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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(4-fluorophenyl)methyl]-5-[(1S)-1-(1-prop-2-enyltetrazol-5-yl)sulfanylethyl]-1,2,4-oxadiazole —— C15H15FN6OS
    3-[(4-fluorophenyl)methyl]-5-[(1S)-1-(1-prop-2-enyltetrazol-5-yl)sulfanylethyl]-1,2,4-oxadiazole
    —— 5-Ethylsulfanylpyridazine-3,4-diamine —— C6H10N4S
    5-Ethylsulfanylpyridazine-3,4-diamine
    —— 4-amino-2-[(1S)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanylpyrimidine-5-carbonitrile —— C14H17N5OS
    4-amino-2-[(1S)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanylpyrimidine-5-carbonitrile
    —— 4-amino-2-[(1R)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanylpyrimidine-5-carbonitrile —— C14H17N5OS
    4-amino-2-[(1R)-1-(5-tert-butyl-1,3-oxazol-2-yl)ethyl]sulfanylpyrimidine-5-carbonitrile
    —— 3-[(4-fluorophenyl)methyl]-5-[(1R)-1-(1-prop-2-enyltetrazol-5-yl)sulfanylethyl]-1,2,4-oxadiazole —— C15H15FN6OS
    3-[(4-fluorophenyl)methyl]-5-[(1R)-1-(1-prop-2-enyltetrazol-5-yl)sulfanylethyl]-1,2,4-oxadiazole
    —— 4-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-2H-triazole —— C10H10FN3S
    4-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-2H-triazole
    —— 4-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-2H-triazole —— C10H10FN3S
    4-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-2H-triazole
    —— N-[(1S)-1-(2-hydroxyphenyl)ethyl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C17H17F3N2O2S
    N-[(1S)-1-(2-hydroxyphenyl)ethyl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— N-[(1R)-1-(2-hydroxyphenyl)ethyl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C17H17F3N2O2S
    N-[(1R)-1-(2-hydroxyphenyl)ethyl]-N-methyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— [(E)-2,3-bis(phenylsulfanyl)prop-2-enyl]-dimethylazanium —— C17H20NS2+
    [(E)-2,3-bis(phenylsulfanyl)prop-2-enyl]-dimethylazanium
    —— N-Cyclohexyldithiocarbamic acid, ammonium salt —— C7H15N2S2+
    N-Cyclohexyldithiocarbamic acid, ammonium salt
    —— 2-[(4-Chlorophenyl)sulfanyl]-1-phenyl-1-ethanone oxime —— C14H12ClNOS
    2-[(4-Chlorophenyl)sulfanyl]-1-phenyl-1-ethanone oxime
    —— (Z)-3-[5-(4-chlorophenyl)sulfanylfuran-2-yl]-2-cyano-N-(oxolan-2-ylmethyl)prop-2-enamide —— C19H17ClN2O3S
    (Z)-3-[5-(4-chlorophenyl)sulfanylfuran-2-yl]-2-cyano-N-(oxolan-2-ylmethyl)prop-2-enamide
    —— (2S)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3R)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide —— C19H27FN2O2S2
    (2S)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3R)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide
    —— N-cyclopropyl-2-[(1S)-1-(2,6-difluorophenyl)ethyl]sulfanyl-5-nitropyrimidin-4-amine —— C15H14F2N4O2S
    N-cyclopropyl-2-[(1S)-1-(2,6-difluorophenyl)ethyl]sulfanyl-5-nitropyrimidin-4-amine
    —— 1-bromo-2-[(2S)-2-methyl-3-methylsulfonylpropyl]sulfanylbenzene —— C11H15BrO2S2
    1-bromo-2-[(2S)-2-methyl-3-methylsulfonylpropyl]sulfanylbenzene
    —— (2R)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide —— C19H27FN2O2S2
    (2R)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C19H19N11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— (2R)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3R)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide —— C19H27FN2O2S2
    (2R)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3R)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide
    —— 1-bromo-2-[(2R)-2-methyl-3-methylsulfonylpropyl]sulfanylbenzene —— C11H15BrO2S2
    1-bromo-2-[(2R)-2-methyl-3-methylsulfonylpropyl]sulfanylbenzene
    —— (2S)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide —— C19H27FN2O2S2
    (2S)-3-(4-fluorophenyl)sulfanyl-2-methyl-N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]propanamide
    —— [(Z)-4-amino-3-cyano-2-oxopent-3-enyl] 3-phenylsulfanylpropanoate —— C15H16N2O3S
    [(Z)-4-amino-3-cyano-2-oxopent-3-enyl] 3-phenylsulfanylpropanoate
    —— (4E)-5-{[(4-chlorophenyl)sulfanyl]methyl}-4-[4-(dimethylamino)benzylidene]-2-phenyl-2,4-dihydro-3H-pyrazol-3-one —— C25H22ClN3OS
    (4E)-5-{[(4-chlorophenyl)sulfanyl]methyl}-4-[4-(dimethylamino)benzylidene]-2-phenyl-2,4-dihydro-3H-pyrazol-3-one
    —— 3-cyclopropyl-5-[(2S)-4-phenylsulfanylbutan-2-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazole —— C18H23N3S2
    3-cyclopropyl-5-[(2S)-4-phenylsulfanylbutan-2-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazole
    —— 3-cyclopropyl-5-[(2R)-4-phenylsulfanylbutan-2-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazole —— C18H23N3S2
    3-cyclopropyl-5-[(2R)-4-phenylsulfanylbutan-2-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazole
    —— N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C16H17ClN4OS
    N-[(Z)-1-(4-chlorophenyl)ethylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— [(E)-2-nitro-2-phenylsulfanylethenyl]benzene —— C14H11NO2S
    [(E)-2-nitro-2-phenylsulfanylethenyl]benzene
    —— 2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-phenylethylideneamino]acetamide —— C23H26N6OS
    2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-phenylethylideneamino]acetamide
    —— 5-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-3-propan-2-yl-1,2,4-oxadiazole —— C16H20N2O3S
    5-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-3-propan-2-yl-1,2,4-oxadiazole
    —— 5-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-3-propan-2-yl-1,2,4-oxadiazole —— C16H20N2O3S
    5-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-3-propan-2-yl-1,2,4-oxadiazole
    —— 2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S,2S)-2-(trifluoromethyl)cyclohexyl]acetamide —— C14H20F3N3O2S2
    2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S,2S)-2-(trifluoromethyl)cyclohexyl]acetamide
    —— prop-2-en-1-yl (2E)-7-methyl-2-(4-methylbenzylidene)-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C26H24N2O3S2
    prop-2-en-1-yl (2E)-7-methyl-2-(4-methylbenzylidene)-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (E)-2-[1-[(E)-1-cyano-2-ethoxyethenyl]sulfonyl-2-ethoxyethenyl]sulfonyl-3-ethoxyprop-2-enenitrile —— C14H18N2O7S2
    (E)-2-[1-[(E)-1-cyano-2-ethoxyethenyl]sulfonyl-2-ethoxyethenyl]sulfonyl-3-ethoxyprop-2-enenitrile
    —— 1,2-Dichloro-3-isothiocyanato-1-propene —— C4H3Cl2NS
    1,2-Dichloro-3-isothiocyanato-1-propene
    —— 3-phenylsulfanyl-N-[(Z)-1-thiophen-2-ylethylideneamino]propanamide —— C15H16N2OS2
    3-phenylsulfanyl-N-[(Z)-1-thiophen-2-ylethylideneamino]propanamide
    —— 2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R,2S)-2-(trifluoromethyl)cyclohexyl]acetamide —— C14H20F3N3O2S2
    2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R,2S)-2-(trifluoromethyl)cyclohexyl]acetamide
    —— (2S)-N-(cyclooctylmethyl)-2-propan-2-ylsulfonylpropanamide —— C15H29NO3S
    (2S)-N-(cyclooctylmethyl)-2-propan-2-ylsulfonylpropanamide
    —— 2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S,2R)-2-(trifluoromethyl)cyclohexyl]acetamide —— C14H20F3N3O2S2
    2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S,2R)-2-(trifluoromethyl)cyclohexyl]acetamide
    —— 1-[2-(2-methyl-1,2,4-triazol-3-yl)ethyl]-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C17H25N5OS
    1-[2-(2-methyl-1,2,4-triazol-3-yl)ethyl]-3-[(1R)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— 1-[2-(2-methyl-1,2,4-triazol-3-yl)ethyl]-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea —— C17H25N5OS
    1-[2-(2-methyl-1,2,4-triazol-3-yl)ethyl]-3-[(1S)-1-(4-propan-2-ylsulfanylphenyl)ethyl]urea
    —— (2R)-2-[[4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]cyclohexan-1-one —— C10H12F3N3OS
    (2R)-2-[[4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]cyclohexan-1-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-methylphenyl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C21H20N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-methylphenyl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— (2S)-2-[[4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]cyclohexan-1-one —— C10H12F3N3OS
    (2S)-2-[[4-(2,2,2-trifluoroethyl)-1,2,4-triazol-3-yl]sulfanyl]cyclohexan-1-one
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-(thiophen-2-yl)ethylidene]acetohydrazide —— C17H15ClN4OS4
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-(thiophen-2-yl)ethylidene]acetohydrazide
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]acetamide —— C19H16ClFN4OS3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]acetamide
    —— (E)-4-hydroxy-3-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]pent-3-en-2-one —— C8H10N2O2S3
    (E)-4-hydroxy-3-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]pent-3-en-2-one
    —— (3R)-1-propan-2-yl-3-(2H-triazol-4-ylsulfanyl)piperidin-2-one —— C10H16N4OS
    (3R)-1-propan-2-yl-3-(2H-triazol-4-ylsulfanyl)piperidin-2-one
    —— (3S)-1-propan-2-yl-3-(2H-triazol-4-ylsulfanyl)piperidin-2-one —— C10H16N4OS
    (3S)-1-propan-2-yl-3-(2H-triazol-4-ylsulfanyl)piperidin-2-one
    —— (2R)-N-cyclopropyl-N-(thiophen-2-ylmethyl)-2,3-dihydro-1,4-benzoxathiine-2-carboxamide —— C17H17NO2S2
    (2R)-N-cyclopropyl-N-(thiophen-2-ylmethyl)-2,3-dihydro-1,4-benzoxathiine-2-carboxamide
    —— (2S)-N-cyclopropyl-N-(thiophen-2-ylmethyl)-2,3-dihydro-1,4-benzoxathiine-2-carboxamide —— C17H17NO2S2
    (2S)-N-cyclopropyl-N-(thiophen-2-ylmethyl)-2,3-dihydro-1,4-benzoxathiine-2-carboxamide