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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5,7,19,21,33,35-hexaaza-13,27,41-tri-tert-butyl-6,20,34-tripropylsulfanyl-2,10,16,24,30,38-hexahomo-3,9,17,23,31,37-hexathiacalix[6]arene 1401318-20-4 C57H72N6S9
    5,7,19,21,33,35-hexaaza-13,27,41-tri-tert-butyl-6,20,34-tripropylsulfanyl-2,10,16,24,30,38-hexahomo-3,9,17,23,31,37-hexathiacalix[6]arene
    —— (3R,4R,5R)-1-allyl-3,4-bis(tert-butyldimethylsilyloxy)-5-(difluoro(phenylthio)methyl)-5-hydroxypyrrolidin-2-one 1401240-37-6 C26H43F2NO4SSi2
    (3R,4R,5R)-1-allyl-3,4-bis(tert-butyldimethylsilyloxy)-5-(difluoro(phenylthio)methyl)-5-hydroxypyrrolidin-2-one
    —— 5,7,19,21,33,35-hexaaza-13,27,41-tri-tert-butyl-6,20,34-trimethylsulfanyl-2,10,16,24,30,38-hexahomo-3,9,17,23,31,37-hexathiacalix[6]arene 1401318-22-6 C51H60N6S9
    5,7,19,21,33,35-hexaaza-13,27,41-tri-tert-butyl-6,20,34-trimethylsulfanyl-2,10,16,24,30,38-hexahomo-3,9,17,23,31,37-hexathiacalix[6]arene
    —— (1R)-1-deuteriobut-3-ene-1-thiol 1404591-94-1 C4H8S
    (1R)-1-deuteriobut-3-ene-1-thiol
    —— 4-(2-Azidosulfonylethylamino)-4-oxobutanoic acid 1408310-94-0 C6H10N4O5S
    4-(2-Azidosulfonylethylamino)-4-oxobutanoic acid
    —— 2-[5-(2-Benzylsulfanyl-5-chlorothiophen-3-yl)-3-(4-fluorophenyl)-3,4-dihydropyrazol-2-yl]-4-(4-chlorophenyl)-1,3-thiazole 1416015-23-0 C29H20Cl2FN3S3
    2-[5-(2-Benzylsulfanyl-5-chlorothiophen-3-yl)-3-(4-fluorophenyl)-3,4-dihydropyrazol-2-yl]-4-(4-chlorophenyl)-1,3-thiazole
    —— tert-butyl (4R)-2,2-dimethyl-4-[(2-phenyl-1,3-dithian-2-yl)methyl]-1,3-oxazolidine-3-carboxylate 1434253-83-4 C21H31NO3S2
    tert-butyl (4R)-2,2-dimethyl-4-[(2-phenyl-1,3-dithian-2-yl)methyl]-1,3-oxazolidine-3-carboxylate
    —— tert-butyl (4R)-2,2-dimethyl-4-[(2-thiophen-2-yl-1,3-dithian-2-yl)methyl]-1,3-oxazolidine-3-carboxylate 1434253-90-3 C19H29NO3S3
    tert-butyl (4R)-2,2-dimethyl-4-[(2-thiophen-2-yl-1,3-dithian-2-yl)methyl]-1,3-oxazolidine-3-carboxylate
    —— 2-[5-(2-Benzylsulfanyl-5-chlorothiophen-3-yl)-3-(4-chlorophenyl)-3,4-dihydropyrazol-2-yl]-4-(4-chlorophenyl)-1,3-thiazole 1416015-20-7 C29H20Cl3N3S3
    2-[5-(2-Benzylsulfanyl-5-chlorothiophen-3-yl)-3-(4-chlorophenyl)-3,4-dihydropyrazol-2-yl]-4-(4-chlorophenyl)-1,3-thiazole
    —— 4-[5-(2-benzylsulfanyl-5-chlorothiophen-3-yl)-2-[4-(4-chlorophenyl)-1,3-thiazol-2-yl]-3,4-dihydropyrazol-3-yl]-N,N-dimethylaniline 1416015-26-3 C31H26Cl2N4S3
    4-[5-(2-benzylsulfanyl-5-chlorothiophen-3-yl)-2-[4-(4-chlorophenyl)-1,3-thiazol-2-yl]-3,4-dihydropyrazol-3-yl]-N,N-dimethylaniline
    —— 2-[2-[[3-[[2-[[Cyano-(5,6-dioxocyclohexa-1,3-dien-1-yl)methyl]amino]phenyl]sulfanylmethyl]-2,4,6-trimethylphenyl]methylsulfanyl]anilino]-2-(5,6-dioxocyclohexa-1,3-dien-1-yl)acetonitrile 1417893-25-4 C39H32N4O4S2
    2-[2-[[3-[[2-[[Cyano-(5,6-dioxocyclohexa-1,3-dien-1-yl)methyl]amino]phenyl]sulfanylmethyl]-2,4,6-trimethylphenyl]methylsulfanyl]anilino]-2-(5,6-dioxocyclohexa-1,3-dien-1-yl)acetonitrile
    —— 1,4,8-trithiaspiro[4.5]decane-6-carbaldehyde 1413945-56-8 C8H12OS3
    1,4,8-trithiaspiro[4.5]decane-6-carbaldehyde
    —— 4-(4-nitrophenyl)sulfanyl-N,3-diphenylisochromen-1-imine 1413416-87-1 C27H18N2O3S
    4-(4-nitrophenyl)sulfanyl-N,3-diphenylisochromen-1-imine
    —— methyl 1,4,8-trithiaspiro[4.5]decane-6-carboxylate 1413945-51-3 C9H14O2S3
    methyl 1,4,8-trithiaspiro[4.5]decane-6-carboxylate
    —— 1,4,8-trithiaspiro[4.5]decan-6-ylmethanol 1413945-53-5 C8H14OS3
    1,4,8-trithiaspiro[4.5]decan-6-ylmethanol
    —— 3-(Phenoxymethyl)-4-phenyl-5-phenylsulfanyl-1,2,4-triazole 1418012-76-6 C21H17N3OS
    3-(Phenoxymethyl)-4-phenyl-5-phenylsulfanyl-1,2,4-triazole
    —— 2-[4-[4-[[Amino-(hydroxyamino)methylidene]amino]phenyl]sulfanylphenyl]-1-hydroxyguanidine 1418793-62-0 C14H16N6O2S
    2-[4-[4-[[Amino-(hydroxyamino)methylidene]amino]phenyl]sulfanylphenyl]-1-hydroxyguanidine
    —— Dimethyl 2-[(4-fluorophenyl)sulfanyl-(2,3,6-trifluorophenyl)methyl]propanedioate 1420649-43-9 C18H14F4O4S
    Dimethyl 2-[(4-fluorophenyl)sulfanyl-(2,3,6-trifluorophenyl)methyl]propanedioate
    —— Dimethyl 2-[(3,4-difluorophenyl)sulfanyl-(2,3,6-trifluorophenyl)methyl]propanedioate 1420649-45-1 C18H13F5O4S
    Dimethyl 2-[(3,4-difluorophenyl)sulfanyl-(2,3,6-trifluorophenyl)methyl]propanedioate
    —— [2-[2-[(Dimethylamino)methyl]-4-iodophenyl]sulfanylphenyl]methanol 1419268-86-2 C16H18INOS
    [2-[2-[(Dimethylamino)methyl]-4-iodophenyl]sulfanylphenyl]methanol
    —— [2-[2-[(Dimethylamino)methyl]-4-tributylstannylphenyl]sulfanylphenyl]methanol 1419268-91-9 C28H45NOSSn
    [2-[2-[(Dimethylamino)methyl]-4-tributylstannylphenyl]sulfanylphenyl]methanol
    —— Dimethyl 2-[(4-bromophenyl)sulfanyl-(2,3,6-trifluorophenyl)methyl]propanedioate 1420649-41-7 C18H14BrF3O4S
    Dimethyl 2-[(4-bromophenyl)sulfanyl-(2,3,6-trifluorophenyl)methyl]propanedioate
    —— 7-[(2-Methoxyphenyl)methyl]-5-(2-methoxyphenyl)sulfanyl-4-methylpyrrolo[2,3-d]pyrimidin-2-amine 1424430-62-5 C22H22N4O2S
    7-[(2-Methoxyphenyl)methyl]-5-(2-methoxyphenyl)sulfanyl-4-methylpyrrolo[2,3-d]pyrimidin-2-amine
    —— 2-(5-ethylsulfanyl-1,3,4-oxadiazol-2-yl)-N-phenylaniline 1449224-26-3 C16H15N3OS
    2-(5-ethylsulfanyl-1,3,4-oxadiazol-2-yl)-N-phenylaniline
    —— 7-Benzyl-5-(4-chlorophenyl)sulfanyl-4-methylpyrrolo[2,3-d]pyrimidin-2-amine 1424430-61-4 C20H17ClN4S
    7-Benzyl-5-(4-chlorophenyl)sulfanyl-4-methylpyrrolo[2,3-d]pyrimidin-2-amine
    —— 7-Benzyl-5-(4-methoxyphenyl)sulfanyl-4-methylpyrrolo[2,3-d]pyrimidin-2-amine 1424430-60-3 C21H20N4OS
    7-Benzyl-5-(4-methoxyphenyl)sulfanyl-4-methylpyrrolo[2,3-d]pyrimidin-2-amine
    —— 7-[(4-Methoxyphenyl)methyl]-5-(2-methoxyphenyl)sulfanyl-4-methylpyrrolo[2,3-d]pyrimidin-2-amine 1424430-63-6 C22H22N4O2S
    7-[(4-Methoxyphenyl)methyl]-5-(2-methoxyphenyl)sulfanyl-4-methylpyrrolo[2,3-d]pyrimidin-2-amine
    —— 4-Methyl-7-[(3,4,5-trimethoxyphenyl)methyl]-5-(3,4,5-trimethoxyphenyl)sulfanylpyrrolo[2,3-d]pyrimidin-2-amine 1424430-65-8 C26H30N4O6S
    4-Methyl-7-[(3,4,5-trimethoxyphenyl)methyl]-5-(3,4,5-trimethoxyphenyl)sulfanylpyrrolo[2,3-d]pyrimidin-2-amine
    —— 7-Benzyl-4-methyl-5-phenylsulfanylpyrrolo[2,3-d]pyrimidin-2-amine 1424430-58-9 C20H18N4S
    7-Benzyl-4-methyl-5-phenylsulfanylpyrrolo[2,3-d]pyrimidin-2-amine
    —— 5-(2-Methoxyphenyl)sulfanyl-4-methyl-7-[(3,4,5-trimethoxyphenyl)methyl]pyrrolo[2,3-d]pyrimidin-2-amine 1424430-64-7 C24H26N4O4S
    5-(2-Methoxyphenyl)sulfanyl-4-methyl-7-[(3,4,5-trimethoxyphenyl)methyl]pyrrolo[2,3-d]pyrimidin-2-amine
    —— 7-Benzyl-5-(2-methoxyphenyl)sulfanyl-4-methylpyrrolo[2,3-d]pyrimidin-2-amine 1424430-59-0 C21H20N4OS
    7-Benzyl-5-(2-methoxyphenyl)sulfanyl-4-methylpyrrolo[2,3-d]pyrimidin-2-amine
    —— (3E,10E)-1-[2-[(E)-pent-3-enyl]-1,3-dithian-2-yl]dodeca-3,10-dien-1-ol 1419178-80-5 C21H36OS2
    (3E,10E)-1-[2-[(E)-pent-3-enyl]-1,3-dithian-2-yl]dodeca-3,10-dien-1-ol
    —— (1E)-1-diphenylphosphoryl-3-methyl-2-phenylsulfanylpenta-1,4-dien-3-ol 1417916-26-7 C24H23O2PS
    (1E)-1-diphenylphosphoryl-3-methyl-2-phenylsulfanylpenta-1,4-dien-3-ol
    —— [[(1E)-3-methylidene-2-phenylsulfanylpenta-1,4-dienyl]-phenylphosphoryl]benzene 1417916-22-3 C24H21OPS
    [[(1E)-3-methylidene-2-phenylsulfanylpenta-1,4-dienyl]-phenylphosphoryl]benzene
    —— 5-Ethenyl-5-methyl-2,2-diphenyl-4-phenylsulfanyloxaphosphol-2-ium;chloride 1417916-30-3 C24H22OPS*Cl
    5-Ethenyl-5-methyl-2,2-diphenyl-4-phenylsulfanyloxaphosphol-2-ium;chloride
    —— 1-Methyl-3-(3-methylbut-2-enyl)thiourea 1416430-53-9 C7H14N2S
    1-Methyl-3-(3-methylbut-2-enyl)thiourea
    —— 1-Tert-butyl-3-(3-methylbut-2-enyl)thiourea 1416430-54-0 C10H20N2S
    1-Tert-butyl-3-(3-methylbut-2-enyl)thiourea
    —— 1-(3-Methylbut-2-enyl)-3-prop-2-enylthiourea 1416430-55-1 C9H16N2S
    1-(3-Methylbut-2-enyl)-3-prop-2-enylthiourea
    —— 2-naphthalen-2-yl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1416576-54-9 C27H23NO3S
    2-naphthalen-2-yl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-(1-benzofuran-2-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1416576-59-4 C25H21NO4S
    2-(1-benzofuran-2-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-(1H-indol-2-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1416576-58-3 C25H22N2O3S
    2-(1H-indol-2-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-(1-benzothiophen-2-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1416576-60-7 C25H21NO3S2
    2-(1-benzothiophen-2-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-naphthalen-1-yl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1416576-51-6 C27H23NO3S
    2-naphthalen-1-yl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-cyclobutyl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1416576-63-0 C21H23NO3S
    2-cyclobutyl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 1-allyl-4-(phenylthio)-6-(E-1-propenyl)-1,2,5,6-tetrahydro-2-pyridinone 1415683-62-3 C17H19NOS
    1-allyl-4-(phenylthio)-6-(E-1-propenyl)-1,2,5,6-tetrahydro-2-pyridinone
    —— 2-cyclopentyl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1416576-65-2 C22H25NO3S
    2-cyclopentyl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-(1-benzothiophen-3-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1416576-61-8 C25H21NO3S2
    2-(1-benzothiophen-3-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-cyclohexyl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1416576-67-4 C23H27NO3S
    2-cyclohexyl-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 2-(1H-pyrazol-4-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole 1416576-20-9 C20H19N3O3S
    2-(1H-pyrazol-4-yl)-3-(3,4,5-trimethoxyphenyl)sulfanyl-1H-indole
    —— 1-Bromo-4-[1-(4-bromophenyl)sulfanyl-2,3,3,4,4,4-hexafluorobut-1-enyl]sulfanylbenzene 1416359-96-0 C16H8Br2F6S2
    1-Bromo-4-[1-(4-bromophenyl)sulfanyl-2,3,3,4,4,4-hexafluorobut-1-enyl]sulfanylbenzene