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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3,22-bis(tert-butylsulfanyl)-28,29-dinitro-5,6,12,13,19,20,25,26,31,32-decadehydro-27,30-etheno-7,11:14,18-dimethenodibenzo[a,k]cyclooctacosane 914673-96-4 C48H34N2O4S2
    3,22-bis(tert-butylsulfanyl)-28,29-dinitro-5,6,12,13,19,20,25,26,31,32-decadehydro-27,30-etheno-7,11:14,18-dimethenodibenzo[a,k]cyclooctacosane
    —— 6-(1-ethyl-1H-pyrazol-4-yl)-3-(methylthio)-1,2,4-triazine 1380345-42-5 C9H11N5S
    6-(1-ethyl-1H-pyrazol-4-yl)-3-(methylthio)-1,2,4-triazine
    —— 2-methyl-2-(methylsulfonyl)propan-1-amine hydrochloride 1314129-42-4 C5H13NO2S*ClH
    2-methyl-2-(methylsulfonyl)propan-1-amine hydrochloride
    —— 3-methylthio-6-(4-bromophenyl)-1,2,4-triazine 1380345-64-1 C10H8BrN3S
    3-methylthio-6-(4-bromophenyl)-1,2,4-triazine
    —— 7-(2-Benzoxazolylthio)-2,3-dihydro-1,4-benzodioxin-6-amine 1019538-82-9 C15H12N2O3S
    7-(2-Benzoxazolylthio)-2,3-dihydro-1,4-benzodioxin-6-amine
    —— N'-((2-methylthio)benzylidene)benzene-1,2-diamine 1312549-04-4 C14H14N2S
    N'-((2-methylthio)benzylidene)benzene-1,2-diamine
    —— 4-[5-(4-fluorophenylamino)-[1,3,4]thiadiazol-2-ylsulfanyl]-benzenesulfonamide 1076689-60-5 C14H11FN4O2S3
    4-[5-(4-fluorophenylamino)-[1,3,4]thiadiazol-2-ylsulfanyl]-benzenesulfonamide
    —— 6-(Propylthio)-3-pyridinamine 52025-16-8 C8H12N2S
    6-(Propylthio)-3-pyridinamine
    —— 2-(4-pentenylthio)-2-methylpropanal 135937-83-6 C9H16OS
    2-(4-pentenylthio)-2-methylpropanal
    —— 2-butylthio-2-methylpropanal 89812-34-0 C8H16OS
    2-butylthio-2-methylpropanal
    —— (1S)-1-(2-phenylsulfanylphenyl)ethanamine 1227795-23-4 C14H15NS
    (1S)-1-(2-phenylsulfanylphenyl)ethanamine
    —— (I+/-R)-I+/--Methyl-4-(phenylthio)benzenemethanamine 1228568-46-4 C14H15NS
    (I+/-R)-I+/--Methyl-4-(phenylthio)benzenemethanamine
    —— 2-((2-hexyl-4-methylphenyl)sulfanyl)-1,3,5-triisopropylbenzene 648436-70-8 C28H42S
    2-((2-hexyl-4-methylphenyl)sulfanyl)-1,3,5-triisopropylbenzene
    —— Ethyl 3-[(3'-phenylsulfanyl)thiolanyl]propionate 294211-67-9 C15H20O3S2
    Ethyl 3-[(3'-phenylsulfanyl)thiolanyl]propionate
    —— methyl 4-((4-methyl-2-(trimethylsilyl)phenyl)sulfanyl)benzoate 648436-73-1 C18H22O2SSi
    methyl 4-((4-methyl-2-(trimethylsilyl)phenyl)sulfanyl)benzoate
    —— 3-[(3'-Phenylsulfanyl)thiolanyl]propan-1,3-diol 294211-68-0 C13H18O2S2
    3-[(3'-Phenylsulfanyl)thiolanyl]propan-1,3-diol
    —— 3-Hydroxy-3-[methoxy(phenylsulfanyl)methyl]thiolane 294211-66-8 C12H16O2S2
    3-Hydroxy-3-[methoxy(phenylsulfanyl)methyl]thiolane
    —— 3-(Phenylsulfanyl)thiolane-3-carboxaldehyde 179088-77-8 C11H12OS2
    3-(Phenylsulfanyl)thiolane-3-carboxaldehyde
    —— (Z)-2-(benzyloxy)-N-methyl-3-(phenylthio)acrylamide 90461-25-9 C17H17NO2S
    (Z)-2-(benzyloxy)-N-methyl-3-(phenylthio)acrylamide
    —— (2-Ethylsulfanyl-phenyl)-propyl-amine 827026-24-4 C11H17NS
    (2-Ethylsulfanyl-phenyl)-propyl-amine
    —— O-(1-ethoxy-2,2-diethylvinyl) S-methyl dithiocarbonate 123311-29-5 C10H18O2S2
    O-(1-ethoxy-2,2-diethylvinyl) S-methyl dithiocarbonate
    —— 3-hydroxypropylisothiocyanate 4404-46-0 C4H7NOS
    3-hydroxypropylisothiocyanate
    —— (4-Bromo-2-ethylsulfanyl-phenyl)-methyl-amine 827026-20-0 C9H12BrNS
    (4-Bromo-2-ethylsulfanyl-phenyl)-methyl-amine
    —— 4-methyl-6-ethyl-2,3-dihydrothieno[2,3-c]furan 908239-73-6 C9H12OS
    4-methyl-6-ethyl-2,3-dihydrothieno[2,3-c]furan
    —— 3-(Methylthio)-N-(thiophen-3-ylmethyl)aniline 1019484-55-9 C12H13NS2
    3-(Methylthio)-N-(thiophen-3-ylmethyl)aniline
    —— tetrahydro-2-imino-3-methanesulfonyl-3-thiophenecarboxamide 863328-79-4 C6H10N2O3S2
    tetrahydro-2-imino-3-methanesulfonyl-3-thiophenecarboxamide
    —— 4-[4-(4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-51-9 C21H22N2O4S
    4-[4-(4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 1-methoxy-4-[[4-(2-nitroethenyl)phenyl]thio]benzene 477256-51-2 C15H13NO3S
    1-methoxy-4-[[4-(2-nitroethenyl)phenyl]thio]benzene
    —— 1-{4-[4-(4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-ethanone 1173658-68-8 C20H20N2O2S2
    1-{4-[4-(4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-ethanone
    —— 5-acetyl-4-[4-(4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one 1173658-52-0 C20H20N2O3S
    5-acetyl-4-[4-(4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one
    —— 4-[4-(4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-67-7 C21H22N2O3S2
    4-[4-(4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 4-Amino-2-{[(4-methylphenyl)sulfanyl]methyl}phenol 89307-35-7 C14H15NOS
    4-Amino-2-{[(4-methylphenyl)sulfanyl]methyl}phenol
    —— N-Boc-O-methyl-L-serine thioamide 161561-66-6 C9H18N2O3S
    N-Boc-O-methyl-L-serine thioamide
    —— (E)-2-(4-(methylthio)benzylidene)hydrazinecarbothioamide 65110-21-6 C9H11N3S2
    (E)-2-(4-(methylthio)benzylidene)hydrazinecarbothioamide
    —— 3-Butenethioamide, N-methyl- 80598-89-6 C5H9NS
    3-Butenethioamide, N-methyl-
    —— 5-(3,5-dichlorophenylthio)-4-isopropyl-2-(2-hydroxyethyl)-1-methyl-1H-imidazole 178982-63-3 C15H18Cl2N2OS
    5-(3,5-dichlorophenylthio)-4-isopropyl-2-(2-hydroxyethyl)-1-methyl-1H-imidazole
    —— (E,R)-4-tert-butoxycarbonylamino-5-phenylsulfanylpent-2-enoic acid tert-butyl ester 406235-20-9 C20H29NO4S
    (E,R)-4-tert-butoxycarbonylamino-5-phenylsulfanylpent-2-enoic acid tert-butyl ester
    —— 7-Methyl-3-phenyl-6,7-dihydro-4H-[1,3]thiazolo[2,3-c][1,2,4]triazin-4-one 87450-81-5 C12H11N3OS
    7-Methyl-3-phenyl-6,7-dihydro-4H-[1,3]thiazolo[2,3-c][1,2,4]triazin-4-one
    —— 1-(4-isopropylamino-2-methylsulphanyl-pyrimidin-5-yl)-ethanone 1204400-55-4 C10H15N3OS
    1-(4-isopropylamino-2-methylsulphanyl-pyrimidin-5-yl)-ethanone
    —— Carbamothioic acid, methyl-, S-(8-mercaptooctyl) ester 652150-45-3 C10H21NOS2
    Carbamothioic acid, methyl-, S-(8-mercaptooctyl) ester
    —— 2,3-Dihydro-6-phenyl-5H-thiazolo<2,3-c><1,2,4>-triazin-5-on 56040-93-8 C11H9N3OS
    2,3-Dihydro-6-phenyl-5H-thiazolo<2,3-c><1,2,4>-triazin-5-on
    —— 2,3-Dihydro-6-phenyl-7H-thiazolo<3,2-b><1,2,4>triazin-7-on 87844-08-4 C11H9N3OS
    2,3-Dihydro-6-phenyl-7H-thiazolo<3,2-b><1,2,4>triazin-7-on
    —— 3-methylthio-4-nitroso-6-phenyl-1,2,4-triazine-5-one 106119-80-6 C10H8N4O2S
    3-methylthio-4-nitroso-6-phenyl-1,2,4-triazine-5-one
    —— 6-Phenyl-3-(2-propyn-1-ylthio)-1,2,4-triazin-5-ol 97099-89-3 C12H9N3OS
    6-Phenyl-3-(2-propyn-1-ylthio)-1,2,4-triazin-5-ol
    —— 3-(allythio)-6-phenyl-1,2,4-triazin-5(2H)-one 87450-65-5 C12H11N3OS
    3-(allythio)-6-phenyl-1,2,4-triazin-5(2H)-one
    —— 3-but-3-yn-2-ylsulfanyl-6-phenyl-2H-1,2,4-triazin-5-one 97099-91-7 C13H11N3OS
    3-but-3-yn-2-ylsulfanyl-6-phenyl-2H-1,2,4-triazin-5-one
    —— 6-methylidene-3-phenyl-[1,3]thiazolo[2,3-c][1,2,4]triazin-4-one 97099-94-0 C12H9N3OS
    6-methylidene-3-phenyl-[1,3]thiazolo[2,3-c][1,2,4]triazin-4-one
    —— 7-methyl-6-methylidene-3-phenyl-[1,3]thiazolo[2,3-c][1,2,4]triazin-4-one 97099-96-2 C13H11N3OS
    7-methyl-6-methylidene-3-phenyl-[1,3]thiazolo[2,3-c][1,2,4]triazin-4-one
    —— 2-methyl-3-methylidene-6-phenyl-[1,3]thiazolo[3,2-b][1,2,4]triazin-7-one 97099-99-5 C13H11N3OS
    2-methyl-3-methylidene-6-phenyl-[1,3]thiazolo[3,2-b][1,2,4]triazin-7-one
    —— 3-methylidene-6-phenyl-[1,3]thiazolo[3,2-b][1,2,4]triazin-7-one 97099-97-3 C12H9N3OS
    3-methylidene-6-phenyl-[1,3]thiazolo[3,2-b][1,2,4]triazin-7-one