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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4lambda6,16lambda6-Dithiaheptacyclo[17.5.1.11,21.17,11.17,13.19,13.119,23]triacontane 4,4,16,16-tetraoxide 180317-15-1 C28H44O4S2
    4lambda6,16lambda6-Dithiaheptacyclo[17.5.1.11,21.17,11.17,13.19,13.119,23]triacontane 4,4,16,16-tetraoxide
    —— (Z)-4,4,4-Trifluoro-3-(hexane-1-sulfonyl)-but-2-enenitrile 222547-12-8 C10H14F3NO2S
    (Z)-4,4,4-Trifluoro-3-(hexane-1-sulfonyl)-but-2-enenitrile
    —— S-{2-[bis(3'-isopropylpyrazol-1'-yl)methyl]phenyl}-N,N-dimethylthiocarbamate 1026902-33-9 C22H29N5OS
    S-{2-[bis(3'-isopropylpyrazol-1'-yl)methyl]phenyl}-N,N-dimethylthiocarbamate
    —— 1,2-bis(methylthio) hexane 144742-64-3 C8H18S2
    1,2-bis(methylthio) hexane
    —— Acetic acid 1-phenylsulfanyl-cyclopropyl ester 64416-53-1 C11H12O2S
    Acetic acid 1-phenylsulfanyl-cyclopropyl ester
    —— 6-Methanesulfinyl-6,6-bis-methylsulfanyl-hexan-3-one 1027014-10-3 C9H18O2S3
    6-Methanesulfinyl-6,6-bis-methylsulfanyl-hexan-3-one
    —— 2-{[3-({[tert-butyl(dimethyl)silyl]oxy}methyl)-2-methylphenyl]sulfanyl}-1-ethanol 339354-94-8 C16H28O2SSi
    2-{[3-({[tert-butyl(dimethyl)silyl]oxy}methyl)-2-methylphenyl]sulfanyl}-1-ethanol
    —— (2Z,4Z,6Z)-4-cyano-8,8-dimethyl-2,6-bis(phenylthio)nona-2,4,6-trienal 403719-69-7 C24H23NOS2
    (2Z,4Z,6Z)-4-cyano-8,8-dimethyl-2,6-bis(phenylthio)nona-2,4,6-trienal
    —— 5,5'-[1,3-propanediylbis(thio)]bis(1-benzyl-1H-tetrazole) 1043192-79-5 C19H20N8S2
    5,5'-[1,3-propanediylbis(thio)]bis(1-benzyl-1H-tetrazole)
    —— 2-(4-chloro-5-fluoro-2-nitro-phenylthio)-N,N-dimethylbenzamide 474432-19-4 C15H12ClFN2O3S
    2-(4-chloro-5-fluoro-2-nitro-phenylthio)-N,N-dimethylbenzamide
    —— Sulfonium, dimethyl-2-propenyl- 44398-00-7 C5H11S+
    Sulfonium, dimethyl-2-propenyl-
    —— (1R,2R)-2-[2-[[tert-butyl(dimethyl)silyl]oxymethyl]phenyl]-2-(2-methoxypropan-2-yloxy)-1-(6,6,8-trimethyl-1,4-dithiaspiro[4.5]dec-7-en-7-yl)ethanol 159143-41-6 C30H50O4S2Si
    (1R,2R)-2-[2-[[tert-butyl(dimethyl)silyl]oxymethyl]phenyl]-2-(2-methoxypropan-2-yloxy)-1-(6,6,8-trimethyl-1,4-dithiaspiro[4.5]dec-7-en-7-yl)ethanol
    —— 1-(2-benzylthiobenzyl)-5-methoxypyrrolidin-2-one 350500-14-0 C19H21NO2S
    1-(2-benzylthiobenzyl)-5-methoxypyrrolidin-2-one
    —— 3-cyclohexenyl ethyl sulfide 91737-93-8 C8H14S
    3-cyclohexenyl ethyl sulfide
    —— S-tert-butyl (2R)-2-[(1R,7aR)-7a-methyl-5-oxo-4-phenylthio-2,3,5,6,7,7a-hexahydro-1H-inden-1-yl]-4-[(4S)-2,2,5,5-tetramethyl-1,3-dioxolan-4-yl]butanethioate 203392-60-3 C31H44O4S2
    S-tert-butyl (2R)-2-[(1R,7aR)-7a-methyl-5-oxo-4-phenylthio-2,3,5,6,7,7a-hexahydro-1H-inden-1-yl]-4-[(4S)-2,2,5,5-tetramethyl-1,3-dioxolan-4-yl]butanethioate
    —— 3,5-dimethylbenzenethioacetaldehyde diethyl acetal 346592-15-2 C14H22O2S
    3,5-dimethylbenzenethioacetaldehyde diethyl acetal
    —— lithium;bis(phenylsulfanyl)methylsulfanylbenzene —— C19H15LiS3
    lithium;bis(phenylsulfanyl)methylsulfanylbenzene
    —— (R)-3,3-bis(ethylthio)tetrahydro-2H-pyran-2-carboxaldehyde 121620-34-6 C10H18O2S2
    (R)-3,3-bis(ethylthio)tetrahydro-2H-pyran-2-carboxaldehyde
    —— 2-Hydroxy-2-(4-methylsulfanyl-phenyl)-1-pyridin-4-yl-ethanone 72873-68-8 C14H13NO2S
    2-Hydroxy-2-(4-methylsulfanyl-phenyl)-1-pyridin-4-yl-ethanone
    —— 2-dithiabutanediyl[3]metacyclo[2](2,6)pyridinophane 362595-84-4 C18H19NS2
    2-dithiabutanediyl[3]metacyclo[2](2,6)pyridinophane
    —— 2-{3-[((E)-2-Hex-4-enyl)-[1,3]dithian-2-yl]-propyl}-[1,3]dioxolane 253197-43-2 C16H28O2S2
    2-{3-[((E)-2-Hex-4-enyl)-[1,3]dithian-2-yl]-propyl}-[1,3]dioxolane
    —— 5-[(3,4-Dimethoxy-2-methoxymethoxy-phenyl)-methoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole 171780-61-3 C22H26N2O5S
    5-[(3,4-Dimethoxy-2-methoxymethoxy-phenyl)-methoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole
    —— 2-(2,2-Dimethyl-[1,3]dioxolan-4-ylmethylsulfanyl)-pyridine 144365-93-5 C11H15NO2S
    2-(2,2-Dimethyl-[1,3]dioxolan-4-ylmethylsulfanyl)-pyridine
    —— 3-thiapentane-1,5-diyl diisothiocyanate 39219-64-2 C6H8N2S3
    3-thiapentane-1,5-diyl diisothiocyanate
    —— methyl 4-methyl-5-phenylsulfanyl-(E,4S)-2-pentenoate 688364-58-1 C13H16O2S
    methyl 4-methyl-5-phenylsulfanyl-(E,4S)-2-pentenoate
    —— (4S,6S,8S,10S,14R,16R,18R,22R)-4,6,8,14,16,18,22-heptamethoxy-10-hydroxy-12-(trimethylenedithio)-1-pentacosene 160382-08-1 C35H68O8S2
    (4S,6S,8S,10S,14R,16R,18R,22R)-4,6,8,14,16,18,22-heptamethoxy-10-hydroxy-12-(trimethylenedithio)-1-pentacosene
    —— (3R,5R)-3-[(2S)-2-[tert-butyl(dimethyl)silyl]oxy-9-trimethylsilylnon-8-ynyl]-5-methyl-3-phenylsulfanyloxolan-2-one 152037-54-2 C29H48O3SSi2
    (3R,5R)-3-[(2S)-2-[tert-butyl(dimethyl)silyl]oxy-9-trimethylsilylnon-8-ynyl]-5-methyl-3-phenylsulfanyloxolan-2-one
    —— (4S,5R)-4-(fluoromethyl)-5-[4-(methylthio)phenyl]-2-phenyl-4,5-dihydro-1,3-oxazole 126428-98-6 C17H16FNOS
    (4S,5R)-4-(fluoromethyl)-5-[4-(methylthio)phenyl]-2-phenyl-4,5-dihydro-1,3-oxazole
    —— (S)-3-((R)-1-Hydroxymethyl-allyl)-6,10-dithia-spiro[4.5]decan-1-one 164229-10-1 C12H18O2S2
    (S)-3-((R)-1-Hydroxymethyl-allyl)-6,10-dithia-spiro[4.5]decan-1-one
    —— 1-((1R,2S)-2-Methyl-1-oxo-1λ<sup>4</sup>-[1,3]dithian-2-yl)-3-phenyl-propan-1-one 186146-40-7 C14H18O2S2
    1-((1R,2S)-2-Methyl-1-oxo-1λ<sup>4</sup>-[1,3]dithian-2-yl)-3-phenyl-propan-1-one
    —— 2-ethoxycarbonyl-2-phenylthio-3-vinylidene-5-pentanolide 144511-97-7 C16H16O4S
    2-ethoxycarbonyl-2-phenylthio-3-vinylidene-5-pentanolide
    —— 6,6-dimethyl-3-methylthio-1-(pyrid-3-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one 252056-21-6 C16H17NOS2
    6,6-dimethyl-3-methylthio-1-(pyrid-3-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one
    —— tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-dimethyl-silane 218439-21-5 C21H42O3S2Si
    tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-dimethyl-silane
    —— ethyl (4R,5S)-2,2-dimethyl-5-(2-methyl-1-phenylsulfanylpropan-2-yl)-1,3-dioxolane-4-carboxylate 169899-78-9 C18H26O4S
    ethyl (4R,5S)-2,2-dimethyl-5-(2-methyl-1-phenylsulfanylpropan-2-yl)-1,3-dioxolane-4-carboxylate
    —— (3'R,4''S)-methyl 2-[3'-(2"-dimethyl-1",3"-dioxolan-4"-yl)-3'-(2"'-furyl)]propyl-4-phenylthio-acetoacetate 256343-63-2 C23H28O6S
    (3'R,4''S)-methyl 2-[3'-(2"-dimethyl-1",3"-dioxolan-4"-yl)-3'-(2"'-furyl)]propyl-4-phenylthio-acetoacetate
    —— 1-{2,6-dichloro-4-[(phenylthio)methyl]pyridin-3-yl}hex-5-en-1-one 607708-24-7 C18H17Cl2NOS
    1-{2,6-dichloro-4-[(phenylthio)methyl]pyridin-3-yl}hex-5-en-1-one
    —— 2-((R)-4-Azido-nonyl)-2-((E)-(S)-4-methoxymethoxy-non-5-enyl)-[1,3]dithiane 211678-50-1 C24H45N3O2S2
    2-((R)-4-Azido-nonyl)-2-((E)-(S)-4-methoxymethoxy-non-5-enyl)-[1,3]dithiane
    —— 4-chloro-6-(N-isobutyloamino)-2-methylmercaptopyrimidine 841260-72-8 C9H14ClN3S
    4-chloro-6-(N-isobutyloamino)-2-methylmercaptopyrimidine
    —— 2-Methoxy-[1,3]dithiolo[4,5-d][1,3]dithiol-5-one 172949-09-6 C5H4O2S4
    2-Methoxy-[1,3]dithiolo[4,5-d][1,3]dithiol-5-one
    —— 3-(2,5-dimethylphenyl)-sulfanyl-propionic acid methyl ester 571167-32-3 C12H16O2S
    3-(2,5-dimethylphenyl)-sulfanyl-propionic acid methyl ester
    —— D-(-)-threo-2-phenyl-4-(4-(methylthio)phenyl)-2-oxazole-5-methanol 96795-24-3 C17H17NO2S
    D-(-)-threo-2-phenyl-4-(4-(methylthio)phenyl)-2-oxazole-5-methanol
    —— n-Hexadecyl-methyl-dithiolcarbonat 41320-32-5 C18H36OS2
    n-Hexadecyl-methyl-dithiolcarbonat
    —— (2-Methoxymethoxy-ethylsulfanyl)-benzene 123299-87-6 C10H14O2S
    (2-Methoxymethoxy-ethylsulfanyl)-benzene
    —— 3-(6,7-Dihydro-5H-thieno[3,2-b]thiopyran-3-yloxy)-propane-1,2-diol 177974-79-7 C10H14O3S2
    3-(6,7-Dihydro-5H-thieno[3,2-b]thiopyran-3-yloxy)-propane-1,2-diol
    —— (3S,4S)-5,5,5-trifluoro-4-hydroxy-3-(p-tolylthio)pentanoic acid 473435-94-8 C12H13F3O3S
    (3S,4S)-5,5,5-trifluoro-4-hydroxy-3-(p-tolylthio)pentanoic acid
    —— (3aR,6aR)-3-[1-((2R,3R,4S)-4-Methyl-5-oxo-3-phenylsulfanyl-tetrahydro-furan-2-yloxy)-meth-(E)-ylidene]-3,3a,4,6a-tetrahydro-cyclopenta[b]furan-2-one 159655-80-8 C19H18O5S
    (3aR,6aR)-3-[1-((2R,3R,4S)-4-Methyl-5-oxo-3-phenylsulfanyl-tetrahydro-furan-2-yloxy)-meth-(E)-ylidene]-3,3a,4,6a-tetrahydro-cyclopenta[b]furan-2-one
    —— 4,5-Ethylenedithio-1,2-dithiol-3-thione 103656-48-0 C5H4S5
    4,5-Ethylenedithio-1,2-dithiol-3-thione
    —— tert-Butyl-((7R,9S)-9-methyl-8-oxa-1,4-dithia-spiro[4.5]dec-7-yloxy)-diphenyl-silane 148066-65-3 C24H32O2S2Si
    tert-Butyl-((7R,9S)-9-methyl-8-oxa-1,4-dithia-spiro[4.5]dec-7-yloxy)-diphenyl-silane
    —— [(E)-2-but-3-en-2-yloxy-3,3,3-trifluoroprop-1-enyl]sulfanylbenzene 177272-45-6 C13H13F3OS
    [(E)-2-but-3-en-2-yloxy-3,3,3-trifluoroprop-1-enyl]sulfanylbenzene
    —— [(E)-heptadec-2-enyl]sulfanylbenzene 172703-30-9 C23H38S
    [(E)-heptadec-2-enyl]sulfanylbenzene