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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [4-chloro-2-(n-octyl)-3-isothiazolon-5-yl]-(1-oxypyridin-2-yl)sulfide —— C16H21ClN2O2S2
    [4-chloro-2-(n-octyl)-3-isothiazolon-5-yl]-(1-oxypyridin-2-yl)sulfide
    —— [4-chloro-2-(n-octyl)-3-isothiazolon-5-yl]-(1-oxypyridin-2-yl)sulfide —— C32H40Cl2N4O4S3
    [4-chloro-2-(n-octyl)-3-isothiazolon-5-yl]-(1-oxypyridin-2-yl)sulfide
    —— 2-[1-(2,6-Difluorophenyl)ethylthio]pyridine 1-oxide —— C13H11F2NOS
    2-[1-(2,6-Difluorophenyl)ethylthio]pyridine 1-oxide
    —— 2-[1-(2-chloro-6-fluorophenyl)ethylthio]pyridine 1-oxide —— C13H11ClFNOS
    2-[1-(2-chloro-6-fluorophenyl)ethylthio]pyridine 1-oxide
    —— [2-methyl-3-isothiazolon-5-yl]-(1-oxypyridin-2-yl)sulfide —— C18H14N4O4S3
    [2-methyl-3-isothiazolon-5-yl]-(1-oxypyridin-2-yl)sulfide
    —— benzyl (3-chlorophenyl) sulfide —— C13H11ClS
    benzyl (3-chlorophenyl) sulfide
    —— 8-(hexamethyleniminomethyl)-10H-pyrazino[2,3-b][1,4]benzothiazine —— C17H20N4S
    8-(hexamethyleniminomethyl)-10H-pyrazino[2,3-b][1,4]benzothiazine
    —— 5-chloro-2-[[4-(hexahydro-1H-azepin-1-yl)butyl]thio]-benzoxazole —— C17H23ClN2OS
    5-chloro-2-[[4-(hexahydro-1H-azepin-1-yl)butyl]thio]-benzoxazole
    —— 5-(3,5-Dichlorophenylthio)-4-isopropyl-1-(pyridin-4-ylmethyl)-1H-imidazol-2-ylmethyl di-n-butylaminomethylcarbamate —— C29H39Cl2N5O2S
    5-(3,5-Dichlorophenylthio)-4-isopropyl-1-(pyridin-4-ylmethyl)-1H-imidazol-2-ylmethyl di-n-butylaminomethylcarbamate
    —— 5-(3,5-Dichlorophenylthio)-4-isopropyl-1-(pyridin-4-ylmethyl)-1H-imidazol-2-ylmethyl morpholinomethylcarbamate —— C25H29Cl2N5O3S
    5-(3,5-Dichlorophenylthio)-4-isopropyl-1-(pyridin-4-ylmethyl)-1H-imidazol-2-ylmethyl morpholinomethylcarbamate
    —— 2,5-bis<(2-cyanoethyl)thio>-2,4-hexadiene-1,6-diol —— C12H16N2O2S2
    2,5-bis<(2-cyanoethyl)thio>-2,4-hexadiene-1,6-diol
    —— 5,6-dihydro-4H-thieno[2,3-b]thiopyran-5-amine hydrochloride —— C7H9NS2*ClH
    5,6-dihydro-4H-thieno[2,3-b]thiopyran-5-amine hydrochloride
    —— 5-ethoxycarbonylamino-5,6-dihydro-4H-thieno[2,3-b]thiopyran —— C10H13NO2S2
    5-ethoxycarbonylamino-5,6-dihydro-4H-thieno[2,3-b]thiopyran
    —— N-methoxy-S-methylthiouronium iodide —— C3H8N2OS*HI
    N-methoxy-S-methylthiouronium iodide
    —— N-methoxy-4-[(4-methylphenyl)thio]thieno[2,3-c]pyridine-2-carboxamide —— C16H14N2O2S2
    N-methoxy-4-[(4-methylphenyl)thio]thieno[2,3-c]pyridine-2-carboxamide
    —— <i>N</i>-allyl-<i>N</i>'-methoxy-thiourea —— C5H10N2OS
    <i>N</i>-allyl-<i>N</i>'-methoxy-thiourea
    —— 2-aminocyclopentene-1-dithiocarboxylic acid —— C6H11NS2
    2-aminocyclopentene-1-dithiocarboxylic acid
    —— 1,1-d2-octadecanethiol —— C18H38S
    1,1-d2-octadecanethiol
    —— 6-chloro-2-(isopropylthio)-3-nitropyridine —— C8H9ClN2O2S
    6-chloro-2-(isopropylthio)-3-nitropyridine
    —— 3-(4-fluorophenyl)-6-hydroxy-2-(methylthio)pyrimidin-4(3H)-one —— C11H9FN2O2S
    3-(4-fluorophenyl)-6-hydroxy-2-(methylthio)pyrimidin-4(3H)-one
    —— 5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-thionaphthol —— C14H20OS
    5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-thionaphthol
    —— Endo-3-(3-pentylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[2.2.1]heptane fumarate —— C4H4O4*C13H21N3S2
    Endo-3-(3-pentylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[2.2.1]heptane fumarate
    —— 4-[2-(7-methyl-pyrido[2,3-d]pyrimidin-4-ylamino)-4-nitro-phenylsulfanyl]-phenol —— C20H15N5O3S
    4-[2-(7-methyl-pyrido[2,3-d]pyrimidin-4-ylamino)-4-nitro-phenylsulfanyl]-phenol
    —— N,N-dimethylaminoethanethiol —— C4H11NS
    N,N-dimethylaminoethanethiol
    —— 4-[2-(7-isopropyl-pyrido[2,3-d]pyrimidin-4-ylamino)-4-nitro-phenylsulfanyl]-phenol —— C22H19N5O3S
    4-[2-(7-isopropyl-pyrido[2,3-d]pyrimidin-4-ylamino)-4-nitro-phenylsulfanyl]-phenol
    —— 3,5-Dichloro-4-(4'-methoxy-3'-(6-methoxy-pyridin-3-ylmethyl)phenylthio)-nitrobenzene —— C20H16Cl2N2O4S
    3,5-Dichloro-4-(4'-methoxy-3'-(6-methoxy-pyridin-3-ylmethyl)phenylthio)-nitrobenzene
    —— 3-(Trifluoromethyl)-4-(4-pyridinylthio)aniline —— C12H9F3N2S
    3-(Trifluoromethyl)-4-(4-pyridinylthio)aniline
    —— formimidoyl(chlorocarbonyl)disulfane —— C4H6ClNO2S2
    formimidoyl(chlorocarbonyl)disulfane
    —— (+/-)-2-amino-4-methanesulfonyl-butan-1-ol —— C5H13NO3S
    (+/-)-2-amino-4-methanesulfonyl-butan-1-ol
    —— dithiocarbonic acid S,S-dihexyl ester —— C13H26OS2
    dithiocarbonic acid S,S-dihexyl ester
    —— 1,1-dichloro-2-methyl-4-phenylthiobutene —— C11H12Cl2S
    1,1-dichloro-2-methyl-4-phenylthiobutene
    —— (endo, syn)-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azabicyclo[3.3.1]non-9-yl]acetic acid —— C21H24N4O2S
    (endo, syn)-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azabicyclo[3.3.1]non-9-yl]acetic acid
    —— ethyl (syn)-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azabicyclo[3.3.1]non-9-yl]acetate —— C23H28N4O2S
    ethyl (syn)-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azabicyclo[3.3.1]non-9-yl]acetate
    —— tetradecane-1-thiol; lead (II)-salt —— 2C14H29S*Pb
    tetradecane-1-thiol; lead (II)-salt
    —— O-ethyl S-(2-(methoxy(methyl)amino)-2-oxoethyl) carbonodithioate —— C7H13NO3S2
    O-ethyl S-(2-(methoxy(methyl)amino)-2-oxoethyl) carbonodithioate
    —— 3-(3-Hexylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1, 1-dimethylpyridinium iodide —— C15H26N3S2*I
    3-(3-Hexylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1, 1-dimethylpyridinium iodide
    —— (2'S,4'S,5'R)-N,N-diisopropyl-2-[3,4-dimethyl-5-phenyl-1,3-oxazolan-2-yl]-6-(phenylsulfanyl)benzamide —— C30H36N2O2S
    (2'S,4'S,5'R)-N,N-diisopropyl-2-[3,4-dimethyl-5-phenyl-1,3-oxazolan-2-yl]-6-(phenylsulfanyl)benzamide
    —— (7R)-8-phenylthio-paeonimetabolin I —— C16H18O4S
    (7R)-8-phenylthio-paeonimetabolin I
    —— (7S)-8-phenylthio-paeonimetabolin I —— C16H18O4S
    (7S)-8-phenylthio-paeonimetabolin I
    —— 2-carboxymethylthio-5-(2-chlorophenyl)-1,3,4-oxadiazole 485334-66-5 C10H7ClN2O3S
    2-carboxymethylthio-5-(2-chlorophenyl)-1,3,4-oxadiazole
    —— 2-(p-tolylthio)tetrahydro-2H-pyran —— C12H16OS
    2-(p-tolylthio)tetrahydro-2H-pyran
    —— 5-(3,5-dichlorophenylthio)-4-isopropyl-2-(p-methoxybenzyloxymethyl)-1-(2-(pyridin-2-yl)ethyl)-1H-imidazole —— C28H29Cl2N3O2S
    5-(3,5-dichlorophenylthio)-4-isopropyl-2-(p-methoxybenzyloxymethyl)-1-(2-(pyridin-2-yl)ethyl)-1H-imidazole
    —— 2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-1-(1,2-dihydro-2-oxopyridin-3-ylmethyl)-4-isopropyl-1H-imidazole —— C26H25Cl2N3O2S
    2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-1-(1,2-dihydro-2-oxopyridin-3-ylmethyl)-4-isopropyl-1H-imidazole
    —— 2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(3-(pyridin-2-yl)propyl)-1H-imidazole —— C28H29Cl2N3OS
    2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(3-(pyridin-2-yl)propyl)-1H-imidazole
    —— [1,2-dimethyl-5-(3,5-dimethylphenylthio)-1H-imidazol-4-yl]methanol —— C14H18N2OS
    [1,2-dimethyl-5-(3,5-dimethylphenylthio)-1H-imidazol-4-yl]methanol
    —— 4-chloromethyl-1,2-dimethyl-5-(3,5-dimethylphenylthio)imidazole —— C14H17ClN2S
    4-chloromethyl-1,2-dimethyl-5-(3,5-dimethylphenylthio)imidazole
    —— [2-t-butyldimethylsilyloxymethyl-5-(3-chlorophenylthio)-1H-imidazol-4-yl]methanol —— C17H25ClN2O2SSi
    [2-t-butyldimethylsilyloxymethyl-5-(3-chlorophenylthio)-1H-imidazol-4-yl]methanol
    —— methyl 3-((2,4-dimethylphenyl)thio)-2-hydroxy-2-methylpropanoate —— C13H18O3S
    methyl 3-((2,4-dimethylphenyl)thio)-2-hydroxy-2-methylpropanoate
    —— (2,4-dimethylphenyl)(2-nitrophenyl)sulfane —— C14H13NO2S
    (2,4-dimethylphenyl)(2-nitrophenyl)sulfane
    —— (2,4-dimethylphenyl)(2-fluorophenyl)sulfane —— C14H13FS
    (2,4-dimethylphenyl)(2-fluorophenyl)sulfane