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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-butyl-1-[5,5-dimethyl-3-({(E)-[4-(methylsulfanyl)phenyl]methylidene}amino)-2-thioxo-1,3-thiazolidin-4-yl]-1-hydroxyurea —— C18H26N4O2S3
    3-butyl-1-[5,5-dimethyl-3-({(E)-[4-(methylsulfanyl)phenyl]methylidene}amino)-2-thioxo-1,3-thiazolidin-4-yl]-1-hydroxyurea
    —— 2-(2-amino-1,3-thiazol-4-yl)-N-[(E)-(2-methylsulfanylthiophen-3-yl)methylideneamino]acetamide —— C11H12N4OS3
    2-(2-amino-1,3-thiazol-4-yl)-N-[(E)-(2-methylsulfanylthiophen-3-yl)methylideneamino]acetamide
    —— 3-chloro-N'-[(E)-{4-[(4-chlorophenyl)sulfanyl]-3-nitrophenyl}methylidene]benzohydrazide —— C20H13Cl2N3O3S
    3-chloro-N'-[(E)-{4-[(4-chlorophenyl)sulfanyl]-3-nitrophenyl}methylidene]benzohydrazide
    —— 2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1E)-1-(furan-2-yl)ethylidene]acetohydrazide —— C17H15ClN4O2S3
    2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1E)-1-(furan-2-yl)ethylidene]acetohydrazide
    —— N'-[(E)-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]acetohydrazide —— C13H11ClN2O2S
    N'-[(E)-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]acetohydrazide
    —— 2-(2-methylphenoxy)-N-[(E)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]acetamide —— C23H17N5O6S2
    2-(2-methylphenoxy)-N-[(E)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]acetamide
    —— N-[(E)-(4-bromophenyl)methylideneamino]-2-(2-ethylsulfanyl-6-methylpyrimidin-4-yl)oxyacetamide —— C16H17BrN4O2S
    N-[(E)-(4-bromophenyl)methylideneamino]-2-(2-ethylsulfanyl-6-methylpyrimidin-4-yl)oxyacetamide
    —— (E)-N-(3-methylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)-1-pyridin-3-ylmethanimine —— C10H9N7S
    (E)-N-(3-methylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)-1-pyridin-3-ylmethanimine
    —— N-[(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]benzamide —— C19H14N4O2S
    N-[(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]benzamide
    —— 2-[(E)-[2-(4,6-dimethoxypyrimidin-2-yl)sulfanylphenyl]methylideneamino]oxy-N-[(2-methylphenyl)methyl]propanamide —— C24H26N4O4S
    2-[(E)-[2-(4,6-dimethoxypyrimidin-2-yl)sulfanylphenyl]methylideneamino]oxy-N-[(2-methylphenyl)methyl]propanamide
    —— 2-({4-allyl-5-[(4-chloroanilino)methyl]-4H-1,2,4-triazol-3-yl}sulfanyl)-N'-(2-chlorobenzylidene)propanohydrazide —— C22H22Cl2N6OS
    2-({4-allyl-5-[(4-chloroanilino)methyl]-4H-1,2,4-triazol-3-yl}sulfanyl)-N'-(2-chlorobenzylidene)propanohydrazide
    —— 4-amino-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-1,2,5-oxadiazole-3-carboxamide —— C11H11N5O2S
    4-amino-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-1,2,5-oxadiazole-3-carboxamide
    —— N-[(E)-(4-chlorophenyl)methylideneamino]-2-(6-methyl-2-methylsulfanylpyrimidin-4-yl)oxyacetamide —— C15H15ClN4O2S
    N-[(E)-(4-chlorophenyl)methylideneamino]-2-(6-methyl-2-methylsulfanylpyrimidin-4-yl)oxyacetamide
    —— N-[(E)-benzylideneamino]-2-(5-methylpyrimidin-2-yl)sulfanylacetamide —— C14H14N4OS
    N-[(E)-benzylideneamino]-2-(5-methylpyrimidin-2-yl)sulfanylacetamide
    —— Hydrazine, 1-[3-chloro-4-(2-methylphenylthio)phenyl]-2-nitromethylidene- —— C14H12ClN3O2S
    Hydrazine, 1-[3-chloro-4-(2-methylphenylthio)phenyl]-2-nitromethylidene-
    —— Methanehydrazonic acid, N-[3-(methylthio)-1,2,4-thiadiazol-5-yl]-, ethyl ester —— C6H10N4OS2
    Methanehydrazonic acid, N-[3-(methylthio)-1,2,4-thiadiazol-5-yl]-, ethyl ester
    —— 2,2'-[1,2-Ethanediylidene]bis[N'-[4-[methylthio]phenyl] —— C18H22N8S2
    2,2'-[1,2-Ethanediylidene]bis[N'-[4-[methylthio]phenyl]
    —— 2,2'-1,2-Ethanediylidene]bis[N'-[3-[methylthio]phenyl]hydrazinecarboximidamide] —— C18H22N8S2
    2,2'-1,2-Ethanediylidene]bis[N'-[3-[methylthio]phenyl]hydrazinecarboximidamide]
    —— Propanehydrazide, N2-ethoxymethylene-2-[5-(4-pyridyl)-1,3,4-oxadiazol-2-ylthio]- —— C13H15N5O3S
    Propanehydrazide, N2-ethoxymethylene-2-[5-(4-pyridyl)-1,3,4-oxadiazol-2-ylthio]-
    —— Propionaldehyde, 2-methyl-2-(methylsulfonyl)-, oxime —— C5H11NO3S
    Propionaldehyde, 2-methyl-2-(methylsulfonyl)-, oxime
    —— Benzhydrazide, N2-[5-(8-quinolylthio)furfurylideno]- —— C21H15N3O2S
    Benzhydrazide, N2-[5-(8-quinolylthio)furfurylideno]-
    —— 3-Phenylamino-4-phenyl-5-(6-methyl-3-methylthio-5-oxo-4,5-dihydro-1,2,4-triazin-4-yl)imino-4,5(3H)-dihydro-1,2,4-triazole —— C19H18N8OS
    3-Phenylamino-4-phenyl-5-(6-methyl-3-methylthio-5-oxo-4,5-dihydro-1,2,4-triazin-4-yl)imino-4,5(3H)-dihydro-1,2,4-triazole
    —— N'-[(E)-{5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]-3-methoxybenzohydrazide —— C22H19N3O4S2
    N'-[(E)-{5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]-3-methoxybenzohydrazide
    —— 3-nitro-N'-[(E)-{5-[(4-oxo-3-phenyl-3,4-dihydroquinazolin-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide —— C26H17N5O5S
    3-nitro-N'-[(E)-{5-[(4-oxo-3-phenyl-3,4-dihydroquinazolin-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide
    —— N',N''-{Sulfanediylbis[5,2-furandiyl(E)methylylidene]}bis[2-(2,4-dibromo-6-methoxyphenoxy)acetohydrazide] —— C28H22Br4N4O8S
    N',N''-{Sulfanediylbis[5,2-furandiyl(E)methylylidene]}bis[2-(2,4-dibromo-6-methoxyphenoxy)acetohydrazide]
    —— 3-bromo-N'-[(E)-{5-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide —— C19H11BrN4O4S2
    3-bromo-N'-[(E)-{5-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide
    —— N'-[(E)-[5-(Pyridin-2-ylsulfanyl)furan-2-YL]methylidene]octanehydrazide —— C18H23N3O2S
    N'-[(E)-[5-(Pyridin-2-ylsulfanyl)furan-2-YL]methylidene]octanehydrazide
    —— N',N''-{sulfanediylbis[furan-5,2-diyl(E)methylylidene]}bis[2-(3-methylphenoxy)acetohydrazide] —— C28H26N4O6S
    N',N''-{sulfanediylbis[furan-5,2-diyl(E)methylylidene]}bis[2-(3-methylphenoxy)acetohydrazide]
    —— N'-[(E)-[5-(1,3-Benzothiazol-2-ylsulfanyl)furan-2-YL]methylidene]-3-nitrobenzohydrazide —— C19H12N4O4S2
    N'-[(E)-[5-(1,3-Benzothiazol-2-ylsulfanyl)furan-2-YL]methylidene]-3-nitrobenzohydrazide
    —— dibutyltin(2+);[2-[methylsulfanyl(sulfoniumylidene)methyl]cyclopentylidene]azanide —— C22H40N2S4Sn+2
    dibutyltin(2+);[2-[methylsulfanyl(sulfoniumylidene)methyl]cyclopentylidene]azanide
    —— N'-{(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-3-bromobenzohydrazide —— C19H13BrN4O2S
    N'-{(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene}-3-bromobenzohydrazide
    —— 2-(naphthalen-1-yl)-N'-[(E)-{5-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]acetohydrazide —— C24H16N4O4S2
    2-(naphthalen-1-yl)-N'-[(E)-{5-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]acetohydrazide
    —— dimethyltin(2+);[2-[methylsulfanyl(sulfoniumylidene)methyl]cyclopentylidene]azanide —— C16H28N2S4Sn+2
    dimethyltin(2+);[2-[methylsulfanyl(sulfoniumylidene)methyl]cyclopentylidene]azanide
    —— 1-phenyl-3-[(E)-1-[[5-[(2E)-2-(phenylcarbamothioylhydrazinylidene)propyl]sulfanyl-2-sulfanylidene-1,3-dithiol-4-yl]sulfanyl]propan-2-ylideneamino]thiourea —— C23H24N6S7
    1-phenyl-3-[(E)-1-[[5-[(2E)-2-(phenylcarbamothioylhydrazinylidene)propyl]sulfanyl-2-sulfanylidene-1,3-dithiol-4-yl]sulfanyl]propan-2-ylideneamino]thiourea
    —— N-[(E)-benzylideneamino]-2-(2,3,4,5,6-pentachlorophenyl)sulfanylacetamide —— C15H9Cl5N2OS
    N-[(E)-benzylideneamino]-2-(2,3,4,5,6-pentachlorophenyl)sulfanylacetamide
    —— N-[(E)-(4-methoxyphenyl)methylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine —— C23H19N3OS2
    N-[(E)-(4-methoxyphenyl)methylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine
    —— [(E)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]thiourea —— C15H12N4OS2
    [(E)-(5-quinolin-8-ylsulfanylfuran-2-yl)methylideneamino]thiourea
    —— 2-(1,3-benzothiazol-2-ylsulfanyl)-3-[(E)-(2-phenylhydrazinylidene)methyl]-4H-pyrido[1,2-a]pyrimidin-4-one —— C22H15N5OS2
    2-(1,3-benzothiazol-2-ylsulfanyl)-3-[(E)-(2-phenylhydrazinylidene)methyl]-4H-pyrido[1,2-a]pyrimidin-4-one
    —— Carbon monoxide;manganese;methyl(3-oxopropyl)sulfanium —— C8H8MnO5S
    Carbon monoxide;manganese;methyl(3-oxopropyl)sulfanium
    —— 2-benzylsulfanyl-N-[(E)-1-(4-pentylphenyl)ethylideneamino]pyrimidin-4-amine —— C24H28N4S
    2-benzylsulfanyl-N-[(E)-1-(4-pentylphenyl)ethylideneamino]pyrimidin-4-amine
    —— 2-benzylsulfanyl-N-[(E)-1-(4-butylphenyl)ethylideneamino]pyrimidin-4-amine —— C23H26N4S
    2-benzylsulfanyl-N-[(E)-1-(4-butylphenyl)ethylideneamino]pyrimidin-4-amine
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-1-phenylethylideneamino]acetamide —— C16H15ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-1-phenylethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-[4-[(E)-[[2-(4-chlorophenyl)sulfanylacetyl]hydrazinylidene]methyl]phenyl]methylideneamino]acetamide —— C24H20Cl2N4O2S2
    2-(4-chlorophenyl)sulfanyl-N-[(E)-[4-[(E)-[[2-(4-chlorophenyl)sulfanylacetyl]hydrazinylidene]methyl]phenyl]methylideneamino]acetamide
    —— N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-phenylcyclopropanecarbohydrazide —— C18H18N2OS
    N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-phenylcyclopropanecarbohydrazide
    —— (NE)-N-[[4-[(E)-hydroxyiminomethyl]-2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine —— C8H10N2O2S3
    (NE)-N-[[4-[(E)-hydroxyiminomethyl]-2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine
    —— N'-(4-(Methylthio)benzylidene)bicyclo[4.1.0]heptane-7-carbohydrazide —— C16H20N2OS
    N'-(4-(Methylthio)benzylidene)bicyclo[4.1.0]heptane-7-carbohydrazide
    —— 2-[(4-Bromo-2-fluorophenyl)methylsulfanyl]-5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazole —— C16H11BrClFN2S3
    2-[(4-Bromo-2-fluorophenyl)methylsulfanyl]-5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazole
    —— N'-[5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide —— C12H12ClFN4S2
    N'-[5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide
    —— N'-[5-[(5-chloro-1,3-benzothiazol-2-yl)sulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylethanimidamide —— C13H12ClN5S3
    N'-[5-[(5-chloro-1,3-benzothiazol-2-yl)sulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylethanimidamide
    —— [(E)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-(3-methylphenyl)carbamate —— C14H12Cl2N4O2S
    [(E)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-(3-methylphenyl)carbamate