butan-2-one —— C14H18O2S
    4-hydroxy-4-(1-(phenylthio)cyclobutyl)butan-2-one
    —— {[2-(2,2-dibutyl-2-stannahexyl)phenyl]methylthio}benzene —— C26H40SSn
    {[2-(2,2-dibutyl-2-stannahexyl)phenyl]methylthio}benzene
    —— 2-chloro-1,1-bis-methylsulfanyl-ethane —— C4H9ClS2
    2-chloro-1,1-bis-methylsulfanyl-ethane
    —— 7H-3-propyl-7-methoxy-6-phenyl-s-triazolo[3,4-b][1,3,4]thiadiazine —— C14H16N4OS
    7H-3-propyl-7-methoxy-6-phenyl-s-triazolo[3,4-b][1,3,4]thiadiazine
    —— [(R)-8-fluoro-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-yl-methyl]amine phosphate —— C17H17F2NS*(x)H3O4P
    [(R)-8-fluoro-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-yl-methyl]amine phosphate
    —— 2-(4-acetamidophenylsulfinyl)diphenyl sulfide —— C20H17NO2S2
    2-(4-acetamidophenylsulfinyl)diphenyl sulfide
    —— tert-butyl 1-[3-(methylthio)-1,2,4-triazin-6-yl]ethylcarbamate —— C11H18N4O2S
    tert-butyl 1-[3-(methylthio)-1,2,4-triazin-6-yl]ethylcarbamate
    —— 3-furan-2-yl-5-methylsulfanyl-1(2)<i>H</i>-pyrazole-4-carbonitrile —— C9H7N3OS
    3-furan-2-yl-5-methylsulfanyl-1(2)<i>H</i>-pyrazole-4-carbonitrile
    —— tetramethyl sulfoxide —— C4H12OS
    tetramethyl sulfoxide
    —— ethyl 3-nitro-3-phenyl-2-phenylthio-propanoate —— C17H17NO4S
    ethyl 3-nitro-3-phenyl-2-phenylthio-propanoate
    —— 1-bromo-3-(methylsulfonyl)propane 859940-73-1 C4H9BrO2S
    1-bromo-3-(methylsulfonyl)propane
    —— 5-(3,5-Dichlorophenylthio)-2-methyl-4-isopropyl-1-[(pyridin-4-yl)methyl]-1H-pyrrole-3-carboxylic acid —— C21H20Cl2N2O2S
    5-(3,5-Dichlorophenylthio)-2-methyl-4-isopropyl-1-[(pyridin-4-yl)methyl]-1H-pyrrole-3-carboxylic acid
    —— tris<2,5-bis(methylthio)-3-thienyl>carbinol —— C19H22OS9
    tris<2,5-bis(methylthio)-3-thienyl>carbinol
    —— 2-(3-Chloro-propyl)-2-ethyl-[1,3]oxathiolane —— C8H15ClOS
    2-(3-Chloro-propyl)-2-ethyl-[1,3]oxathiolane
    —— 1-((R)-2-Methyl-1,1-dioxo-1λ<sup>6</sup>-[1,3]dithiolan-2-yl)-propan-1-one —— C7H12O3S2
    1-((R)-2-Methyl-1,1-dioxo-1λ<sup>6</sup>-[1,3]dithiolan-2-yl)-propan-1-one
    —— 4-chloro-N-(3-hydroxypropyl)-2-phenylsulfanyl-5-sulfamoyl-benzamide —— C16H17ClN2O4S2
    4-chloro-N-(3-hydroxypropyl)-2-phenylsulfanyl-5-sulfamoyl-benzamide
    —— 5-methyl-2,3-dihydro-benzo[<i>f</i>]imidazo[1,2-<i>d</i>][1,4]thiazepine —— C12H12N2S
    5-methyl-2,3-dihydro-benzo[<i>f</i>]imidazo[1,2-<i>d</i>][1,4]thiazepine
    —— 3-(trifluoromethyl)-2H-thiete 1,1-dioxide 2445790-63-4 C4H3F3O2S
    3-(trifluoromethyl)-2H-thiete 1,1-dioxide
    —— methyl 2-methyl-3-oxo-4-(phenylthio)butanoate —— C12H14O3S
    methyl 2-methyl-3-oxo-4-(phenylthio)butanoate
    —— N-[2-[[(2,3-difluorophenyl)methyl]thio]-6-[2-(2,2-dimethyl-1,3-dioxolan-4-yl)-ethyl]-pyrimidin-4-yl]azetidine-1-sulphonamide —— C21H26F2N4O4S2
    N-[2-[[(2,3-difluorophenyl)methyl]thio]-6-[2-(2,2-dimethyl-1,3-dioxolan-4-yl)-ethyl]-pyrimidin-4-yl]azetidine-1-sulphonamide
    —— 1-(N-4-chlorophenylmethylideneamino)-1,6-dihydro-2-methylthio-6-oxopyrimidine —— C12H10ClN3OS
    1-(N-4-chlorophenylmethylideneamino)-1,6-dihydro-2-methylthio-6-oxopyrimidine
    —— 4-(7-bromo-4-(mesitylthio)-5H-pyrrolo[3,2-d]pyrimidin-2-ylamino)benzonitrile —— C22H18BrN5S
    4-(7-bromo-4-(mesitylthio)-5H-pyrrolo[3,2-d]pyrimidin-2-ylamino)benzonitrile
    —— 3-(cyclohex-1-enyl)-4-(4-nitrophenylsulfenyl)isoquinoline —— C21H18N2O2S
    3-(cyclohex-1-enyl)-4-(4-nitrophenylsulfenyl)isoquinoline
    —— 1-(4-fluorophenyl)-2-(p-tolylthio)ethanol —— C15H15FOS
    1-(4-fluorophenyl)-2-(p-tolylthio)ethanol
    —— 5-amino-7-[(4-chlorophenyl)thio]-2-methyl-2,4-diphenyl-1,2-dihydro-1,6-naphthyridine-8-carbonitrile —— C28H21ClN4S
    5-amino-7-[(4-chlorophenyl)thio]-2-methyl-2,4-diphenyl-1,2-dihydro-1,6-naphthyridine-8-carbonitrile
    —— N-phenyl-5-(propylthio)-7-(thiazol-2-ylthio)thiazolo[5,4-d]pyrimidin-2-amine —— C17H15N5S4
    N-phenyl-5-(propylthio)-7-(thiazol-2-ylthio)thiazolo[5,4-d]pyrimidin-2-amine
    —— 4-benzyl-3-[(4-chlorobenzyl)thio]-5-thien-2-yl-4H-1,2,4-triazole —— C20H16ClN3S2
    4-benzyl-3-[(4-chlorobenzyl)thio]-5-thien-2-yl-4H-1,2,4-triazole
    —— 5,6-dihydro-6-dimethylaminomethyl-4H-thieno[2,3-b]thiopyran-2-sulfonamide —— C10H16N2O2S3
    5,6-dihydro-6-dimethylaminomethyl-4H-thieno[2,3-b]thiopyran-2-sulfonamide
    —— 3-chloro-4-(2,4-dichlorophenylthio)aniline —— C12H8Cl3NS
    3-chloro-4-(2,4-dichlorophenylthio)aniline