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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2-Methylsulfanyl-pyrimidin-4-ylsulfanyl)-acetic acid hydrazide 64679-83-0 C7H10N4OS2
    (2-Methylsulfanyl-pyrimidin-4-ylsulfanyl)-acetic acid hydrazide
    —— 1,3,4,5,6-pentamethyl-2-(methylthio)-pyridinium iodide 81045-24-1 C11H18NS*I
    1,3,4,5,6-pentamethyl-2-(methylthio)-pyridinium iodide
    —— 2,6-Bis-benzo[1,3]dithiol-2-ylidene-4,8-bis-(3,5-di-tert-butyl-benzyloxy)-benzo[1,2-d;4,5-d']bis[1,3]dithiole 112549-49-2 C52H54O2S8
    2,6-Bis-benzo[1,3]dithiol-2-ylidene-4,8-bis-(3,5-di-tert-butyl-benzyloxy)-benzo[1,2-d;4,5-d']bis[1,3]dithiole
    —— 1-[4,5-Dihydro-1-methyl-8-propylsulfanyl-1H-thieno[3,4-g]indazol-6-yl]-1-ethanone 364762-09-4 C15H18N2OS2
    1-[4,5-Dihydro-1-methyl-8-propylsulfanyl-1H-thieno[3,4-g]indazol-6-yl]-1-ethanone
    —— phenyl 2-methyl-N-(2-methylphenyl)-3-phenoxy-2-propenimidothioate 1158861-58-5 C23H21NOS
    phenyl 2-methyl-N-(2-methylphenyl)-3-phenoxy-2-propenimidothioate
    —— 4-(dimethyl(phenyl)silanyl)-3-[3-(2-methyl-[1,3]dithian-2-yl)-propylidene]-dihydro-furan-2-one 1256752-79-0 C20H28O2S2Si
    4-(dimethyl(phenyl)silanyl)-3-[3-(2-methyl-[1,3]dithian-2-yl)-propylidene]-dihydro-furan-2-one
    —— (3S,4S)-3,4-dihydroxy-threitolcyclopentanonedimethyldithioketal-S-oxide 172588-67-9 C7H14O3S2
    (3S,4S)-3,4-dihydroxy-threitolcyclopentanonedimethyldithioketal-S-oxide
    —— 200728-23-0 C21H24Br2O3S12
    —— 1,1,1,2,2-pentafluoro-5-[(3-iodopropyl)sulphanyl]pentane 199730-81-9 C8H12F5IS
    1,1,1,2,2-pentafluoro-5-[(3-iodopropyl)sulphanyl]pentane
    —— 4-Dimethylamino-4'-isothiocyanatodiphenylsulfid 19822-36-7 C15H14N2S2
    4-Dimethylamino-4'-isothiocyanatodiphenylsulfid
    —— [1-(4-Benzylsulfanyl-6-imino-1-p-tolyl-1,6-dihydro-pyrimidin-5-yl)-meth-(E)-ylidene]-p-tolyl-amine 98381-53-4 C26H24N4S
    [1-(4-Benzylsulfanyl-6-imino-1-p-tolyl-1,6-dihydro-pyrimidin-5-yl)-meth-(E)-ylidene]-p-tolyl-amine
    —— 3-(6-amino-8-((6-iodobenzo[d][1,3]dioxol-5-yl)thio)-9H-purin-9-yl)-N-(tert-butyl)propane-1-sulfonamide 1402546-41-1 C19H23IN6O4S2
    3-(6-amino-8-((6-iodobenzo[d][1,3]dioxol-5-yl)thio)-9H-purin-9-yl)-N-(tert-butyl)propane-1-sulfonamide
    —— Digermane, 1,1,2,2-tetraethyl-1,2-bis(methylthio)- 91123-32-9 C10H26Ge2S2
    Digermane, 1,1,2,2-tetraethyl-1,2-bis(methylthio)-
    —— trifluoromethyl(pentafluoroethyl)tetrasulfane 64997-73-5 C3F8S4
    trifluoromethyl(pentafluoroethyl)tetrasulfane
    —— m-fluorophenyl perfluoroisopropyl sulfide 75220-58-5 C9H4F8S
    m-fluorophenyl perfluoroisopropyl sulfide
    —— 3-hydroxy-2,4-dimethyl-2-phenylsulfanylpentanenitrile 343955-88-4 C13H17NOS
    3-hydroxy-2,4-dimethyl-2-phenylsulfanylpentanenitrile
    —— cycloheptyl-N-[(2S)-1-[5-(1-dimethylaminocarbonyl-1-methylethylthio)-1,3,4-oxadiazol-2-yl]-4-methyl-1-oxo-2-pentyl]carboxamide 477345-94-1 C22H36N4O4S
    cycloheptyl-N-[(2S)-1-[5-(1-dimethylaminocarbonyl-1-methylethylthio)-1,3,4-oxadiazol-2-yl]-4-methyl-1-oxo-2-pentyl]carboxamide
    —— 3-[4-(4-Chloro-2-nitro-phenylsulfanyl)-phenyl]-2-quinolin-4-yl-thiazolidin-4-one 131716-79-5 C24H16ClN3O3S2
    3-[4-(4-Chloro-2-nitro-phenylsulfanyl)-phenyl]-2-quinolin-4-yl-thiazolidin-4-one
    —— 1-[3-Bromo-6-(2-chloro-4-fluoro-phenylsulfanyl)-pyridin-2-ylmethyl]-3-(2,6-dichloro-phenyl)-1-(4-methoxy-benzyl)-urea 643762-64-5 C27H20BrCl3FN3O2S
    1-[3-Bromo-6-(2-chloro-4-fluoro-phenylsulfanyl)-pyridin-2-ylmethyl]-3-(2,6-dichloro-phenyl)-1-(4-methoxy-benzyl)-urea
    —— 853938-55-3 C31H33N5O5S2
    —— 1361045-53-5 C20H23F2N3OS
    —— 2-Amino-6-[[2-(4-fluoroanilino)-1,3-thiazol-4-yl]methylsulfanyl]-4-(oxan-3-yl)pyridine-3,5-dicarbonitrile 1030622-82-2 C22H19FN6OS2
    2-Amino-6-[[2-(4-fluoroanilino)-1,3-thiazol-4-yl]methylsulfanyl]-4-(oxan-3-yl)pyridine-3,5-dicarbonitrile
    —— 2-(diethylamino)-1, 1-difluoro-2-oxoethanesulfonylfluoride 648-75-9 C6H10F3NO3S
    2-(diethylamino)-1, 1-difluoro-2-oxoethanesulfonylfluoride
    —— 2-bromophenyl cyclopentyl sulfide 1616956-07-0 C11H13BrS
    2-bromophenyl cyclopentyl sulfide
    —— 2-octyl thiocyanate 10435-90-2 C9H17NS
    2-octyl thiocyanate
    —— 5-chloro-4-(3,4-dichlorophenylthio)-2-fluoro-N-(methylsulfonyl)benzamide 1354960-55-6 C14H9Cl3FNO3S2
    5-chloro-4-(3,4-dichlorophenylthio)-2-fluoro-N-(methylsulfonyl)benzamide
    —— 1,1,1,2,3,3-hexafluoro-3-[(1,1,2,3,3,3-hexafluoro-2-fluorosulfonylpropoxy)methoxy]propane-2-sulfonyl fluoride 130518-91-1 C7H2F14O6S2
    1,1,1,2,3,3-hexafluoro-3-[(1,1,2,3,3,3-hexafluoro-2-fluorosulfonylpropoxy)methoxy]propane-2-sulfonyl fluoride
    —— N,N-Diaethyl-thiocarbaminsaeure-<pentachlor-thiophenylester> 91092-74-9 C11H10Cl5NS2
    N,N-Diaethyl-thiocarbaminsaeure-<pentachlor-thiophenylester>
    —— ethyl 2-[2-(2,4-difluorophenylamino)-6-ethylthio-5-fluoronicotinoyl]acetate 105152-51-0 C18H17F3N2O3S
    ethyl 2-[2-(2,4-difluorophenylamino)-6-ethylthio-5-fluoronicotinoyl]acetate
    —— 1-phenylthiovinyl ethyl sulfone 99485-28-6 C10H12O2S2
    1-phenylthiovinyl ethyl sulfone
    —— 9,9-dichloro-5-phenylthio-1-azabicyclo<3.3.1>nonane 115909-40-5 C14H17Cl2NS
    9,9-dichloro-5-phenylthio-1-azabicyclo<3.3.1>nonane
    —— N-benzyl-2-methyl-3-(phenylthio)propionamide 138428-89-4 C17H19NOS
    N-benzyl-2-methyl-3-(phenylthio)propionamide
    —— trans-2-Chlor-1-cycloheptyl-phenylsulfid 64741-06-6 C13H17ClS
    trans-2-Chlor-1-cycloheptyl-phenylsulfid
    —— [2-(4-Chloro-phenylsulfanyl)-ethyl]-cyclohexyl-amine; hydrochloride 115346-92-4 C14H20ClNS*ClH
    [2-(4-Chloro-phenylsulfanyl)-ethyl]-cyclohexyl-amine; hydrochloride
    —— 1-Methylsulphonyl-2-<2-(methylthio)ethylsulfonyl>ethane 146035-04-3 C6H14O4S3
    1-Methylsulphonyl-2-<2-(methylthio)ethylsulfonyl>ethane
    —— 3<i>H</i>,3'<i>H</i>-6,6'-sulfanediyl-bis-benzothiazole-2-thione 63063-65-0 C14H8N2S5
    3<i>H</i>,3'<i>H</i>-6,6'-sulfanediyl-bis-benzothiazole-2-thione
    —— 4,5-dichloro-2-(4-chlorophenylthio)benzoic acid 5101-67-7 C13H7Cl3O2S
    4,5-dichloro-2-(4-chlorophenylthio)benzoic acid
    —— 2-t-Butylthio-4-ethylpyridin 31579-73-4 C11H17NS
    2-t-Butylthio-4-ethylpyridin
    —— (2-ethylmercapto-thiazol-5-yl)-(4-dimethylamino-benzyliden)-amine 100720-66-9 C14H17N3S2
    (2-ethylmercapto-thiazol-5-yl)-(4-dimethylamino-benzyliden)-amine
    —— 1,3-Dithiolan-2,2-dithiopropansaeure-diethylester 69881-70-5 C13H22O4S2
    1,3-Dithiolan-2,2-dithiopropansaeure-diethylester
    —— 67120-71-2 C15H20S2
    —— 4-Ethoxy-2-methylsulfanyl-3-phenyl-thiophene 72946-78-2 C13H14OS2
    4-Ethoxy-2-methylsulfanyl-3-phenyl-thiophene
    —— 1,3-bis-(2,2-dimethoxy-ethylsulfanyl)-benzene 855242-32-9 C14H22O4S2
    1,3-bis-(2,2-dimethoxy-ethylsulfanyl)-benzene
    —— 4-(5-methyl-furan-2-ylsulfanyl)-butyric acid ethyl ester 62880-36-8 C11H16O3S
    4-(5-methyl-furan-2-ylsulfanyl)-butyric acid ethyl ester
    —— 4-chloro-N-diazo-1,1,2,2,3,3,4,4-octafluorobutane-1-sulfonamide 1314878-65-3 C4ClF8N3O2S
    4-chloro-N-diazo-1,1,2,2,3,3,4,4-octafluorobutane-1-sulfonamide
    —— 1-Phenylthio-cyclopentadien 82146-68-7 C11H10S
    1-Phenylthio-cyclopentadien
    —— 2,2'-((thiobis(4,1-phenylene))bis(ethan-1-yl-1-ylidene))bis(hydrazine-1-carboxamide) 745076-14-6 C18H20N6O2S
    2,2'-((thiobis(4,1-phenylene))bis(ethan-1-yl-1-ylidene))bis(hydrazine-1-carboxamide)
    —— bis-(5-methylsulfanyl-[1,3,4]thiadiazol-3-yl)-methane 859460-77-8 C7H12N4S4
    bis-(5-methylsulfanyl-[1,3,4]thiadiazol-3-yl)-methane
    —— (2-ethylmercapto-thiazol-5-yl)-benzyliden-amine 100517-57-5 C12H12N2S2
    (2-ethylmercapto-thiazol-5-yl)-benzyliden-amine
    —— (RS,2R)-2-tert-butylsulfinyl-3-methyl-1-butanol 300593-30-0 C9H20O2S
    (RS,2R)-2-tert-butylsulfinyl-3-methyl-1-butanol