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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(1-Methyl-cyclopropyl)-6-methylsulfanyl-[1,2,4,5]tetrazine 159801-89-5 C7H10N4S
    3-(1-Methyl-cyclopropyl)-6-methylsulfanyl-[1,2,4,5]tetrazine
    —— [3-(4-aminophenylsulphanyl)phenyl]acetic acid 365250-53-9 C14H13NO2S
    [3-(4-aminophenylsulphanyl)phenyl]acetic acid
    —— 6-vinyl-1,4-dithiaspiro<4.5>dec-6-en-8-ol 155996-12-6 C10H14OS2
    6-vinyl-1,4-dithiaspiro<4.5>dec-6-en-8-ol
    —— N-methyl-2-(3-pyridyl)-1,3-oxathiane-2-carbothioamide 82081-63-8 C11H14N2OS2
    N-methyl-2-(3-pyridyl)-1,3-oxathiane-2-carbothioamide
    —— 4,4-dimethyl-5-phenylsulphenylcyclopent-2-enone 335343-28-7 C13H14OS
    4,4-dimethyl-5-phenylsulphenylcyclopent-2-enone
    —— 1-((S)-3-Azido-2-hydroxy-propyl)-5-methyl-2-methylsulfanyl-1H-pyrimidin-4-one 208513-40-0 C9H13N5O2S
    1-((S)-3-Azido-2-hydroxy-propyl)-5-methyl-2-methylsulfanyl-1H-pyrimidin-4-one
    —— Methyl (2R,3R,4S)-<5-oxo-4-(phenylthio)-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>tetrahydrofuran-3-yl>acetate 162264-90-6 C31H36O5SSi
    Methyl (2R,3R,4S)-<5-oxo-4-(phenylthio)-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>tetrahydrofuran-3-yl>acetate
    —— 3-(Propane-1-sulfonyl)-cyclohexanone 185408-84-8 C9H16O3S
    3-(Propane-1-sulfonyl)-cyclohexanone
    —— 2,4-Bis-(2-p-tolyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole 147089-54-1 C32H25NS4
    2,4-Bis-(2-p-tolyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole
    —— 2,3-Dimethyl-5-methylsulfanyl-3,4-dihydro-2H-pyrrole 1027601-39-3 C7H13NS
    2,3-Dimethyl-5-methylsulfanyl-3,4-dihydro-2H-pyrrole
    —— (E)-(R)-4-hydroxy-1-methyl-2-butenyl phenyl sulfide 267668-20-2 C11H14OS
    (E)-(R)-4-hydroxy-1-methyl-2-butenyl phenyl sulfide
    —— 2-(2-Butoxyethylsulfanyl)phenol 210350-91-7 C12H18O2S
    2-(2-Butoxyethylsulfanyl)phenol
    —— (E)-(R)-4-bromo-1-methyl-2-butenyl phenyl sulfide 267668-21-3 C11H13BrS
    (E)-(R)-4-bromo-1-methyl-2-butenyl phenyl sulfide
    —— 5-Ethyl-6-methylsulfanyl-1-phenylmethoxypyrimidine-2,4-dione 191472-47-6 C14H16N2O3S
    5-Ethyl-6-methylsulfanyl-1-phenylmethoxypyrimidine-2,4-dione
    —— N-(1,1-Dioxo-4-phenylsulfanyl-2,5-dihydro-1H-1λ<sup>6</sup>-thiophen-3-yl)-acetamide 192988-15-1 C12H13NO3S2
    N-(1,1-Dioxo-4-phenylsulfanyl-2,5-dihydro-1H-1λ<sup>6</sup>-thiophen-3-yl)-acetamide
    —— N-[(3,5-dimethoxy-2-phenylsulfanylphenyl)methyl]-N-(2-hydroxyethyl)formamide 212184-66-2 C18H21NO4S
    N-[(3,5-dimethoxy-2-phenylsulfanylphenyl)methyl]-N-(2-hydroxyethyl)formamide
    —— 3,7,11-Trichloro-1,9-dinitrobenzo[d][1,3,6,2]benzodioxathiaphosphocine 11-oxide 21386-24-3 C12H4Cl3N2O7PS
    3,7,11-Trichloro-1,9-dinitrobenzo[d][1,3,6,2]benzodioxathiaphosphocine 11-oxide
    —— 2,2-Dimethyl-propionic acid (E)-5-{4-methoxy-2-[(E)-6-(4-methoxy-2-phenylsulfanylmethyl-pyridin-3-yl)-hex-3-enyl]-pyridin-3-yl}-pent-2-enyl ester 211758-76-8 C35H44N2O4S
    2,2-Dimethyl-propionic acid (E)-5-{4-methoxy-2-[(E)-6-(4-methoxy-2-phenylsulfanylmethyl-pyridin-3-yl)-hex-3-enyl]-pyridin-3-yl}-pent-2-enyl ester
    —— 2-(Methylthio)-I+/--phenyl-5-oxazolemethanol 201017-91-6 C11H11NO2S
    2-(Methylthio)-I+/--phenyl-5-oxazolemethanol
    —— (5,6-Dimethyl-4-oxo-4H-thieno[2,3-d][1,3]oxazin-2-ylsulfanyl)-acetic acid methyl ester 207744-09-0 C11H11NO4S2
    (5,6-Dimethyl-4-oxo-4H-thieno[2,3-d][1,3]oxazin-2-ylsulfanyl)-acetic acid methyl ester
    —— 4-Chloro-2-[(4-chlorophenyl)thio]-5-thiazolecarboxaldehyde 199851-24-6 C10H5Cl2NOS2
    4-Chloro-2-[(4-chlorophenyl)thio]-5-thiazolecarboxaldehyde
    —— 2-(4-Hydroxy-phenyl)-2,3-dihydro-benzo[1,4]oxathiine-5,7-diol 342646-92-8 C14H12O4S
    2-(4-Hydroxy-phenyl)-2,3-dihydro-benzo[1,4]oxathiine-5,7-diol
    —— (3S,4aS)-4a-Methyl-3-phenylsulfanyl-3,4,4a,5,6,7-hexahydro-1H-quinolin-2-one 118664-21-4 C16H19NOS
    (3S,4aS)-4a-Methyl-3-phenylsulfanyl-3,4,4a,5,6,7-hexahydro-1H-quinolin-2-one
    —— 3-Isopropylsulfanyl-5-piperidin-1-yl-[1,2,4]triazine 187099-37-2 C11H18N4S
    3-Isopropylsulfanyl-5-piperidin-1-yl-[1,2,4]triazine
    —— methyl 2-methyl-3-sulfonyltridecanoate 294201-72-2 C14H28O4S
    methyl 2-methyl-3-sulfonyltridecanoate
    —— N-[(3-Chloro-phenyl)-p-tolylsulfanyl-methyl]-formamide 1027905-74-3 C15H14ClNOS
    N-[(3-Chloro-phenyl)-p-tolylsulfanyl-methyl]-formamide
    —— 7-(Phenylsulfanylmethyl)-1,4-dioxaspiro[4.5]decane-7-carbonitrile 178207-74-4 C16H19NO2S
    7-(Phenylsulfanylmethyl)-1,4-dioxaspiro[4.5]decane-7-carbonitrile
    —— 2-<(2,4-diacetylaminophenyl)thio>benzothiazole 219649-10-2 C17H15N3O2S2
    2-<(2,4-diacetylaminophenyl)thio>benzothiazole
    —— (2R,3S,4R)-4-methyl-5-oxo-4-phenylsulfanyl-2-tridecyloxolane-3-carboxylic acid 180267-08-7 C25H38O4S
    (2R,3S,4R)-4-methyl-5-oxo-4-phenylsulfanyl-2-tridecyloxolane-3-carboxylic acid
    —— 4-Ethylsulfanyl-6-phenyl-thieno[2,3-c]furan 181868-55-3 C14H12OS2
    4-Ethylsulfanyl-6-phenyl-thieno[2,3-c]furan
    —— 3-(5-Methyl-2-methylsulfanyl-pyrimidin-4-yloxy)-propan-1-ol 190069-96-6 C9H14N2O2S
    3-(5-Methyl-2-methylsulfanyl-pyrimidin-4-yloxy)-propan-1-ol
    —— 4-Bromo-5-[(tert-butyl-dimethyl-silanyloxy)-(3,4-dimethoxy-2-methoxymethoxy-phenyl)-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole 197151-42-1 C27H37BrN2O5SSi
    4-Bromo-5-[(tert-butyl-dimethyl-silanyloxy)-(3,4-dimethoxy-2-methoxymethoxy-phenyl)-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole
    —— (E,E)-3-[5-(tert-butyldimethylsiloxy)pent-3-en-1-yl]-2-(6-{4-methoxy-2-[(phenylsulfanyl)methyl]pyridyn-3-yl}hex-3-en-1-yl)-4-methoxypyridine 211758-75-7 C36H50N2O3SSi
    (E,E)-3-[5-(tert-butyldimethylsiloxy)pent-3-en-1-yl]-2-(6-{4-methoxy-2-[(phenylsulfanyl)methyl]pyridyn-3-yl}hex-3-en-1-yl)-4-methoxypyridine
    —— 2-(4,5-Bis-hexadecylsulfanyl-[1,3]dithiol-2-ylidene)-4,6-dimethyl-[1,3]dithiolo[4,5-c]pyrrole-5-carboxylic acid tert-butyl ester 188014-45-1 C47H81NO2S6
    2-(4,5-Bis-hexadecylsulfanyl-[1,3]dithiol-2-ylidene)-4,6-dimethyl-[1,3]dithiolo[4,5-c]pyrrole-5-carboxylic acid tert-butyl ester
    —— [(4-(2-cyanoethyl)phenyl)thio]acetic acid 340131-08-0 C11H11NO2S
    [(4-(2-cyanoethyl)phenyl)thio]acetic acid
    —— ethyl [(4-(2-cyanoethyl)phenyl)thio]acetate 340131-06-8 C13H15NO2S
    ethyl [(4-(2-cyanoethyl)phenyl)thio]acetate
    —— (2R)-3-[2-(2,2-dimethoxyethyl)-1,3-dithian-2-yl]propane-1,2-diol 153607-82-0 C11H22O4S2
    (2R)-3-[2-(2,2-dimethoxyethyl)-1,3-dithian-2-yl]propane-1,2-diol
    —— 1,3-Dimethyl-5-[3-(2-methyl-benzyloxy)-prop-2-ynylsulfanyl]-1H-pyrimidine-2,4-dione 310405-11-9 C17H18N2O3S
    1,3-Dimethyl-5-[3-(2-methyl-benzyloxy)-prop-2-ynylsulfanyl]-1H-pyrimidine-2,4-dione
    —— 5-Ethyl-1-(2-methoxyethoxy)-6-methylsulfanylpyrimidine-2,4-dione 191472-49-8 C10H16N2O4S
    5-Ethyl-1-(2-methoxyethoxy)-6-methylsulfanylpyrimidine-2,4-dione
    —— 6-Methylsulfanyl-5-propan-2-yl-1-propoxypyrimidine-2,4-dione 191472-36-3 C11H18N2O3S
    6-Methylsulfanyl-5-propan-2-yl-1-propoxypyrimidine-2,4-dione
    —— tert-Butyl-dimethyl-(3,3,4,6,7-pentamethyl-2,3-dihydro-benzo[b]thiophen-5-yloxy)-silane 205182-92-9 C19H32OSSi
    tert-Butyl-dimethyl-(3,3,4,6,7-pentamethyl-2,3-dihydro-benzo[b]thiophen-5-yloxy)-silane
    —— 4-[2-(5-methyl-2-methylsulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)ethyl]isoxazole-3-carboxylic acid ethyl ester 190070-36-1 C14H17N3O4S
    4-[2-(5-methyl-2-methylsulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)ethyl]isoxazole-3-carboxylic acid ethyl ester
    —— [(3aR,4S,7aS)-1-[(E,2R)-5-tert-butylsulfonylpent-4-en-2-yl]-7a-methyl-3,3a,4,5,6,7-hexahydroinden-4-yl]oxy-triethylsilane 250384-97-5 C25H46O3SSi
    [(3aR,4S,7aS)-1-[(E,2R)-5-tert-butylsulfonylpent-4-en-2-yl]-7a-methyl-3,3a,4,5,6,7-hexahydroinden-4-yl]oxy-triethylsilane
    —— (2R,6S,7S,9R,14R,15R)-14-<(S)-(tert-Butyldimethylsilyloxy)phenylmethyl>-15-hydroxymethyl-2,9-bis(phenylthiomethyl)-1,8,13,16-tetraoxadispiro<5.0.5.4>hexadecane 244155-76-8 C40H54O6S2Si
    (2R,6S,7S,9R,14R,15R)-14-<(S)-(tert-Butyldimethylsilyloxy)phenylmethyl>-15-hydroxymethyl-2,9-bis(phenylthiomethyl)-1,8,13,16-tetraoxadispiro<5.0.5.4>hexadecane
    —— 2,2-bis(methylthio)-1-cyclobutanemethanol 294868-55-6 C7H14OS2
    2,2-bis(methylthio)-1-cyclobutanemethanol
    —— (2S,3S)-3-Hydroxy-2-phenylsulfanyl-butyric acid methyl ester 95190-82-2 C11H14O3S
    (2S,3S)-3-Hydroxy-2-phenylsulfanyl-butyric acid methyl ester
    —— 2-azido-1,3-benzodithiol-4-carboxyic acid methyl ester 311311-02-1 C9H7N3O2S2
    2-azido-1,3-benzodithiol-4-carboxyic acid methyl ester
    —— 4-Phenyl-6-phenylsulfanylmethyl-hept-6-en-2-one 172978-85-7 C20H22OS
    4-Phenyl-6-phenylsulfanylmethyl-hept-6-en-2-one
    —— 2-Methylsulfanyl-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-1-ylium 105580-78-7 C6H7S5
    2-Methylsulfanyl-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-1-ylium
    —— 4-Phenyl-6-phenylsulfanylmethyl-hept-6-en-2-ol 1027295-76-6 C20H24OS
    4-Phenyl-6-phenylsulfanylmethyl-hept-6-en-2-ol