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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— benzene;(3,5-dimethylphenyl)-[2-[2-(3,5-dimethylphenyl)azanidylphenyl]sulfanylphenyl]azanide;ruthenium(2+) 472969-05-4 C34H32N2RuS
    benzene;(3,5-dimethylphenyl)-[2-[2-(3,5-dimethylphenyl)azanidylphenyl]sulfanylphenyl]azanide;ruthenium(2+)
    —— 2-Tert-butylsulfinyl-1-(1-methylcyclohexa-2,5-dien-1-yl)ethanone 676608-21-2 C13H20O2S
    2-Tert-butylsulfinyl-1-(1-methylcyclohexa-2,5-dien-1-yl)ethanone
    —— (2R,4R)-1-[2-[2-(4-hydroxyphenyl)ethyl]-1,3-dithian-2-yl]heptadecane-2,4-diol 1187560-44-6 C29H50O3S2
    (2R,4R)-1-[2-[2-(4-hydroxyphenyl)ethyl]-1,3-dithian-2-yl]heptadecane-2,4-diol
    —— 1-[3-((R)-4-Methyl-5-oxo-2,5-dihydro-furan-2-yl)-propyl]-5-phenylsulfanyl-pyrrolidin-2-one 794528-65-7 C18H21NO3S
    1-[3-((R)-4-Methyl-5-oxo-2,5-dihydro-furan-2-yl)-propyl]-5-phenylsulfanyl-pyrrolidin-2-one
    —— Phenol, 4-[(2-hydroxypropyl)thio]- 69274-28-8 C9H12O2S
    Phenol, 4-[(2-hydroxypropyl)thio]-
    —— 3-[4-(2-Dimethylaminomethyl-phenylsulfanyl)-3-nitro-phenyl]-propan-1-ol 627488-62-4 C18H22N2O3S
    3-[4-(2-Dimethylaminomethyl-phenylsulfanyl)-3-nitro-phenyl]-propan-1-ol
    —— 19,25,31,36-Tetratert-butyl-40,41-dihydroxy-3,15-dioxa-6,8,10,12-tetrathiaheptacyclo[15.15.7.123,27.134,38.02,29.07,11.016,21]hentetraconta-1,7(11),16,18,20,23(41),24,26,29,31,34,36,38(40)-tridecaene-9-thione 863915-93-9 C51H62O4S5
    19,25,31,36-Tetratert-butyl-40,41-dihydroxy-3,15-dioxa-6,8,10,12-tetrathiaheptacyclo[15.15.7.123,27.134,38.02,29.07,11.016,21]hentetraconta-1,7(11),16,18,20,23(41),24,26,29,31,34,36,38(40)-tridecaene-9-thione
    —— 6-(but-3-enyl)-4-(phenylthio)-1,2,5,6-tetrahydropyridin-2-one 597556-95-1 C15H17NOS
    6-(but-3-enyl)-4-(phenylthio)-1,2,5,6-tetrahydropyridin-2-one
    —— 1,4-Benzoxathiin, 2,3-dihydro-2-methyl-6-(phenylmethoxy)-, (2S)- 918137-22-1 C16H16O2S
    1,4-Benzoxathiin, 2,3-dihydro-2-methyl-6-(phenylmethoxy)-, (2S)-
    —— (R)-2,2,2-trifluoro-1-[(2-methnasulfanyl)phenyl]ethylamine hydrochloride 842169-98-6 C9H10F3NS*ClH
    (R)-2,2,2-trifluoro-1-[(2-methnasulfanyl)phenyl]ethylamine hydrochloride
    —— (I+/-R)-2-(Methylthio)-I+/--(trifluoromethyl)benzenemethanamine 843608-55-9 C9H10F3NS
    (I+/-R)-2-(Methylthio)-I+/--(trifluoromethyl)benzenemethanamine
    —— 2-Chloro-1,3,5-trimethyl-4-oct-1-ynylsulfanyl-benzene 648436-21-9 C17H23ClS
    2-Chloro-1,3,5-trimethyl-4-oct-1-ynylsulfanyl-benzene
    —— 1H-Imidazol-2-amine, 4,5-dihydro-N-[4-(2-naphthalenylthio)phenyl]- 827610-27-5 C19H17N3S
    1H-Imidazol-2-amine, 4,5-dihydro-N-[4-(2-naphthalenylthio)phenyl]-
    —— Benzenamine, 2,4-dichloro-N-[[2-(phenylthio)phenyl]methylene]- 646067-20-1 C19H13Cl2NS
    Benzenamine, 2,4-dichloro-N-[[2-(phenylthio)phenyl]methylene]-
    —— 2-Iodo-ethanethiol 62620-25-1 C2H5IS
    2-Iodo-ethanethiol
    —— 8-Bromo-9-methyl-6-phenylsulfanyl-9H-purine 736143-06-9 C12H9BrN4S
    8-Bromo-9-methyl-6-phenylsulfanyl-9H-purine
    —— (E)-3-[3-(3-Benzyloxymethyl-2-phenylsulfanyl-3H-imidazol-4-yl)-1H-indol-2-yl]-acrylic acid ethyl ester 391913-73-8 C30H27N3O3S
    (E)-3-[3-(3-Benzyloxymethyl-2-phenylsulfanyl-3H-imidazol-4-yl)-1H-indol-2-yl]-acrylic acid ethyl ester
    —— 1-L-3-O-(3-phenyl-3-phenylthiopropanoyl)-4-O-trimethylacetyl-1,2:5,6-di-O-isopropylidene-chiro-inositol 769931-76-2 C32H40O8S
    1-L-3-O-(3-phenyl-3-phenylthiopropanoyl)-4-O-trimethylacetyl-1,2:5,6-di-O-isopropylidene-chiro-inositol
    —— (S)-(+)-1-(p-tolylsulfanyl)-3,3-dimethyl-2-butanol 477761-28-7 C13H20OS
    (S)-(+)-1-(p-tolylsulfanyl)-3,3-dimethyl-2-butanol
    —— Guanidine, N-[4-[(4-chlorophenyl)thio]phenyl]-N'-ethyl- 677343-22-5 C15H16ClN3S
    Guanidine, N-[4-[(4-chlorophenyl)thio]phenyl]-N'-ethyl-
    —— 1H-Imidazole, 1-methyl-2-[(3,4,4-trifluoro-3-butenyl)thio]- 539850-80-1 C8H9F3N2S
    1H-Imidazole, 1-methyl-2-[(3,4,4-trifluoro-3-butenyl)thio]-
    —— (S)-4-[(R)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-(1-methylene-octadecyloxy)-methyl]-2,2-dimethyl-5-phenylsulfanyl-[1,3]dioxolane 356074-24-3 C36H60O5S
    (S)-4-[(R)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-(1-methylene-octadecyloxy)-methyl]-2,2-dimethyl-5-phenylsulfanyl-[1,3]dioxolane
    —— (6,7-dihydro-5-thia-8-aza-benzocyclohepten-9-yl)-hydrazine 23483-18-3 C9H11N3S
    (6,7-dihydro-5-thia-8-aza-benzocyclohepten-9-yl)-hydrazine
    —— Benzenecarboximidamide, 4-[(4-methoxyphenyl)thio]- 677343-15-6 C14H14N2OS
    Benzenecarboximidamide, 4-[(4-methoxyphenyl)thio]-
    —— Methylglyoxal-<bis-(1,3-propylen)-dithioacetal> 53178-56-6 C9H16S4
    Methylglyoxal-<bis-(1,3-propylen)-dithioacetal>
    —— dimethyl-[[(N-methyl-C-methylsulfanylcarbonimidoyl)amino]methylidene]azanium;iodide 283168-65-0 C6H13N3S*HI
    dimethyl-[[(N-methyl-C-methylsulfanylcarbonimidoyl)amino]methylidene]azanium;iodide
    —— 4-benzyl-3-(benzylthio)-5-thien-2-yl-4H-1,2,4-triazole 139614-68-9 C20H17N3S2
    4-benzyl-3-(benzylthio)-5-thien-2-yl-4H-1,2,4-triazole
    —— 3,4-Dibromo-2-phenylsulfanyl-furan 505048-35-1 C10H6Br2OS
    3,4-Dibromo-2-phenylsulfanyl-furan
    —— (9S)-9-(tert-butyldiphenylsilyloxy)-8-(2-hydroxyethyl)-7-hydroxymethyl-1,5-dithiaspiro[5.4]dec-7-ene 769168-64-1 C27H36O3S2Si
    (9S)-9-(tert-butyldiphenylsilyloxy)-8-(2-hydroxyethyl)-7-hydroxymethyl-1,5-dithiaspiro[5.4]dec-7-ene
    —— Benzoic acid, 4-[[4-[(4,5-dihydro-1H-imidazol-2-yl)amino]phenyl]thio]- 677343-51-0 C16H15N3O2S
    Benzoic acid, 4-[[4-[(4,5-dihydro-1H-imidazol-2-yl)amino]phenyl]thio]-
    —— (+)-(4R)-4-[(1R)-2-Hydroxy-1-vinylethyl]-2,2-propanedithiocyclopentan-1-one 319906-95-1 C12H18O2S2
    (+)-(4R)-4-[(1R)-2-Hydroxy-1-vinylethyl]-2,2-propanedithiocyclopentan-1-one
    —— N<sup>4</sup>-allyl-6-(benzylsulfanyl)-2,4-diaminopyrimidine 674310-79-3 C14H16N4S
    N<sup>4</sup>-allyl-6-(benzylsulfanyl)-2,4-diaminopyrimidine
    —— Guanidine, N-[[4-[(4-chlorophenyl)thio]phenyl]methyl]-N'-ethyl- 677343-07-6 C16H18ClN3S
    Guanidine, N-[[4-[(4-chlorophenyl)thio]phenyl]methyl]-N'-ethyl-
    —— Guanidine, N,N'-diethyl-N''-[4-[(4-methoxyphenyl)thio]phenyl]- 677343-06-5 C18H23N3OS
    Guanidine, N,N'-diethyl-N''-[4-[(4-methoxyphenyl)thio]phenyl]-
    —— tert-butyl-diphenyl-[(Z)-2-pyridin-2-ylsulfanyl-2-tri(propan-2-yl)silyloxyethenoxy]silane 1000004-71-6 C32H45NO2SSi2
    tert-butyl-diphenyl-[(Z)-2-pyridin-2-ylsulfanyl-2-tri(propan-2-yl)silyloxyethenoxy]silane
    —— (1'R,2R,3R,4S,5S)-4-azido-2-(1'-hydroxy-2',2'-bis-phenylsulfanyl-ethyl)-5-methoxy-5-methyl-tetrahydro-pyran-3-ol 864941-71-9 C21H25N3O4S2
    (1'R,2R,3R,4S,5S)-4-azido-2-(1'-hydroxy-2',2'-bis-phenylsulfanyl-ethyl)-5-methoxy-5-methyl-tetrahydro-pyran-3-ol
    —— 1H-Imidazole, 4,5-dihydro-2-[4-[(4-methoxyphenyl)thio]phenyl]- 677343-16-7 C16H16N2OS
    1H-Imidazole, 4,5-dihydro-2-[4-[(4-methoxyphenyl)thio]phenyl]-
    —— 5-(2-Fluoro-phenyl)-6-methyl-4-methylsulfanyl-2-oxo-2H-pyran-3-carbonitrile 864370-24-1 C14H10FNO2S
    5-(2-Fluoro-phenyl)-6-methyl-4-methylsulfanyl-2-oxo-2H-pyran-3-carbonitrile
    —— (1-Difluoromethylene-butylsulfanyl)-benzene 161144-43-0 C11H12F2S
    (1-Difluoromethylene-butylsulfanyl)-benzene
    —— 6-benzenesulfanyl-2-heptyl-3,4-dihydro-2H-pyran 553670-66-9 C18H26OS
    6-benzenesulfanyl-2-heptyl-3,4-dihydro-2H-pyran
    —— 1H-Imidazole, 4,5-dihydro-2-[[4-[(4-methoxyphenyl)thio]phenyl]methyl]- 677343-14-5 C17H18N2OS
    1H-Imidazole, 4,5-dihydro-2-[[4-[(4-methoxyphenyl)thio]phenyl]methyl]-
    —— 19,25,31,36-Tetratert-butyl-40,41-dihydroxy-3,15-dioxa-6,8,10,12-tetrathiaheptacyclo[15.15.7.123,27.134,38.02,29.07,11.016,21]hentetraconta-1,7(11),16,18,20,23(41),24,26,29,31,34,36,38(40)-tridecaen-9-one 197228-57-2 C51H62O5S4
    19,25,31,36-Tetratert-butyl-40,41-dihydroxy-3,15-dioxa-6,8,10,12-tetrathiaheptacyclo[15.15.7.123,27.134,38.02,29.07,11.016,21]hentetraconta-1,7(11),16,18,20,23(41),24,26,29,31,34,36,38(40)-tridecaen-9-one
    —— 3-[4-(2-Dimethylcarbamoyl-phenylsulfanyl)-3-nitro-phenyl]-propionic acid methyl ester 627488-12-4 C19H20N2O5S
    3-[4-(2-Dimethylcarbamoyl-phenylsulfanyl)-3-nitro-phenyl]-propionic acid methyl ester
    —— (S)-(1-phenylethyl)-(2-phenylsulfenylcyclohex-1-enyl)amine 272787-49-2 C20H23NS
    (S)-(1-phenylethyl)-(2-phenylsulfenylcyclohex-1-enyl)amine
    —— 5-[2-(2-benzyloxyethyl)-3,5-diethyl-3H-imidazol-4-ylsulfanyl]-isophthalonitrile 868525-12-6 C24H24N4OS
    5-[2-(2-benzyloxyethyl)-3,5-diethyl-3H-imidazol-4-ylsulfanyl]-isophthalonitrile
    —— Ecg1qci7DB 757211-45-3 C20H20Cl2N4O3S
    Ecg1qci7DB
    —— 3-pentyl-6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 86628-11-7 C15H18N4S
    3-pentyl-6-phenyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 2-Propylmercapto-ethyl-isothiocyanat 89676-98-2 C6H11NS2
    2-Propylmercapto-ethyl-isothiocyanat
    —— 2-acetyl-6,10-dithiaspiro[4,5]dec-2-ene 868764-58-3 C10H14OS2
    2-acetyl-6,10-dithiaspiro[4,5]dec-2-ene
    —— iodo(methylsulfonyl)methane 798568-07-7 C2H5IO2S
    iodo(methylsulfonyl)methane