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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(3S)-1,1-dioxothiolan-3-yl] 2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C16H19N3O4S3
    [(3S)-1,1-dioxothiolan-3-yl] 2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (2S)-N-cycloheptyl-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C19H26N4OS2
    (2S)-N-cycloheptyl-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-prop-2-enylpropanamide —— C15H18N4OS2
    (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-prop-2-enylpropanamide
    —— (2R)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-propylpropanamide —— C15H20N4OS2
    (2R)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-propylpropanamide
    —— 5-[[4-Cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-3-thiophen-3-yl-1,2,4-oxadiazole —— C17H15N5OS3
    5-[[4-Cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-3-thiophen-3-yl-1,2,4-oxadiazole
    —— (2S)-N-cycloheptyl-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C20H28N4OS2
    (2S)-N-cycloheptyl-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-methoxyethyl)propanamide —— C15H20N4O2S2
    (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-methoxyethyl)propanamide
    —— (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-methylpropyl)propanamide —— C16H22N4OS2
    (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-methylpropyl)propanamide
    —— (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-propylpropanamide —— C15H20N4OS2
    (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-propylpropanamide
    —— (2R)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C16H20N4O3S3
    (2R)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C20H21FN4OS2
    (2S)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— (2S)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C20H29N5O2S
    (2S)-2-[[5-(3-amino-3-oxopropyl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— methyl N-[(2R)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]carbamate —— C14H16N4O3S2
    methyl N-[(2R)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanoyl]carbamate
    —— (2S)-N-[(2-chlorophenyl)methyl]-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C18H15Cl2N3O2S
    (2S)-N-[(2-chlorophenyl)methyl]-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-1-(azepan-1-yl)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C17H20ClN3O2S
    (2S)-1-(azepan-1-yl)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— methyl N-[(2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoyl]carbamate —— C15H18N4O3S2
    methyl N-[(2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanoyl]carbamate
    —— (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N,N-di(propan-2-yl)propanamide —— C18H26N4OS2
    (2S)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N,N-di(propan-2-yl)propanamide
    —— (2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C20H21FN4OS2
    (2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— (2S)-N-(2-cyanoethyl)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide —— C16H19N5OS2
    (2S)-N-(2-cyanoethyl)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide
    —— (2S)-1-(azepan-1-yl)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one —— C19H26N4OS2
    (2S)-1-(azepan-1-yl)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one
    —— (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-cyanoethyl)-N-methylpropanamide —— C15H15ClN4O2S
    (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-cyanoethyl)-N-methylpropanamide
    —— (2R)-N-tert-butyl-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C15H18ClN3O2S
    (2R)-N-tert-butyl-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C16H14ClN3O2S2
    (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— (2R)-N-[(2-chlorophenyl)methyl]-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C18H15Cl2N3O2S
    (2R)-N-[(2-chlorophenyl)methyl]-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C18H15ClFN3O2S
    (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— [(3R)-1,1-dioxothiolan-3-yl] 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C14H13ClN2O5S2
    [(3R)-1,1-dioxothiolan-3-yl] 2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— (2S)-N-tert-butyl-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C15H18ClN3O2S
    (2S)-N-tert-butyl-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— methyl N-[(2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate —— C13H12ClN3O4S
    methyl N-[(2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate
    —— (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(1-cyanocyclohexyl)-N-methylpropanamide —— C19H21ClN4O2S
    (2S)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(1-cyanocyclohexyl)-N-methylpropanamide
    —— (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C15H16ClN3O4S2
    (2R)-2-[[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— 2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-[(4-fluorophenyl)methyl]-N-methylacetamide —— C15H20FN5OS
    2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-[(4-fluorophenyl)methyl]-N-methylacetamide
    —— (2S)-2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C16H22FN5OS
    (2S)-2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide
    —— 2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-(furan-2-ylmethyl)-N-methylacetamide —— C13H19N5O2S
    2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-(furan-2-ylmethyl)-N-methylacetamide
    —— N-[(2-bromophenyl)methyl]-2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-methylacetamide —— C15H20BrN5OS
    N-[(2-bromophenyl)methyl]-2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-methylacetamide
    —— (2R)-2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide —— C16H22FN5OS
    (2R)-2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-[(1R)-1-(4-fluorophenyl)ethyl]propanamide
    —— 5-[(1-Tert-butyltetrazol-5-yl)sulfanylmethyl]-3-thiophen-2-yl-1,2,4-oxadiazole —— C12H14N6OS2
    5-[(1-Tert-butyltetrazol-5-yl)sulfanylmethyl]-3-thiophen-2-yl-1,2,4-oxadiazole
    —— 4-[(1-Tert-butyltetrazol-5-yl)sulfanylmethyl]-2-(4-chlorophenyl)-1,3-thiazole —— C15H16ClN5S2
    4-[(1-Tert-butyltetrazol-5-yl)sulfanylmethyl]-2-(4-chlorophenyl)-1,3-thiazole
    —— 6-Amino-1-cyclopropyl-5-[2-(3,4-difluorophenyl)sulfanylacetyl]pyrimidine-2,4-dione —— C15H13F2N3O3S
    6-Amino-1-cyclopropyl-5-[2-(3,4-difluorophenyl)sulfanylacetyl]pyrimidine-2,4-dione
    —— 4-Cyclopropyl-3-[(2,3-difluorophenyl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazole —— C16H13F2N3S2
    4-Cyclopropyl-3-[(2,3-difluorophenyl)methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazole
    —— Methyl 1-cyclopropyl-4-[2-(3,4-difluorophenyl)sulfanylacetyl]-2,5-dimethylpyrrole-3-carboxylate —— C19H19F2NO3S
    Methyl 1-cyclopropyl-4-[2-(3,4-difluorophenyl)sulfanylacetyl]-2,5-dimethylpyrrole-3-carboxylate
    —— 2-(3-Chlorophenyl)-5-[(3-methyl-1,2-oxazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole —— C13H10ClN3O2S
    2-(3-Chlorophenyl)-5-[(3-methyl-1,2-oxazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 5-[(2,3-difluorophenyl)methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine —— C10H9F2N3S2
    5-[(2,3-difluorophenyl)methylsulfanyl]-N-methyl-1,3,4-thiadiazol-2-amine
    —— 2-[(2,3-Difluorophenyl)methylsulfanyl]-5-(3,5-dimethylphenyl)-1,3,4-oxadiazole —— C17H14F2N2OS
    2-[(2,3-Difluorophenyl)methylsulfanyl]-5-(3,5-dimethylphenyl)-1,3,4-oxadiazole
    —— 1-[(2R)-2-(2-fluorophenyl)-1,3-thiazolidin-3-yl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C14H15FN4OS3
    1-[(2R)-2-(2-fluorophenyl)-1,3-thiazolidin-3-yl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 3-[5-[(2,3-Difluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]propanamide —— C13H14F2N4OS
    3-[5-[(2,3-Difluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— N'-[2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2-(4-methyl-1,3-thiazol-2-yl)acetohydrazide —— C18H19N5O3S2
    N'-[2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-2-(4-methyl-1,3-thiazol-2-yl)acetohydrazide
    —— 1-[(2S)-2-(2-fluorophenyl)-1,3-thiazolidin-3-yl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C14H15FN4OS3
    1-[(2S)-2-(2-fluorophenyl)-1,3-thiazolidin-3-yl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— (2R)-2-[[5-(2-piperidin-1-ylethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylpropanamide —— C18H31N5OS
    (2R)-2-[[5-(2-piperidin-1-ylethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylpropanamide
    —— methyl N-[2-[[5-(2-piperidin-1-ium-1-ylethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetyl]carbamate —— C16H26N5O3S+
    methyl N-[2-[[5-(2-piperidin-1-ium-1-ylethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetyl]carbamate
    —— Methyl 3-[[5-(3-amino-3-oxopropyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C10H16N4O3S
    Methyl 3-[[5-(3-amino-3-oxopropyl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]propanoate