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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— benzenecarbaldehyde N-[6-chloro-2-(methylsulfanyl)-4-pyrimidinyl]hydrazone 339017-98-0 C12H11ClN4S
    benzenecarbaldehyde N-[6-chloro-2-(methylsulfanyl)-4-pyrimidinyl]hydrazone
    —— Tert-butyl (1-{5-[(4-fluorobenzyl)sulfanyl]-1,3,4-oxadiazol-2-yl}-2-methylbutyl)carbamate —— C19H26FN3O3S
    Tert-butyl (1-{5-[(4-fluorobenzyl)sulfanyl]-1,3,4-oxadiazol-2-yl}-2-methylbutyl)carbamate
    —— 1-[2,5-Dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]-2-[[5-[2-[2,5-dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C28H36N4O4S3
    1-[2,5-Dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]-2-[[5-[2-[2,5-dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 2-[4-(methoxyiminomethyl)-2-nitrophenyl]sulfanylaniline —— C14H13N3O3S
    2-[4-(methoxyiminomethyl)-2-nitrophenyl]sulfanylaniline
    —— 3,4-dimethyl-5-({[2-(4-methylphenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-4H-1,2,4-triazole —— C15H16N4S2
    3,4-dimethyl-5-({[2-(4-methylphenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)-4H-1,2,4-triazole
    —— 5-Phenylsulfanylthiadiazole —— C8H6N2S2
    5-Phenylsulfanylthiadiazole
    —— 3-[5-[4-(Difluoromethylsulfanyl)phenyl]furan-2-yl]-2-(4-phenyl-1,3-thiazol-2-yl)prop-2-enenitrile —— C23H14F2N2OS2
    3-[5-[4-(Difluoromethylsulfanyl)phenyl]furan-2-yl]-2-(4-phenyl-1,3-thiazol-2-yl)prop-2-enenitrile
    —— 12-Methoxysulfonothioyldodecan-1-amine —— C13H29NO2S2
    12-Methoxysulfonothioyldodecan-1-amine
    —— Ethyl 2-{[3-(4-ethylphenyl)-7-oxo-6-phenyl-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL]sulfanyl}acetate —— C23H21N3O3S3
    Ethyl 2-{[3-(4-ethylphenyl)-7-oxo-6-phenyl-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL]sulfanyl}acetate
    —— 6-methylsulfanyl-3,8-diphenyl-1H-[1,3]thiazolo[3,4-b][1,2,4]triazin-5-ium-2-one —— C18H14N3OS2+
    6-methylsulfanyl-3,8-diphenyl-1H-[1,3]thiazolo[3,4-b][1,2,4]triazin-5-ium-2-one
    —— 3-(ethylsulfanyl)-5-(thiophen-2-yl)-4H-1,2,4-triazol-4-amine 118158-92-2 C8H10N4S2
    3-(ethylsulfanyl)-5-(thiophen-2-yl)-4H-1,2,4-triazol-4-amine
    —— bis(7-methyl-5-oxo-5H-1,3,4-thiadiazolo<3,2-a>pyrimidyl-2)sulfide —— C12H8N6O2S3
    bis(7-methyl-5-oxo-5H-1,3,4-thiadiazolo<3,2-a>pyrimidyl-2)sulfide
    —— 2-{[4-(2-Thienyl)-2-pyrimidinyl]sulfanyl}acetonitrile —— C10H7N3S2
    2-{[4-(2-Thienyl)-2-pyrimidinyl]sulfanyl}acetonitrile
    —— (2-Benzylsulfanyl-5-chlorophenyl)-cyclopropylmethanamine —— C17H18ClNS
    (2-Benzylsulfanyl-5-chlorophenyl)-cyclopropylmethanamine
    —— N-[2-(cyclohexen-1-yl)ethyl]-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H20FN3OS3
    N-[2-(cyclohexen-1-yl)ethyl]-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 3-(4-chlorophenyl)sulfanyl-N-(1-methoxypropan-2-yl)propanamide —— C13H18ClNO2S
    3-(4-chlorophenyl)sulfanyl-N-(1-methoxypropan-2-yl)propanamide
    —— 5-[[4-Bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(2-methoxyethyl)-2-(4-methoxyphenyl)imino-1,3-thiazolidin-4-one —— C24H20BrClN2O4S2
    5-[[4-Bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(2-methoxyethyl)-2-(4-methoxyphenyl)imino-1,3-thiazolidin-4-one
    —— 2-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(furan-2-yl)ethanone —— C8H7N3O2S2
    2-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-(furan-2-yl)ethanone
    —— 2-cyano-N-(furan-2-ylmethyl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enamide —— C19H14N2O3S
    2-cyano-N-(furan-2-ylmethyl)-3-(5-phenylsulfanylfuran-2-yl)prop-2-enamide
    —— {5-[1-Methyl-pent-4-en-(Z)-ylidene-hydrazinocarbonylmethylsulfanyl]-[1,3,4]thiadiazol-2-ylsulfanyl}-acetic acid [1-methyl-pent-4-en-(E)-ylidene]-hydrazide —— C18H26N6O2S3
    {5-[1-Methyl-pent-4-en-(Z)-ylidene-hydrazinocarbonylmethylsulfanyl]-[1,3,4]thiadiazol-2-ylsulfanyl}-acetic acid [1-methyl-pent-4-en-(E)-ylidene]-hydrazide
    —— 2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methylcyclohexyl)acetamide —— C17H20ClN3OS3
    2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methylcyclohexyl)acetamide
    —— sodium;1-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-phenylmethanimidothioate —— C12H10N3NaOS2
    sodium;1-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-phenylmethanimidothioate
    —— N-ethyl-3-[[5-(5-methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C11H14N4O3S
    N-ethyl-3-[[5-(5-methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 3-chloro-N-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide —— C20H13Cl2N3O3S
    3-chloro-N-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide
    —— 4-[[4-(4-Chlorophenyl)sulfanylphenyl]methylidene]-5-methyl-2-phenylpyrazol-3-one —— C23H17ClN2OS
    4-[[4-(4-Chlorophenyl)sulfanylphenyl]methylidene]-5-methyl-2-phenylpyrazol-3-one
    —— N-[(6-methylpyridin-2-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C14H14N4OS
    N-[(6-methylpyridin-2-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— 2-N-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-N-phenyl-6-pyrrolidin-1-yl-1,3,5-triazine-2,4-diamine —— C27H26N8O2S
    2-N-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-N-phenyl-6-pyrrolidin-1-yl-1,3,5-triazine-2,4-diamine
    —— 1-Methyl-2'-[4-(phenylsulfanyl)phenyl]-1',10b'-dihydrospiro[piperidine-4,5'-pyrazolo[1,5-c][1,3]benzoxazine] —— C27H27N3OS
    1-Methyl-2'-[4-(phenylsulfanyl)phenyl]-1',10b'-dihydrospiro[piperidine-4,5'-pyrazolo[1,5-c][1,3]benzoxazine]
    —— 4-(4-Bromophenyl)sulfanyl-6-(methylsulfonylmethyl)-2-phenylpyrimidine —— C18H15BrN2O2S2
    4-(4-Bromophenyl)sulfanyl-6-(methylsulfonylmethyl)-2-phenylpyrimidine
    —— 1-Cyclopentyl-3-[3-(propan-2-yloxy)propyl]thiourea —— C12H24N2OS
    1-Cyclopentyl-3-[3-(propan-2-yloxy)propyl]thiourea
    —— N'-octadec-9-enylethanedithioamide —— C20H38N2S2
    N'-octadec-9-enylethanedithioamide
    —— 4-(4-Methylsulfonylphenyl)sulfanylbenzoic acid —— C14H12O4S2
    4-(4-Methylsulfonylphenyl)sulfanylbenzoic acid
    —— 4-Methylphenyl 4-[(4-methylphenyl)sulfanyl]-3-nitrobenzyl ether —— C21H19NO3S
    4-Methylphenyl 4-[(4-methylphenyl)sulfanyl]-3-nitrobenzyl ether
    —— [5-(Sulfomethylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanylmethanesulfonic acid —— C4H6N2O6S5
    [5-(Sulfomethylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanylmethanesulfonic acid
    —— 2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dicyclohexylacetamide —— C26H36N4OS
    2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N,N-dicyclohexylacetamide
    —— methyl 2-[[5-(4-chlorophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C27H21ClN2O4S2
    methyl 2-[[5-(4-chlorophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 2-methylpropyl 2-[[4-(diethylamino)phenyl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C30H35N3O3S2
    2-methylpropyl 2-[[4-(diethylamino)phenyl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— methyl 2-[[4-(diethylamino)phenyl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C27H29N3O3S2
    methyl 2-[[4-(diethylamino)phenyl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— N-(2-methoxyethyl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C14H16N2O2S2
    N-(2-methoxyethyl)-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— ethyl N-[2-(2,4-dinitrophenyl)sulfanyl-1,3-benzothiazol-6-yl]carbamate —— C16H12N4O6S2
    ethyl N-[2-(2,4-dinitrophenyl)sulfanyl-1,3-benzothiazol-6-yl]carbamate
    —— 3-(3-chloro-1,2,4-triazol-1-yl)-N-(2-phenylsulfanylphenyl)adamantane-1-carboxamide —— C25H25ClN4OS
    3-(3-chloro-1,2,4-triazol-1-yl)-N-(2-phenylsulfanylphenyl)adamantane-1-carboxamide
    —— 3-Ethyl-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C19H16N2O3S3
    3-Ethyl-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— 2-[2-(azepan-1-yl)-6-methylpyrimidin-4-yl]sulfanyl-N-[(2-chlorophenyl)methylideneamino]acetamide —— C20H24ClN5OS
    2-[2-(azepan-1-yl)-6-methylpyrimidin-4-yl]sulfanyl-N-[(2-chlorophenyl)methylideneamino]acetamide
    —— 2-(6-methyl-1H-benzimidazol-2-yl)-3-(2-phenylsulfanylphenyl)prop-2-enenitrile —— C23H17N3S
    2-(6-methyl-1H-benzimidazol-2-yl)-3-(2-phenylsulfanylphenyl)prop-2-enenitrile
    —— [1-(2,3-Dihydroindol-1-yl)-1-oxopropan-2-yl] 2-[2-nitro-4-(trifluoromethyl)phenyl]sulfanylbenzoate —— C25H19F3N2O5S
    [1-(2,3-Dihydroindol-1-yl)-1-oxopropan-2-yl] 2-[2-nitro-4-(trifluoromethyl)phenyl]sulfanylbenzoate
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(1-propan-2-ylpiperidin-4-ylidene)amino]acetamide —— C18H26BrN3OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(1-propan-2-ylpiperidin-4-ylidene)amino]acetamide
    —— N,N-dibenzyl-2-[[5-(2,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C27H28N4OS2
    N,N-dibenzyl-2-[[5-(2,6-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— Ethyl 5-hydroxy-4,4-dimethyl-1-(trifluoromethyl)-2-oxa-7-thiabicyclo[3.2.1]octane-6-carboxylate —— C12H17F3O4S
    Ethyl 5-hydroxy-4,4-dimethyl-1-(trifluoromethyl)-2-oxa-7-thiabicyclo[3.2.1]octane-6-carboxylate
    —— 4-(4-bromophenyl)sulfanyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran 7,7-dioxide —— C13H11BrO2S3
    4-(4-bromophenyl)sulfanyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran 7,7-dioxide
    —— 2-[[4-(4-Methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-[1,3]thiazolo[3,2-a]benzimidazol-1-one —— C23H15N3O3S2
    2-[[4-(4-Methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-[1,3]thiazolo[3,2-a]benzimidazol-1-one