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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(E)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-2-(4-chlorophenoxy)acetamide —— C22H15ClN4O4S2
    N-[(E)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-2-(4-chlorophenoxy)acetamide
    —— (1S)-2-(4-chlorophenyl)sulfanyl-1-cyclopropyl-N-methylethanamine —— C12H16ClNS
    (1S)-2-(4-chlorophenyl)sulfanyl-1-cyclopropyl-N-methylethanamine
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(E)-1-phenylethylideneamino]acetamide —— C18H19BrN2OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(E)-1-phenylethylideneamino]acetamide
    —— 2,4-dichloro-N-[(E)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide —— C21H11Cl2N5O5S2
    2,4-dichloro-N-[(E)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide
    —— (E)-1-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine —— C16H13N5O2S
    (E)-1-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine
    —— N-[(E)-benzylideneamino]-2-[4,6-bis(methylsulfanyl)pyrimidin-2-yl]sulfanylacetamide —— C15H16N4OS3
    N-[(E)-benzylideneamino]-2-[4,6-bis(methylsulfanyl)pyrimidin-2-yl]sulfanylacetamide
    —— N-[(E)-(3-hydroxyphenyl)methylideneamino]-2-phenylsulfanylpropanamide —— C16H16N2O2S
    N-[(E)-(3-hydroxyphenyl)methylideneamino]-2-phenylsulfanylpropanamide
    —— N-[(E)-(4-bromophenyl)methylideneamino]-2-phenylsulfanylpropanamide —— C16H15BrN2OS
    N-[(E)-(4-bromophenyl)methylideneamino]-2-phenylsulfanylpropanamide
    —— 2-[(2E)-2-{2-[(4-chlorophenyl)sulfanyl]benzylidene}hydrazinyl]-4,6-di(piperidin-1-yl)-1,3,5-triazine —— C26H30ClN7S
    2-[(2E)-2-{2-[(4-chlorophenyl)sulfanyl]benzylidene}hydrazinyl]-4,6-di(piperidin-1-yl)-1,3,5-triazine
    —— N'-((4-BR-2-Thienyl)methylene)2-((5-ME-1,3,4-thiadiazol-2-YL)thio)acetohydrazide —— C10H9BrN4OS3
    N'-((4-BR-2-Thienyl)methylene)2-((5-ME-1,3,4-thiadiazol-2-YL)thio)acetohydrazide
    —— 2-(4,6-Dimethyl-pyrimidin-2-ylsulfanyl)-acetic acid (4-BR-benzylidene)-hydrazide —— C15H15BrN4OS
    2-(4,6-Dimethyl-pyrimidin-2-ylsulfanyl)-acetic acid (4-BR-benzylidene)-hydrazide
    —— (NZ)-N-[4-(4-chlorophenyl)sulfanyl-3-nitro-1,1-dioxo-2H-thiophen-5-ylidene]hydroxylamine —— C10H7ClN2O5S2
    (NZ)-N-[4-(4-chlorophenyl)sulfanyl-3-nitro-1,1-dioxo-2H-thiophen-5-ylidene]hydroxylamine
    —— N-[(E)-[2-(1,3-benzothiazol-2-ylsulfanyl)-9-methyl-4-oxopyrido[1,2-a]pyrimidin-3-yl]methylideneamino]pyridine-4-carboxamide —— C23H16N6O2S2
    N-[(E)-[2-(1,3-benzothiazol-2-ylsulfanyl)-9-methyl-4-oxopyrido[1,2-a]pyrimidin-3-yl]methylideneamino]pyridine-4-carboxamide
    —— (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(5-chloro-2-fluorophenyl)methanimine —— C16H12ClFN4S
    (E)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(5-chloro-2-fluorophenyl)methanimine
    —— N,N-Dimethyl-4-[(E)-{[3-(methylsulfanyl)-4H-1,2,4-triazol-4-YL]imino}methyl]aniline —— C12H15N5S
    N,N-Dimethyl-4-[(E)-{[3-(methylsulfanyl)-4H-1,2,4-triazol-4-YL]imino}methyl]aniline
    —— (E)-1-(2-Fluorophenyl)-N-[3-(methylsulfanyl)-4H-1,2,4-triazol-4-YL]methanimine —— C10H9FN4S
    (E)-1-(2-Fluorophenyl)-N-[3-(methylsulfanyl)-4H-1,2,4-triazol-4-YL]methanimine
    —— 2-(4,6-DI-ME-Pyrimidin-2-ylsulfanyl)-acetic acid pyridin-4-ylmethylene-hydrazide —— C14H15N5OS
    2-(4,6-DI-ME-Pyrimidin-2-ylsulfanyl)-acetic acid pyridin-4-ylmethylene-hydrazide
    —— N,N'-bis[(E)-(4-methylsulfanylphenyl)methylideneamino]heptanediamide —— C23H28N4O2S2
    N,N'-bis[(E)-(4-methylsulfanylphenyl)methylideneamino]heptanediamide
    —— 3-bromo-N-[(E)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide —— C21H12BrN5O5S2
    3-bromo-N-[(E)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide
    —— 6-Tert-butyl-4-((2-furylmethylene)amino)-3-(methylthio)-1,2,4-triazin-5(4H)-one —— C13H16N4O2S
    6-Tert-butyl-4-((2-furylmethylene)amino)-3-(methylthio)-1,2,4-triazin-5(4H)-one
    —— N'-{(E)-[4-(diethylamino)phenyl]methylidene}-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetohydrazide —— C16H21N5OS2
    N'-{(E)-[4-(diethylamino)phenyl]methylidene}-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetohydrazide
    —— 3-[(E)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]quinazolin-4-one —— C21H13ClN4O3S
    3-[(E)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]quinazolin-4-one
    —— 2-(4,5-dichloropyridin-2-yl)sulfanyl-N-[(E)-furan-2-ylmethylideneamino]acetamide —— C12H9Cl2N3O2S
    2-(4,5-dichloropyridin-2-yl)sulfanyl-N-[(E)-furan-2-ylmethylideneamino]acetamide
    —— N,N-dimethyl-N'-[3-methyl-4-(2-nitrophenyl)sulfanyl-1,2-oxazol-5-yl]methanimidamide —— C13H14N4O3S
    N,N-dimethyl-N'-[3-methyl-4-(2-nitrophenyl)sulfanyl-1,2-oxazol-5-yl]methanimidamide
    —— 2-(4,5-dichloropyridin-2-yl)sulfanyl-N-[(E)-pyridin-3-ylmethylideneamino]acetamide —— C13H10Cl2N4OS
    2-(4,5-dichloropyridin-2-yl)sulfanyl-N-[(E)-pyridin-3-ylmethylideneamino]acetamide
    —— 3-nitro-N'-{(E)-[4-oxo-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-3-yl]methylidene}benzohydrazide —— C22H15N5O4S
    3-nitro-N'-{(E)-[4-oxo-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-3-yl]methylidene}benzohydrazide
    —— 1-benzyl-3-[(E)-(4-methylsulfanylphenyl)methylideneamino]thiourea —— C16H17N3S2
    1-benzyl-3-[(E)-(4-methylsulfanylphenyl)methylideneamino]thiourea
    —— 1-[(E)-(4-oxo-2-phenylsulfanylpyrido[1,2-a]pyrimidin-3-yl)methylideneamino]-3-prop-2-enylthiourea —— C19H17N5OS2
    1-[(E)-(4-oxo-2-phenylsulfanylpyrido[1,2-a]pyrimidin-3-yl)methylideneamino]-3-prop-2-enylthiourea
    —— 3-chloro-4-methyl-N-[(E)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]aniline —— C18H14ClN5O2S
    3-chloro-4-methyl-N-[(E)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]aniline
    —— 1-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-(oxolan-2-ylmethyl)thiourea —— C14H19N3OS2
    1-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-(oxolan-2-ylmethyl)thiourea
    —— N'-[(E)-(2-hydroxyphenyl)methylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C19H18N4O2S3
    N'-[(E)-(2-hydroxyphenyl)methylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(E)-pyridin-3-ylmethylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C18H14ClN9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(E)-pyridin-3-ylmethylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(2-chlorophenyl)ethylidene]-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide —— C21H19ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(2-chlorophenyl)ethylidene]-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-5-propyl-1H-1,2,3-triazole-4-carbohydrazide —— C16H18N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-5-propyl-1H-1,2,3-triazole-4-carbohydrazide
    —— 4-methyl-N-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-3-nitrobenzenesulfonamide —— C17H15N7O6S2
    4-methyl-N-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-3-nitrobenzenesulfonamide
    —— N'-[(1E)-1-(4-fluorophenyl)ethylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide —— C14H13FN4OS
    N'-[(1E)-1-(4-fluorophenyl)ethylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide
    —— 5-fluoro-4-morpholin-4-yl-N-[(E)-(5-phenylsulfanylfuran-2-yl)methylideneamino]pyrimidin-2-amine —— C19H18FN5O2S
    5-fluoro-4-morpholin-4-yl-N-[(E)-(5-phenylsulfanylfuran-2-yl)methylideneamino]pyrimidin-2-amine
    —— (E)-({5-[(4-chlorophenyl)sulfanyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl}methylidene)amino 2-methylpropanoate —— C16H15ClF3N3O2S
    (E)-({5-[(4-chlorophenyl)sulfanyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl}methylidene)amino 2-methylpropanoate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(4-cyclohexylphenyl)ethylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C26H28N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(4-cyclohexylphenyl)ethylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— N'-[(E)-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]-3-(dimethylamino)benzohydrazide —— C20H17BrClN3O2S
    N'-[(E)-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]-3-(dimethylamino)benzohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(5-methylfuran-2-yl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C18H16N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(5-methylfuran-2-yl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— N-[(E)-1-(3-bromophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H19BrN4OS3
    N-[(E)-1-(3-bromophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N'-[(E)-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]pyridine-3-carbohydrazide —— C17H11BrClN3O2S
    N'-[(E)-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]pyridine-3-carbohydrazide
    —— (E)-({5-[(4-chlorophenyl)sulfanyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl}methylidene)amino 2,4-dichlorobenzoate —— C19H11Cl3F3N3O2S
    (E)-({5-[(4-chlorophenyl)sulfanyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl}methylidene)amino 2,4-dichlorobenzoate
    —— 5-[(4-chlorophenyl)sulfanyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazole-4-carbaldehyde O-methyloxime —— C13H11ClF3N3OS
    5-[(4-chlorophenyl)sulfanyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazole-4-carbaldehyde O-methyloxime
    —— N-(benzoyloxy)-N-{[5-[(4-chlorophenyl)sulfanyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methylene}amine —— C19H13ClF3N3O2S
    N-(benzoyloxy)-N-{[5-[(4-chlorophenyl)sulfanyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methylene}amine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(2-chlorophenyl)ethylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide —— C17H16ClN11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(2-chlorophenyl)ethylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide
    —— 2-(4-fluorophenyl)-N-[(E)-(2-phenylsulfanylphenyl)methylideneamino]acetamide —— C21H17FN2OS
    2-(4-fluorophenyl)-N-[(E)-(2-phenylsulfanylphenyl)methylideneamino]acetamide
    —— 2-[(3-methoxyphenyl)sulfanyl]-5-nitrobenzenecarbaldehyde O-methyloxime —— C15H14N2O4S
    2-[(3-methoxyphenyl)sulfanyl]-5-nitrobenzenecarbaldehyde O-methyloxime
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(5-methylthiophen-2-yl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C18H16N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(5-methylthiophen-2-yl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide