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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— bis-ethanesulfonyl-methanesulfonyl-methane 59099-56-8 C6H14O6S3
    bis-ethanesulfonyl-methanesulfonyl-methane
    —— Ferrocene, 1,1'-(methylenebis(thio))- 71794-57-5 C11H10FeS2-6
    Ferrocene, 1,1'-(methylenebis(thio))-
    —— 5-bromo-2-[1-methyl-5-(2,2,2-trifluoroethoxy)-3-trifluoro-methyl-1H-pyrazol-4-ylmethylsulfanyl]-thiazole 915135-81-8 C11H8BrF6N3OS2
    5-bromo-2-[1-methyl-5-(2,2,2-trifluoroethoxy)-3-trifluoro-methyl-1H-pyrazol-4-ylmethylsulfanyl]-thiazole
    —— (<i>S</i>)-2-dimethylthiocarbamoyloxy-propionic acid 923-18-2 C6H11NO3S
    (<i>S</i>)-2-dimethylthiocarbamoyloxy-propionic acid
    —— (<i>R</i>)-2-dimethylthiocarbamoyloxy-propionic acid 923-18-2 C6H11NO3S
    (<i>R</i>)-2-dimethylthiocarbamoyloxy-propionic acid
    —— (<i>S</i>)-2-ethylsulfanylthiocarbonyloxy-propionic acid 924-62-9 C6H10O3S2
    (<i>S</i>)-2-ethylsulfanylthiocarbonyloxy-propionic acid
    —— 1,1'-Ferrocenetrisulfide 32677-78-4 C10H8FeS3-6
    1,1'-Ferrocenetrisulfide
    —— Ferrocene, 1,1'-(1,5-pentanediylbis(thio))- 98150-61-9 C15H18FeS2-6
    Ferrocene, 1,1'-(1,5-pentanediylbis(thio))-
    —— Ferrocene, 1,1'-(1,2-ethanediylbis(thio))- 84756-01-4 C12H12FeS2-6
    Ferrocene, 1,1'-(1,2-ethanediylbis(thio))-
    —— 1,4-benzenebis(thioacetic acid) 20084-29-1 C10H10O4S2
    1,4-benzenebis(thioacetic acid)
    —— N-ethyl-5-acetylvaleramide ethylene dithioketal 168268-54-0 C11H21NOS2
    N-ethyl-5-acetylvaleramide ethylene dithioketal
    —— methyl 3-[2-(tert-butoxycarbonylamino)thiazol-5-yl]sulfanylpropanoate 1305274-69-4 C12H18N2O4S2
    methyl 3-[2-(tert-butoxycarbonylamino)thiazol-5-yl]sulfanylpropanoate
    —— 5-(Methylthio)-4-penten-1-ol 1070799-11-9 C6H12OS
    5-(Methylthio)-4-penten-1-ol
    —— 3-[2-(tert-butoxycarbonylamino)thiazol-5-yl]sulfanylpropanoic acid 1305274-71-8 C11H16N2O4S2
    3-[2-(tert-butoxycarbonylamino)thiazol-5-yl]sulfanylpropanoic acid
    —— 4-(phenylthio)-2-(trifluoromethyl)aniline 59432-00-7 C13H10F3NS
    4-(phenylthio)-2-(trifluoromethyl)aniline
    —— 2-amino-4-(2-furyl)-6-methylsulfanyl-pyrimidine-5-carbonitrile 68364-49-8 C10H8N4OS
    2-amino-4-(2-furyl)-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 1-(Dimesitylboryl)-8-(phenylthio)naphthalene 1258402-68-4 C34H33BS
    1-(Dimesitylboryl)-8-(phenylthio)naphthalene
    —— xylylthioacetic acid 253304-13-1 C10H12O2S
    xylylthioacetic acid
    —— Ferrocene, 1,1'-(1,4-butanediylbis(thio))- 98150-60-8 C14H16FeS2-6
    Ferrocene, 1,1'-(1,4-butanediylbis(thio))-
    —— 4-furan-2-yl-2,6-bis-methylsulfanyl-pyrimidine-5-carbonitrile 68388-55-6 C11H9N3OS2
    4-furan-2-yl-2,6-bis-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 4-furan-2-yl-2-methyl-6-methylsulfanyl-pyrimidine-5-carbonitrile 68364-39-6 C11H9N3OS
    4-furan-2-yl-2-methyl-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 5-Trifluormethylmercapto-2,4,6-trichloro-pyrimidin 108255-35-2 C5Cl3F3N2S
    5-Trifluormethylmercapto-2,4,6-trichloro-pyrimidin
    —— 6-methyl-2-(4-nitro-phenylsulfanyl)-pyrimidin-4-ylamine 120735-22-0 C11H10N4O2S
    6-methyl-2-(4-nitro-phenylsulfanyl)-pyrimidin-4-ylamine
    —— 2-(4-amino-phenylsulfanyl)-6-methyl-pyrimidin-4-ylamine 120735-24-2 C11H12N4S
    2-(4-amino-phenylsulfanyl)-6-methyl-pyrimidin-4-ylamine
    —— 3-(4-amino-phenylsulfanyl)-propionic acid 30086-23-8 C9H11NO2S
    3-(4-amino-phenylsulfanyl)-propionic acid
    —— 2,2,2-trifluoro-N-[2-[4-[[3-(aminocarbonyl)-4-nitrophenyl]thio]phenyl]ethyl]acetamide 870104-61-3 C17H14F3N3O4S
    2,2,2-trifluoro-N-[2-[4-[[3-(aminocarbonyl)-4-nitrophenyl]thio]phenyl]ethyl]acetamide
    —— (1-Chloro-cyclohexylsulfanyl)-benzene 89423-43-8 C12H15ClS
    (1-Chloro-cyclohexylsulfanyl)-benzene
    —— (S)-3-hydroxy-N,N,14-trimethylpentadecanethioamide 1402050-26-3 C18H37NOS
    (S)-3-hydroxy-N,N,14-trimethylpentadecanethioamide
    —— 2-(3-hydroxyphenylthio)-3-[3-(pyridin-4-yl)propoxy]pyridine 263390-95-0 C19H18N2O2S
    2-(3-hydroxyphenylthio)-3-[3-(pyridin-4-yl)propoxy]pyridine
    —— 2-[1-(cyclopentyloxy)-3-(phenylthio)-2-propyn-1-yl]thiophene 1356910-92-3 C18H18OS2
    2-[1-(cyclopentyloxy)-3-(phenylthio)-2-propyn-1-yl]thiophene
    —— 3-[(S-pivaloyloxymethyl-4-thiothymin-1-ylacetyl)amino]propyne 161098-28-8 C16H21N3O4S
    3-[(S-pivaloyloxymethyl-4-thiothymin-1-ylacetyl)amino]propyne
    —— 3-(ethylthio)-2,1-benzisothiazole 67943-94-6 C9H9NS2
    3-(ethylthio)-2,1-benzisothiazole
    —— (2S,3S,4R,6S)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol 338387-38-5 C19H32O3SSi
    (2S,3S,4R,6S)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol
    —— 2-(3-cyclopentyloxyphenylthio)-3-[3-(pyridin-4-yl)propoxy]pyridine 263391-00-0 C24H26N2O2S
    2-(3-cyclopentyloxyphenylthio)-3-[3-(pyridin-4-yl)propoxy]pyridine
    —— 1-phenyl-5-(phenylthio)oct-7-en-4-one 1589514-37-3 C20H22OS
    1-phenyl-5-(phenylthio)oct-7-en-4-one
    —— Acetic acid, (phenylthio)(triphenylarsoranylidene)-, ethyl ester 518035-71-7 C28H25AsO2S
    Acetic acid, (phenylthio)(triphenylarsoranylidene)-, ethyl ester
    —— p-methylphenyl phenyldithioacetate 378791-48-1 C15H14S2
    p-methylphenyl phenyldithioacetate
    —— 2-(butylthio)-4-(5-phenylpent-1-ynyl)oxazole 1268685-56-8 C18H21NOS
    2-(butylthio)-4-(5-phenylpent-1-ynyl)oxazole
    —— 2-fluoro-N-methoxymethyl-4-(trifluoromethylthio)-aniline 935440-18-9 C9H9F4NOS
    2-fluoro-N-methoxymethyl-4-(trifluoromethylthio)-aniline
    —— p-bromophenyl propanedithioate 340814-59-7 C9H9BrS2
    p-bromophenyl propanedithioate
    —— but-2-ene-1,4-dithiol 6725-69-5 C4H8S2
    but-2-ene-1,4-dithiol
    —— p-chlorophenyl phenyldithioacetate 378791-49-2 C14H11ClS2
    p-chlorophenyl phenyldithioacetate
    —— 1-Methyl-2-pivalyloxymethylthioimidazole 80693-27-2 C10H16N2O2S
    1-Methyl-2-pivalyloxymethylthioimidazole
    —— 4-bis(phenylthio)methoxy-2-methylbut-1-ene 746638-51-7 C18H20OS2
    4-bis(phenylthio)methoxy-2-methylbut-1-ene
    —— 6-(4-fluorophenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one 742699-57-6 C24H17FO2S
    6-(4-fluorophenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one
    —— 4-(4-methylsulfanylphenyl)-3,6-diphenylpyran-2-one 742699-51-0 C24H18O2S
    4-(4-methylsulfanylphenyl)-3,6-diphenylpyran-2-one
    —— 6-(4-methylphenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one 742699-52-1 C25H20O2S
    6-(4-methylphenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one
    —— 6-(4-ethylphenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one 742699-53-2 C26H22O2S
    6-(4-ethylphenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one
    —— 4-(allylthio)-1-phenylpyrimidin-2(1H)-one 917081-61-9 C13H12N2OS
    4-(allylthio)-1-phenylpyrimidin-2(1H)-one
    —— 6-(4-methylsulfanylphenyl)-3,4-diphenylpyran-2-one 742699-50-9 C24H18O2S
    6-(4-methylsulfanylphenyl)-3,4-diphenylpyran-2-one