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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5E)-3-ethyl-5-[(5-nitro-2-phenylsulfanylphenyl)methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C18H14N2O3S3
    (5E)-3-ethyl-5-[(5-nitro-2-phenylsulfanylphenyl)methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— N-[(Z)-[3-(4-chlorophenyl)-4-phenyl-1,3-thiazol-2-ylidene]amino]-2-[(5-pyridin-2-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C24H17ClN6OS3
    N-[(Z)-[3-(4-chlorophenyl)-4-phenyl-1,3-thiazol-2-ylidene]amino]-2-[(5-pyridin-2-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (3E)-3-[[2-[2-[(2E)-2-(3-carboxy-4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]-6-oxocyclohexa-1,4-diene-1-carboxylic acid —— C26H18N4O6S
    (3E)-3-[[2-[2-[(2E)-2-(3-carboxy-4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]-6-oxocyclohexa-1,4-diene-1-carboxylic acid
    —— (6Z)-3-phenyl-6-(p-tolylmethylene)thiazolo[2,3-b]thiazol-4-ium-5-one —— C19H14NOS2+
    (6Z)-3-phenyl-6-(p-tolylmethylene)thiazolo[2,3-b]thiazol-4-ium-5-one
    —— 2-[(Z)-(6-chloro-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methylideneamino]guanidine —— C7H9ClN6S
    2-[(Z)-(6-chloro-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methylideneamino]guanidine
    —— 2-((5-((5-Oxo-2-thioxo-4-imidazolidinylidene)methyl)-2-thienyl)thio)benzoic acid —— C15H10N2O3S3
    2-((5-((5-Oxo-2-thioxo-4-imidazolidinylidene)methyl)-2-thienyl)thio)benzoic acid
    —— 2-Butene, 2-(ethylthio)-, (Z)- —— C6H12S
    2-Butene, 2-(ethylthio)-, (Z)-
    —— 2-((2-Amino-4-chloro-5-[18F]fluorophenyl)thio)-N,N-dimethylbenzenmethanamine —— C16H17ClFNS
    2-((2-Amino-4-chloro-5-[18F]fluorophenyl)thio)-N,N-dimethylbenzenmethanamine
    —— iron(3+);tetrathiocyanate —— C4FeN4S4-
    iron(3+);tetrathiocyanate
    —— [(Z)-1-phenylethylideneamino] 2-[4-thiophen-2-yl-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylacetate —— C19H14F3N3O2S2
    [(Z)-1-phenylethylideneamino] 2-[4-thiophen-2-yl-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylacetate
    —— (Z)-1-(4-bromophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C17H15BrN4S
    (Z)-1-(4-bromophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— 2-methyl-N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide —— C19H17N5O3S
    2-methyl-N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide
    —— 2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-furan-2-ylmethylideneamino]acetamide —— C19H20N6O2S
    2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-furan-2-ylmethylideneamino]acetamide
    —— N-[(Z)-1-(4-methylphenyl)ethylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C16H17N3OS
    N-[(Z)-1-(4-methylphenyl)ethylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(E)-(1,3-dimethylpyrazol-4-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide 349560-77-6 C13H15N5OS
    N-[(E)-(1,3-dimethylpyrazol-4-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(Z)-benzylideneamino]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C12H13N5OS
    N-[(Z)-benzylideneamino]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— [(E)-(3-ethylsulfanylthiophen-2-yl)methylideneamino]urea —— C8H11N3OS2
    [(E)-(3-ethylsulfanylthiophen-2-yl)methylideneamino]urea
    —— N-[(Z)-(4-chlorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H12Cl2N2OS
    N-[(Z)-(4-chlorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— 2,2-dimethyl-N-[(1S)-2,2,2-trichloro-1-phenylsulfanylethyl]propanamide —— C13H16Cl3NOS
    2,2-dimethyl-N-[(1S)-2,2,2-trichloro-1-phenylsulfanylethyl]propanamide
    —— [(Z)-(5-methylsulfanylthiophen-3-yl)methylideneamino]urea —— C7H9N3OS2
    [(Z)-(5-methylsulfanylthiophen-3-yl)methylideneamino]urea
    —— (NZ)-N-[[2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine —— C7H9NOS3
    (NZ)-N-[[2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine
    —— N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C18H22N4OS
    N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— (2S)-2-phenylsulfanyl-N-[(Z)-pyridin-4-ylmethylideneamino]propanamide —— C15H15N3OS
    (2S)-2-phenylsulfanyl-N-[(Z)-pyridin-4-ylmethylideneamino]propanamide
    —— (Z)-1-(4-bromophenyl)-N-(3-methylsulfanyl-1,2,4-triazol-4-yl)methanimine —— C10H9BrN4S
    (Z)-1-(4-bromophenyl)-N-(3-methylsulfanyl-1,2,4-triazol-4-yl)methanimine
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-pyridin-3-ylmethylideneamino]acetamide —— C14H15N5OS
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-pyridin-3-ylmethylideneamino]acetamide
    —— (2Z)-2-(2-chloro-6-fluorobenzylidene)-1-benzothiophen-3(2H)-one —— C15H8ClFOS
    (2Z)-2-(2-chloro-6-fluorobenzylidene)-1-benzothiophen-3(2H)-one
    —— N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C17H21N5OS
    N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(2-chloro-6-fluorophenyl)methanimine —— C16H12ClFN4S
    (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(2-chloro-6-fluorophenyl)methanimine
    —— (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-chlorophenyl)methanimine —— C16H13ClN4S
    (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-chlorophenyl)methanimine
    —— N-[(Z)-(4-fluorophenyl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C14H12FN3OS
    N-[(Z)-(4-fluorophenyl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— ethyl N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]carbamate —— C14H13ClN2O3S
    ethyl N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]carbamate
    —— (Z)-1-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]-N-(1,2,4-triazol-4-yl)methanimine —— C14H9N5OS2
    (Z)-1-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]-N-(1,2,4-triazol-4-yl)methanimine
    —— (Z)-1-(4-fluorophenyl)-N-(3-methylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)methanimine —— C11H9FN6S
    (Z)-1-(4-fluorophenyl)-N-(3-methylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)methanimine
    —— 2-[(3-chlorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-2-yl]-1,3,4-oxadiazole —— C13H14ClN3OS
    2-[(3-chlorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-2-yl]-1,3,4-oxadiazole
    —— (1S)-1-[5-[(3-fluorophenyl)methylthio]-1,3,4-oxadiazol-2-yl]-2-methyl-1-butanamine —— C14H18FN3OS
    (1S)-1-[5-[(3-fluorophenyl)methylthio]-1,3,4-oxadiazol-2-yl]-2-methyl-1-butanamine
    —— 2-Diethylamino-4-phenylthiooct-2-ene nitrile —— C18H26N2S
    2-Diethylamino-4-phenylthiooct-2-ene nitrile
    —— trans-3-Chloro-4-methylthio-hex-3-ene —— C7H13ClS
    trans-3-Chloro-4-methylthio-hex-3-ene
    —— (1Z)-N-(pentafluoro-lambda6-sulfanyl)-1-phenylsulfanylmethanimidoyl chloride —— C7H5ClF5NS2
    (1Z)-N-(pentafluoro-lambda6-sulfanyl)-1-phenylsulfanylmethanimidoyl chloride
    —— (2E)-2-(phenylsulfanylmethylidene)cyclohexan-1-one —— C13H14OS
    (2E)-2-(phenylsulfanylmethylidene)cyclohexan-1-one
    —— Sulfide,5-dimethyl-2-hexenyl- —— C10H19ClS
    Sulfide,5-dimethyl-2-hexenyl-
    —— 6-Ethyl-4,5,7,8-tetrathia-2-undecene —— C9H18S4
    6-Ethyl-4,5,7,8-tetrathia-2-undecene
    —— N-({5-[(4-chlorophenyl)thio]-2-furyl}methylene)-4H-1,2,4-triazol-4-amine —— C13H9ClN4OS
    N-({5-[(4-chlorophenyl)thio]-2-furyl}methylene)-4H-1,2,4-triazol-4-amine
    —— 2-(5-amino-1,3,4-thiadiazol-2-yl)-N'-[(E)-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]acetohydrazide —— C15H12ClN5O2S2
    2-(5-amino-1,3,4-thiadiazol-2-yl)-N'-[(E)-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene]acetohydrazide
    —— (E)-1-(4-Bromophenyl)-N-[3-(methylsulfanyl)-4H-1,2,4-triazol-4-YL]methanimine —— C10H9BrN4S
    (E)-1-(4-Bromophenyl)-N-[3-(methylsulfanyl)-4H-1,2,4-triazol-4-YL]methanimine
    —— N'-{(E)-[4-oxo-2-(pyridin-2-ylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-3-yl]methylidene}benzohydrazide —— C21H15N5O2S
    N'-{(E)-[4-oxo-2-(pyridin-2-ylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-3-yl]methylidene}benzohydrazide
    —— (6E)-4-bromo-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]cyclohexa-2,4-dien-1-one —— C18H16BrN3OS
    (6E)-4-bromo-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]cyclohexa-2,4-dien-1-one
    —— Cambridge id 5604120 —— C15H11F4NO4S
    Cambridge id 5604120
    —— 2-(2-Chlorophenyl)-5-propylsulfanyl-1,3,4-oxadiazole —— C11H11ClN2OS
    2-(2-Chlorophenyl)-5-propylsulfanyl-1,3,4-oxadiazole
    —— ethyl (2R)-2-methyl-1,3-oxathiolane-2-carboxylate —— C7H12O3S
    ethyl (2R)-2-methyl-1,3-oxathiolane-2-carboxylate
    —— 5-amino-N'-[(1E)-(4-fluorophenyl)methylene]-N-methyl-3-(methylthio)-1H-1,2,4-triazole-1-carbothiohydrazide —— C12H13FN6S2
    5-amino-N'-[(1E)-(4-fluorophenyl)methylene]-N-methyl-3-(methylthio)-1H-1,2,4-triazole-1-carbothiohydrazide