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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(5-amino-3-methylthio-1H-1,2,4-triazol-1-yl)-5-benzylthio-1,3,4-thiadiazole —— C12H12N6S3
    2-(5-amino-3-methylthio-1H-1,2,4-triazol-1-yl)-5-benzylthio-1,3,4-thiadiazole
    —— 3-[(4-Chlorobenzyl)sulfanyl]-6-phenyl-1,2,4-triazin-5-ol —— C16H12ClN3OS
    3-[(4-Chlorobenzyl)sulfanyl]-6-phenyl-1,2,4-triazin-5-ol
    —— (2-benzyl-6,7-dihydro-5H-[1,2,4]triazolo[5,1-b][1,3]thiazin-6-yl) methanesulfonate —— C13H15N3O3S2
    (2-benzyl-6,7-dihydro-5H-[1,2,4]triazolo[5,1-b][1,3]thiazin-6-yl) methanesulfonate
    —— 2,6-Dimethyl-3,5-bis(methylsulfanyl)-1,2,4-triazin-2-ium —— C7H12N3S2+
    2,6-Dimethyl-3,5-bis(methylsulfanyl)-1,2,4-triazin-2-ium
    —— ethyl 2-[(5-oxo-6-phenyl-4H-1,2,4-triazin-3-yl)sulfanyl]butanoate —— C15H17N3O3S
    ethyl 2-[(5-oxo-6-phenyl-4H-1,2,4-triazin-3-yl)sulfanyl]butanoate
    —— 8a-Phenyl-2,3,5,6,7,8-hexahydro-[1,3]dithiolo[1,2-a]thiopyran-4-ium;bromide —— C13H17BrS2
    8a-Phenyl-2,3,5,6,7,8-hexahydro-[1,3]dithiolo[1,2-a]thiopyran-4-ium;bromide
    —— 8a-Phenyl-2,3,5,6,7,8-hexahydro-[1,3]dithiolo[1,2-a]thiopyran-4-ium —— C13H17S2+
    8a-Phenyl-2,3,5,6,7,8-hexahydro-[1,3]dithiolo[1,2-a]thiopyran-4-ium
    —— zinc;(6E)-6-(1H-[1,3]thiazolo[5,4-b]pyridin-2-ylidene)cyclohexa-2,4-diene-1-thione —— C12H8N2S2Zn+2
    zinc;(6E)-6-(1H-[1,3]thiazolo[5,4-b]pyridin-2-ylidene)cyclohexa-2,4-diene-1-thione
    —— 3-[2-(5-hydroxy-3,5-dimethyl-4H-pyrazol-1-yl)-2-oxoethyl]-6-methyl-2-methylsulfanylpyrimidin-4-one —— C13H18N4O3S
    3-[2-(5-hydroxy-3,5-dimethyl-4H-pyrazol-1-yl)-2-oxoethyl]-6-methyl-2-methylsulfanylpyrimidin-4-one
    —— 2-endo-(Hydroxymethyl)-3-exo-((methoxymethoxy)methyl)-5-(phenylsulfenyl)-7-oxabicyclo<2.2.1>hept-5-ene —— C16H20O4S
    2-endo-(Hydroxymethyl)-3-exo-((methoxymethoxy)methyl)-5-(phenylsulfenyl)-7-oxabicyclo<2.2.1>hept-5-ene
    —— spiro<12-methyl-2-thiatricyclo<6.3.1.0<sup>4,12</sup>>dodeca-3,7-diene-9,2'-<1',3'>dithiane> —— C15H20S3
    spiro<12-methyl-2-thiatricyclo<6.3.1.0<sup>4,12</sup>>dodeca-3,7-diene-9,2'-<1',3'>dithiane>
    —— (1aS,3aR,7aR)-2,3a,7,7-tetramethyl-2-phenylsulfanyl-1,1a,3,4,5,6-hexahydrocyclopropa[i]indene —— C20H28S
    (1aS,3aR,7aR)-2,3a,7,7-tetramethyl-2-phenylsulfanyl-1,1a,3,4,5,6-hexahydrocyclopropa[i]indene
    —— 6-(Pyridin-2-ylsulfanyl)-2-trifluoromethyl-1H-benzoimidazole —— C13H8F3N3S
    6-(Pyridin-2-ylsulfanyl)-2-trifluoromethyl-1H-benzoimidazole
    —— 1-Methyl-4-((Z)-1-nitro-4-phenyl-but-1-enylsulfanyl)-benzene —— C17H17NO2S
    1-Methyl-4-((Z)-1-nitro-4-phenyl-but-1-enylsulfanyl)-benzene
    —— ethyl (E)-4-[4-(dimethylamino)phenyl]sulfanyl-2-methylpent-2-enoate —— C16H23NO2S
    ethyl (E)-4-[4-(dimethylamino)phenyl]sulfanyl-2-methylpent-2-enoate
    —— 2,2-Bis(phenylsulfanyl)oxolane —— C16H16OS2
    2,2-Bis(phenylsulfanyl)oxolane
    —— 1-methyl-3-methylsulfanyl-4H-1,2,4-triazin-1-ium-5-one —— C5H8N3OS+
    1-methyl-3-methylsulfanyl-4H-1,2,4-triazin-1-ium-5-one
    —— 4,5-dihydro-1-methyl-3-methylthio-5-oxo-1,2,4-triazonium iodide —— C5H8N3OS*I
    4,5-dihydro-1-methyl-3-methylthio-5-oxo-1,2,4-triazonium iodide
    —— (2-Phenylsulfanylphenyl)-pyrrolidin-1-yldiazene —— C16H17N3S
    (2-Phenylsulfanylphenyl)-pyrrolidin-1-yldiazene
    —— (3-Methyl-2-phenylsulfanyl-but-1-enylidene)-p-tolyl-amine —— C18H19NS
    (3-Methyl-2-phenylsulfanyl-but-1-enylidene)-p-tolyl-amine
    —— 1-(2-Methylphenyl)sulfanyl-4-morpholin-4-ylbutan-2-one —— C15H21NO2S
    1-(2-Methylphenyl)sulfanyl-4-morpholin-4-ylbutan-2-one
    —— Tert-butyl-dimethyl-(2-phenylsulfanylethenoxy)silane —— C14H22OSSi
    Tert-butyl-dimethyl-(2-phenylsulfanylethenoxy)silane
    —— 2-<6'-(ethynyloxy)hexyl>-2-methyl-1,3-dithiane —— C13H22OS2
    2-<6'-(ethynyloxy)hexyl>-2-methyl-1,3-dithiane
    —— trans-4-Thiophenoxy-1,1,1-trifluoro-3-buten-2-one —— C10H7F3OS
    trans-4-Thiophenoxy-1,1,1-trifluoro-3-buten-2-one
    —— (5r,6t)-5,6-epoxy-5-methyl-1-hepten-3-yl phenyl sulfide —— C14H18OS
    (5r,6t)-5,6-epoxy-5-methyl-1-hepten-3-yl phenyl sulfide
    —— 2,3,4,5,6,7-Hexahydro-8H-1,8-benzothiazecine-8-carboxaldehyde —— C13H17NOS
    2,3,4,5,6,7-Hexahydro-8H-1,8-benzothiazecine-8-carboxaldehyde
    —— (4S)-4-[(1R)-1-deuterioethyl]-4-[(3R)-4-hydroxy-3-methylbutyl]-1,3-dioxolane-2-thione —— C10H18O3S
    (4S)-4-[(1R)-1-deuterioethyl]-4-[(3R)-4-hydroxy-3-methylbutyl]-1,3-dioxolane-2-thione
    —— 1-(allenylthio)-2,5,5-trimethyl-3-vinyl-2-cyclohexene —— C14H20S
    1-(allenylthio)-2,5,5-trimethyl-3-vinyl-2-cyclohexene
    —— (2R,3S)-2-<(methylsulfonyl)methyl>-3-propyloxirane —— C7H14O3S
    (2R,3S)-2-<(methylsulfonyl)methyl>-3-propyloxirane
    —— (S)-9-Methyl-8-oxa-1,4-dithia-spiro[4.5]decan-7-ol —— C8H14O2S2
    (S)-9-Methyl-8-oxa-1,4-dithia-spiro[4.5]decan-7-ol
    —— 2-[(Z)-prop-1-enyl]oxocane-2-thiol —— C10H18OS
    2-[(Z)-prop-1-enyl]oxocane-2-thiol
    —— 1-Octyl-4-[10-(1-octylpyridin-1-ium-4-yl)sulfanyldecylsulfanyl]pyridin-1-ium —— C36H62N2S2+2
    1-Octyl-4-[10-(1-octylpyridin-1-ium-4-yl)sulfanyldecylsulfanyl]pyridin-1-ium
    —— Methyl 5-[4-[(5-methoxycarbonyl-1,3-dithiol-3-ium-4-yl)sulfanyl]butylsulfanyl]-1,3-dithiol-1-ium-4-carboxylate;diperchlorate —— C14H16Cl2O12S6
    Methyl 5-[4-[(5-methoxycarbonyl-1,3-dithiol-3-ium-4-yl)sulfanyl]butylsulfanyl]-1,3-dithiol-1-ium-4-carboxylate;diperchlorate
    —— Methyl 5-[4-[(5-methoxycarbonyl-1,3-dithiol-3-ium-4-yl)sulfanyl]butylsulfanyl]-1,3-dithiol-1-ium-4-carboxylate —— C14H16O4S6+2
    Methyl 5-[4-[(5-methoxycarbonyl-1,3-dithiol-3-ium-4-yl)sulfanyl]butylsulfanyl]-1,3-dithiol-1-ium-4-carboxylate
    —— [5-(3,5-Dichlorophenyl)sulfanyl-1-[[3-(diethoxyphosphorylmethoxy)phenyl]methyl]-4-propan-2-ylimidazol-2-yl]methyl carbamate —— C26H32Cl2N3O6PS
    [5-(3,5-Dichlorophenyl)sulfanyl-1-[[3-(diethoxyphosphorylmethoxy)phenyl]methyl]-4-propan-2-ylimidazol-2-yl]methyl carbamate
    —— prop-2-enylcarbamothioic S-acid —— C4H7NOS
    prop-2-enylcarbamothioic S-acid
    —— 5-(2,6-dichlorophenyl)sulfanyl-N-[3-[(3R)-1-methylpyrrolidin-3-yl]oxy-4-(trifluoromethyl)phenyl]thiophene-2-sulfonamide —— C22H19Cl2F3N2O3S3
    5-(2,6-dichlorophenyl)sulfanyl-N-[3-[(3R)-1-methylpyrrolidin-3-yl]oxy-4-(trifluoromethyl)phenyl]thiophene-2-sulfonamide
    —— 4-bromo-N-[4-chloro-3-[(3R)-1-methylpyrrolidin-3-yl]oxyphenyl]-5-(4-fluorophenyl)sulfanylthiophene-2-sulfonamide —— C21H19BrClFN2O3S3
    4-bromo-N-[4-chloro-3-[(3R)-1-methylpyrrolidin-3-yl]oxyphenyl]-5-(4-fluorophenyl)sulfanylthiophene-2-sulfonamide
    —— (3-{4-[3-phenethyl-1-(3-phenylpropyl)ureido]phenylsulphanyl}phenyl)acetic acid 735273-63-9 C32H32N2O3S
    (3-{4-[3-phenethyl-1-(3-phenylpropyl)ureido]phenylsulphanyl}phenyl)acetic acid
    —— (1'S,8'aS)-1'-[tert-butyl(diphenyl)silyl]oxy-8'a-methylspiro[1,3-dithiolane-2,6'-3,4,7,8-tetrahydro-2H-naphthalene]-1'-carbonitrile —— C30H37NOS2Si
    (1'S,8'aS)-1'-[tert-butyl(diphenyl)silyl]oxy-8'a-methylspiro[1,3-dithiolane-2,6'-3,4,7,8-tetrahydro-2H-naphthalene]-1'-carbonitrile
    —— {3-[3-(1,3-diphenethylureido)phenylsulphanyl]phenyl}acetic acid 735273-88-8 C31H30N2O3S
    {3-[3-(1,3-diphenethylureido)phenylsulphanyl]phenyl}acetic acid
    —— [3-[4-[Butylcarbamoyl(3-phenylpropyl)amino]phenyl]sulfanylphenyl] butanoate —— C30H36N2O3S
    [3-[4-[Butylcarbamoyl(3-phenylpropyl)amino]phenyl]sulfanylphenyl] butanoate
    —— [(E)-1-(4-methylphenyl)sulfanyl-5-trimethylsilyl-3,3-bis(2-trimethylsilylethynyl)pent-1-en-4-ynyl]diazene —— C25H36N2SSi3
    [(E)-1-(4-methylphenyl)sulfanyl-5-trimethylsilyl-3,3-bis(2-trimethylsilylethynyl)pent-1-en-4-ynyl]diazene
    —— Ethyl 2-[4-[3-[3-phenylpropyl(prop-2-enylcarbamoyl)amino]phenyl]sulfanylphenyl]acetate —— C29H32N2O3S
    Ethyl 2-[4-[3-[3-phenylpropyl(prop-2-enylcarbamoyl)amino]phenyl]sulfanylphenyl]acetate
    —— {3-[4-(3-benzyl-1-heptylureido)phenylsulphanyl]phenyl}acetic acid 735273-96-8 C29H34N2O3S
    {3-[4-(3-benzyl-1-heptylureido)phenylsulphanyl]phenyl}acetic acid
    —— {4-[3-(1-phenethyl-3-phenylureido)phenylsulphanyl]phenyl}acetic acid —— C29H26N2O3S
    {4-[3-(1-phenethyl-3-phenylureido)phenylsulphanyl]phenyl}acetic acid
    —— N-{6-{[(1R)-2-hydroxy-1-methylethyl]amino}-2-[(2,3,4-trifluorobenzyl)thio]pyrimidin-4-yl}azetidine-1-sulfonamide —— C17H20F3N5O3S2
    N-{6-{[(1R)-2-hydroxy-1-methylethyl]amino}-2-[(2,3,4-trifluorobenzyl)thio]pyrimidin-4-yl}azetidine-1-sulfonamide
    —— lithium;5-[[3,4-dimethoxy-2-(methoxymethoxy)phenyl]-(methoxymethoxy)methyl]-1-methyl-2-phenylsulfanyl-4H-imidazol-4-ide —— C23H27LiN2O6S
    lithium;5-[[3,4-dimethoxy-2-(methoxymethoxy)phenyl]-(methoxymethoxy)methyl]-1-methyl-2-phenylsulfanyl-4H-imidazol-4-ide
    —— 2-[4-Tert-butyl-5-(2,4-dichlorophenyl)sulfanyl-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-6-yl]acetic acid —— C23H24Cl2N2O2S
    2-[4-Tert-butyl-5-(2,4-dichlorophenyl)sulfanyl-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-6-yl]acetic acid
    —— {3-[4-(3-butyl-1-heptylureido)phenylsulphanyl]phenyl}acetic acid 735274-20-1 C26H36N2O3S
    {3-[4-(3-butyl-1-heptylureido)phenylsulphanyl]phenyl}acetic acid