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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(tert-butylthio)benzaldehyde oxime —— C11H15NOS
    2-(tert-butylthio)benzaldehyde oxime
    —— N,N-dimethyl-N'-[3-(3-nitropyridin-2-yl)sulfanyl-1H-1,2,4-triazol-5-yl]methanimidamide —— C10H11N7O2S
    N,N-dimethyl-N'-[3-(3-nitropyridin-2-yl)sulfanyl-1H-1,2,4-triazol-5-yl]methanimidamide
    —— N'-[3-(2-chloro-6-nitrophenyl)sulfanyl-1H-1,2,4-triazol-5-yl]-N,N-dimethylmethanimidamide —— C11H11ClN6O2S
    N'-[3-(2-chloro-6-nitrophenyl)sulfanyl-1H-1,2,4-triazol-5-yl]-N,N-dimethylmethanimidamide
    —— N,N-dimethyl-N'-[5-(3-nitropyridin-2-yl)sulfanyl-1,3,4-thiadiazol-2-yl]methanimidamide —— C10H10N6O2S2
    N,N-dimethyl-N'-[5-(3-nitropyridin-2-yl)sulfanyl-1,3,4-thiadiazol-2-yl]methanimidamide
    —— 1-[(E)-(2-tert-butylsulfanylphenyl)methylideneamino]-3-(2-methylbutan-2-yl)thiourea —— C17H27N3S2
    1-[(E)-(2-tert-butylsulfanylphenyl)methylideneamino]-3-(2-methylbutan-2-yl)thiourea
    —— (E)-6-methyl-5-(2-(4-(methylthio)benzylidene)hydrazinyl)-1,2,4-triazin-3(2H)-one —— C12H13N5OS
    (E)-6-methyl-5-(2-(4-(methylthio)benzylidene)hydrazinyl)-1,2,4-triazin-3(2H)-one
    —— 2-[(4-chlorophenyl)sulfanyl]-2-methylpropanal O-methyloxime —— C11H14ClNOS
    2-[(4-chlorophenyl)sulfanyl]-2-methylpropanal O-methyloxime
    —— 2-methyl-2-(phenylsulfanyl)propanal O-methyloxime —— C11H15NOS
    2-methyl-2-(phenylsulfanyl)propanal O-methyloxime
    —— (E)-N-[2-methyl-2-(phenylsulfanyl)propylidene]hydroxylamine —— C10H13NOS
    (E)-N-[2-methyl-2-(phenylsulfanyl)propylidene]hydroxylamine
    —— 3-nitro-4-{[3-(trifluoromethyl)phenyl]sulfanyl}benzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime —— C21H13Cl2F3N2O3S
    3-nitro-4-{[3-(trifluoromethyl)phenyl]sulfanyl}benzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime
    —— 4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(3,4-dichlorobenzyl)oxime —— C20H13Cl3N2O3S
    4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(3,4-dichlorobenzyl)oxime
    —— 4-[(4-methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-methyloxime —— C15H14N2O3S
    4-[(4-methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-methyloxime
    —— [(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea —— C14H10ClF3N4S2
    [(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea
    —— (E)-1-(4-chlorophenyl)-2-(4-chlorophenyl)sulfanyl-N-methoxyethanimine —— C15H13Cl2NOS
    (E)-1-(4-chlorophenyl)-2-(4-chlorophenyl)sulfanyl-N-methoxyethanimine
    —— 4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,4-dichlorobenzyl)oxime —— C20H13Cl3N2O3S
    4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,4-dichlorobenzyl)oxime
    —— 1-tert-butyl-3-[(E)-[2-[(4-chlorophenyl)methylsulfanyl]pyrimidin-4-yl]methylideneamino]thiourea —— C17H20ClN5S2
    1-tert-butyl-3-[(E)-[2-[(4-chlorophenyl)methylsulfanyl]pyrimidin-4-yl]methylideneamino]thiourea
    —— 4-[(4-Chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde oxime —— C13H9ClN2O3S
    4-[(4-Chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde oxime
    —— N,N-dimethyl-N'-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]methanimidamide —— C13H16N4S2
    N,N-dimethyl-N'-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]methanimidamide
    —— N'-(5-hexylsulfanyl-1,3,4-thiadiazol-2-yl)-N,N-dimethylmethanimidamide —— C11H20N4S2
    N'-(5-hexylsulfanyl-1,3,4-thiadiazol-2-yl)-N,N-dimethylmethanimidamide
    —— N,N-dimethyl-N'-(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)methanimidamide —— C8H14N4S2
    N,N-dimethyl-N'-(5-propylsulfanyl-1,3,4-thiadiazol-2-yl)methanimidamide
    —— 1-tert-butyl-3-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea —— C18H18ClF3N4S2
    1-tert-butyl-3-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea
    —— 3-(methylsulfanyl)-N-[(E)-thiophen-2-ylmethylidene]-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine —— C9H8N6S2
    3-(methylsulfanyl)-N-[(E)-thiophen-2-ylmethylidene]-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine
    —— 2-Methyl-N'-[(E)-[5-(pyridin-2-ylsulfanyl)furan-2-YL]methylidene]benzohydrazide —— C18H15N3O2S
    2-Methyl-N'-[(E)-[5-(pyridin-2-ylsulfanyl)furan-2-YL]methylidene]benzohydrazide
    —— (NE)-N-(5,6-dihydrothieno[2,3-b]thiopyran-4-ylidene)hydroxylamine —— C7H7NOS2
    (NE)-N-(5,6-dihydrothieno[2,3-b]thiopyran-4-ylidene)hydroxylamine
    —— N-{(E)-[5-(quinolin-8-ylsulfanyl)furan-2-yl]methylidene}-4H-1,2,4-triazol-4-amine —— C16H11N5OS
    N-{(E)-[5-(quinolin-8-ylsulfanyl)furan-2-yl]methylidene}-4H-1,2,4-triazol-4-amine
    —— 2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-N'-[(E)-thiophen-2-ylmethylidene]acetohydrazide —— C13H14N4OS2
    2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-N'-[(E)-thiophen-2-ylmethylidene]acetohydrazide
    —— N'-[(E)-(3-chlorophenyl)methylidene]-2-(phenylsulfanyl)acetohydrazide —— C15H13ClN2OS
    N'-[(E)-(3-chlorophenyl)methylidene]-2-(phenylsulfanyl)acetohydrazide
    —— [4-Bromo-5-(4-chlorophenylthio)(2-furyl)](hydroxyimino)methane —— C11H7BrClNO2S
    [4-Bromo-5-(4-chlorophenylthio)(2-furyl)](hydroxyimino)methane
    —— {[5-Ethylthio-4-((hydroxyimino)methyl)(2-thienyl)]methyl}dimethylamine —— C10H16N2OS2
    {[5-Ethylthio-4-((hydroxyimino)methyl)(2-thienyl)]methyl}dimethylamine
    —— N-[(E)-furan-2-ylmethylidene]-3-(methylsulfanyl)-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine —— C9H8N6OS
    N-[(E)-furan-2-ylmethylidene]-3-(methylsulfanyl)-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine
    —— 2-[(2-methylphenyl)sulfanyl]-N'-[(E)-(6-methylpyridin-2-yl)methylidene]acetohydrazide —— C16H17N3OS
    2-[(2-methylphenyl)sulfanyl]-N'-[(E)-(6-methylpyridin-2-yl)methylidene]acetohydrazide
    —— N-[(E)-[4-(m-tolyl)-3-phenyl-thiazol-2-ylidene]amino]-2-[[5-(2-pyridyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C25H20N6OS3
    N-[(E)-[4-(m-tolyl)-3-phenyl-thiazol-2-ylidene]amino]-2-[[5-(2-pyridyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N'-[(E)-(2-tert-butylsulfanylphenyl)methyleneamino]pyridine-2-carboxamidine —— C17H20N4S
    N'-[(E)-(2-tert-butylsulfanylphenyl)methyleneamino]pyridine-2-carboxamidine
    —— 1-(amino-lambda4-sulfanylidyne)-N-[(E)-1-(4-chlorophenyl)sulfanylpropan-2-ylideneamino]methanamine —— C10H12ClN3S2
    1-(amino-lambda4-sulfanylidyne)-N-[(E)-1-(4-chlorophenyl)sulfanylpropan-2-ylideneamino]methanamine
    —— (6E)-4-amino-3-[(4-nitrophenyl)diazenyl]-5-oxo-6-[[4-[4-[2-(4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2,7-disulfonic acid —— C34H24N8O10S3
    (6E)-4-amino-3-[(4-nitrophenyl)diazenyl]-5-oxo-6-[[4-[4-[2-(4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2,7-disulfonic acid
    —— 2-nitro-N'-{3-nitro-4-[(1-methyl-1H-imidazol-2-yl)sulfanyl]benzylidene}benzohydrazide —— C18H14N6O5S
    2-nitro-N'-{3-nitro-4-[(1-methyl-1H-imidazol-2-yl)sulfanyl]benzylidene}benzohydrazide
    —— (E)-1-phenyl-N-(5-phenylsulfanyl-1H-indol-2-yl)methanimine —— C21H16N2S
    (E)-1-phenyl-N-(5-phenylsulfanyl-1H-indol-2-yl)methanimine
    —— N'-[(E)-{4-[(1-methyl-1H-imidazol-2-yl)sulfanyl]-3-nitrophenyl}methylidene]-2-(naphthalen-1-yl)acetohydrazide —— C23H19N5O3S
    N'-[(E)-{4-[(1-methyl-1H-imidazol-2-yl)sulfanyl]-3-nitrophenyl}methylidene]-2-(naphthalen-1-yl)acetohydrazide
    —— 1-amino-3-[(E)-heptan-2-ylideneamino]thiourea —— C8H18N4S
    1-amino-3-[(E)-heptan-2-ylideneamino]thiourea
    —— 1-amino-3-[(E)-butan-2-ylideneamino]thiourea —— C5H12N4S
    1-amino-3-[(E)-butan-2-ylideneamino]thiourea
    —— 1-amino-3-[(E)-octan-2-ylideneamino]thiourea —— C9H20N4S
    1-amino-3-[(E)-octan-2-ylideneamino]thiourea
    —— S-methyl (2E)-5-benzylsulfanyl-2-methylsulfanylcarbonylimino-1,3,4-thiadiazole-3-carbothioate;S-methyl 5-benzylsulfanyl-2-propanoylimino-1,3,4-thiadiazole-3-carbothioate —— C27H28N6O4S7
    S-methyl (2E)-5-benzylsulfanyl-2-methylsulfanylcarbonylimino-1,3,4-thiadiazole-3-carbothioate;S-methyl 5-benzylsulfanyl-2-propanoylimino-1,3,4-thiadiazole-3-carbothioate
    —— (3E)-3-[[4-[4-[(2E)-2-(3-carboxy-4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]-2-sulfophenyl]sulfanyl-3-sulfophenyl]hydrazinylidene]-6-oxocyclohexa-1,4-diene-1-carboxylic acid —— C26H18N4O12S3
    (3E)-3-[[4-[4-[(2E)-2-(3-carboxy-4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]-2-sulfophenyl]sulfanyl-3-sulfophenyl]hydrazinylidene]-6-oxocyclohexa-1,4-diene-1-carboxylic acid
    —— N-[(E)-1-(2-chlorophenyl)ethylideneamino]-2-[(3-methyl-1H-1,2,4-triazol-5-yl)sulfanyl]acetamide —— C13H14ClN5OS
    N-[(E)-1-(2-chlorophenyl)ethylideneamino]-2-[(3-methyl-1H-1,2,4-triazol-5-yl)sulfanyl]acetamide
    —— 2-morpholino-N-[(Z)-[2-oxo-2-(4-phenylsulfanylphenyl)ethylidene]amino]acetamide —— C20H21N3O3S
    2-morpholino-N-[(Z)-[2-oxo-2-(4-phenylsulfanylphenyl)ethylidene]amino]acetamide
    —— N-[(Z)-[2-oxo-2-(4-phenylsulfanylphenyl)ethylidene]amino]-2-(1-piperidyl)acetamide —— C21H23N3O2S
    N-[(Z)-[2-oxo-2-(4-phenylsulfanylphenyl)ethylidene]amino]-2-(1-piperidyl)acetamide
    —— N'-[(E)-(2-Chlorophenyl)methylidene]-2-(pyrimidin-2-ylsulfanyl)propanehydrazide —— C14H13ClN4OS
    N'-[(E)-(2-Chlorophenyl)methylidene]-2-(pyrimidin-2-ylsulfanyl)propanehydrazide
    —— N,N-dimethyl-N'-[1-methyl-5-(5-nitropyridin-2-yl)sulfanyl-1,2,4-triazol-3-yl]methanimidamide —— C11H13N7O2S
    N,N-dimethyl-N'-[1-methyl-5-(5-nitropyridin-2-yl)sulfanyl-1,2,4-triazol-3-yl]methanimidamide
    —— 3-chloro-N'-{(E)-[3-nitro-4-(4H-1,2,4-triazol-3-ylsulfanyl)phenyl]methylidene}benzohydrazide —— C16H11ClN6O3S
    3-chloro-N'-{(E)-[3-nitro-4-(4H-1,2,4-triazol-3-ylsulfanyl)phenyl]methylidene}benzohydrazide
    —— 2-(1,3-benzothiazol-2-ylsulfanyl)-3-[(E)-(tert-butylhydrazinylidene)methyl]-9-methylpyrido[1,2-a]pyrimidin-4-one —— C21H21N5OS2
    2-(1,3-benzothiazol-2-ylsulfanyl)-3-[(E)-(tert-butylhydrazinylidene)methyl]-9-methylpyrido[1,2-a]pyrimidin-4-one