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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,2-dimethyl-6-[2-(5-methyl-5-methylcarbamoyl-hexyl)-[1,3]dithian-2-yl]-hexanoic acid methylamide 413628-25-8 C22H42N2O2S2
    2,2-dimethyl-6-[2-(5-methyl-5-methylcarbamoyl-hexyl)-[1,3]dithian-2-yl]-hexanoic acid methylamide
    —— 3-methylthiopropanal 54261-38-0 C4H8S
    3-methylthiopropanal
    —— ((E)-2-Nitro-propenylsulfanyl)-benzene 101933-31-7 C9H9NO2S
    ((E)-2-Nitro-propenylsulfanyl)-benzene
    —— 4-bromo-2,6-dimethylthioanisole 648906-19-8 C9H11BrS
    4-bromo-2,6-dimethylthioanisole
    —— 1-phenylsulfanyl-decan-4-one 62358-94-5 C16H24OS
    1-phenylsulfanyl-decan-4-one
    —— 2-((1H-tetrazol-5-yl)thio)acetamide 1619908-33-6 C3H5N5OS
    2-((1H-tetrazol-5-yl)thio)acetamide
    —— (2S,4R)-4,5-bis[[tert-butyl(diphenyl)silyl]oxy]-1-[2-[(2S)-2-methoxypent-4-enyl]-1,3-dithian-2-yl]pentan-2-ol 204448-39-5 C47H64O4S2Si2
    (2S,4R)-4,5-bis[[tert-butyl(diphenyl)silyl]oxy]-1-[2-[(2S)-2-methoxypent-4-enyl]-1,3-dithian-2-yl]pentan-2-ol
    —— 4-Benzo[1,3]dioxol-5-ylmethyl-2-bromo-1-methyl-5-phenylsulfanyl-1H-imidazole 181880-03-5 C18H15BrN2O2S
    4-Benzo[1,3]dioxol-5-ylmethyl-2-bromo-1-methyl-5-phenylsulfanyl-1H-imidazole
    —— 5-chloro-2-phenylsulfanyl-[3]pyridylamine 99852-32-1 C11H9ClN2S
    5-chloro-2-phenylsulfanyl-[3]pyridylamine
    —— 1-(tert-Butyldimethylsiloxy)-1-(phenylthio)ethene 136629-03-3 C14H22OSSi
    1-(tert-Butyldimethylsiloxy)-1-(phenylthio)ethene
    —— (2R,4S,5R)-4-[(Z)-3-[(2R)-3,3-bis(ethylsulfanyl)oxan-2-yl]prop-2-enyl]-2-phenyl-1,3-dioxan-5-ol 193970-59-1 C22H32O4S2
    (2R,4S,5R)-4-[(Z)-3-[(2R)-3,3-bis(ethylsulfanyl)oxan-2-yl]prop-2-enyl]-2-phenyl-1,3-dioxan-5-ol
    —— {5-[(3,4-Dimethoxy-2-methoxymethoxy-phenyl)-methoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazol-4-yl}-(4-methoxy-phenyl)-methanol 197151-44-3 C30H34N2O7S
    {5-[(3,4-Dimethoxy-2-methoxymethoxy-phenyl)-methoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazol-4-yl}-(4-methoxy-phenyl)-methanol
    —— S-Methylsulfenyl O-Ethyl Thiocarbonate 64231-91-0 C4H8O2S2
    S-Methylsulfenyl O-Ethyl Thiocarbonate
    —— N-cyano-N'-methyl-N'-trimethylsilylmethyl-S-methylisothiourea 137777-76-5 C8H17N3SSi
    N-cyano-N'-methyl-N'-trimethylsilylmethyl-S-methylisothiourea
    —— S-(2-Amino-3,4-dicarbamoylpyrrol-2-yl)thioessigsaeureethylester 120168-29-8 C10H14N4O4S
    S-(2-Amino-3,4-dicarbamoylpyrrol-2-yl)thioessigsaeureethylester
    —— (1S,4S,8R)-8-[(1R)-1-(phenylthiomethyl)-2-methylpropyl]-1-methylbicyclo[2.2.2]oct-5-en-2-one 583865-98-9 C20H26OS
    (1S,4S,8R)-8-[(1R)-1-(phenylthiomethyl)-2-methylpropyl]-1-methylbicyclo[2.2.2]oct-5-en-2-one
    —— 2-(Phenylsulfanyl)cyclobutane-1-carboxylic acid 88112-37-2 C11H12O2S
    2-(Phenylsulfanyl)cyclobutane-1-carboxylic acid
    —— 4-[3-(tert-butyldimethylsiloxy)-4-methoxybenzyl]-5-(4-methoxybenzyl)-1-methyl-2-phenylsulfanyl-1H-imidazole 443095-84-9 C32H40N2O3SSi
    4-[3-(tert-butyldimethylsiloxy)-4-methoxybenzyl]-5-(4-methoxybenzyl)-1-methyl-2-phenylsulfanyl-1H-imidazole
    —— 2,2'-bis[(S)-4-isopropyloxazolin-2-yl]diphenylsulfide 464181-03-1 C24H28N2O2S
    2,2'-bis[(S)-4-isopropyloxazolin-2-yl]diphenylsulfide
    —— 2-(S)-mercaptopropanol 16495-24-2 C3H8OS
    2-(S)-mercaptopropanol
    —— 5-tert-butyl-2,3-dihydrobenzo[b]thiophene-2,3-dione 1284213-64-4 C12H12O2S
    5-tert-butyl-2,3-dihydrobenzo[b]thiophene-2,3-dione
    —— 3-ethyl-2-(phenylthio)-1,3-butadiene 144453-29-2 C12H14S
    3-ethyl-2-(phenylthio)-1,3-butadiene
    —— N-(2-(methylsulfanyl)-5,6-dihydro-4H-furo[2,3-b]pyridine)but-3-enamide 325737-00-6 C12H15NO2S
    N-(2-(methylsulfanyl)-5,6-dihydro-4H-furo[2,3-b]pyridine)but-3-enamide
    —— N-[(2S)-1-hydroxy-3-methylbutan-2-yl]ethanethioamide 1084771-95-8 C7H15NOS
    N-[(2S)-1-hydroxy-3-methylbutan-2-yl]ethanethioamide
    —— ethanethioic acid S-(methoxymethyl) ester 38634-58-1 C4H8O2S
    ethanethioic acid S-(methoxymethyl) ester
    —— 3-chloro-1,1-bis-ethanesulfonyl-propane 500779-49-7 C7H15ClO4S2
    3-chloro-1,1-bis-ethanesulfonyl-propane
    —— bis-(pentane-1-sulfonyl)-methane 18068-31-0 C11H24O4S2
    bis-(pentane-1-sulfonyl)-methane
    —— 3-((4R,5R)-2,2-Dimethyl-5-phenylsulfanyl-[1,3]dioxolan-4-yl)-propan-1-ol 864948-21-0 C14H20O3S
    3-((4R,5R)-2,2-Dimethyl-5-phenylsulfanyl-[1,3]dioxolan-4-yl)-propan-1-ol
    —— (S)-3-[4-(3-hydroxy-butylsulfanyl)-2-methyl-phenyl]-propionic acid methyl ester 847346-76-3 C15H22O3S
    (S)-3-[4-(3-hydroxy-butylsulfanyl)-2-methyl-phenyl]-propionic acid methyl ester
    —— (E)-methyl hex-1-enyl sulfoxide 71559-68-7 C7H14OS
    (E)-methyl hex-1-enyl sulfoxide
    —— 3-((p-chlorophenyl)thio)cyclohexanone 64924-10-3 C12H13ClOS
    3-((p-chlorophenyl)thio)cyclohexanone
    —— 1-(tetrahydropyran-2-yl)-3-ethyl-5-methylthiopyrazolo<3,4-e><1,3>oxazin-7-one 116992-68-8 C13H17N3O3S
    1-(tetrahydropyran-2-yl)-3-ethyl-5-methylthiopyrazolo<3,4-e><1,3>oxazin-7-one
    —— 2,3-Dihydrobenzothiophene-3-carboxylic acid 19156-56-0 C9H8O2S
    2,3-Dihydrobenzothiophene-3-carboxylic acid
    —— 3-ethyl-1,1,1-tris(methylthio)heptane 480425-00-1 C12H26S3
    3-ethyl-1,1,1-tris(methylthio)heptane
    —— 2-bromo-1,1-difluoro-4,8-dimethyl-1-methylthiononane 480425-08-9 C12H23BrF2S
    2-bromo-1,1-difluoro-4,8-dimethyl-1-methylthiononane
    —— 5,10-Dithia-1,8-diazatricyclo[7.3.0.03,7]dodeca-3,6,8-trien-2-one 120079-27-8 C8H6N2OS2
    5,10-Dithia-1,8-diazatricyclo[7.3.0.03,7]dodeca-3,6,8-trien-2-one
    —— 8-chloro-2,3-dihydro-5H-thiazolo<3,2-a>thieno<3,4-d>pyrimidin-5-one 126636-81-5 C8H5ClN2OS2
    8-chloro-2,3-dihydro-5H-thiazolo<3,2-a>thieno<3,4-d>pyrimidin-5-one
    —— Gwxjcyvgwmmndx-uhfffaoysa- 120079-34-7 C9H8N2OS2
    Gwxjcyvgwmmndx-uhfffaoysa-
    —— 3,4,7,8-Tetrakis(trifluormethyl)-1,2,5,6-tetrathiocin 651-38-7 C8F12S4
    3,4,7,8-Tetrakis(trifluormethyl)-1,2,5,6-tetrathiocin
    —— N-(6-(2-(2-methylphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-54-0 C20H16N4OS2
    N-(6-(2-(2-methylphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(phenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-35-7 C19H14N4OS2
    N-(6-(2-(phenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(3-methoxyphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-61-9 C20H16N4O2S2
    N-(6-(2-(3-methoxyphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(3-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112980-30-9 C19H13FN4OS2
    N-(6-(2-(3-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(4-methylphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-56-2 C20H16N4OS2
    N-(6-(2-(4-methylphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(4-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-43-7 C19H13FN4OS2
    N-(6-(2-(4-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(2-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-37-9 C19H13FN4OS2
    N-(6-(2-(2-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— 3-ethyl-1-propyl-1<i>H</i>,8<i>H</i>-pyrimido[5,4-<i>b</i>][1,4]thiazine-2,4,7-trione 3950-00-3 C11H15N3O3S
    3-ethyl-1-propyl-1<i>H</i>,8<i>H</i>-pyrimido[5,4-<i>b</i>][1,4]thiazine-2,4,7-trione
    —— n-butyl [(3-nitropyridin-2-yl)sulfanyl]acetate 1378234-14-0 C11H14N2O4S
    n-butyl [(3-nitropyridin-2-yl)sulfanyl]acetate
    —— 3-allylthiosulfanyl-6-homopiperidinylaminopyridazine 1221438-73-8 C13H20N4S
    3-allylthiosulfanyl-6-homopiperidinylaminopyridazine
    —— (6-amino-3-ethyl-2,4-dioxo-1-propyl-1,2,3,4-tetrahydro-pyrimidin-5-ylsulfanyl)-acetic acid 91194-51-3 C11H17N3O4S
    (6-amino-3-ethyl-2,4-dioxo-1-propyl-1,2,3,4-tetrahydro-pyrimidin-5-ylsulfanyl)-acetic acid