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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— {(3aR,4S,7aS)-1-[(R)-4,4-Difluoro-1-methyl-4-(2-methyl-propane-2-sulfonyl)-butyl]-7a-methyl-3a,4,5,6,7,7a-hexahydro-3H-inden-4-yloxy}-triethyl-silane 250384-93-1 C25H46F2O3SSi
    {(3aR,4S,7aS)-1-[(R)-4,4-Difluoro-1-methyl-4-(2-methyl-propane-2-sulfonyl)-butyl]-7a-methyl-3a,4,5,6,7,7a-hexahydro-3H-inden-4-yloxy}-triethyl-silane
    —— E/Z-dispiro(5-chloro-6-phenylsulfanyl-2,3-dihydro-1H-benzimidazole-2,1'-cyclohexane-4',2''-5''-chloro-6''-phenylsulfanyl-2'',3''-dihydro-1''H-benzimidazole) 252680-83-4 C30H26Cl2N4S2
    E/Z-dispiro(5-chloro-6-phenylsulfanyl-2,3-dihydro-1H-benzimidazole-2,1'-cyclohexane-4',2''-5''-chloro-6''-phenylsulfanyl-2'',3''-dihydro-1''H-benzimidazole)
    —— N-butylpentanethioamide 214349-83-4 C9H19NS
    N-butylpentanethioamide
    —— 5-hydrazino-2,3-dihydrothieno[3,2-f]-1,4-thiazepine 193674-20-3 C7H9N3S2
    5-hydrazino-2,3-dihydrothieno[3,2-f]-1,4-thiazepine
    —— 2,6-Bis-propylsulfanyl-phenol 197149-22-7 C12H18OS2
    2,6-Bis-propylsulfanyl-phenol
    —— 1,3-Dimethyl-5-[3-(4-methyl-benzyloxy)-prop-2-ynylsulfanyl]-1H-pyrimidine-2,4-dione 310405-12-0 C17H18N2O3S
    1,3-Dimethyl-5-[3-(4-methyl-benzyloxy)-prop-2-ynylsulfanyl]-1H-pyrimidine-2,4-dione
    —— (3aR,7aS)-1-[(E)-(R)-4-Fluoro-1-methyl-4-(2-methyl-propane-2-sulfonyl)-but-3-enyl]-7a-methyl-3,3a,5,6,7,7a-hexahydro-inden-4-one 250385-02-5 C19H29FO3S
    (3aR,7aS)-1-[(E)-(R)-4-Fluoro-1-methyl-4-(2-methyl-propane-2-sulfonyl)-but-3-enyl]-7a-methyl-3,3a,5,6,7,7a-hexahydro-inden-4-one
    —— ethyl N-benzyl-N-[3-[benzyl(ethoxycarbonyl)amino]-2-oxo-1-phenylsulfanylpropyl]carbamate 253590-95-3 C29H32N2O5S
    ethyl N-benzyl-N-[3-[benzyl(ethoxycarbonyl)amino]-2-oxo-1-phenylsulfanylpropyl]carbamate
    —— (1'S,2S,3S)-3-(1'-tert-butoxydimethylsilyloxy-2'-methylpropyl)-2-(4''-methylphenylthio)-2-nitrooxirane 228716-92-5 C19H31NO4SSi
    (1'S,2S,3S)-3-(1'-tert-butoxydimethylsilyloxy-2'-methylpropyl)-2-(4''-methylphenylthio)-2-nitrooxirane
    —— 3-[3-[Tert-butyl(dimethyl)silyl]oxy-2-phenylpropyl]-4-phenylsulfanyl-1,3-oxazolidin-2-one 219708-62-0 C24H33NO3SSi
    3-[3-[Tert-butyl(dimethyl)silyl]oxy-2-phenylpropyl]-4-phenylsulfanyl-1,3-oxazolidin-2-one
    —— 2-Methyl-4-(3-methylphenyl)sulfanylbutan-2-ol 213121-85-8 C12H18OS
    2-Methyl-4-(3-methylphenyl)sulfanylbutan-2-ol
    —— (1E,3E)-1-morpholino-2-(phenylthio)buta-1,3-diene 133870-26-5 C14H17NOS
    (1E,3E)-1-morpholino-2-(phenylthio)buta-1,3-diene
    —— 2-(2-phenylacetyl)-2-ethyl-1,3-dithiane 172754-36-8 C14H18OS2
    2-(2-phenylacetyl)-2-ethyl-1,3-dithiane
    —— (Z)-1-Methylsulfonylbut-1-ene 185844-52-4 C5H10O2S
    (Z)-1-Methylsulfonylbut-1-ene
    —— 1<i>t</i>-methanesulfonyl-but-1-ene 56569-00-7 C5H10O2S
    1<i>t</i>-methanesulfonyl-but-1-ene
    —— 2-methyl-2-[2-(1-methoxycyclohexyl)ethynyl]-1,3-dithiolane 253436-92-9 C13H20OS2
    2-methyl-2-[2-(1-methoxycyclohexyl)ethynyl]-1,3-dithiolane
    —— methyl 3-sulfonyltridecanoate 294201-63-1 C13H26O4S
    methyl 3-sulfonyltridecanoate
    —— ethyl 4,5-dihydro-4-methyl-3-methylthio-5-oxo-1,2-dithiolo<4,3-b>pyrrole-6-carboxylate 229483-77-6 C10H11NO3S3
    ethyl 4,5-dihydro-4-methyl-3-methylthio-5-oxo-1,2-dithiolo<4,3-b>pyrrole-6-carboxylate
    —— (3aR,4S,7aS)-1-[(R)-4,4-Difluoro-1-methyl-4-(2-methyl-propane-2-sulfonyl)-butyl]-7a-methyl-3a,4,5,6,7,7a-hexahydro-3H-inden-4-ol 250384-94-2 C19H32F2O3S
    (3aR,4S,7aS)-1-[(R)-4,4-Difluoro-1-methyl-4-(2-methyl-propane-2-sulfonyl)-butyl]-7a-methyl-3a,4,5,6,7,7a-hexahydro-3H-inden-4-ol
    —— methyl (5S,6E,8E)-5-hydroxy-11-[2-[(Z)-oct-2-enyl]-1,3-dithian-2-yl]undeca-6,8-dienoate 185202-30-6 C24H40O3S2
    methyl (5S,6E,8E)-5-hydroxy-11-[2-[(Z)-oct-2-enyl]-1,3-dithian-2-yl]undeca-6,8-dienoate
    —— (E)-2-ethoxy-1,1,1-trifluoro-6,6-dimethyl-3-(phenylthio)hept-2-en-4-yne 253670-66-5 C17H19F3OS
    (E)-2-ethoxy-1,1,1-trifluoro-6,6-dimethyl-3-(phenylthio)hept-2-en-4-yne
    —— (S)-3-Allyl-3-phenylsulfanyl-5-triisopropylsilanyloxymethyl-dihydro-furan-2-one 189516-39-0 C23H36O3SSi
    (S)-3-Allyl-3-phenylsulfanyl-5-triisopropylsilanyloxymethyl-dihydro-furan-2-one
    —— methyl 2-methylthiocyclohexenyl-1-carbodithioate 50267-85-1 C9H14S3
    methyl 2-methylthiocyclohexenyl-1-carbodithioate
    —— tert-butyl N-(3-amino-3-sulfanylidenepropyl)-N-[3-[(3-amino-3-sulfanylidenepropyl)-[(2-methylpropan-2-yl)oxycarbonyl]amino]propyl]carbamate 187745-65-9 C19H36N4O4S2
    tert-butyl N-(3-amino-3-sulfanylidenepropyl)-N-[3-[(3-amino-3-sulfanylidenepropyl)-[(2-methylpropan-2-yl)oxycarbonyl]amino]propyl]carbamate
    —— N-(1-Methylene-2-phenylsulfanyl-allyl)-acetamide 192988-12-8 C12H13NOS
    N-(1-Methylene-2-phenylsulfanyl-allyl)-acetamide
    —— Pyridinium, 4,4'-[1,6-hexanediylbis(thio)]bis[1-octadecyl-, diiodide 202071-04-3 C52H94I2N2S2
    Pyridinium, 4,4'-[1,6-hexanediylbis(thio)]bis[1-octadecyl-, diiodide
    —— 5-[1-(tert-butyldimethylsiloxy)-1-(3,4-dimethoxy-2-methoxymethoxyphenyl)methyl]-4-[1-hydroxy-1-(4-methoxyphenyl)methyl]-1-methyl-2-phenylthio-1H-imidazole 197151-40-9 C35H46N2O7SSi
    5-[1-(tert-butyldimethylsiloxy)-1-(3,4-dimethoxy-2-methoxymethoxyphenyl)methyl]-4-[1-hydroxy-1-(4-methoxyphenyl)methyl]-1-methyl-2-phenylthio-1H-imidazole
    —— 2-Hept-3-ynylsulfanylphenol 217187-35-4 C13H16OS
    2-Hept-3-ynylsulfanylphenol
    —— Acetic acid 3,3,3-trifluoro-1-propylsulfanyl-propyl ester 201862-02-4 C8H13F3O2S
    Acetic acid 3,3,3-trifluoro-1-propylsulfanyl-propyl ester
    —— (Z,Z)-1,4-bis(tert-butylthio)-1,3-butadiene 186499-99-0 C12H22S2
    (Z,Z)-1,4-bis(tert-butylthio)-1,3-butadiene
    —— 4,4,5-Trimethyl-5-phenylsulfanyl-cyclopent-2-enone 335343-32-3 C14H16OS
    4,4,5-Trimethyl-5-phenylsulfanyl-cyclopent-2-enone
    —— (1R,2S,5R)-2-fluoro-1-{[(4-methylphenyl)sulfenyl]methyl}-5-methyl-6,8-dioxabicyclo[3.2.1]octane 281193-51-9 C15H19FO2S
    (1R,2S,5R)-2-fluoro-1-{[(4-methylphenyl)sulfenyl]methyl}-5-methyl-6,8-dioxabicyclo[3.2.1]octane
    —— 7-tert-butyloxycarbonyl-3-methylthio-5,6-dihydropyrrolo[2,3-c]pyridazine 213320-38-8 C12H17N3O2S
    7-tert-butyloxycarbonyl-3-methylthio-5,6-dihydropyrrolo[2,3-c]pyridazine
    —— 3-Ethoxy-5-phenylsulfanyl-pent-4-ynoic acid benzylamide 181587-47-3 C20H21NO2S
    3-Ethoxy-5-phenylsulfanyl-pent-4-ynoic acid benzylamide
    —— (5R)-5-(2-methoxyethoxymethoxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one 199927-77-0 C10H14O4S4
    (5R)-5-(2-methoxyethoxymethoxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one
    —— 2-(3-bromo-phenylsulfanyl)-5-nitro-pyridine 200930-73-0 C11H7BrN2O2S
    2-(3-bromo-phenylsulfanyl)-5-nitro-pyridine
    —— 6-Methylsulfanyl-1-(2-phenylethoxy)-5-propylpyrimidine-2,4-dione 191472-57-8 C16H20N2O3S
    6-Methylsulfanyl-1-(2-phenylethoxy)-5-propylpyrimidine-2,4-dione
    —— 4,4'-(p-xylylenedithio)bis(5-carbomethoxy-1,3-dithiol-2-one) 191932-37-3 C18H14O6S6
    4,4'-(p-xylylenedithio)bis(5-carbomethoxy-1,3-dithiol-2-one)
    —— 4-hydrazino-2-isopropylsulfanyl-6-methyl-pyrimidine 90112-05-3 C8H14N4S
    4-hydrazino-2-isopropylsulfanyl-6-methyl-pyrimidine
    —— 2-[(4-methylphenyl)thio]-6-chlorobenzaldehyde 331282-88-3 C14H11ClOS
    2-[(4-methylphenyl)thio]-6-chlorobenzaldehyde
    —— 1-((S)-2,3-Dihydroxy-propyl)-5-methyl-2-methylsulfanyl-1H-pyrimidin-4-one 208513-35-3 C9H14N2O3S
    1-((S)-2,3-Dihydroxy-propyl)-5-methyl-2-methylsulfanyl-1H-pyrimidin-4-one
    —— 4,5-(1,4-dimethoxy-2,3-phenylenedithio)-1,3-dithiole-2-thione 259813-15-5 C11H8O2S5
    4,5-(1,4-dimethoxy-2,3-phenylenedithio)-1,3-dithiole-2-thione
    —— 5-[3-(4-Chloro-benzyloxy)-prop-2-ynylsulfanyl]-1,3-dimethyl-1H-pyrimidine-2,4-dione 310405-08-4 C16H15ClN2O3S
    5-[3-(4-Chloro-benzyloxy)-prop-2-ynylsulfanyl]-1,3-dimethyl-1H-pyrimidine-2,4-dione
    —— 1-(3-Amino-5-tridecylsulfanyl-1,2,4-triazol-4-yl)ethanone 183793-96-6 C17H32N4OS
    1-(3-Amino-5-tridecylsulfanyl-1,2,4-triazol-4-yl)ethanone
    —— ((S)-2-Oxo-3-phenylsulfanyl-5-triisopropylsilanyloxymethyl-tetrahydro-furan-3-yl)-acetaldehyde 189516-40-3 C22H34O4SSi
    ((S)-2-Oxo-3-phenylsulfanyl-5-triisopropylsilanyloxymethyl-tetrahydro-furan-3-yl)-acetaldehyde
    —— 4-Ethylsulfanyl-5,6-dimethyl-1H-pyrimidin-2-one 175354-50-4 C8H12N2OS
    4-Ethylsulfanyl-5,6-dimethyl-1H-pyrimidin-2-one
    —— 5,6-dihydro-4-methyl-2-methylthiofuro<2,3-d>pyrimidine 16285-48-6 C8H10N2OS
    5,6-dihydro-4-methyl-2-methylthiofuro<2,3-d>pyrimidine
    —— 2,2-Dimethyl-propionic acid (Z)-5-{4-methoxy-2-[(Z)-6-(4-methoxy-2-phenylsulfanylmethyl-pyridin-3-yl)-hex-3-enyl]-pyridin-3-yl}-pent-2-enyl ester 211758-85-9 C35H44N2O4S
    2,2-Dimethyl-propionic acid (Z)-5-{4-methoxy-2-[(Z)-6-(4-methoxy-2-phenylsulfanylmethyl-pyridin-3-yl)-hex-3-enyl]-pyridin-3-yl}-pent-2-enyl ester
    —— ethyl 2,2-bis(methylthio)-1-cyclobutanecarboxylate 294868-54-5 C9H16O2S2
    ethyl 2,2-bis(methylthio)-1-cyclobutanecarboxylate
    —— 4-(2-cyanoethylthio)-5-methoxycarbonyl-1,3-dithiol-2-one 191932-41-9 C8H7NO3S3
    4-(2-cyanoethylthio)-5-methoxycarbonyl-1,3-dithiol-2-one