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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-(2,4-difluorophenylthio)-4-isopropyl-2-methylimidazole —— C13H14F2N2S
    5-(2,4-difluorophenylthio)-4-isopropyl-2-methylimidazole
    —— 4-(2,4-difluorophenylthio)-1-ethoxymethyl-5-isopropyl-2-methyl imidazole —— C16H20F2N2OS
    4-(2,4-difluorophenylthio)-1-ethoxymethyl-5-isopropyl-2-methyl imidazole
    —— 5-(2,4-difluorophenylthio)-1-ethoxymethyl-4-isopropyl-2-methylimidazole —— C16H20F2N2OS
    5-(2,4-difluorophenylthio)-1-ethoxymethyl-4-isopropyl-2-methylimidazole
    —— 2-(nonafluorobutylsulfanyl)pyridine —— C9H4F9NS
    2-(nonafluorobutylsulfanyl)pyridine
    —— 2-{[1,2,3,4-Tetrahydro-3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)-2,4-dioxothieno[2,3-d]pyrimidin-5-yl]thio}pyridine N-oxide —— C27H25N3O3S2
    2-{[1,2,3,4-Tetrahydro-3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)-2,4-dioxothieno[2,3-d]pyrimidin-5-yl]thio}pyridine N-oxide
    —— 1,1-dichloro-2,2-difluoro-1-(2-pyridylthio)-4-pentene —— C10H9Cl2F2NS
    1,1-dichloro-2,2-difluoro-1-(2-pyridylthio)-4-pentene
    —— 1-(Methanesulfonyl)oxo-octane —— C9H18O3S
    1-(Methanesulfonyl)oxo-octane
    —— hexyloxycarbonyl isothiocyanate —— C8H13NO2S
    hexyloxycarbonyl isothiocyanate
    —— (1S,2R,3S,4R,5S)-ethyl 4-(chlorocarbonyl)-5-nitro-3-(pentan-3-yloxy)-2-(p-tolylthio)cyclohexanecarboxylate —— C22H30ClNO6S
    (1S,2R,3S,4R,5S)-ethyl 4-(chlorocarbonyl)-5-nitro-3-(pentan-3-yloxy)-2-(p-tolylthio)cyclohexanecarboxylate
    —— (1R,2S,3R,4S,6S)-4-(ethoxycarbonyl)-6-nitro-2-(pentan-3-yloxy)-3-(p-tolylthio)cyclohexanecarboxylic acid —— C22H31NO7S
    (1R,2S,3R,4S,6S)-4-(ethoxycarbonyl)-6-nitro-2-(pentan-3-yloxy)-3-(p-tolylthio)cyclohexanecarboxylic acid
    —— (1S,2R,3S,4R,5S)-4-acetylamino-3-(1-ethylpropoxy)-5-nitro-2-p-tolylsulfanylcyclohexanecarboxylic acid ethyl ester —— C23H34N2O6S
    (1S,2R,3S,4R,5S)-4-acetylamino-3-(1-ethylpropoxy)-5-nitro-2-p-tolylsulfanylcyclohexanecarboxylic acid ethyl ester
    —— GCD-187 193681-31-1 C17H19F3N5O5PS
    GCD-187
    —— 2-amino-6-[(4-methoxyphenyl)sulfanyl]purine —— C12H11N5OS
    2-amino-6-[(4-methoxyphenyl)sulfanyl]purine
    —— 2-((cyclopropylmethyl)sulfonyl)acetic acid —— C6H10O4S
    2-((cyclopropylmethyl)sulfonyl)acetic acid
    —— 2-((cyclobutylmethyl)sulfonyl)acetic acid —— C7H12O4S
    2-((cyclobutylmethyl)sulfonyl)acetic acid
    —— 2-(heptylsulfonyl)acetic acid —— C9H18O4S
    2-(heptylsulfonyl)acetic acid
    —— 2-((cyclohexylmethyl)sulfonyl)acetic acid —— C9H16O4S
    2-((cyclohexylmethyl)sulfonyl)acetic acid
    —— 6-(1-methyl-4-nitro-5-imidazolyl)mercapto-7,8-trimethylenepurine —— C12H11N7O2S
    6-(1-methyl-4-nitro-5-imidazolyl)mercapto-7,8-trimethylenepurine
    —— N-cyclopentyl-2-((5-methyl-4-phenethyl-4H-1,2,4-triazol-3-yl)thio)acetamide —— C18H24N4OS
    N-cyclopentyl-2-((5-methyl-4-phenethyl-4H-1,2,4-triazol-3-yl)thio)acetamide
    —— 2-[(4-chloro-6-{[4-(4-chlorophenyl)-1,3-thiazol-2-yl]amino}pyrimidin-2-yl)sulfanyl]acetic acid —— C15H10Cl2N4O2S2
    2-[(4-chloro-6-{[4-(4-chlorophenyl)-1,3-thiazol-2-yl]amino}pyrimidin-2-yl)sulfanyl]acetic acid
    —— 2-[(4-chloro-6-{[4-(4-chlorophenyl)-1,3-thiazol-2-yl]amino}pyrimidin-2-yl)sulfanyl]butanoic acid —— C17H14Cl2N4O2S2
    2-[(4-chloro-6-{[4-(4-chlorophenyl)-1,3-thiazol-2-yl]amino}pyrimidin-2-yl)sulfanyl]butanoic acid
    —— (E)-ethyl-3-(4-(ethylamino)-6-methyl-2-(methylthio)pyrimidin-5-yl)acrylate —— C13H19N3O2S
    (E)-ethyl-3-(4-(ethylamino)-6-methyl-2-(methylthio)pyrimidin-5-yl)acrylate
    —— 1,4,8,11-tetrakis(2-perfluorohexylsulfinylethyl)-1,4,8,11-tetraazacyclotetradecade —— C42H36F52N4O4S4
    1,4,8,11-tetrakis(2-perfluorohexylsulfinylethyl)-1,4,8,11-tetraazacyclotetradecade
    —— 1,4,8,11-tetrakis(2-perfluorohexylsulfonylethyl)-1,4,8,11-tetraazacyclotetradecade —— C42H36F52N4O8S4
    1,4,8,11-tetrakis(2-perfluorohexylsulfonylethyl)-1,4,8,11-tetraazacyclotetradecade
    —— 1,2-bis(butylsulfinyl)ethane —— C10H22O2S2
    1,2-bis(butylsulfinyl)ethane
    —— 1,3-Bis(6-amino-3,5-dicyan-4-methylthiopyridin-2-ylthio)propan-2-on —— C19H14N8OS4
    1,3-Bis(6-amino-3,5-dicyan-4-methylthiopyridin-2-ylthio)propan-2-on
    —— 1,3-Bis(4-cyan-1-morpholino-5,6,7,8-tetrahydroisochinolin-3-ylthio)propan-2-on —— C31H36N6O3S2
    1,3-Bis(4-cyan-1-morpholino-5,6,7,8-tetrahydroisochinolin-3-ylthio)propan-2-on
    —— 1,3-Bis[(1-methyl-1H-imidazol-2-yl)thio]-2-propanone —— C11H14N4OS2
    1,3-Bis[(1-methyl-1H-imidazol-2-yl)thio]-2-propanone
    —— 4-(chloromethyl)-2-(methylthio)thiazole —— C5H6ClNS2
    4-(chloromethyl)-2-(methylthio)thiazole
    —— 2-amino-4-(cis-4-{[tert-butyl(dimethyl)silyl]oxy}cyclohexyl)-6-[({2-[(4-fluorophenyl)amino]-1,3-thiazol-4-yl}methyl)thio]pyridine-3,5-dicarbonitrile —— C29H35FN6OS2Si
    2-amino-4-(cis-4-{[tert-butyl(dimethyl)silyl]oxy}cyclohexyl)-6-[({2-[(4-fluorophenyl)amino]-1,3-thiazol-4-yl}methyl)thio]pyridine-3,5-dicarbonitrile
    —— oxetan-3-yl N-[5-(phenylsulfanyl)-1H-1,3-benzodiazol-2-yl]carbamate —— C17H15N3O3S
    oxetan-3-yl N-[5-(phenylsulfanyl)-1H-1,3-benzodiazol-2-yl]carbamate
    —— 4-phenyl-3-(4-piperidylthio)furoxan —— C13H15N3O2S
    4-phenyl-3-(4-piperidylthio)furoxan
    —— 3-methylthiomethyloxy-1-adamantyl methacrylate —— C16H24O3S
    3-methylthiomethyloxy-1-adamantyl methacrylate
    —— DMSO-d(1) —— C2H6OS
    DMSO-d(1)
    —— (4,4-dimethyl-8-phenylthio-4,5-dihydrothieno[3,4-g]-1,2-benzisoxazol-6-yl)(pyrrolidin-1-yl)methanone —— C22H22N2O2S2
    (4,4-dimethyl-8-phenylthio-4,5-dihydrothieno[3,4-g]-1,2-benzisoxazol-6-yl)(pyrrolidin-1-yl)methanone
    —— 6,6-Dimethyl-1-(isoxazol-5-yl)-3-methylthio-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one —— C14H15NO2S2
    6,6-Dimethyl-1-(isoxazol-5-yl)-3-methylthio-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one
    —— 4,4-dimethyl-8-methylthio-6-(1-methyl-1,2,4-triazol-3-yl)-4,5-dihydrothieno[3,4-g]-1,2-benzisoxazole —— C15H16N4OS2
    4,4-dimethyl-8-methylthio-6-(1-methyl-1,2,4-triazol-3-yl)-4,5-dihydrothieno[3,4-g]-1,2-benzisoxazole
    —— 1-(2-bromomethyl-3-hydroxy-2-hydroxymethylpropyl)-6-methyl-2-(methylsulfanyl)pyrimidin-4(1H)-one —— C11H17BrN2O3S
    1-(2-bromomethyl-3-hydroxy-2-hydroxymethylpropyl)-6-methyl-2-(methylsulfanyl)pyrimidin-4(1H)-one
    —— 3-((4-bromophenyl)thio)-1H-indole —— C14H10BrNS
    3-((4-bromophenyl)thio)-1H-indole
    —— 6-methyl-2-((4-phenylbutyl)thio)pyrimidin-4-ol —— C15H18N2OS
    6-methyl-2-((4-phenylbutyl)thio)pyrimidin-4-ol
    —— S-(3-fluorobenzyl)-6-methyl-2-thiouracil —— C12H11FN2OS
    S-(3-fluorobenzyl)-6-methyl-2-thiouracil
    —— 2-{[(4-chlorophenyl)methyl]thio}-6-methylpyrimidin-4-ol 159333-55-8 C12H11ClN2OS
    2-{[(4-chlorophenyl)methyl]thio}-6-methylpyrimidin-4-ol
    —— 5a-Acetylamino-2-methyl-5a,6,7,8,9,9a-hexahydro-4H-pyrimido<2,1-b>benzothiazol-4-on —— C13H17N3O2S
    5a-Acetylamino-2-methyl-5a,6,7,8,9,9a-hexahydro-4H-pyrimido<2,1-b>benzothiazol-4-on
    —— 6-methyl-2-[(pyridin-2-ylmethyl)sulfanyl]pyrimidin-4-ol 132147-55-8 C11H11N3OS
    6-methyl-2-[(pyridin-2-ylmethyl)sulfanyl]pyrimidin-4-ol
    —— 2-[(4-methylpyridin-2-yl)methyl]-thio-6-methyl-4(3H)-pyrimidinone —— C12H13N3OS
    2-[(4-methylpyridin-2-yl)methyl]-thio-6-methyl-4(3H)-pyrimidinone
    —— 6-methyl-2-(2-morpholino-2-oxoethylthio)pyrimidin-4(3H)-one —— C11H15N3O3S
    6-methyl-2-(2-morpholino-2-oxoethylthio)pyrimidin-4(3H)-one
    —— 4-Chloro-6-methyl-2-(piperidin-4-ylsulfanyl)pyridine —— C11H15ClN2S
    4-Chloro-6-methyl-2-(piperidin-4-ylsulfanyl)pyridine
    —— O-octadecyl S-(trifluoromethyl)carbonothioate —— C20H37F3O2S
    O-octadecyl S-(trifluoromethyl)carbonothioate
    —— O-octadecyl S-(trifluoromethyl)carbonodithioate —— C20H37F3OS2
    O-octadecyl S-(trifluoromethyl)carbonodithioate
    —— 4,6-dibromo-2-(propylthio)5-amino-pyrimidine —— C7H9Br2N3S
    4,6-dibromo-2-(propylthio)5-amino-pyrimidine