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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,6-dibromo-4-(heptafluoro-n-propylthio)aniline 847622-69-9 C9H4Br2F7NS
    2,6-dibromo-4-(heptafluoro-n-propylthio)aniline
    —— (Z)-2-(4-bromobenzylidene)benzo[b]thiophen-3(2H)-one 101000-97-9 C15H9BrOS
    (Z)-2-(4-bromobenzylidene)benzo[b]thiophen-3(2H)-one
    —— 1-nitro-1-(phenylthio)-2-propanol 67808-90-6 C9H11NO3S
    1-nitro-1-(phenylthio)-2-propanol
    —— 2-[4-(dimethylamino)benzylidene]-1-benzothiophen-3(2H)-one 942434-36-8 C17H15NOS
    2-[4-(dimethylamino)benzylidene]-1-benzothiophen-3(2H)-one
    —— deuteriomethylsulfanyl-benzene 64732-79-2 C7H8S
    deuteriomethylsulfanyl-benzene
    —— (3S,4S)-4-tert-Butyl-3-phenylsulfanyl-oxetan-2-one 114059-26-6 C13H16O2S
    (3S,4S)-4-tert-Butyl-3-phenylsulfanyl-oxetan-2-one
    —— 2-furfurylidene-benzo[<i>b</i>]thiophen-3-one 3407-14-5 C13H8O2S
    2-furfurylidene-benzo[<i>b</i>]thiophen-3-one
    —— (2E)-2-(2-furylmethylene)-1'-benzothiophen-3(2H)-one 1006603-24-2 C13H8O2S
    (2E)-2-(2-furylmethylene)-1'-benzothiophen-3(2H)-one
    —— N-[2-(diethylamino)ethyl]-2-phenylsulfanylacetamide 35859-07-5 C14H22N2OS
    N-[2-(diethylamino)ethyl]-2-phenylsulfanylacetamide
    —— 1-(hydroxymethyl)-1-(phenylsulfenyl)cyclopentane 57557-47-8 C12H16OS
    1-(hydroxymethyl)-1-(phenylsulfenyl)cyclopentane
    —— (Phenylthio)acetic acid 2-(dimethylamino)-1-methylethyl ester 35859-03-1 C13H19NO2S
    (Phenylthio)acetic acid 2-(dimethylamino)-1-methylethyl ester
    —— 2-(Dimethylamino)ethyl 2-phenylsulfanylacetate 35859-01-9 C12H17NO2S
    2-(Dimethylamino)ethyl 2-phenylsulfanylacetate
    —— 2-(Diethylamino)ethyl 2-phenylsulfanylacetate 35859-02-0 C14H21NO2S
    2-(Diethylamino)ethyl 2-phenylsulfanylacetate
    —— 2-(2-Oxocyclohexyl)-2-phenylsulfanylacetic acid 344440-96-6 C14H16O3S
    2-(2-Oxocyclohexyl)-2-phenylsulfanylacetic acid
    —— (4R)-2,2-dimethyl-3-(2-phenylsulfanylacetyl)-1,3-oxazolidine-4-carbaldehyde 1025965-41-6 C14H17NO3S
    (4R)-2,2-dimethyl-3-(2-phenylsulfanylacetyl)-1,3-oxazolidine-4-carbaldehyde
    —— ethyl (S)-3-<(phenylthioacetyl)pyrrolidin-2-yl>propenoate 146405-66-5 C17H21NO3S
    ethyl (S)-3-<(phenylthioacetyl)pyrrolidin-2-yl>propenoate
    —— (2S)-1-(2-phenylsulfanylacetyl)pyrrolidine-2-carbaldehyde 122030-56-2 C13H15NO2S
    (2S)-1-(2-phenylsulfanylacetyl)pyrrolidine-2-carbaldehyde
    —— N-[2-(dimethylamino)ethyl]-2-phenylsulfanylacetamide 35859-06-4 C12H18N2OS
    N-[2-(dimethylamino)ethyl]-2-phenylsulfanylacetamide
    —— 2-furyl phenylthiomethyl ketone 122657-58-3 C12H10O2S
    2-furyl phenylthiomethyl ketone
    —— vinyl 2-(phenylthio)acetate 1173105-42-4 C10H10O2S
    vinyl 2-(phenylthio)acetate
    —— tert-butyl (6S,7R,7aS)-5,6,7,7a-tetrahydro-3,3-dimethyl-5-oxo-6-phenylthio-1H,3H-pyrrolo<1,2-c>oxazol-7-ylacetate 161644-50-4 C20H27NO4S
    tert-butyl (6S,7R,7aS)-5,6,7,7a-tetrahydro-3,3-dimethyl-5-oxo-6-phenylthio-1H,3H-pyrrolo<1,2-c>oxazol-7-ylacetate
    —— [(4R)-9-fluoro-1,1-dioxo-2-prop-2-enyl-3,4-dihydro-5,1lambda6,2-benzoxathiazepin-4-yl]methyl 2-phenylsulfanylacetate 1216844-77-7 C20H20FNO5S2
    [(4R)-9-fluoro-1,1-dioxo-2-prop-2-enyl-3,4-dihydro-5,1lambda6,2-benzoxathiazepin-4-yl]methyl 2-phenylsulfanylacetate
    —— 2,3-Dihydroxypropyl (phenylthio)acetate 168258-00-2 C11H14O4S
    2,3-Dihydroxypropyl (phenylthio)acetate
    —— tert-butyl-2-chloro-2-(phenylthio)acetate 135996-01-9 C12H15ClO2S
    tert-butyl-2-chloro-2-(phenylthio)acetate
    —— α-<4-Brom-phenylmercapto>-phenyl-essigsaeure 93533-99-4 C14H11BrO2S
    α-<4-Brom-phenylmercapto>-phenyl-essigsaeure
    —— 3-dodec-11-enyl-(5S)-methyl-3-phenylsulfanyl-dihydrofuran-2-one 943024-25-7 C23H34O2S
    3-dodec-11-enyl-(5S)-methyl-3-phenylsulfanyl-dihydrofuran-2-one
    —— (E)-1-methoxy-2-methyl-3-phenylthio-1-propene 119046-73-0 C11H14OS
    (E)-1-methoxy-2-methyl-3-phenylthio-1-propene
    —— Methyl 4-<(phenylthio)acetoxy>but-2(E)-enoate 168258-01-3 C13H14O4S
    Methyl 4-<(phenylthio)acetoxy>but-2(E)-enoate
    —— Ethyl (4R)-2-methyl-4-(phenylthioacetoxy)hept-2(E)-enoate 162264-77-9 C18H24O4S
    Ethyl (4R)-2-methyl-4-(phenylthioacetoxy)hept-2(E)-enoate
    —— 1-[(4R,5R)-4-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2,5-trimethyl-1,3-oxazolidin-3-yl]-2-phenylsulfanylethanone 1027202-80-7 C21H35NO3SSi
    1-[(4R,5R)-4-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2,5-trimethyl-1,3-oxazolidin-3-yl]-2-phenylsulfanylethanone
    —— 9-(phenylthio)-7-oxaspiro<5.4>decan-8-one 53138-49-1 C15H18O2S
    9-(phenylthio)-7-oxaspiro<5.4>decan-8-one
    —— 2-bromo-2-(4-bromophenylthio)acetic acid 90111-06-1 C8H6Br2O2S
    2-bromo-2-(4-bromophenylthio)acetic acid
    —— (4S)-4-hydroxy-2-phenylsulfanylpentanoic acid 288585-37-5 C11H14O3S
    (4S)-4-hydroxy-2-phenylsulfanylpentanoic acid
    —— 2-Oxoethyl 2-phenylsulfanylacetate 1027974-76-0 C10H10O3S
    2-Oxoethyl 2-phenylsulfanylacetate
    —— (2R,3R,4S)-[5-oxo-4-(phenylthio)-2-propyl-tetrahydrofuran-3-yl]acetic acid 750544-42-4 C15H18O4S
    (2R,3R,4S)-[5-oxo-4-(phenylthio)-2-propyl-tetrahydrofuran-3-yl]acetic acid
    —— N-methyl-2,2-bis(phenylsulfanyl)-N-<1-(3-pyridyl)vinyl>acetamide 142609-31-2 C22H20N2OS2
    N-methyl-2,2-bis(phenylsulfanyl)-N-<1-(3-pyridyl)vinyl>acetamide
    —— (3S,4R,5R)-4-(2-hydroxyethyl)-3-phenylthio-5-propyldihydrofuran-2(3H)-one 817616-81-2 C15H20O3S
    (3S,4R,5R)-4-(2-hydroxyethyl)-3-phenylthio-5-propyldihydrofuran-2(3H)-one
    —— (1R)-1-<1(S)-1,2-Dihydroxyethyl>butyl (phenylthio)acetate 134829-38-2 C14H20O4S
    (1R)-1-<1(S)-1,2-Dihydroxyethyl>butyl (phenylthio)acetate
    —— (1R,5S,7aR)-7a-methyl-2,3,5,6,7,7a-hexahydrospiro[indene-1,2'-oxiran]-5-yl 2-(phenylthio)acetate 1315116-70-1 C19H22O3S
    (1R,5S,7aR)-7a-methyl-2,3,5,6,7,7a-hexahydrospiro[indene-1,2'-oxiran]-5-yl 2-(phenylthio)acetate
    —— Methyl (4R)-4-<(phenylthio)acetoxy>hept-2(E)-enoate 134829-39-3 C16H20O4S
    Methyl (4R)-4-<(phenylthio)acetoxy>hept-2(E)-enoate
    —— S-{2-[bis(3',5'-dimethylpyrazol-1'-yl)methyl]phenyl}-N,N-dimethylthiocarbamate 1025810-05-2 C20H25N5OS
    S-{2-[bis(3',5'-dimethylpyrazol-1'-yl)methyl]phenyl}-N,N-dimethylthiocarbamate
    —— trifluoromethyl(chlorodifluoromethyl)trisulfane 959041-26-0 C2ClF5S3
    trifluoromethyl(chlorodifluoromethyl)trisulfane
    —— 3-(2-But-3-enyl-1,3-dithiolan-2-yl)-4,6-dihydrothieno[3,4-c]furan 5,5-dioxide 154343-76-7 C13H16O3S3
    3-(2-But-3-enyl-1,3-dithiolan-2-yl)-4,6-dihydrothieno[3,4-c]furan 5,5-dioxide
    —— sulfonyl-bis-acetaldehyde 7383-58-6 C4H6O4S
    sulfonyl-bis-acetaldehyde
    —— 4-(p-bromophenylthio)-3-hydroxythiolane 1,1-dioxide 899434-63-0 C10H11BrO3S2
    4-(p-bromophenylthio)-3-hydroxythiolane 1,1-dioxide
    —— propylsulfanyl-methanol 62839-42-3 C4H10OS
    propylsulfanyl-methanol
    —— 3-{[(5-chloro-thiophen-3-yl)methyl]thio}-6-cyclopentyl-1,2,4-triazin-5(2H)-one 824983-30-4 C13H14ClN3OS2
    3-{[(5-chloro-thiophen-3-yl)methyl]thio}-6-cyclopentyl-1,2,4-triazin-5(2H)-one
    —— (1,1-dioxo-2,3,6,7-tetrahydrothiepin-4-yl)methanol 1393559-72-2 C7H12O3S
    (1,1-dioxo-2,3,6,7-tetrahydrothiepin-4-yl)methanol
    —— (1R)-1-phenyl-N-(2-phenylsulfanylethyl)ethanamine 350678-27-2 C16H19NS
    (1R)-1-phenyl-N-(2-phenylsulfanylethyl)ethanamine
    —— 6-(4-chlorophenyl)-5-methyl-3-methylthio-1,2,4-triazine 87123-71-5 C11H10ClN3S
    6-(4-chlorophenyl)-5-methyl-3-methylthio-1,2,4-triazine