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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Chloro-5-(trifluoromethylthio)aniline 933674-81-8 C7H5ClF3NS
    2-Chloro-5-(trifluoromethylthio)aniline
    —— Ethyl 3-(4-bromophenylthio)-2-cyano-3-(methylthio)acrylate —— C13H12BrNO2S2
    Ethyl 3-(4-bromophenylthio)-2-cyano-3-(methylthio)acrylate
    —— Ethyl 3-(4-chlorophenylthio)-2-cyano-3-(methylthio)acrylate —— C13H12ClNO2S2
    Ethyl 3-(4-chlorophenylthio)-2-cyano-3-(methylthio)acrylate
    —— Triethyl-{(3aR,4S,7aS)-1-[(E)-(R)-4-fluoro-1-methyl-4-(2-methyl-propane-2-sulfonyl)-but-3-enyl]-7a-methyl-3a,4,5,6,7,7a-hexahydro-3H-inden-4-yloxy}-silane 250385-03-6 C25H45FO3SSi
    Triethyl-{(3aR,4S,7aS)-1-[(E)-(R)-4-fluoro-1-methyl-4-(2-methyl-propane-2-sulfonyl)-but-3-enyl]-7a-methyl-3a,4,5,6,7,7a-hexahydro-3H-inden-4-yloxy}-silane
    —— 4-Amino-3-allylthio-5-methyl-4H-1,2,4-triazole 341520-10-3 C6H10N4S
    4-Amino-3-allylthio-5-methyl-4H-1,2,4-triazole
    —— 2-(4,5-Bis-hexadecylsulfanyl-[1,3]dithiol-2-ylidene)-4,6-dimethyl-5H-[1,3]dithiolo[4,5-c]pyrrole 188014-44-0 C42H73NS6
    2-(4,5-Bis-hexadecylsulfanyl-[1,3]dithiol-2-ylidene)-4,6-dimethyl-5H-[1,3]dithiolo[4,5-c]pyrrole
    —— 2-Oct-2-ynylsulfanylphenol 217187-39-8 C14H18OS
    2-Oct-2-ynylsulfanylphenol
    —— (1S)-1-phenyl-N-(2-phenylsulfanylethyl)ethanamine 350678-28-3 C16H19NS
    (1S)-1-phenyl-N-(2-phenylsulfanylethyl)ethanamine
    —— 1-(2,5-Dimethyl-phenylsulfanyl)-2,5-dimethyl-4-methylsulfanyl-benzene 175548-63-7 C17H20S2
    1-(2,5-Dimethyl-phenylsulfanyl)-2,5-dimethyl-4-methylsulfanyl-benzene
    —— 2-Butylsulfanyl-thioisonicotinamide 180791-06-4 C10H14N2S2
    2-Butylsulfanyl-thioisonicotinamide
    —— N-[(1R)-1-phenylethyl]-N-(2-phenylsulfanylethyl)formamide 350678-31-8 C17H19NOS
    N-[(1R)-1-phenylethyl]-N-(2-phenylsulfanylethyl)formamide
    —— [(2R,3R,3aR,9aR)-2-(2,4-Dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-3-phenylsulfanyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-acetic acid tert-butyl ester 185556-93-8 C33H52N2O8SSi2
    [(2R,3R,3aR,9aR)-2-(2,4-Dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-3-phenylsulfanyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-acetic acid tert-butyl ester
    —— 5-[4-methoxy-2-[(E)-6-[4-methoxy-2-(phenylsulfanylmethyl)pyridin-3-yl]hex-3-enyl]pyridin-3-yl]pent-1-en-3-yl 2,2-dimethylpropanoate 211758-67-7 C35H44N2O4S
    5-[4-methoxy-2-[(E)-6-[4-methoxy-2-(phenylsulfanylmethyl)pyridin-3-yl]hex-3-enyl]pyridin-3-yl]pent-1-en-3-yl 2,2-dimethylpropanoate
    —— (2Z,4Z,6Z)-8,8-dimethyl-2,4-bis(phenylthio)nona-1,4,6-trienal ethyl acetal 213456-92-9 C33H38O2S3
    (2Z,4Z,6Z)-8,8-dimethyl-2,4-bis(phenylthio)nona-1,4,6-trienal ethyl acetal
    —— 3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone 220008-41-3 C23H36O2S2Si
    3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone
    —— dimethyl(2-methylprop-2-enyl)[1-phenyl-3,3-bis(phenylthio)propoxy]silane 332188-29-1 C27H32OS2Si
    dimethyl(2-methylprop-2-enyl)[1-phenyl-3,3-bis(phenylthio)propoxy]silane
    —— [2R-(1E,2α,3α,5β)]-[[[3,5-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-[(phenylthio)methyl]cyclohexylidene]methyl]thio]benzene 331732-45-7 C32H50O2S2Si2
    [2R-(1E,2α,3α,5β)]-[[[3,5-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-[(phenylthio)methyl]cyclohexylidene]methyl]thio]benzene
    —— 2-(3,3-dimethylbutanoyl)-2-ethyl-1,3-dithiane 332048-52-9 C12H22OS2
    2-(3,3-dimethylbutanoyl)-2-ethyl-1,3-dithiane
    —— 2-methyl-4(5)-methylthioimidazole 205311-55-3 C5H8N2S
    2-methyl-4(5)-methylthioimidazole
    —— 2-Ethylsulfanyl-isonicotinonitrile 180790-91-4 C8H8N2S
    2-Ethylsulfanyl-isonicotinonitrile
    —— 3-(3-Hydroxy-propyl)-5-methyl-2-methylsulfanyl-3H-pyrimidin-4-one 190069-94-4 C9H14N2O2S
    3-(3-Hydroxy-propyl)-5-methyl-2-methylsulfanyl-3H-pyrimidin-4-one
    —— 8-Oxa-1,4-dithiaspiro[4.5]decan-6-amine 205234-27-1 C7H13NOS2
    8-Oxa-1,4-dithiaspiro[4.5]decan-6-amine
    —— 6-acetoxy-4-(phenylthio)oct-2-yne 333347-52-7 C16H20O2S
    6-acetoxy-4-(phenylthio)oct-2-yne
    —— 1-Isocyanato-4-phenylsulfanylmethyl-benzene 1027150-33-9 C14H11NOS
    1-Isocyanato-4-phenylsulfanylmethyl-benzene
    —— 4-amino-2-(3,5-dibromophenylmethylthio)-6-hydroxypyrimidine 166751-50-4 C11H9Br2N3OS
    4-amino-2-(3,5-dibromophenylmethylthio)-6-hydroxypyrimidine
    —— N-benzyl-N-methyl-2-[2-(4-methylphenyl)sulfanylphenyl]acetamide 207349-82-4 C23H23NOS
    N-benzyl-N-methyl-2-[2-(4-methylphenyl)sulfanylphenyl]acetamide
    —— Methanesulfonic acid 1-methyl-3-phenyl-5-phenylsulfanylmethyl-hex-5-enyl ester 1026571-95-8 C21H26O3S2
    Methanesulfonic acid 1-methyl-3-phenyl-5-phenylsulfanylmethyl-hex-5-enyl ester
    —— ethyl 3-(ethylsulfinyl)propanoate 137959-01-4 C7H14O3S
    ethyl 3-(ethylsulfinyl)propanoate
    —— Pyridinium, 4,4'-[1,3-propanediylbis(thio)]bis[1-decyl-, diiodide 202070-88-0 C33H56I2N2S2
    Pyridinium, 4,4'-[1,3-propanediylbis(thio)]bis[1-decyl-, diiodide
    —— (S)-2-(dimethylamino)-1-(phenylthio)-3-methylbutane 105206-85-7 C13H21NS
    (S)-2-(dimethylamino)-1-(phenylthio)-3-methylbutane
    —— 2-[(5-Oxido-4-phenyl-1,2,5-oxadiazol-5-ium-3-yl)sulfanyl]ethanamine 186408-82-2 C10H11N3O2S
    2-[(5-Oxido-4-phenyl-1,2,5-oxadiazol-5-ium-3-yl)sulfanyl]ethanamine
    —— (1R,3aS,4R,6aS)-1,4-dimethylspiro[1,3,3a,4,6,6a-hexahydropentalene-5,2'-1,3-dithiolane]-2-one 207747-76-0 C12H18OS2
    (1R,3aS,4R,6aS)-1,4-dimethylspiro[1,3,3a,4,6,6a-hexahydropentalene-5,2'-1,3-dithiolane]-2-one
    —— ((Z)-1-Diethoxymethyl-3,3-dimethyl-but-1-enylsulfanyl)-benzene 213456-79-2 C17H26O2S
    ((Z)-1-Diethoxymethyl-3,3-dimethyl-but-1-enylsulfanyl)-benzene
    —— 1,2,5,8-Dithiadiazecine, 3,6,7,10-tetrahydro-3,3,6,6,10,10-hexamethyl- 90905-95-6 C12H22N2S2
    1,2,5,8-Dithiadiazecine, 3,6,7,10-tetrahydro-3,3,6,6,10,10-hexamethyl-
    —— (3R,4aS)-4a-Methyl-3-phenylsulfanyl-3,4,4a,5,6,7-hexahydro-1H-quinolin-2-one 118664-22-5 C16H19NOS
    (3R,4aS)-4a-Methyl-3-phenylsulfanyl-3,4,4a,5,6,7-hexahydro-1H-quinolin-2-one
    —— 2-(1-hydroxy-2-phenylethyl)-2-ethyl-1,3-dithiane 172754-55-1 C14H20OS2
    2-(1-hydroxy-2-phenylethyl)-2-ethyl-1,3-dithiane
    —— 2-<(2,4-diaminophenyl)thio>benzothiazole 219649-05-5 C13H11N3S2
    2-<(2,4-diaminophenyl)thio>benzothiazole
    —— methyl 4-[2-[(1E,3Z)-pentadeca-1,3-dien-6,9-diynyl]-1,3-dithiolan-2-yl]butanoate 208394-60-9 C23H32O2S2
    methyl 4-[2-[(1E,3Z)-pentadeca-1,3-dien-6,9-diynyl]-1,3-dithiolan-2-yl]butanoate
    —— 2-Methyl-5-methylsulfonyl-4-phenylsulfanylbenzoyl chloride 180528-88-5 C15H13ClO3S2
    2-Methyl-5-methylsulfonyl-4-phenylsulfanylbenzoyl chloride
    —— (2Z,4Z)-6,6-dimethyl-2,4-bis(phenylthio)hepta-2,4-dienal diethyl acetal 213456-89-4 C25H32O2S2
    (2Z,4Z)-6,6-dimethyl-2,4-bis(phenylthio)hepta-2,4-dienal diethyl acetal
    —— 2-(2,6-Diphenylthian-4-ylidene)-[1,3]dithiolo[4,5-d][1,3]dithiol-5-one 177546-04-2 C21H16OS5
    2-(2,6-Diphenylthian-4-ylidene)-[1,3]dithiolo[4,5-d][1,3]dithiol-5-one
    —— (E)-N-methoxy-1-(2-phenylsulfanylphenyl)ethanimine 356790-08-4 C15H15NOS
    (E)-N-methoxy-1-(2-phenylsulfanylphenyl)ethanimine
    —— (2S)-2-(methoxymethyl)-1-(phenylsulfanylmethyl)pyrrolidine 192185-02-7 C13H19NOS
    (2S)-2-(methoxymethyl)-1-(phenylsulfanylmethyl)pyrrolidine
    —— 5-(3-Benzyloxy-prop-2-ynylsulfanyl)-1,3-dimethyl-1H-pyrimidine-2,4-dione 310405-09-5 C16H16N2O3S
    5-(3-Benzyloxy-prop-2-ynylsulfanyl)-1,3-dimethyl-1H-pyrimidine-2,4-dione
    —— (1R,2R,5R)-2-fluoro-1-{[(4-methylphenyl)sulfenyl]methyl}-5-methyl-6,8-dioxabicyclo[3.2.1]octane 281193-44-0 C15H19FO2S
    (1R,2R,5R)-2-fluoro-1-{[(4-methylphenyl)sulfenyl]methyl}-5-methyl-6,8-dioxabicyclo[3.2.1]octane
    —— (Z)-5-{4-Methoxy-2-[(Z)-6-(4-methoxy-2-phenylsulfanylmethyl-pyridin-3-yl)-hex-3-enyl]-pyridin-3-yl}-pent-2-en-1-ol 211758-84-8 C30H36N2O3S
    (Z)-5-{4-Methoxy-2-[(Z)-6-(4-methoxy-2-phenylsulfanylmethyl-pyridin-3-yl)-hex-3-enyl]-pyridin-3-yl}-pent-2-en-1-ol
    —— 6-Methylsulfanyl-1-(3-phenylpropyl)-5-propan-2-ylpyrimidine-2,4-dione 172256-49-4 C17H22N2O2S
    6-Methylsulfanyl-1-(3-phenylpropyl)-5-propan-2-ylpyrimidine-2,4-dione
    —— methyl 4-[2-[(1E,3Z,6Z,9Z)-pentadeca-1,3,6,9-tetraenyl]-1,3-dithiolan-2-yl]butanoate 201273-28-1 C23H36O2S2
    methyl 4-[2-[(1E,3Z,6Z,9Z)-pentadeca-1,3,6,9-tetraenyl]-1,3-dithiolan-2-yl]butanoate
    —— (1S,4S,5S)-2-(phenylsulfenyl)-5-((tert-butyldimethylsilyl)oxy)bicyclo<2.2.2>oct-2-ene 177748-76-4 C20H30OSSi
    (1S,4S,5S)-2-(phenylsulfenyl)-5-((tert-butyldimethylsilyl)oxy)bicyclo<2.2.2>oct-2-ene
    —— 5-[3-(2-Chloro-benzyloxy)-prop-2-ynylsulfanyl]-1,3-dimethyl-1H-pyrimidine-2,4-dione 310405-07-3 C16H15ClN2O3S
    5-[3-(2-Chloro-benzyloxy)-prop-2-ynylsulfanyl]-1,3-dimethyl-1H-pyrimidine-2,4-dione